Photochemical activation of chlorine by iron-oxide aerosol     

Julian?WittmerEmail author  Cornelius?ZetzschEmail author 《Journal of Atmospheric Chemistry》2017,74(2):187-204

The photochemical activation of chlorine by dissolved iron in artificial sea-salt aerosol droplets and by highly dispersed iron oxide (Fe₂O₃) aerosol particles (mainly hematite, specific surface ~150 m² g^?1) exposed to gaseous HCl, was investigated in humidified air in a Teflon simulation chamber. Employing the radical-clock technique, we quantified the production of gaseous atomic chlorine (Cl) from the irradiated aerosol. When the salt aerosol contained Fe₂O₃ at pH 6, no significant Cl production was observed, even if the dissolution of iron was forced by “weathering” (repeatedly freezing and thawing for five times). Adjusting the pH in the stock suspension to 2.6, 2.2, and 1.9 and equilibrating for one week resulted in a quantifiable amount of dissolved iron (0.03, 0.2, and 0.6 mmol L^?1, respectively) and in gaseous Cl production rates of ~1.6, 6, and 8?×?10²¹ atoms cm^?2 h^?1, respectively. In a further series of experiments, the pure Fe₂O₃ aerosol was exposed to various levels of gaseous hydrogen chloride (HCl). The resulting Cl production rates ranged from 8?×?10²⁰ Cl atoms cm^?2 h^?1 (at ~4 ppb HCl) to 5?×?10²² Cl atoms cm^?2 h^?1 (at ~350 ppb HCl) and confirmed the uptake and conversion of HCl to atomic Cl (at HCl to Cl conversion yields of 2–5 %, depending on the relative humidity). The Fe₂O₃ experiments indicate that iron-induced Cl formation may be important for highly soluble combustion-aerosol particles in marine environments in the presence of gaseous HCl.  相似文献   

Remote sensing and GIS based determination of groundwater dependent ecosystems in the Western Cape, South Africa   总被引：4，自引：0，他引：4  

Zahn Münch  Julian Conrad 《Hydrogeology Journal》2007,15(1):19-28

Finding the location of groundwater dependent ecosystems (GDEs) is important in determining the extent of restrictions that need to be placed upon the abstraction of groundwater. Remote sensing was combined with geographical information system (GIS) modelling to produce a GDE probability rating map for the Sandveld region, South Africa. Landsat TM imagery identified the areas indicating the probable presence of GDEs and GIS assisted in their delineation. Three GIS models were generated: a GIS model predicting landscape wetness potential (LWP model) based on terrain morphological features; the LWP model was modified to highlight groundwater generated landscape wetness potential (the resulting GglWP model); and a groundwater elevation model was interpolated, combining groundwater level measurements in boreholes in the region with digital elevation model data. Biomass indicators generated from Landsat were classified and combined with the GIS models, followed by field verification of riverine and wetland GDEs. The LWP model provided the most accurate results of the three models tested for GDEs in this region.

Zahn MünchEmail:

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A New Method of Significance Testing for Correlation-Coefficient Fields and Its Application     

Xiaojuan SUN  Siyan LI  Julian XL WANG  Panxing WANG  Dong GUO 《大气科学进展》2022,39(3):529-535

Correlation-coefficient fields are widely used in short-term climate prediction research. The most frequently used significance test method for the correlation-coefficient field was proposed by Livezey, in which the number of significantcorrelation lattice(station) points on the correlation coherence map is used as the statistic. However, the method is based on two assumptions:(1) the spatial distribution of the lattice(station) points is uniform;and(2) there is no correlation between the physical quantities in the correlation-coefficient field. However, in reality, the above two assumptions are not valid.Therefore, we designed a more reasonable method for significance testing of the correlation-coefficient field. Specifically, a new statistic, the significant-correlation area, is introduced to eliminate the inhomogeneity of the grid(station)-point distribution, and an empirical Monte Carlo method is employed to eliminate the spatial correlation of the matrix.Subsequently, the new significance test was used for simultaneous correlation-coefficient fields between intensities of the atmospheric activity center in the Northern Hemisphere and temperature/precipitation in China. The results show that the new method is more reasonable than the Livezey method.  相似文献   

Multimodal water age distributions and the challenge of complex hydrological landscapes     

Nicolas B. Rodriguez  Paolo Benettin  Julian Klaus 《水文研究》2020,34(12):2707-2724

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Iron and Pyritization in Wetland Soils of the Florida Coastal Everglades     

Paul Julian  Randy Chambers  Timothy Russell 《Estuaries and Coasts》2017,40(3):822-831

We explored environmental factors influencing soil pyrite formation within different wetland regions of Everglades National Park. Within the Shark River Slough (SRS) region, soils had higher organic matter (62.65 ± 1.88 %) and lower bulk density (0.19 ± 0.01 g cm^?3) than soils within Taylor Slough (TS; 14.35 ± 0.82 % and 0.45 ± 0.01 g cm^?3, respectively), Panhandle (Ph; 15.82 ± 1.37 % and 0.34 ± 0.009 g cm^?3, respectively), and Florida Bay (FB; 5.63 ± 0.19 % and 0.73 ± 0.02 g cm^?3, respectively) regions. Total reactive sulfide and extractable iron (Fe) generally were greatest in soils from the SRS region, and the degree of pyritization (DOP) was higher in soils from both SRS (0.62 ± 0.02) and FB (0.52 ± 0.03) regions relative to TS and Ph regions (0.30 ± 0.02 and 0.31 ± 0.02, respectively). Each region, however, had different potential limits to pyrite formation, with SRS being Fe and sulfide limited and FB being Fe and organic matter limited. Due to the calcium-rich soils of TS and Ph regions, DOP was relatively suppressed. Annual water flow volume was positively correlated with soil DOP. Soil DOP also varied in relation to distance from water management features and soil percent organic matter. We demonstrate the potential use of soil DOP as a proxy for soil oxidation state, thereby facilitating comparisons of wetland soils under different flooding regimes, e.g., spatially or between wet years versus dry years. Despite its low total abundance, Fe plays an important role in sulfur dynamics and other biogeochemical cycles that characterize wetland soils of the Florida coastal Everglades.  相似文献   

Between-Population Differences in Multi-stressor Tolerance During Embryo Development in the American Horseshoe Crab, <Emphasis Type="Italic">Limulus polyphemus</Emphasis>     

M. Christina Vasquez  H. Jane Brockmann  David Julian 《Estuaries and Coasts》2017,40(5):1487-1501

The American horseshoe crab, Limulus polyphemus, is found along the Atlantic and Gulf of Mexico coasts in genetically isolated populations. Eggs are laid in shoreline beaches that expose developing embryos to combinations of environmental stressors. Whether populations of L. polyphemus differ in multi-stressor tolerance had never been tested. We assessed the multi-stressor tolerance of L. polyphemus embryos from a population in Delaware Bay (DE) and determined whether these differed from the multi-stressor tolerance of embryos from a more southerly Florida Gulf Coast (FGC) population. We monitored the field sediment temperatures and determined multi-stressor tolerance of DE embryos, then compared these to published data for FGC embryos. For multi-stressor tolerance, we assessed development success of embryos in 2-week exposures to 36 full-factorial combinations of temperature (20, 25, 30, 35 °C), salinity (5, 15, and 34 ppt), and ambient O₂ (5, 13, and 21% O₂), followed by 2 weeks in recovery conditions. Sediment temperatures in the DE site ranged from 9.5 to 46 °C, with extended periods exceeding 35 °C. Development success was similar between the DE and FGC populations in 14 of 26 multi-stressor combinations. The DE embryos were generally more successful in conditions that included high temperature or moderate hyposalinity, whereas the FGC embryos were generally more successful in conditions that included extreme hyposalinity. This suggests that although multi-stressor tolerances are generally similar between the two populations, specific differences exist that correlate more with differences in nest microenvironment than latitude.  相似文献   

Reconstructing a prehistoric topography using legacy point data in a depositional environment          下载免费PDF全文

Julian A. M. Vermeer  Peter A. Finke  Ann Zwertvaegher  Vanessa Gelorini  Machteld Bats  Marc Antrop  Jacques Verniers  Philippe Crombé 《地球表面变化过程与地形》2014,39(5):632-645

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Empirical ground-motion models for point- and extended-source crustal earthquake scenarios in Europe and the Middle East   总被引：12，自引：9，他引：3  

S. Akkar  M. A. Sandıkkaya  J. J. Bommer 《Bulletin of Earthquake Engineering》2014,12(1):359-387

This article presents the latest generation of ground-motion models for the prediction of elastic response (pseudo-) spectral accelerations, as well as peak ground acceleration and velocity, derived using pan-European databases. The models present a number of novelties with respect to previous generations of models (Ambraseys et al. in Earthq Eng Struct Dyn 25:371–400, 1996, Bull Earthq Eng 3:1–53, 2005; Bommer et al. in Bull Earthq Eng 1:171–203, 2003; Akkar and Bommer in Seismol Res Lett 81:195–206, 2010), namely: inclusion of a nonlinear site amplification function that is a function of $\text{ V }_\mathrm{S30}$ and reference peak ground acceleration on rock; extension of the magnitude range of applicability of the model down to $\text{ M }_\mathrm{w}$ 4; extension of the distance range of applicability out to 200 km; extension to shorter and longer periods (down to 0.01 s and up to 4 s); and consistent models for both point-source (epicentral, $\text{ R }_\mathrm{epi}$ , and hypocentral distance, $\text{ R }_\mathrm{hyp}$ ) and finite-fault (distance to the surface projection of the rupture, $\text{ R }_\mathrm{JB}$ ) distance metrics. In addition, data from more than 1.5 times as many earthquakes, compared to previous pan-European models, have been used, leading to regressions based on approximately twice as many records in total. The metadata of these records have been carefully compiled and reappraised in recent European projects. These improvements lead to more robust ground-motion prediction equations than have previously been published for shallow (focal depths less than 30 km) crustal earthquakes in Europe and the Middle East. We conclude with suggestions for the application of the equations to seismic hazard assessments in Europe and the Middle East within a logic-tree framework to capture epistemic uncertainty.  相似文献   

High-Frequency Rayleigh-Wave Method     

Jianghai Xia  Richard D Millerg  Xu Yixian  Luo Yinhe  Chen Chao  Liu Jiangping  Julian Ivanov  Chong Zeng 《中国地质大学学报(英文版)》2009,20(3)

High-frequency (≥2 Hz) Rayleigh-wave data acquired with a multichannei recording sys-tem have been utilized to determine shear (S)-wave velocities in near-surface geophysics since the early 1980s. This overview article discusses the main research results of high-frequency surface-wave tech-niques achieved by research groups at the Kansas Geological Survey and China University of Geosciences in the last 15 years. The multichannel analysis of surface wave (MASW) method is a nou-iuvasive acoustic approach to estimate near-surface S-wave velocity. The differences between MASW results and direct borehole measurements are approximately 15% or less and random. Studies show that simultaneous inversion with higher modes and the fundamental mode can increase model resolution and an investigation depth. The other important seismic property, quality factor (Q), can also be estimated with the MASW method by inverting attenuation coefficients of Rayleigh waves. An inverted model (S-wave velocity or Q) obtained using a damped least-squares method can be assessed by an optimal damping vector in a vicinity of the inverted model determined by an objective function, which is the trace of a weighted sum of model-resolution and model-covariance matrices. Current developments include modeling high-frequency Rayleigh-waves in near-surface media, which builds a foundation for shallow seismic or Rayleigh-wave inversion in the time-offset domain; imaging dispersive energy with high resolution in the frequency-velocity domain and possibly with data in an arbitrary acquisition geometry, which opens a door for 3D surface-wave techniques; and successfully separating surface-wave modes, which provides a valuable tool to perform S-wave velocity profiling with high-horizontal resolution.  相似文献   

Regional Temperature Forecast for the Next Day in Hong Kong          下载免费PDF全文

LAM Hil  SHUM Karen Kit-ying  TANG Julian Shu-yan 《Acta Meteorologica Sinica》2011,25(6):725-733

For a century or so, the Hong Kong Observatory (HKO) has been providing temperature forecast for the whole of Hong Kong with the HKO Headquarters as the reference location. In recent decades, due to spreading of population from the main urban center to satellite towns, there is an increasing demand for regional temperature forecasts. To support such provision, the HKO has developed a regression model to provide objective guidance to forecasters in formulating forecasts of maximum and minimum temperatures for the next day at various locations in Hong Kong. In this paper, the regression model is presented, together with the assessment of its performance. Based on the verification of one year of forecasts, it is found that the root mean square errors (RMSEs) of maximum (minimum) temperature forecasts are from about 1.3 to 2.1 (1.1 to 1.4) degrees, respectively. The regression model is shown to have generally out-performed the operational regional spectral model then operated by HKO. Regional temperature forecast methods of other meteorological or research centers are also surveyed. Equipped with the regression model, the HKO has launched an online regional temperature forecast service for the next day in Hong Kong since March 2008.  相似文献