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71.
Rhenium and osmium isotopes in sulfide minerals from the Bagdad porphyry Cu–Mo deposit have been used to determine timing of mineralization and the source of osmium and, by inference, ore metals. Molybdenite, chalcopyrite and pyrite were analyzed mainly from the quartz monzonite and porphyritic quartz monzonite units, which are characterized by moderate to strong potassic alteration (secondary biotite and K-feldspar). Rhenium concentrations in molybdenite are between 330 and 642 ppm. Four Re–Os analyses of two molybdenite samples from the quartz monzonite and porphyritic quartz monzonite yield a weighted average age of 71.8±0.2 Ma (2s). Analyses of a third sample from a molybdenite vein in Precambrian rocks, outside of the main ore zone, yield a weighted average age of 75.9±0.2 Ma (2s), and provide evidence of two separate mineralization episodes. Chalcopyrite samples contain 6 to 12 ppt Os and 1.7 to 4.1 ppb Re; 187Os/ 188Os initial ratios are between 0.1 and 0.8. Pyrite samples have osmium and rhenium concentrations varying in the range 8–17 ppt and 3.9–6.8 ppb, respectively. Analyses from these pyrite samples yield an eight-point isochron with an age of 77±15 Ma (2s) and an initial 187Os/ 188Os ratio of 2.1±0.8 (MSWD=0.90). The results presented here add to the growing body of work indicating that porphyry-type mineralization is produced by long-term, multiple episodes of magmatism and associated mineralization. The data also support the hypothesis that a significant part of the metals and magmas may have a crustal source, as has been suggested for other copper deposits and districts in Arizona. 相似文献
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Javier Fernández-Suárez Fernando Corfu Ricardo Arenas Alberto Marcos José R. Martínez Catalán Florentino García Jacobo Abati Francisco J. Fernández 《Contributions to Mineralogy and Petrology》2002,143(2):236-253
. A isotope dilution thermal ionisation mass spectrometry U-Pb geochronological study was carried out on the high-pressure and high-temperature units (HP-HT units) overlying the oceanic suture in the Allochthonous Complexes of the NW Iberian Variscan Belt. The rocks investigated are seven granulite- to eclogite-facies paragneisses and one leucosome within mafic high-pressure granulites in the Ordenes and Cabo Ortegal Complexes of NW Spain. U-Pb dating of zircon, monazite, titanite and rutile reveal the presence of a pervasive Early Ordovician metamorphic event at ca. 500-480 Ma and a later Early Devonian event at ca. 400-380 Ma. The U-Pb ages, in conjunction with petrological and structural data, indicate that the high-pressure event recorded by these rocks is Early Ordovician in age. Monazite ages in the paragneisses suggest that peak metamorphic conditions were reached at ca. 500-485 Ma. Subsequently, the rock ensemble underwent exhumation accompanied by partial melting and zircon growth at ca. 485-470 Ma. Melting of mafic granulites was coeval with this latter episode as indicated by zircon crystallisation age in the leucosomes dated at ca. 486 Ma. Based on these data and on the general features of magmatism and metamorphic evolution, it is proposed that this process took place at a convergent plate boundary within a peri-Gondwanan oceanic domain. Monazite, titanite and rutile data in some of the samples studied show evidence of a second metamorphic episode that took place between ca. 400 and 380 Ma (with a peak at ca. 390-385 Ma). This Early Devonian event, at variance with the previous one, was not pervasive, but, rather, was localised in areas of intense Variscan tectonothermal reworking. It is claimed that this later metamorphic event was recorded by the U-Pb system in areas where monazite and titanite growth was enhanced by fluid circulation in highly strained rocks (Variscan shear zones). According to previous structural studies and Ar-Ar dating of fabrics, this Early Devonian episode took place as the HP-HT units were deformed and thrusted upon the ophiolitic units in the early stages of the Variscan collision. 相似文献
74.
Pilar Drake Alberto M. Arias Francisco Baldó José A. Cuesta Antonio Rodríguez Alfonso Silva-Garcia Ignacio Sobrino Diego García-González Carlos Fernández-Delgado 《Estuaries and Coasts》2002,25(3):451-468
The aquatic macrofauna of the Guadalquivir estuary were sampled (1 mm mesh persiana net) at 5 sampling sites located along the entire (except the tidal freshwater region) estuarine gradient of salinity (outer 50 km). A total of 134 fish and macroinvertebrate species was collected but only 62 were considered common or regularly present in the estuary. Univariate measures of the community structure showed statistically significant differences among sampling sites: species richness, abundance, and biomass decreased in the upstream direction, being positively correlated with the salinity. Temporal differences of these three variables were also statistically significant. While a clear seasonal pattern (minimum densities in winter and maximum in spring-summer) was observed for abundance and biomass, no such pattern existed for the number of species. Mysids was the most dominant group throughout the estuary (96% to 99% of abundance; 49% to 85% of biomass), although fish biomass was also important at the outer estuary (36% to 38%). Multivariate analyses indicated highly significant spatial variation in the macrofaunal communities observed along the salinity gradient. These analyses suggest that the underlying structure was a continuum with more or less overlapping distributions of the species dependent on their ability to tolerate different physicochemical conditions. There were also significant temporal (intermonthly + interannual) variation of the estuarine community; the relative multivariate dispersion indicated that monthly variation was more considerable (relative multivariate dispersion >1) at the outer part of the estuary during the wet year (last 20 km) and was higher in the inner stations during the dry year (32 to 50 km from the river mouth). Since a clear negative exponential relationship was observed between the freshwater input (from a dam located 110 km upstream) and water salinity at all sampling stations, it is concluded that the human freshwater management is probably affecting the studied estuarine communities. While the higher seasonal (long-term) stability of the salinity gradient, due to the human control of the freshwater input, may facilitate the recruitment of marine species juveniles during the meteorologically unstable early-spring, the additional (short-term) salinity fluctuations during the warm period may negatively affect species that complete their lifecycle within the estuary. 相似文献
75.
Contradictory results are reported for the behaviour of quaternary ammonium compounds (QACs) in sewage treatment plants (STPs). QACs may sorb onto activated sludge. Only little information is available with respect to effects of QACs against bacteria in STPs. Only 5 to 15 % of bacteria present in sewage sludge can be detected by means of culture dependent microbiological methods. The shift of the bacterial populations due to effects of test compounds have not been studied up to now with culture independent methods. The microbial populations shift was studied in situ using culture independent chemotaxonomy profiling ubiquinones and polyamines. Additionally, toxic effects of QACs against bacteria present in the test vessels of the Zahn‐Wellens test (OECD 302 B) were assessed with a toxicity control in the test. The ubiquinone profiles representing changes in Gram‐negative populations mainly showed that the activated sludge was affected only in test vessels containing benzalkonium chloride. According to chemotaxonomy Acinetobacter or/and some members of Pseudomonas spp. have been selected by benzalkonium chloride after some adaptation period (8 to 12 days). 相似文献
76.
Jean‐Jacques Macaire Saïda Bellemlih Christian Di‐Giovanni Patrick De Luca Lionel Visset Jacques Bernard 《地球表面变化过程与地形》2002,27(9):991-1009
In the Négron River catchment area (162 km2), surface‐sediment stores are composed of periglacial calcareous ‘grèze’ (5 × 106 t) and loess (21 × 106 t), and Holocene alluvium (12·6 × 106 t), peat (0·6 × 106 t) and colluvium (18·5 × 106 t). Seventy‐five per cent of the Holocene sediments is stored along the thalwegs. Present net sediment yield, calculated from solid discharge at the Négron outlet, is low (0·6 t km?2 a?1) due to the dominance of carbonate rocks in the catchment. Mean sediment yield during the Holocene period is 7·0 t km?2 a?1 from alluvium stores and 7·6 t km?2 a?1 from colluvium stores. Thus, the gross sediment yield during the Holocene period is about 18·7 t km?2 a?1 and the sediment delivery ratio 3 per cent. The yield considerably varies from one sub‐basin to another (3·9 to 24·5 t km?2 a?1) according to lithology: about 25 per cent and 50 per cent of initial stores of periglacial grèze and loess respectively were reworked during the Holocene period. Sediment yield has increased by a factor of 6 in the last 1000 years, due to the development of agriculture. The very high rate of sediment storage on the slope during that period (88 per cent of the yield) can be accounted for by the formation of cultivation steps (‘rideaux’). It is predicted that the current destruction of these steps will result in a sediment wave reaching the valley floors in the coming decades. Subboreal and Subatlantic sediments and pollen assemblages in the Taligny marsh, where one‐third of the alluvium is stored, show the predominant influence of human activity during these periods in the Négron catchment. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
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79.
Gil A. J. Rodríguez-Caderot G. Lacy M. C. Ruiz A. M. Sanz de Galdeano C. Alfaro P. 《Studia Geophysica et Geodaetica》2002,46(3):395-410
The Granada Basin (Central Betic Cordillera), one of the most seismically active areas of the Iberian Peninsula, is currently subjected to NW-SE compression and NE-SW extension. The present day extension is accommodated by normal faults with various orientations but particularly with a NW-SE strike. At the surface, these active NW-SE normal faults are mainly concentrated on the NE part of the Basin. In this part we have selected a 15-km long segment where several active normal faults crop out. Using the marine Tortonian rocks as a reference, we have calculated a minimum extensional rate of 0.15-0.30 mm/year. The observed block rotation, the listric geometry of faults at depth and the distribution of seismicity over the whole Basin, indicate that this rate is a minimum value. In the framework of an interdisciplinary research project a non-permanent GPS-network has been established in the central sector of Betic Cordillera to monitor the crustal deformations. The first two observation campaigns were done in 1999 and 2000. 相似文献
80.
The differentiation of units in the Sierra de Almagro has been a source of controversy. There were defined the Almagride and Ballabona–Cucharón complexes, the former considered by several authors as part of a Subbetic metamorphosed and outcropping in a tectonic window. In this study, the units of Ballabona, Almagro and Cucharón are integrated into a single one, that of Tres Pacos, because they correspond to different parts of the same stratigraphic series. This unit is tectonically over the Nevado–Filabride Complex. The existence of the Almagride and Ballabona–Cucharón complexes is discarded and their units form part of the Alpujarride Complex. To cite this article: C. Sanz de Galdeano, F.J. Garc??a Tortosa, C. R. Geoscience 334 (2002) 355–362. 相似文献