Levels of chlorinated hydrocarbons and trace metals in bivalves and nearshore sediments from the Dominican Republic     

Luciano Sbriz  Margarita R. Aquino  Natividad M. Alberto de rodriguez  Scott W. Fowler  Jose L. Sericano 《Marine pollution bulletin》1998,36(12):971-979

Bivalves (Crassostrea rizhophorae, Isognomon alatus, Codakia orbicularis Linné, and Tellina fausta) and sediment samples collected from 12 locations along the Dominican Republic coastline were used to assess the degree of nearshore contamination by selected chlorinated hydrocarbons and heavy metals. Concentrations of total chlordanes, DDTs and PCBs ranged from 0.51 to 7.47 ng/g, < MDL to 30.9 ng/g and 11.3 to 82.3 ng/g, and from < MDL to 1.73 ng/g, 0.21 to 12.5 ng/g and 0.46 to 41.9 ng/g in bivalves and surface sediments, respectively. The concentration ranges of predominantly anthropogenic Cu, Pb and Zn were 3.08–866 μg/g, 0.08–1.46 μg/g and 22.9–4380 μg/g in bivalve soft parts and 1.01–111 mg/g, 0.420–134 μg/g and 1.96–277 μg/g in surface sediments, respectively. Mercury concentrations ranged from 0.290 to 7.02 μg/g and from 0.096 to 0.565 μg/g in both matrices. The relatively high Hg concentrations found in bivalves from two stations in Bahia Samana, near to a known source of past Hg contamination in the sediments, require a more in-depth survey of the area. In general the concentrations of selected chlorinated hydrocarbons and trace metals, compared with those reported for the same matrices in the Caribbean and west Atlantic coastal areas, show at present the existence of only very localized contamination problems in the Dominican Republic.  相似文献   

Geodetic constraints on active tectonics of the Western Mediterranean: Implications for the kinematics and dynamics of the Nubia-Eurasia plate boundary zone     

Philippe Vernant  Abdelali Fadil  Taoufik Mourabit  Driss Ouazar  Achraf Koulali  Jose Martin Davila  Jorge Garate  Simon McClusky  Robert Reilinger 《Journal of Geodynamics》2010,49(3-4):123-129

We present GPS observations in Morocco and adjacent areas of Spain from 15 continuous (CGPS) and 31 survey-mode (SGPS) sites extending from the stable part of the Nubian plate to central Spain. We determine a robust velocity field for the W Mediterranean that we use to constrain models for the Iberia-Nubia plate boundary. South of the High Atlas Mountain system, GPS motions are consistent with Nubia plate motions from prior geodetic studies. We constrain shortening in the Atlas system to <1.5 mm/yr, 95% confidence level. North of the Atlas Mountains, the GPS velocities indicate Nubia motion with respect to Eurasia, but also a component of motion normal to the direction of Nubia-Eurasia motion, consisting of southward translation of the Rif Mountains in N Morocco at rates exceeding 5 mm/yr. This southward motion appears to be directly related to Miocene opening of the Alboran Sea. The Betic Mountain system north of the Alboran Sea is characterized by WNW motion with respect to Eurasia at ～1–2 mm/yr, paralleling Nubia-Eurasia relative motion. In addition, sites located in the Betics north of the southerly moving Rif Mountains also indicate a component of southerly motion with respect to Eurasia. We interpret this as indicating that deformation associated with Nubia-Eurasia plate motion extends into the southern Betics, but also that the Betic system may be affected by the same processes that are causing southward motion of the Rif Mountains south of the Alboran Sea. Kinematic modeling indicates that plate boundary geometries that include a boundary through the Straits of Gibraltar are most compatible with the component of motion in the direction of relative plate motion, but that two additional blocks (Alboran-Rif block, Betic Mountain block), independent of both Nubia and Eurasia are needed to account for the motions of the Rif and Betic Mountains normal to the direction of relative plate motion. We speculate that the southward motions of the Alboran-Rif and Betic blocks may be related to mantle flow, possibly induced by southward rollback of the subducted Nubian plate beneath the Alboran Sea and Rif Mountains.  相似文献   

Nocturnal isoprene declines in a semi-urban environment     

David Doughty  Jose D. Fuentes  Ricardo Sakai  Xiao-Ming Hu  Kevin Sanchez 《Journal of Atmospheric Chemistry》2015,72(3-4):215-234

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Centaurus A: VLT Views of the Nearest Giant Elliptical Galaxy     

Dante Minniti  Marina Rejkuba  Doug Geisler  Jose Gabriel Funes 《Astrophysics and Space Science》2004,290(3-4):363-377

VLT images in BVI are used to identify globular clusters in the central region of NGC5128. Based on the sizes, optical magnitudes and colors, a hundred candidate globular clusters are identified with projected galactocentric distances 1 kpc < R _G < 5 kpc. These clusters have magnitudes 18 < V < 20.5 or ?10.3 < M _V < ?7.8 at the distance of this galaxy, and colors 0.8 < V?I < 1.5 and 0.5 < B?V < 1.5. These identifications allow us to compare the properties of the X-ray globular cluster population discovered recently in this galaxy.  相似文献   

Horizontal soil stress changes around displacement piles     

Sayed M. Sayed  Jose L. M. Clemente 《国际地质力学数值与分析法杂志》1990,14(2):131-138

A simplified analysis of the problem of horizontal soil stress changes around circular displacement piles, caused by pile placement, is presented. Pile installation is assumed to cause soil displacements in the horizontal direction only, thus yielding an axisymmetric problem. The soil surrounding the pile is modelled as a weightless non-linear elastic material. Material non-linearity is handled in a simplified manner by adopting secant shear moduli defined in terms of a proportionality coefficient and a softening factor. The resulting equilibrium equation is solved analytically and an expression is obtained which is also conveniently presented in graphical form. The derived expression can be used to estimate horizontal soil stress changes and is incorporated into a simple procedure to estimate the ultimate load or the efficiency of pile groups. Comparisons are made between efficiencies calculated according to this procedure and efficiencies measured in full-scale group load tests in sand.  相似文献   

A multi-physics ensemble of present-day climate regional simulations over the Iberian Peninsula     

Sonia Jerez  Juan Pedro Montavez  Pedro Jimenez-Guerrero  Juan Jose Gomez-Navarro  Raquel Lorente-Plazas  Eduardo Zorita 《Climate Dynamics》2013,40(11-12):3023-3046

This work assesses the influence of the model physics in present-day regional climate simulations. It is based on a multi-phyiscs ensemble of 30-year long MM5 hindcasted simulations performed over a complex and climatically heterogeneous domain as the Iberian Peninsula. The ensemble consists of eight members that results from combining different parametrization schemes for modeling the Planetary Boundary Layer, the cumulus and the microphysics processes. The analysis is made at the seasonal time scale and focuses on mean values and interannual variability of temperature and precipitation. The objectives are (1) to evaluate and characterize differences among the simulations attributable to changes in the physical options of the regional model, and (2) to identify the most suitable parametrization schemes and understand the underlying mechanisms causing that some schemes perform better than others. The results confirm the paramount importance of the model physics, showing that the spread among the various simulations is of comparable magnitude to the spread obtained in similar multi-model ensembles. This suggests that most of the spread obtained in multi-model ensembles could be attributable to the different physical configurations employed in the various models. Second, we obtain that no single ensemble member outperforms the others in every situation. Nevertheless, some particular schemes display a better performance. On the one hand, the non-local MRF PBL scheme reduces the cold bias of the simulations throughout the year compared to the local Eta model. The reason is that the former simulates deeper mixing layers. On the other hand, the Grell parametrization scheme for cumulus produces smaller amount of precipitation in the summer season compared to the more complex Kain-Fritsch scheme by reducing the overestimation in the simulated frequency of the convective precipitation events. Consequently, the interannual variability of precipitation (temperature) diminishes (increases), which implies a better agreement with the observations in both cases. Although these features improve in general the accuracy of the simulations, controversial nuances are also highlighted.  相似文献   

Technologies and science archives for ultraviolet astronomy     

Noah Brosch  Martin Barstow  Jose Chirivella 《Astrophysics and Space Science》2014,354(1):125-141

This paper summarizes 17 talks presented during the Technological sessions at the “Challenges in UV Astronomy” conference. It is based on summaries submitted by the presenters, on the slides of their talks, on notes written by the authors, and on additional material kindly submitted to the lead author. In many instances the summaries were written by the presenters themselves and are included as-submitted to the authors with just minor editorial interference. In other cases one of the editors wrote the summary based on their notes and on the files of the actual presentations. The contributions are placed in the general context of the current knowledge in the field. The sessions were devoted to: [a] detectors, [b] optics, [c] integration and verification procedures for vacuum UV instruments and [d] calibration and archival research. A cautionary note: this is not a regular article in these proceedings presenting one idea, an experiment, of a result. It is rather a distillation of what was presented at the NUVA/ESO/IAG meeting at the sessions deemed technological, therefore it will lack an overall coherence although the individual sections and subsections should be logically connected.  相似文献   

Two-stage aquifer pumping subject to slow desorption and persistent sources     

Saez JA  Harmon TC 《Ground water》2006,44(2):244-255

This work focuses on improving pump-and-treat remediation by optimizing a two-stage operational scheme to reduce volumes extracted when confronted with nonequilibrium desorption, low-permeability units, and continuous contaminant sources such as non-aqueous phase liquids (NAPL). Q1 and Q2 are the initial short-term high pumping rate and later long-term low pumping rate, respectively. A two-dimensional ground water flow and transport management model was used to test the proposed strategy for plumes developed from finite (NAPL-free) and continuous (NAPL-driven) contaminant sources in homogeneous and nonhomogeneous (zoned) aquifers. Remediation scenarios were simulated over durations of 2000, 6000, and 15,000 d to determine (1) the optimal time to switch from a preset Q1 to Q2 and (2) the value of Q2. The problem was constrained by mass removal requirements, maximum allowable downgradient concentrations, and practical bounds on Q2. Q1 was fixed at preset values 50% to 200% higher than the single-stage pumping rates (i.e., steady pumping rates during entire remediation period) necessary to achieve a desired cleanup level and capture the plume. Results for the NAPL-free homogeneous case under nonequilibrium desorption conditions achieved the same level of cleanup as single-stage pumping, while reducing extracted volumes by up to 36%. Comparable savings were obtained with NAPL-driven sources only when the source concentration was reduced by at least 2 orders of magnitude. For the zoned aquifer, the proposed strategy provided volume savings of up to 24% under NAPL-free and reduced source conditions.  相似文献   

The middle Pleistocene transition: characteristics, mechanisms, and implications for long-term changes in atmospheric pCO₂   总被引：1，自引：0，他引：1  

Peter U. Clark  David Archer  David Pollard  Joel D. Blum  Jose A. Rial  Victor Brovkin  Alan C. Mix  Nicklas G. Pisias  Martin Roy 《Quaternary Science Reviews》2006,25(23-24):3150

The emergence of low-frequency, high-amplitude, quasi-periodic (100-kyr) glacial variability during the middle Pleistocene in the absence of any significant change in orbital forcing indicates a fundamental change internal to the climate system. This middle Pleistocene transition (MPT) began 1250 ka and was complete by 700 ka. Its onset was accompanied by decreases in sea surface temperatures (SSTs) in the North Atlantic and tropical-ocean upwelling regions and by an increase in African and Asian aridity and monsoonal intensity. During the MPT, long-term average ice volume gradually increased by 50 m sea-level equivalent, whereas low-frequency ice-volume variability experienced a 100-kyr lull centered on 1000 ka followed by its reappearance 900 ka, although as a broad band of power rather than a narrow, persistent 100-kyr cycle. Additional changes at 900 ka indicate this to be an important time during the MPT, beginning with an 80-kyr event of extreme SST cooling followed by the partial recovery and subsequent stabilization of long-term North Atlantic and tropical ocean SSTs, increasing Southern Ocean SST variability primarily associated with warmer interglacials, the loss of permanent subpolar sea-ice cover, and the emergence of low-frequency variability in Pacific SSTs and global deep-ocean circulation. Since 900 ka, ice sheets have been the only component of the climate system to exhibit consistent low-frequency variability. With the exception of a near-universal organization of low-frequency power associated with marine isotope stages 11 and 12, all other components show an inconsistent distribution of power in frequency-time space, suggesting a highly nonlinear system response to orbital and ice-sheet forcing.Most hypotheses for the origin of the MPT invoke a response to a long-term cooling, possibly induced by decreasing atmospheric pCO₂. None of these hypotheses, however, accounts for the geological constraint that the earliest Northern Hemisphere ice sheets covered a similar or larger area than those that followed the MPT. Given that the MPT was associated with an increase in ice volume, this constraint requires that post-MPT ice sheets were substantially thicker than pre-MPT ice sheets, indicating a change in subglacial conditions that influence ice dynamics. We review evidence in support of the hypothesis that such an increase in ice thickness occurred as crystalline Precambrian Shield bedrock became exposed by glacial erosion of a thick mantle of regolith. This exposure of a high-friction substrate caused thicker ice sheets, with an attendant change in their response to the orbital forcing. Marine carbon isotope data indicate a rapid transfer of organic carbon to inorganic carbon in the ocean system during the MPT. If this carbon came from terrigenous sources, an increase in atmospheric pCO₂ would be likely, which is inconsistent with evidence for widespread cooling, Apparently rapid carbon transfer from terrestrial sources is difficult to reconcile with gradual erosion of regolith. A more likely source of organic carbon and nutrients (which would mitigate pCO₂ rise) is from shelf and upper slope marine sediments, which were fully exposed for the first time in millions of years in response to thickening ice sheets and falling sealevels during the MPT. Modeling indicates that regolith erosion and resulting exposure of crystalline bedrock would cause an increase in long-term silicate weathering rates, in good agreement with marine Sr and Os isotopic records. We use a carbon cycle model to show that a post-MPT increase in silicate weathering rates would lower atmospheric pCO₂ by 7–12 ppm, suggesting that the attendant cooling may have been an important feedback in causing the MPT.  相似文献   

Future regional projections of extreme temperatures in Europe: a nonstationary seasonal approach     

Maria Dolores Frías  Roberto Mínguez  Jose Manuel Gutiérrez  Fernando J. Méndez 《Climatic change》2012,113(2):371-392

This paper analyzes changes of maximum temperatures in Europe, which are evaluated using two state-of-the-art regional climate models from the EU ENSEMBLES project. Extremes are expressed in terms of return values using a time-dependent generalized extreme value (GEV) model fitted to monthly maxima. Unlike the standard GEV method, this approach allows analyzing return periods at different time scales (monthly, seasonal, annual, etc). The study focuses on the end of the 20th century (1961?C2000), used as a calibration/validation period, and assesses the changes projected for the period 2061?C2100 considering the A1B emission scenario. The performance of the regional models is evaluated for each season of the calibration period against the high-resolution gridded E-OBS dataset, showing a similar South-North gradient with larger values over the Mediterranean basin. The inter-RCM changes in the bias pattern with respect to the E-OBS are larger than the bias resulting from a change in the boundary conditions from ERA-40 to ECHAM5 20c3m. The maximum temperature response to increased green house gases, as projected by the A1B scenario, is consistent for both RCMs. Under that scenario, results indicate that the increments for extremes (e.g. 40-year return values) will be two or three times higher than those for the mean seasonal temperatures, particularly during Spring and Summer in Southern Europe.  相似文献