High Acetone Concentrations throughout the 0–12 km Altitude Range over the Tropical Rainforest in Surinam     

U. Pöschl  J. Williams  P. Hoor  H. Fischer  P. J. Crutzen  C. Warneke  R. Holzinger  A. Hansel  A. Jordan  W. Lindinger  H. A. Scheeren  W. Peters  J. Lelieveld 《Journal of Atmospheric Chemistry》2001,38(2):115-132

Airborne measurements of acetone were performed overthe tropical rainforest in Surinam(2°–7° N, 54°–58° W, 0–12 kmaltitude) during the LBA-CLAIRE campaign in March1998, using a novel proton transfer reaction massspectrometer (PTR-MS) that enables the on-linemonitoring of volatile organic compounds (VOC) with ahigher proton affinity than water. The measuredacetone volume mixing ratios ranged from 0.1 nmol/molup to 8 nmol/mol with an overall average of 2.6nmol/mol and a standard deviation of 1.0 nmol/mol. Theobserved altitude profile and correlations with CO,acetonitrile, propane and wind direction are discussedwith respect to potential acetone sources. No linearcorrelation between acetone and CO mixing ratios wasobserved, at variance with results of previousmeasurement campaigns. The mean acetone/CO ratio(0.022) was substantially higher than typical valuesfound before. The abundance of acetone appears to beinfluenced, but not dominated, by biomass burning,thus suggesting large emissions of acetone and/oracetone precursors, such as possibly 2-propanol, fromliving plants or decaying litter in the rainforest.  相似文献   

Photosynthetic responses of Larrea tridentata to a step-increase in atmospheric CO₂at the Nevada Desert FACE Facility     

E. P. Hamerlynck  T. E. Huxman  R. S. Nowak  S. Redar  M. E. Loik  D. N. Jordan  S. F. Zitzer  J. S. Coleman  J. R. Seemann  S. D. Smith   《Journal of Arid Environments》2000,44(4):425

Of all terrestrial ecosystems, the productivity of deserts has been suggested to be the most responsive to increasing atmospheric CO₂. The extent to which this prediction holds will depend in part on plant responses to elevated CO₂under the highly variable conditions characteristic of arid regions. The photosynthetic responses ofLarrea tridentata , an evergreen shrub, to a step-increase in atmospheric CO₂(to 550 μmolmol⁻¹) were examined in the field using Free-Air CO₂Enrichment (FACE) under seasonally varying moisture conditions. Elevated CO₂substantially increased net assimilation rate (A_net) in Larrea during both moist and dry periods of the potential growing season, while stomatal conductance (g_s) did not differ between elevated and ambient CO₂treatments. Seasonal and diurnal gas exchange dynamics in elevated CO₂mirrored patterns in ambient CO₂, indicating that elevated CO₂did not extend photosynthetic activity longer into the dry season or during more stressful times of the day. Net assimilation vs. internal CO₂(A/C_i) responses showed no evidence of photosynthetic down-regulation during the dry season. In contrast, after significant autumn rains, A_max(the CO₂saturated rate of photosynthesis) and CE (carboxylation efficiency) were lower in Larrea under elevated CO₂. In situ chlorophyll fluorescence estimation ofLarrea Photosystem II efficiency (F_v/F_m) responded more to water limitation than to elevated CO₂. These findings suggest that predictions regarding desert plant responses to elevated CO₂should account for seasonal patterns of photosynthetic regulatory responses, which may vary across species and plant functional types.  相似文献   

Quantifying annual groundwater recharge and storage in the central Sierra Nevada using naturally occurring 35S          下载免费PDF全文

Stephanie H. Urióstegui  Richard K. Bibby  Bradley K. Esser  Jordan F. Clark 《水文研究》2017,31(6):1382-1397

Identifying aquifer vulnerability to climate change is of vital importance in the Sierra Nevada and other snow‐dominated basins where groundwater systems are essential to water supply and ecosystem health. Quantifying the component of new (current year's) snowmelt in groundwater and surface water is useful in evaluating aquifer vulnerability because significant annual recharge may indicate that streamflow will respond rapidly to annual variability in precipitation, followed by more gradual decreases in recharge as recharge declines over decades. Hydrologic models and field‐based studies have indicated that young (<1 year) water is an important component of streamflow. The goal of this study was to utilize the short‐lived, naturally occurring cosmogenic isotope sulfur‐35 (³⁵S) to quantify new snowmelt contribution to groundwater and surface waters in Sagehen Creek Basin (SCB) and Martis Valley Groundwater Basin (MVGB) located within the Tertiary volcanics of the central Sierra Nevada, CA. Activities of ³⁵S were measured in dissolved sulfate (³⁵SO₄^2?) in SCB and MVGB snowpack, groundwater, springs, and streamflow. The percent of new snowmelt (PNS) in SCB streamflow ranged from 0.2 ± 6.6% during baseflow conditions to 14.0 ± 3.4% during high‐flow periods of snowmelt. Similar to SCB, the PNS in MVGB groundwater and streamflow was typically <30% with the largest fractions occurring in late spring or early summer following peak streamflow. The consistently low PNS suggests that a significant fraction of annual snowmelt in SCB and MVGB recharges groundwater, and groundwater contributions to streamflow in these systems have the potential to mitigate climate change impacts on runoff.  相似文献   

Holocene relative sea‐level changes in Harris,Outer Hebrides,Scotland, UK     

Jason T. Jordan  David E. Smith  Sue Dawson  Alastair G. Dawson 《第四纪科学杂志》2010,25(2):115-134

Evidence for relative sea‐level changes during the middle and late Holocene is examined from two locations on the Atlantic coast of Harris, Outer Hebrides, Scotland, using morphological mapping and survey, stratigraphical, grain size and diatom analysis, and radiocarbon dating. The earliest event identified is a marine flood, which occurred after 7982–8348 cal. a (7370 ± 80 ¹⁴C a) BP, when the sea crossed a threshold lying at ?0.08 m Ordnance Datum Newlyn (OD) (?2.17 m mean high water springs (MHWS)) before withdrawing. This could have been due to a storm or to the Holocene Storegga Slide tsunami. By 6407–6122 cal. a (5500 ± 60 ¹⁴C a) BP, relative sea levels had begun to fall from a sandflat surface with an indicated MHWS level of between 0.08 and ?1.96 m (?2.01 to ?4.05 m). This fall reached between ?0.30 and ?2.35 m (?2.39 to ?4.44 m) after 5841–5050 cal. a (4760 ± 130 ¹⁴C a) BP, but was succeeded by a relative sea‐level rise which reached between 0.54 and ?1.57 m (?1.55 to ?3.66 m) by 5450–4861 cal. a (4500 ± 100 ¹⁴C a) BP. This rise continued, possibly with an interruption, until a second sandflat surface was reached between 2.34 and ?0.26 m (0.25 to ?2.35 m) between 2952–3375 cal. a (3000 ± 80 ¹⁴C a) and 1948–2325 cal. a (2130 ± 70 ¹⁴C a) BP, before present levels were reached. The regressive episode from the earliest sandflat is correlated with the abandonment of the Main Postglacial Shoreline. It is maintained that the fluctuations in relative sea level recorded can be correlated with similar events elsewhere on the periphery of the glacio‐isostatic centre and may therefore reflect secular changes in nearshore sea surface levels. Despite published evidence from trim lines of differential ice sheet loading across the area, no evidence of variations in uplift between the locations concerned could be found. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Some connections between aerosols,atmospheric transport,and relative humidity at peak Musala     

Peter Nojarov  Ivo Kalapov  Jordan Stamenov  Todor Arsov 《Theoretical and Applied Climatology》2014,115(3-4):471-482

Some connections between aerosols, atmospheric transport, and relative humidity are investigated based on measurements at Basic Environmental Observatory (BEO) station, peak Musala (2,925 masl) for the period January 2009–January 2010. Data are chosen at 0:00 and 12:00 GMT every day. Main methods employed in this research are statistical—nonparametric tests of Mann–Whitney and Spearman. The main conclusion is that greater aerosol load at peak Musala is connected with transport of air masses from north to east horizon quarters. Bigger particles with longer lifetimes come from there. Air coming from the south horizon quarter is aerosol clearer. Relative humidity shows opposite distribution—higher values for transport from south horizon quarter. Correlation between this parameter and aerosols is negative with significant but small value. Distribution of blue, green, and red scattering and backscattering coefficients is similar to distribution of total aerosol concentration. Correlations between scattering and backscattering coefficients and total aerosol concentration are significant and positive. Courses of total aerosol concentration; diameter of particles with maximum concentration; and blue, green, and red scattering and backscattering coefficients have summer maximum and winter minimum. Diurnal course of total aerosol concentration in the two main seasons, winter (January) and summer (July), has day maximum and night minimum. Aerosols at peak Musala are predominantly of transparent or translucent type. The calculation of Ångström exponent α is more precise by using scattering coefficients. The nephelometers data could successfully characterize the haziness of the atmosphere above peak Musala.  相似文献   

The use of airborne laser scanning to develop a pixel-based stratification for a verified carbon offset project     

Jordan Golinkoff  Mark Hanus  Jennifer Carah 《Carbon balance and management》2011,6(1):9

Background  

The voluntary carbon market is a new and growing market that is increasingly important to consider in managing forestland. Monitoring, reporting, and verifying carbon stocks and fluxes at a project level is the single largest direct cost of a forest carbon offset project. There are now many methods for estimating forest stocks with high accuracy that use both Airborne Laser Scanning (ALS) and high-resolution optical remote sensing data. However, many of these methods are not appropriate for use under existing carbon offset standards and most have not been field tested.  相似文献   

CyberShake: A Physics-Based Seismic Hazard Model for Southern California   总被引：2，自引：0，他引：2  

Robert Graves  Thomas H. Jordan  Scott Callaghan  Ewa Deelman  Edward Field  Gideon Juve  Carl Kesselman  Philip Maechling  Gaurang Mehta  Kevin Milner  David Okaya  Patrick Small  Karan Vahi 《Pure and Applied Geophysics》2011,168(3-4):367-381

CyberShake, as part of the Southern California Earthquake Center??s (SCEC) Community Modeling Environment, is developing a methodology that explicitly incorporates deterministic source and wave propagation effects within seismic hazard calculations through the use of physics-based 3D ground motion simulations. To calculate a waveform-based seismic hazard estimate for a site of interest, we begin with Uniform California Earthquake Rupture Forecast, Version 2.0 (UCERF2.0) and identify all ruptures within 200?km of the site of interest. We convert the UCERF2.0 rupture definition into multiple rupture variations with differing hypocenter locations and slip distributions, resulting in about 415,000 rupture variations per site. Strain Green Tensors are calculated for the site of interest using the SCEC Community Velocity Model, Version 4 (CVM4), and then, using reciprocity, we calculate synthetic seismograms for each rupture variation. Peak intensity measures are then extracted from these synthetics and combined with the original rupture probabilities to produce probabilistic seismic hazard curves for the site. Being explicitly site-based, CyberShake directly samples the ground motion variability at that site over many earthquake cycles (i.e., rupture scenarios) and alleviates the need for the ergodic assumption that is implicitly included in traditional empirically based calculations. Thus far, we have simulated ruptures at over 200 sites in the Los Angeles region for ground shaking periods of 2?s and longer, providing the basis for the first generation CyberShake hazard maps. Our results indicate that the combination of rupture directivity and basin response effects can lead to an increase in the hazard level for some sites, relative to that given by a conventional Ground Motion Prediction Equation (GMPE). Additionally, and perhaps more importantly, we find that the physics-based hazard results are much more sensitive to the assumed magnitude-area relations and magnitude uncertainty estimates used in the definition of the ruptures than is found in the traditional GMPE approach. This reinforces the need for continued development of a better understanding of earthquake source characterization and the constitutive relations that govern the earthquake rupture process.  相似文献   

Sorption of selenium(VI) onto anatase: Macroscopic and microscopic characterization     

N. Jordan  H. Foerstendorf  K. Heim  V. Brendler 《Geochimica et cosmochimica acta》2011,75(6):1519-1530

The sorption of selenium(VI) onto pure anatase, a polymorph of titanium dioxide, was investigated. At the macroscopic level, batch experiments and electrophoretic mobility measurements were performed. Selenium(VI) retention was found to be pH-dependent, i.e. sorption of selenium(VI) decreases with increasing pH (pH range 3.5-11). Selenium(VI) sorption dependence on the ionic strength was also evidenced, i.e. sorption increases while the ionic strength decreases. Electrophoretic mobility measurements showed that selenium(VI) sorption had no effect on the isoelectric point of anatase. At the microscopic level, XPS (X-ray Photoelectron Spectroscopy) measurements evidenced the absence of reduction of selenium(VI) during the sorption process. Furthermore, the nature of the sorbed surface species at the anatase/liquid interface was elucidated using Attenuated Total Reflection Fourier-Transform Infrared (ATR FT-IR) spectroscopy. The spectroscopic results strongly suggested the formation of outer-sphere complexes on the whole pH range, in agreement with batch sorption experiments and electrophoretic mobility findings.  相似文献   

The Staffelegg Formation: a new stratigraphic scheme for the Early Jurassic of northern Switzerland     

Achim G. Reisdorf  Andreas Wetzel  Rudolf Schlatter  Peter Jordan 《Swiss Journal of Geoscience》2011,104(1):97-146

The deposits of the Early Jurassic in northern Switzerland accumulated in the relatively slowly subsiding transition zone between the southwestern part of the Swabian basin and the eastern part of the Paris basin under fully marine conditions. Terrigenous fine-grained deposits dominate, but calcarenitic and phosphorit-rich strata are intercalated. The total thickness varies between 25 and 50 m. In the eastern and central parts of N Switzerland, sediments Sinemurian in age constitute about 90% of the total thickness. To the West, however, in the Mont Terri area, Pliensbachian and Toarcian deposits form 70% of the total thickness. Stratigraphic gaps occur on a local to regional scale throughout N Switzerland. Such hiatus comprise a subzone to a stage in time. With respect to lithology and fossil content, the Early Jurassic deposits in northern Switzerland are similar to those in SW Germany. Nonetheless, an exact stratigraphic correlation is hardly possible, particulary in the southern and southwestern Folded Jura where distinct facies changes occur over short distances. Revised existing and new litho- and biostratigraphic data form the base to refine the stratigraphic subdivision of the deposits that have been informally called “Lias”. The name Staffelegg Formation is suggested and defined as the mapping unit for the Early Jurassic. The Staffelegg Formation is introduced for Early Jurassic sediments in northern Switzerland between the Doubs River and Mt. Weissenstein in the west and the Randen Hills located north of the city of Schaffhausen in the east. The Staffelegg Formation starts within the Planorbis zone of the Hettangian. The upper boundary to the overlying Aalenian Opalinus-Ton is diachronous. The lithostratigraphic names previously in use have been replaced by new ones, in accordance within the rules of lithostratigraphic nomenclature. The Staffelegg Formation comprises 11 members and 9 beds. Several of these beds are important correlation horizons in terms of allostratigraphy. Some of them correspond to strata or erosional unconformities encountered in the Swabian realm, some of them can be correlated with strata in the Paris basin. The facies transition to the Paris basin is expressed by introduction of a corresponding lithostratigraphic unit.  相似文献   

Variation in sea temperature and the East Australian Current in the Solitary Islands region between 2001-2008     

Hamish A. Malcolm  Peter L. DaviesAlan Jordan  Stephen D.A. Smith 《Deep Sea Research Part II: Topical Studies in Oceanography》2011,58(5):616-627

Improved understanding of the East Australian Current (EAC) and sea-temperature patterns within the Solitary Islands region of northern New South Wales, an area where tropical and temperate faunas overlap, is an essential step in explaining cross-shelf gradients in biotic patterns. Sea temperature at ∼10 m was logged using thermistors at seven stations every 30 minutes between January 2001 and December 2008. Stations were replicated in three distance-from-shore categories (<1.5; 1.5 to 6; and >6 km from the coast), corresponding with predominant assemblage patterns of reef fish. Daily, monthly, seasonal and yearly sea-temperature patterns were compared between and within stations and distance-from-shore categories. SST images were examined to determine the role of the EAC in producing short-period (2 to 4 days) temperature anomalies. Sea temperatures ranged between 16.6-27.5 °C and were highest offshore and lowest inshore. Offshore sites experienced average temperatures ∼1 °C higher than nearshore sites over the 8-year study. There was considerable variation in sea temperature between years, with 2002 and 2006 being the warmest and 2007 the coolest. These patterns correspond with strong inter-annual variability of the EAC at the scale of the Solitary Islands region. The EAC influenced shelf waters most strongly during late spring/summer when temperatures were also most variable over the smallest temporal scales (hours, days). Short-period anomalies between and within stations could largely be explained by variable encroachment of the EAC across the shelf and/or colder intrusions of water forming adjacent to the coastline. Previous assumptions that the EAC strongly influences gradients in the distribution of tropical species in this nearshore region are strongly supported.  相似文献