where k is a constant equal to 6.5 × 10−16 mol/cm2/s and Ω is the saturation index with respect to magnesite. This equation is consistent with spiral growth step generation controlling magnesite precipitation rates. Corresponding magnesite precipitation rates measured using mixed-flow reactors are shown to be consistent with both the rates measured by HAFM and the spiral growth theory, confirming the rate limiting mechanism. Step advancement, however, is observed to slow far faster than step generation with decreasing temperature; the activation energy for step advancement is 159 kJ/mol whereas step generation rates have an estimated activation energy of 60 kJ/mol. As such, it seems likely that at ambient temperatures magnesite growth is limited by very slow step advancement rates.  相似文献   
70.
Titanite dates crystallization: Slow Pb diffusion during super‐solidus re‐equilibration     
Michael I. H. Hartnady  Christopher L. Kirkland  Chris Clark  Catherine V. Spaggiari  R. Hugh Smithies  Noreen J. Evans  Brad J. McDonald 《Journal of Metamorphic Geology》2019,37(6):823-838
Titanite can be found in rocks of wide compositional range, is reactive, growing or regrowing during metamorphic and hydrothermal events, and is generally amenable to U–Pb geochronology. Experimental evidence suggest that titanite has a closure temperature for Pb ranging from 550 to 650°C, and thus titanite dates are commonly interpreted as cooling ages. However, this view has been challenged in recent years by evidence from natural titanite which suggests the closure temperature may be significantly higher (up to 800°C). Here, we investigate titanite in an enclave of migmatitic gneiss included within a granite intrusion. The titanite crystals exhibit textural features characteristic of fluid‐mediated mass transfer processes on length scales of <100 µm. These textural features are associated with variation in both Pb concentrations and distinct U–Pb isotopic compositions. Zr‐in‐titanite thermometry indicates that modification of the titanite occurred at temperatures in excess of 840°C, in the presence of a high‐T silicate melt. The Pb concentration gradients preserved in these titanite crystals are used to determine the diffusivity of Pb in titanite under high‐T conditions. We estimate diffusivities ranging from 2 × 10?22 to 5 × 10?25 m2/s. These results are significantly lower than experimental data predict yet are consistent with other empirical data on natural titanites, suggesting that Pb diffusivity is similar to that of Sr. Thus our data challenge the wide‐held assumption that U–Pb titanite dates only reflect cooling ages.  相似文献   
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61.
62.
63.
Measurements of ultraviolet line fluxes from Space Telescope Imaging Spectrograph and Far-Ultraviolet Spectroscopic Explorer spectra of the K2-dwarf ε Eri are reported. These are used to develop new emission measure distributions and semi-empirical atmospheric models for the chromosphere and lower transition region of the star. These models are the most detailed constructed to date for a main-sequence star other than the Sun. New ionization balance calculations, which account for the effect of finite density on dielectronic recombination rates, are presented for carbon, nitrogen, oxygen and silicon. The results of these calculations are significantly different from the standard Arnaud & Rothenflug ion balance, particularly for alkali-like ions. The new atmospheric models are used to place constraints on possible first ionization potential (FIP)-related abundance variations in the lower atmosphere and to discuss limitations of single-component models for the interpretation of certain optically thick line fluxes.  相似文献   
64.
65.
Observed solar, interplanetary and geomagnetic time series contain quasi periodicities on scales of 1–2.5 years. The further discovery of 1.3 year fluctuations in helioseismic observations suggests that a variety of signals may be related to the underlying dynamo in the Sun. We use independent component analysis to study the temporal and spatial variations of a few statistically independent global modes of the axisymmetric solar magnetic field over a period of 25 years. Five modes capture the salient properties of the data. Two modes describe the polar and high latitude fields, and present 1–1.5 year quasi periodicities. The other three modes correspond to low and mid-latitude phenomena and show both 1.3 and 1.7-year variations. By comparing the characteristic time scales, dates of occurrence and heliocentric latitudes of these modes, we connect them to their manifestations in heliospheric time series.  相似文献   
66.
Policy makers have now recognised the need to integrate thinking about climate change into all areas of public policy making. However, the discussion of ‘climate policy integration’ has tended to focus on mitigation decisions mostly taken at international and national levels. Clearly, there is also a more locally focused adaptation dimension to climate policy integration, which has not been adequately explored by academics or policy makers. Drawing on a case study of the UK, this paper adopts both a top-down and a bottom-up perspective to explore how far different sub-elements of policies within the agriculture, nature conservation and water sectors support or undermine potential adaptive responses. The top-down approach, which assumes that policies set explicit aims and objectives that are directly translated into action on the ground, combines a content analysis of policy documents with interviews with policy makers. The bottom-up approach recognises the importance of other actors in shaping policy implementation and involves interviews with actors in organisations within the three sectors. This paper reveals that neither approach offers a complete picture of the potentially enabling or constraining effects of different policies on future adaptive planning, but together they offer new perspectives on climate policy integration. These findings inform a discussion on how to implement climate policy integration, including auditing existing policies and ‘climate proofing’ new ones so they support rather than hinder adaptive planning.  相似文献   
67.
68.
We correlate Upper Pleistocene glacial and fluvial deposits of the Cinca and Gállego River valleys (south central Pyrenees and Ebro basin, Spain) using geomorphic position, luminescence dates, and time-related trends in soil development. The ages obtained from glacial deposits indicate glacial periods at 85 ± 5 ka, 64 ± 11 ka, and 36 ± 3 ka (from glacial till) and 20 ± 3 ka (from loess). The fluvial drainage system, fed by glaciers in the headwaters, developed extensive terrace systems in the Cinca River valley at 178 ± 21 ka, 97 ± 16 ka, 61 ± 4 ka, 47 ± 4 ka, and 11 ± 1 ka, and in the Gállego River valley at 151 ± 11 ka, 68 ± 7 ka, and 45 ± 3 ka. The times of maximum geomorphic activity related to cold phases coincide with Late Pleistocene marine isotope stages and Heinrich events. The maximum extent of glaciers during the last glacial occurred at 64 ± 11 ka, and the terraces correlated with this glacial phase are the most extensive in both the Cinca (61 ± 4 ka) and Gállego (68 ± 7 ka) valleys, indicating a strong increase in fluvial discharge and availability of sediments related to the transition to deglaciation. The global Last Glacial Maximum is scarcely represented in the south central Pyrenees owing to dominantly dry conditions at that time. Precipitation must be controlled by the position of the Iberian Peninsula with respect to the North Atlantic atmospheric circulation system. The glacial systems and the associated fluvial dynamic seem sensitive to 1) global climate changes controlled by insolation, 2) North Atlantic thermohaline circulation influenced by freshwater pulses into the North Atlantic, and 3) anomalies in atmospheric circulation in the North Atlantic controlling precipitation on the Iberian Peninsula. Our scenario of glacial and fluvial evolution during the Late Pleistocene in northern Spain could be extrapolated to other glaciated mountainous areas in southern Europe.  相似文献   
69.
Magnesite growth rates as a function of temperature and saturation state   总被引:1,自引:1,他引:0  
Magnesite growth rates and step velocities have been measured systematically as a function of temperature from 80 to 105 °C and saturation state in 0.1 M NaCl solutions using hydrothermal atomic force microscopy (HAFM). The observations indicate that at these conditions magnesite precipitation is dominated by the coupling of step generation via spiral growth at screw dislocations and step advancement away from these dislocations. As these two processes occur in series the slowest of these dominates precipitation rates. At 100 °C magnesite growth rates (r) determined by HAFM are consistent with
r=k(Ω-1)2,
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