Monte Carlo simulation of mixing in Ca3Fe2Ge3O12–Ca4Ge4O12 garnets and implications for the thermodynamic stability of pyrope–majorite solid solution     

Victor L. Vinograd  Bjoern Winkler  Daniel J. Wilson  Andrew Putnis  Julian D. Gale 《Physics and Chemistry of Minerals》2006,33(8-9):533-544

Static lattice energy calculations, based on empirical pair potentials, were performed for a large set of structures differing in the arrangement of octahedral cations within the garnet 2 × 2 × 2 supercell. The compositions of these structures varied between Ca₃Fe₂Ge₃O₁₂ and Ca₄Ge₄O₁₂. The energies were cluster expanded using pair and quaternary terms. The derived ordering constants were used to constrain Monte Carlo simulations of temperature-dependent mixing properties in the ranges of 1,073–3,673 K and 0–10 GPa. The free energies of mixing were calculated using the method of thermodynamic integration. The calculations predict a wide miscibility gap between Fe-rich (cubic) and Fe-pure (tetragonal) garnets consistent with recent experimental observations of Iezzi et al. (Phys Chem Miner 32:197–207, 2005). It is shown that the miscibility gap arises due to a very strong cation ordering at the Fe-pure composition, driven by the charge difference between Ca²⁺ and Ge⁴⁺ cations. The structural and thermodynamic analogies between Ca–Ge and Mg–Si systems suggest that a similar miscibility gap should exist between pyrope and Mg–Si-majorite.  相似文献   

Mantle Convection in the Earth and Planets     

Julian  Lowman 《Geophysical Journal International》2002,150(3):827-827

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北极涛动和南极涛动的年变化特征   总被引：19，自引：2，他引：19       下载免费PDF全文

范丽军  李建平  韦志刚  董文杰  Julian Wang 《大气科学》2003,27(3):419-424

北极涛动(Arctic Oscillation,简称AO)和南极涛动(Antarctic Oscillation,简称AAO)分别用于描述北半球和南半球热带外气候变率的主要模态,它们分别是北半球和南半球中纬度和高纬度之间气压变化的跷跷板结构.作者利用1958年1月～1999年12月的NCEP/NCAR全球再分析月平均资料、北极涛动指数IAO和南极涛动指数IAAO来研究AO和AAO的年变化特征以及AO和AAO与纬向平均的月平均各要素场的相关系数随纬度和月份的变化规律.  相似文献   

Stabilization of Atmospheric Concentrations of Greenhouse Gases     

Jean Koch  Uri Dayan  Shmuel Amir 《Climatic change》2003,57(1-2):227-241

Given the present commitment of the developed countries according to the Kyoto Protocol, most published scenarios demonstrate that global greenhouse gases concentrations would not be stabilized at any level. In order to stabilize these concentrations, a deeper global involvement is needed. Taking Israel as an example of a `recently-developed' country, we assess the role that such countries could play by assuming voluntary commitments in strengthening global involvement. This case as a model may encourage a global scheme for curbing carbon emissions, in which the more developed countries assume a stronger role and the less developed countries participate according to the principle of common but differentiated responsibility. The scheme builds on the inverse relation that exists between the per capita gross domestic product and the rate of increase of emissions due to economic growth. According to this theoretical scheme, the voluntary commitments assumed by the `recently-developed' countries encourage the more developed countries to deepen their involvement by assuming more stringent reductions of emissions at home and transferring technological and financial means to the less developed countries. The proposed scheme would enable non-Annex I countries, both `recently-developed' countries and less developed countries, to participate much earlier in the net mitigation of greenhouse gases.  相似文献   

International greenhouse gas inventory systems: A comparison between CORINAIR and IPCC methodologies in the EU     

Julian E. Salt  Andrea Moran 《Global Environmental Change》1997,7(4):317-336

There are several different approaches currently taken by the 15 EU countries in compiling their IPCC inventories for the FCCC. Six countries (France, Ireland, Italy, Luxembourg, Portugal, Spain) use the CORINAIR system and then aggregate and reformat the data into the required IPCC format. Of the remaining countries, two strictly follow the IPCC methodology (Finland and Greece), five (Denmark, Germany, Netherlands, Sweden, United Kingdom) estimate emissions using a combination of national and IPCC methodologies, while the final two (Austria and Belgium) use a combination of national and CORINAIR methodologies (transformed to IPCC). Comparison of the national inventories in both the IPCC and CORINAIR formats shos some revealing discrepancies between the two systems at both sector and gas level that by chance cancel out when aggregated at the EU level.  相似文献   

Aspects of landslide activity in the Mercantour Massif and the French Riviera, southeastern France     

Maurice Julian  Edward Anthony   《Geomorphology》1996,15(3-4)

Landslides pose serious hazards in the Mercantour Massif and the French Riviera in southeastern France. The context for landslide development is a particularly favourable one, both in terms of the geomorphic and structural setting of this Alpine region, and of the climatic, hydrologic and seismic factors that trigger such failures. High mountain relief and steep slopes constitute a very favourable setting for failures affecting massive basement rocks and a very heterogeneous sedimentary cover whose resistance has been weakened by weathering, tectonic stresses, and cambering due to gravity. Among trigger factors, the important appears to be the precipitation regime. Rainfalls are commonly concentrated into short high-intensity downpours or into bursts of sustained falls over periods of several days, leading to soil saturation and lubrication of potential failure planes. Snowmelt also contributes to these lubrication processes. Earthquakes affecting this region are also a potentially important landslide trigger. However, while a lot of work has been done on the relationship between extreme climatic events and landslide activity, much less is known of the trigger effects of earthquakes.Both the background factors that promote landslide development and the factors that trigger such failures are discussed within a time frame of landslide development. Progressive changes in soil strength due to weathering, rock cambering and shattering processes lead to long-term reduction in resistance. Superimposed on these progressive changes are episodic triggerings related to rainfall and snowmelt episodes or earthquakes. Landslides may occur as shallow, low-volume “one-time” events or may be part of a progressive long-term failure. The former generally affect unconsolidated or clay-rich sedimentary rocks, especially on the coastal hillslopes of the French Riviera. A notable exception of a major, voluminous “one-time” event was the submarine landslide of the Var Delta in 1979. This landslide, like numerous other smaller subaerial landslides onland, was largely a result of human activities. This landslide occurred following extensive modification of the Var Delta and, notably, reclamation of the steep, fine-grained delta front. Deforestation, quarrying, urbanisation and road network developments are various ways in which human activity has destabilized the coastal hillslopes, favouring the development of numerous shallow landslides following each episode of heavy rainfall.Progressive landslides on the upper hillslopes of the Mercantour Massif have developed over long time spans (order of 10¹ to 10⁵ yrs) and have involved more complex interactions between lithological controls, slope characteristics and trigger factors. The Collelongue and Bois de Malbosc landslides have evolved into now stable failures buttressed by resistant migmatitic diorites or amphibolites. The more voluminous and well monitored Clapière landslide is a relatively simple rotational landslide of the toe-failure type. This active landslide poses a serious to inhabitants and infrastructure in the Tinée Valley. The importance of continued field monitoring, modelling and mapping of landslides and their hazards is emphasised.  相似文献   

Gaschromatographische Bestimmung von polychlorierten Biphenylen in Wasser nach Headspace-Festphasenmikroextraktion     

J. Koch  P. Vlker 《洁净——土壤、空气、水》1997,25(4):179-190

Gas-chromatographic Determination of Polychlorinated Biphenyls in Water after Headspace Solid-phase Microextraction Headspace-analytical techniques are usually applied to the determination of easily volatile substances in water, whereas semivolatiles are generally isolated by liquid-liquid or solid-phase extraction. In the present paper, a method is presented for isolating high boiling polychlorinated biphenyls (PCB) using headspace solid-phase microextraction at elevated temperature. In spite of their low vapor pressure, the analytes are adsorbed very efficiently on a poly-dimethylsiloxane-coated fiber. Thus, in combination with GC/ECD, a very simple and sensitive solventless determination of PCB is accomplished. Using the simplest possible standard conditions, limits of determination in the lowest nanogram-per-liter range are achieved. Further increased sensitivity down to the ppq (parts per quadrillion) range is possible by stirring and increasing the sample volume and adsorption time. Moderate matrix effects have been observed in some surface and groundwaters.  相似文献   

Carbon Sequestration, Soil Conservation, and the Kyoto Protocol: Summary of Implications   总被引：1，自引：0，他引：1  

Julian Dumanski 《Climatic change》2004,65(3):255-261

This paper discusses relationships between soil conservation, carbon sequestration, and the Kyoto Protocol. The Kyoto Protocol is the first attempt to use the flexibility of the global market place to stabilize and reduce GHG emissions, mitigate climate change, and promote sustainable development. The protocol emerged first as a framework agreement, but through international negotiations it is progressing into sets of legal articles. These impose obligations on all signatories, but they also identify opportunities for improved environmental land management at local, national and international levels. This is particularly true for soil conservation, where the sequestration of carbon above and below ground increases soil organic matter, enhances soil fertility, and improves production, while concomitantly reducing atmospheric CO₂. It is a classic `win-win' situation. Both the evolving opportunities and the obligations under the Kyoto Protocol are discussed in the paper.  相似文献   

'Just sustainability': the emerging discourse of environmental justice in Britain?   总被引：1，自引：0，他引：1  

Julian Agyeman  Bob Evans 《The Geographical journal》2004,170(2):155-164

Environmental justice is both a vocabulary for political opportunity, mobilization and action, and a policy principle to guide public decision making. It emerged initially in the US, and more recently in the UK, as a new vocabulary underpinning action by community organizations campaigning against environmental injustices. However, as the environmental justice discourse has matured, it has become increasingly evident that it should play a role in the wider agendas for sustainable development and social inclusion. The links between sustainability and environmental justice are becoming clearer and more widely understood in the UK by NGOs and government alike, and it is the potential synergy between these two discourses which is the focus of this paper. This paper argues that the concept of 'just sustainability' provides a discourse for policymakers and activists, which brings together the key dimensions of both environmental justice and sustainable development.  相似文献   

The effective number of cycles of earthquake ground motion     

Jonathan Hancock  Julian J. Bommer 《地震工程与结构动力学》2005,34(6):637-664

The seismic response of any system that accumulates damage under cyclic loading is dependent not only on the maximum amplitude of the motion but also its duration. This is explicitly recognized in methods for estimating the liquefaction potential of soil deposits. Many researchers have proposed that the effective number of cycles of the ground motion is a more robust indicator of the destructive capacity of the shaking than the duration. However, as is the case with strong‐motion duration, there is no universally accepted approach to determining the effective number of cycles of motion, and the different methods that have been proposed can give widely varying results for a particular accelerogram. Definitions of the effective number of cycles of motion are reviewed, classified and compared. Measurements are found to differ particularly for accelerograms with broad‐banded frequency content, which contain a significant number of non‐zero crossing peaks. The key seismological parameters influencing the number of cycles of motion and associated equations for predicting this quantity for future earthquakes are identified. Correlations between cycle counts and different duration measures are explored and found to be rather poor in the absence of additional parameters. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献