Laboratory study of the rates and products of the phototransformations of naphthalene adsorbed on samples of titanium dioxide,ferric oxide,muscovite, and fly ash     

Chantal Guillard  Hervé Delprat  Can Hoang-van  Pierre Pichat 《Journal of Atmospheric Chemistry》1993,16(1):47-59

The photodegradation of naphthalene (NPH), chosen as a model of polynuclear aromatic pollutants, has been studied in the presence of a layer of four water-insoluble inorganic solids which can be found in the troposphere (TiO₂, Fe₂O₃, muscovite, and a fly ash sample). Direct photolysis of NPH is negligible at >340 nm. Dark adsorption of NPH on TiO₂ (mainly anatase, nonporous, 50 m² g^–1) at 293 K corresponds to a surface coverage ofca. 50% at equilibrium. Under these conditions (saturated surface), the stationary-state photocatalytic degradation reaches 0.4 molecule nm^–2 h^–1 (>340 nm, radiant fluxca. 22 mW cm^–2). Dioxygen is required and its partial pressure in air is such that the degradation is zero order in O₂. Water vapor markedly increases the rate. The other particulates have also an effect, less important than that of TiO₂, however quite noticeable with respect to surface area unit for the fly ash sample which contains 3.2% Fe₂O₃. Apart from 1,4-naphthoquinone, which is the main intermediate product in all cases, 2-naphthol, phthalide, phthaldialdehyde, phthalic acid, acetophenone, benzaldehyde, benzoic acid are also formed on dry TiO₂. Depending on their volatility, these compounds are transferred to the gas phase or remain principally adsorbed on the solid particles where they are further transformed. For instance, phthalic acid (or anhydride) and benzoic acid are generated from 1,4-naphthoquinone. Degradation mechanisms are briefly discussed.  相似文献   

Molecular and bulk isotopic analyses of organic matter in marls of the Mulhouse Basin (Tertiary, Alsace, France)     

Hollander DJ  Sinninghe Damste JS  Hayes JM  de Leeuw JW  Huc AY 《Organic Geochemistry》1993,20(8):1253-1263

Contents of 13C in kerogens and carbonates in 21 samples from a core of the MAX borehole, Mulhouse Evaporite Basin, range from -27.3 to -23.5 and -3.7 to -1.8% vs PDB, respectively. Organic nitrogen in the same samples is enriched in 15N relative to atmospheric N2 by 12.2-15.7%. Hydrogen indices and delta values for kerogens vary systematically with facies, averaging 493 mg HC/g Corg and -25.7% in the most saline facies (dominated by inputs from aquatic sources) and 267 mg HC/g Corg and -23.7% in the least saline facies (50/50 aquatic/terrigenous). Values of delta were measured for individual aliphatic hydrocarbons from three samples representing three different organic facies. For all samples, terrigenous inputs were unusually rich in 13C, the estimated delta value for bulk terrigenous debris, apparently derived partly from CAM plants, being -22.5%. In the most saline facies, isotopic evidence indicates the mixing of 13C-depleted products of photosynthetic bacteria with 13C-enriched products of halotolerant eukaryotic algae. At lower salinities, a change in the producer community is marked by a decrease in the 13C content of algal lipids. The content of 13C in algal lipids increases in the least saline facies, due either to succession of different organisms or to decreased concentrations of dissolved CO2.  相似文献   

Corona textures in Proterozoic olivine melanorites of the Equeefa Suite,Natal Metamorphic Province,South Africa     

Dr. G. H. Grantham  Dr. R. J. Thomas  Dr. B. M. Eglington  Dr. D. de Bruin  Dr. A. Atanasov  Dr. M. J. Evans 《Mineralogy and Petrology》1993,49(1-2):91-102

Summary Olivine-plagioclase and phlogopite-plagioclase coronas have been identified from olivine melanorites of the Mid- to Late Proterozoic Equeefa Suite in southern Natal, South Africa. Olivine, in contact with plagioclase, is mantled by a shell of clear orthopyroxene, in turn rimmed by pale green (pargasitic) clinoamphibole. Locally a third rim, composed of a fine pargasite-spinel symplectite is developed adjacent to the plagioclase. The second corona reaction has produced greenish-brown pargasite at phlogopite-plagioclase interfaces. A third, less obvious reaction, between olivine and phlogopite is also noted. Analytical data of all the mineral phases present, along with the coronas, are given. Two-pyroxene thermometry yields magmatic core temperatures ( 1120°C), with rim compositions indicating equilibration at 850°C. Consistent with this, the modelled olivine-plagioclase reaction occurs between 830–1050°C with a_waterbetween 0.1 and 1.0 at 7 kbar. The three reactions took place during a prolonged history of cooling and partial hydration of the magmatic olivine melanorites from over 1000°C down to 600°C. The P-T conditions indicated by the reactions suggest this cooling process was essentially isobaric, indicating that the area was not subjected to rapid uplift or burial throughout this entire period.

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Korona-Texturen in proterozoischen Olivin-Melanoriten der Equeefa Suite, Natal Metamorphic Province, Südafrika

Zusammenfassung Aus Olivin-Melanoriten der mittel- bis spätproterozoischen Equeefa Suite im südlichen Natal, Südafrika, wurden Olivin-Plagioklas und Phlogopit-Plagioklas-Koronartexturen beobachtet. Olivin, der mit Plagioklas im Kontakt steht, wird von einem klaren Saum vom Orthopyroxen ummantelt, der seinerseits von blaßgrünem (pargasitischem) Klinoamphibol umsäumt wird. Stellenweise ist ein dritter Saum, bestehend aus feinkörnigem symplektitischem Pargasit-Spinell im Kontakt mit Plagioklas ausgebildet. Die zweite koronabildende Reaktion resultiert in Bildung eines grünbraunen Pargasites an Phlogopit-Plagioklas Kornkontakten. Eine dritte, weniger auffällige Reaktion zwischen Olivin und Phlogopit wurde ebenfalls beobachtet. Zwei-Pyroxen-Thermometrie ergab magmatische Temperaturen der Kernbereiche ( 1120°C) und belegt eine Gleichgewichtseinstellung in den Randzonen bei ca. 850°C. Olivin-Plagioklas-Modellreaktionen liegen ebenfalls in einem Temperaturbereich von 830–1050°C bei Wasseraktivitäten von 0.1 bis 1.0 und einem Druck von 7 kbar. Die drei Reaktionen liefen im Zuge einer länger andauernden Abkühlung unter teilweiser Hydratisierung der magmatischen Melanorite in einem Temperaturbereich von 1000°C bis ca. 600°C ab. Die aus den Reaktionen ableitbaren P-T-Bedingungen sprechen für eine im wesentlichen isobare Abkhlungsgeschichte und zeigen, daß dieses Gebiet wáhrend dieser gesamten Periode keiner raschen Hebung bzw. keiner Versenkung unterworfen worden ist.

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On the tidal variation of the geopotential     

José M. Ferrándiz  Juan Getino 《Celestial Mechanics and Dynamical Astronomy》1993,57(1-2):279-292

In this paper analytical expressions are derived for the temporal variations ofJ ₂ andJ ₂₂ due to the tides of the solid Earth, taking into account only the deformation of the mantle, and employing a procedure already used by the authors in their Hamiltonian theory of the Earth's rotation, which obtain the necessary parameters in a direct way by integration of those provided by a selected model of Earth interior.Numerical tables giving the periodic variation of coefficients are given, as well as a new prediction for UT1. For J ₂ and J ₂₂ the amplitudes reach such a magnitude that both two variations should not be ignored in studies involving the analysis of highly precise satellite tracking data. Moreover, the possibility of improving our knowledge of the value of those harmonic coefficients in only a more exact digit appears as to be strongly dependent on the limitations in the theoretical modeling of the variations of the inertia tensor due to solid tides.  相似文献   

The role of bathymetry and directional wave conditions on observed crescentic bar dynamics     

Rinse L. de Swart  Francesca Ribas  Gonzalo Simarro  Jorge Guillén  Daniel Calvete 《地球表面变化过程与地形》2021,46(15):3252-3270

Nearshore sandbars are important features in the surf zone of many beaches because they strongly influence the mean circulation and evolving morphology. Due to variations in wave conditions, sandbars can experience cross-shore migration and vary in shape from alongshore uniform (shore-parallel) to alongshore rhythmic (crescentic). Sandbar dynamics have been studied extensively, but existing observational studies usually do not quantify the processes leading to crescentic bar formation and straightening. This study analyses the dynamics of crescentic bar events at the fetch-limited beach of Castelldefels (northwestern Mediterranean Sea, Spain) using 7.5 years of hourly time-exposure video images and detailed wave conditions. The results show that, despite the generally calm wave conditions, the sandbars were very dynamic in the cross-shore and longshore directions. They often migrated rapidly offshore during storms (up to 70 m in one day) and more slowly onshore during post-storm conditions. Crescentic bars were often present at the study site (48% of the time), but only when the sandbar was at least 10 m from the shoreline. They displayed a large variability in wavelengths (100–700 m), alongshore migration speeds (0–50 m/day) and cross-shore amplitudes (5–20 m). Wavelengths increased for larger bar–shoreline distances and the alongshore migration speeds were strongly correlated with the alongshore component of the radiation stresses. Crescentic patterns typically developed during low–medium energetic waves with limited obliquity ( $\theta \lesssim 20$° at 10 m depth), while bar straightening occurred during medium–high energetic waves with strong oblique angles of incidence ( $\theta \gtrsim 15$°). Overall, this study provides further proof for the important role of wave direction in crescentic bar dynamics and highlights the strong dependence of crescentic bar development on the initial bathymetric configuration.  相似文献   

Carbonatites from Eastern Paraguay and genetic relationships with potassic magmatism: C, O, Sr and Nd Isotopes     

F. Castorinal  P. Censi  P. Comin-Chiaramonti  E. M. Piccirillo  A. Alcover Neto  C. B. Gomes  T. I. Ribeiro de Almeida  S. Speziale  M. C. M. Toledo 《Mineralogy and Petrology》1997,61(1-4):237-260

Summary Geochemical characteristics were systematically determined for Early Cretaceous samples of carbonatitic rocks from Eastern Paraguay (Rio Apa, Amambay and Central Provinces). The data show that all the occurrences have an enriched isotopic signature and that the carbonatites have negligible or absent crustal signature. A petrogenetic model (parent liquids, fractional crystallization, hydrothermal interactions and weathering) is proposed as a function of incompatible trace element, stable (O-C) and radiogenic (Sr-Nd) isotope variations with the aim to test the significance of carbonatitic complexes as a marker of the metasomatized subcontinental lithospheric mantle. The results indicate that the carbonatites and primary carbonates from eastern Paraguay, and those from the north eastern Paraná Basin (SE Brazil), were affected by metasomatic events distinct in time and composition.

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Karbonatite aus Ost-Paraguay und ihre genetische Beziehung zu Kalium-Magmatismus: C O, Sr und Nd isotope

Zusammenfassung Die geochemischen Charakteristika von frühkretazischen Karbonatitproben aus Ostparaguay (Rio Alpa, Amambay und Zentrale Provinzen) wurden untersucht. Die Daten belegen, daß alle Vorkommen eine isotopische Anreicherungssignatur zeigen und daß ihnen eine entsprechende Krustensignatur fehlt. Ein Petrologisches Modell (Ausgangsschmelze, fraktionierte Kristallisation, hydrothermale Interaktion und Verwitterung) wird auf Grund der Verteilung der inkompatiblen Spurenelemente, der stabilen (C-O) und radiogenen (Sr-Nd) Isotope vorgeschlagen. Es versucht die Bedeutung der Karbonatitkomplexe als Markerhorizonte des metasomatischen subkontinentalen Mantels zu überprüfen. Die Ergebnisse zeigen, daß die Karbonatite und die primären Karbonate in Ostparaguay, und jene aus dem Paraná Becken SüdostBrasiliens durch zeitlich und zusammensetzungsmäßig unterschiedliche metasomatische Prozesse erfaßt wurden.

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With 10 Figures  相似文献   

Textures exhibited by feldspars in the Giant Mottled Anorthosite (GMA) of the bastard unit in the Upper Critical Zone,Western Bushveld Complex     

W. J. de Klerk 《Mineralogy and Petrology》1995,54(1-2):25-34

Summary The Bastard Unit, overlying the Merensky Unit, is the uppermost and most complete of the cyclic units in the Upper Critical Zone and its upper contact is taken as the boundary between the Critical and Main Zones (as recommended by SACS, 1980). The Unit is different from underlying units for three reasons: it does not have a well-defined top contact (with an overlying unit); it is much thicker than the Merensky and Footwall Units; and it has an unusually thick sequence of mottled anorthosite at its top. This distinctive composite anorthositic sequence is termed the Giant Mottled Anorthosite (GMA) which is predominantly made up of poikilitic anorthosite. The GMA can broadly be subdivided into three distinct parts; the Lower Giant Mottled Anorthosite (LGMA), Giant Mottled Middling (GMM) and the Upper Giant Mottled Anorthosite (UGMA).Petrographic examination of 82 samples taken in the GMA from 11 borehole profiles around the western limb of the Complex revealed that the LGMA and GMM are essentially adcumulates while the UGMA is orthocumulate in character. By its very nature the dominant phase throughout the GMA is cumulus plagioclase feldspar ( 85%) with the balance being made up of intercumulus orthopyroxene and clinopyroxene and minor biofite — all of which constitute the darker mottles. Intercumulus inverted pigeonite occurs in the upper part of the GMM, throughout the UGMA and for c. 30 m into the Main Zone. K-feldspar also joins the paragenesis within the UGMA and occurs both as intercumulus orthoclase and antiperthite. Cumulus plagioclase grains, showing varying degrees of complex oscillatory-zonal growth are common in the upper part of the GMA. These grains are interpreted as records of growth episodes during earlier influxes of magma which were responsible for the development of the underlying cyclic units, but escaped incorporation into the cumulate pile.

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Feldspat-Texturen im Giant Mottled Anorthosite der Bastard-Einheit in der oberen kritischen Zone des westlichen Bushveld-Komplexes

Zusammenfassung Die Bastard-Einheit, die die Merensky-Einheit überlagert, ist die oberste und am besten entwickelte der zyklischen Einheiten in der oberen kritischen Zone; ihr oberer Kontakt gilt als die Grenze zwischen der Kritischen und der Main-Zone (entsprechend den Empfehlungen von SACS, 1980). Die Einheit unterscheidet sich aus drei Gründen von den Einheiten im liegenden: sie hat keinen gut definierten oberen Kontakt (mit einer darüberliegenden Einheit), sie ist wesentlich mächtiger als die Merensky und die Footwall-Einheiten, und sie hat eine ungewöhnliche mächtige Abfolge von Mottled Anorthosite als obersten Teil der Abfolge. Diese wohldefinierte anorthositische Abfolge wird als Giant Mottled Anorthosite (GMA) bezeichnet, und besteht hauptsächlich aus poikilitischem Anorthosit. Die GMA kann in 3 Teile, den unteren (LGMA), den mittleren (GMM) un den oberen (UGMA) unterteilt werden.Die petrographische Untersuchung von 82 Proben in der GMA aus 11 Bohrlöchern im Westteil des Bushveld-Komplexes zeigt, daß LGMA und GMM im wesentlichen Adkumulate sind, während die UGMA ein Orthokumulat darstellt. Die Hauptphase in der gesamten GMA ist Kumulus-Plagioklas ( 85 %); der Rest besteht aus Intercumulus-Orthopyroxen, Klinopyroxen, und geringen Mengen von Biotit. Diese sind die Komponenten der dunkleren mottles. Intercumulus invertierter Pigeonit kommt im oberen Teil der GMM, in der gesamten UGMA und in den unteren 30 Metern der Main-Zone vor. Innerhalb der UGMA tritt K-Feldspat hinzu, dieser kommt als Intercumulus Orthoklas und Antiperthit vor. Körner von Cumulusplagioklas mit verschiedenen Intensitäten komplexer Zonierung sind im oberen Teil der GMA verbreitet. Diese Körner werden als Hinweise auf Wachstumsepisoden während früherer Magmenzufuhr-Phasen interpretiert, die für die Entwicklung der zyklischen Einheiten im Liegenden verantwortlich waren, aber selbst nicht Teil der Cumulatabfolge wurden.

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With 5 Figures  相似文献   

Molecular indicators for palaeoenvironmental change in a Messinian evaporitic sequence (Vena del Gesso, Italy). II: High-resolution variations in abundances and 13C contents of free and sulphur-bound carbon skeletons in a single marl bed     

Kenig F  Damsté JS  Frewin NL  Hayes JM  De Leeuw JW 《Organic Geochemistry》1995,23(6):485-526

The extractable organic matter of 10 immature samples from a marl bed of one evaporitic cycle of the Vena del Gesso sediments (Gessoso-solfifera Fm., Messinian, Italy) was analyzed quantitatively for free hydrocarbons and organic sulphur compounds. Nickel boride was used as a desulphurizing agent to recover sulphur-bound lipids from the polar and asphaltene fractions. Carbon isotopic compositions (delta vs PDB) of free hydrocarbons and of S-bound hydrocarbons were also measured. Relationships between these carbon skeletons, precursor biolipids, and the organisms producing them could then be examined. Concentrations of S-bound lipids and free hydrocarbons and their delta values were plotted vs depth in the marl bed and the profiles were interpreted in terms of variations in source organisms, 13 C contents of the carbon source, and environmentally induced changes in isotopic fractionation. The overall range of delta values measured was 24.7%, from -11.6% for a component derived from green sulphur bacteria (Chlorobiaceae) to -36.3% for a lipid derived from purple sulphur bacteria (Chromatiaceae). Deconvolution of mixtures of components deriving from multiple sources (green and purple sulphur bacteria, coccolithophorids, microalgae and higher plants) was sometimes possible because both quantitative and isotopic data were available and because either the free or S-bound pool sometimes appeared to contain material from a single source. Several free n-alkanes and S-bound lipids appeared to be specific products of upper-water-column primary producers (i.e. algae and cyanobacteria). Others derived from anaerobic photoautotrophs and from heterotrophic protozoa (ciliates), which apparently fed partly on Chlorobiaceae. Four groups of n-alkanes produced by algae or cyanobacteria were also recognized based on systematic variations of abundance and isotopic composition with depth. For hydrocarbons probably derived from microalgae, isotopic variations are well correlated with those of total organic carbon. A resistant aliphatic biomacromolecule produced by microalgae is, therefore, probably an important component of the kerogen. These variations reflect changes in the depositional environment and early diagenetic transformations. Changes in the concentrations of S-bound lipids induced by variations in conditions favourable for sulphurization were discriminated from those related to variations in primary producer assemblages. The water column of the lagoonal basin was stratified and photic zone anoxia occurred during the early and middle stages of marl deposition. During the last stage of the marl deposition the stratification collapsed due to a significant shallowing of the water column. Contributions from anaerobic photoautotrophs were apparently associated with variations in depth of the chemocline.  相似文献   

Dynamical evolution of NEAs: Close encounters, secular perturbations and resonances     

Patrick Michel  Christiane Froeschlé  Paolo Farinella 《Earth, Moon, and Planets》1995,71(3):151-164

We discuss the main mechanisms affecting the dynamical evolution of Near-Earth Asteroids (NEAs) by analyzing the results of three numerical integrations over 1 Myr of the NEA (4179) Toutatis. In the first integration the only perturbing planet is the Earth. So the evolution is dominated by close encounters and looks like a random walk in semimajor axis and a correlated random walk in eccentricity, keeping almost constant the perihelion distance and the Tisserand invariant. In the second integration Jupiter and Saturn are present instead of the Earth, and the 3/1 (mean motion) and v ₆ (secular) resonances substantially change the eccentricity but not the semimajor axis. The third, most realistic, integration including all the three planets together shows a complex interplay of effects, with close encounters switching the orbit between different resonant states and no approximate conservation of the Tisserand invariant. This shows that simplified 3-body or 4-body models cannot be used to predict the typical evolution patterns and time scales of NEAs, and in particular that resonances provide some fast-track dynamical routes from low-eccentricity to very eccentric, planet-crossing orbits.On leave from the Department of Mathematics, University of Pisa, Via Buonarroti 2, 56127 Pisa, Italy, thanks to the G. Colombo fellowships of the European Space Agency.  相似文献   

Jupiter: New retrieved thermal profiles and ammonia distributions     

Daniel Gautier  André Marten  Jean Paul Baluteau  Anne Lacombe 《Icarus》1979,37(1):214-235

New thermal profiles of Jupiter are retrieved from recent far infrared spectral measurements and for H₂ mixing ratios varying from 0.8 to 0.94. The effective temperature corresponding to the inferred thermal profile is 123.15 ± 0.35°K. Far-infrared brightness temperature spectra computed from these profiles are compared to experimental data including measurements made at high spectral resolution in the NH₃ν₂ band at 10 μm and in NH₃ pure rotational bands between 40 and 110 μm. It is found that a strong depletion of NH₃ does occur in the Jovian stratosphere and that ammonia seems to be undersaturated in the upper troposphere.  相似文献