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This paper reviews work related to interbasin groundwater flow (naturally occurring groundwater flow beneath watershed topographic divides) into lowland rainforest watersheds at La Selva Biological Station in Costa Rica. Chemical mixing calculations (based on dissolved chloride) have shown that up to half the water in some streams and up to 84% of the water in some riparian seeps and wells is due to high-solute interbasin groundwater flow (IGF). The contribution is even greater for major ions; IGF accounts for well over 90% of the major ions at these sites. Proportions are highly variable both among watersheds and with elevation within the same watershed (there is greater influence of IGF at lower elevations). The large proportion of IGF found in water in some riparian wetlands suggests that IGF is largely responsible for maintaining these wetlands. δ18O data support the conclusions from the major ion data. Annual water and major ion budgets for two adjacent watersheds, one affected by IGF and the other not, showed that IGF accounted for two-thirds of the water input and 92–99% of the major ion input (depending on the major ion in question) to the former watershed. The large (in some cases, dominating) influence of IGF on watershed surface water quantity and quality has important implications for stream ecology and watershed management in this lowland rainforest. Because of its high phosphorus content, IGF increases a variety of ecological variables (algal growth rates, leaf decay rate, fungal biomass, invertebrate biomass, microbial respiration rates on leaves) in streams at La Selva. The significant rates of IGF at La Selva also suggest the importance of regional (as opposed to small-scale local) water resource planning that links lowland watersheds with regional groundwater. IGF is a relatively unexplored and potentially critical factor in the conservation of lowland rainforest. 相似文献
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Thomas J. Jackson Terry L. Wade José L. Sericano James M. Brooks Jennifer M. Wong Bernardo Garcia-Romero Thomas J. McDonald 《Estuaries and Coasts》1998,21(4):718-730
The temporal distributions for six classes of trace organic contaminants (chlordanes, DDTs, dieldrin, PAHs, PCBs, and butyltins) in oysters from six Galveston Bay sites from National Oceanic and Atmospheric Administration’s National Status and Trends (NS&T) Mussel Watch Program are compared with other NS&T sites from the Gulf of Mexico as well as all NS&T sites of the United States (East Coast, West Coast, and Gulf of Mexico). Decreases in the median for the Gulf-wide concentration of chlordanes, dieldrin, and butyltins occurred during 1986–1994. The Gulfwide median concentrations of DDTs, PAHs, and PCBs exhibited a strong cyclic distribution with time. For Galveston Bay oysters, “high” concentration is defined as the concentration greater than the median plus one standard deviation for all Gulf of Mexico sites. The percentage of sites having high concentrations during 1986–1994 for Galveston Bay oysters are 49% for dieldrin, 45% for butyltins, 40% for chlordanes, 38% for PCBs, 30% for PAHs, and 21% for DDTs. For PCBs, 43% of Galveston Bay oyster samples analyzed over the first 9 yr have concentrations high enough for potential biological effects to be observed in oysters. The percentages in other agents were chlordanes (22%), butyltins (22%), dieldrin (5%), and PAHs (4%). National Academy of Science-proposed regulatory limits for oysters were exceeded in only 2% of Galveston Bay samples for DDTs and 1% for PCBs. All other contaminants were below proposed NAS limits. 相似文献
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Steven R Higgins Guntram Jordan Carrick M Eggleston 《Geochimica et cosmochimica acta》2002,66(18):3201-3210
Magnesite (104) dissolution kinetics were studied in acidic aqueous solutions (2.0 < pH < 4.2) at temperatures between 60 and 90°C by atomic force microscopy (AFM). Comparison of dissolution fluxes obtained by AFM and chemical methods revealed six to seven times larger dissolution fluxes obtained by chemical analysis. Corresponding empirical activation energies were found to be 74 ±22 kJ/mol and 41 ± 4 kJ/mol (at pH 4.2) for the AFM and chemical methods, respectively. The empirical reaction order with respect to proton concentration was 0.36 ± 0.13 and 0.47 ± 0.03 for AFM and chemical methods, respectively. These comparisons suggest that the two experimental measurement methods differ as a result of the different sampling length scales associated with the methods. Negligible changes in step dissolution velocity with changes in bulk pH were found, suggesting that the principal source of increasing dissolution flux with decreasing pH is an increase in step density. However, the observed stable step orientation, which is dependent on pH, suggests that more than one proton adsorption equilibrium should be used to describe the surface chemistry of magnesite in acidic solution. 相似文献
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The period 1996-2001 has witnessed a refocusing of population growth on Sydney and Melbourne as both cities have developed significant concentrations of so-called 'new economy' jobs and taken on, to greater or lesser extents, the characteristics of global cities. The consequence of these trends, for Sydney most particularly, is population growth. This paper establishes this demographic reality by describing recent demographic trends in Sydney and possible future scenarios for Sydney's population, given differing levels of fertility, internal migration and international migration. A related future trend is also traced--that the number of households in Sydney will grow more rapidly than the population due to changes in household structure. This raises the issue of how and where these households will be accommodated, given the relative land shortage in the Sydney Statistical Division and given that there is no doubt that planners in New South Wales will be attempting to maintain and enhance Sydney's status as a global city. In sum, the paper argues that Sydney planners should be preparing for growth of around one million people in the next 20 years and a further one million in the following 30 years. To maintain that potential future residents of Sydney can be redirected to other parts of New South Wales is a vain hope. 相似文献
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The accuracy of gravimetric fractionation as a means of obtaining size fractions from marine sediments has been explored. Analysis of the particle size distribution and sediment properties of fractions obtained using this method was undertaken. This has highlighted the extent to which experimental artefacts rather than variations in sediment characteristics may adversely affect the efficiency of the fractionation process. Copyright © 1999 John Wiley & Sons, Ltd. 相似文献
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