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71.
Arsenic in groundwater of the Red River floodplain, Vietnam: Controlling geochemical processes and reactive transport modeling 总被引:4,自引:0,他引:4
Dieke Postma Flemming Larsen Mai Thanh Duc Pham Quy Nhan 《Geochimica et cosmochimica acta》2007,71(21):5054-5071
The mobilization of arsenic (As) to the groundwater was studied in a shallow Holocene aquifer on the Red River flood plain near Hanoi, Vietnam. The groundwater chemistry was investigated in a transect of 100 piezometers. Results show an anoxic aquifer featuring organic carbon decomposition with redox zonation dominated by the reduction of Fe-oxides and methanogenesis. Enhanced PCO2 pressure causes carbonate dissolution to take place but mainly in the soil and unsaturated zone. The concentration of As increases over depth to a concentration of up to 550 μg/L. Most As is present as As(III) but some As(V) is always found. Arsenic correlates well with NH4, relating its release to organic matter decomposition and the source of As appears to be the Fe-oxides being reduced. Part of the produced Fe(II) is apparently reprecipitated as siderite containing less As. Results from sediment extraction indicate most As to be related to the Fe-oxide fractions. The measured amount of sorbed As is low. In agreement, speciation calculations for a Fe-oxide surface suggest As(III) to constitute only 3% of the surface sites while the remainder is occupied by carbonate and silica species. The evolution in water chemistry over depth is homogeneous and a reactive transport model was constructed to quantify the geochemical processes along the vertical groundwater flow component. A redox zonation model was constructed using the partial equilibrium approach with organic carbon degradation in the sediment as the only rate controlling parameter. Apart from the upper meter a constant degradation rate of 0.15 C mmol/L/yr could explain the redox zonation throughout the aquifer. Modeling also indicates that the Fe-oxide being reduced is of a stable type like goethite or hematite. Arsenic is contained in the Fe-oxides and is first released during their dissolution. Our model further suggests that part of the released As is adsorbed on the surface of the remaining Fe-oxides and in this way may be retarded. 相似文献
72.
73.
Short‐term flood inundation prediction using hydrologic‐hydraulic models forced with downscaled rainfall from global NWP 下载免费PDF全文
A short‐term flood inundation prediction model has been formulated based on the combination of the super‐tank model, forced with downscaled rainfall from a global numerical weather prediction model, and a one‐dimensional (1D) hydraulic model. Different statistical methods for downscaled rainfall have been explored, taking into account the availability of historical data. It has been found that the full implementation of a statistical downscaling model considering physically‐based corrections to the numerical weather prediction model output for rainfall prediction performs better compared with an altitudinal correction method. The integration of the super‐tank model into the 1D hydraulic model demonstrates a minimal requirement for the calibration of rainfall–runoff and flood propagation models. Updating the model with antecedent rainfall and regular forecast renewal has enhanced the model's capabilities as a result of the data assimilation processes of the runoff and numerical weather prediction models. The results show that the predicted water levels demonstrate acceptable agreement with those measured by stream gauges and comparable to those reproduced using the actual rainfall. Moreover, the predicted flood inundation depth and extent exhibit reasonably similar tendencies to those observed in the field. However, large uncertainties are observed in the prediction results in lower, flat portions of the river basin where the hydraulic conditions are not properly analysed by the 1D flood propagation model. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
74.
75.
利用Micaps资料、NCEP再分析资料和中山市紫马岭观测站的逐时整点能见度、气温、相对湿度、风等资料,对2012年2月29日—3月3日发生在中山市的一次平流雾天气过程进行分析,结果为:(1)该次大雾过程是在下垫面温度较低、温度露点差在1℃以下,相对湿度在90%~95%,风速较小等气象条件下形成的;(2)近地面层弱辐合、中低层弱辐散的散度场配置,低层暖湿平流的增湿作用,以及逆温层的存在均为大雾的形成和维持提供了有利条件;(3)冷空气势力减弱,地面开始增温导致逆温层破坏、水汽不饱和使能见度迅速回升,大雾天气结束。 相似文献
76.
Mobile in‐situ sensor platforms such as Unmanned Aerial Vehicles can be used in environmental monitoring. In time‐critical monitoring scenarios as for example in emergency response, and in the exploration of highly dynamic phenomena, obtaining the relevant data with one or few mobile sensors is challenging. It requires an intelligent sampling strategy that integrates prior information and adapts to the dynamics of the observed phenomenon, based on the collected sensor data. Available information about the observed phenomenon may be incomplete or imprecise and therefore insufficient for quantitative modeling. We address this problem by reasoning about the plume movement and size on a qualitative level and present an algorithm for tracking a dynamic plume that integrates this qualitative information with the collected sensor data. We evaluate our algorithm using simulated data sets of three different moving and expanding gas plumes. By means of simulations we show that the qualitative methods can be used to infer new information about the properties of a moving plume and to adapt the sensor movement for tracking the plume. Both can be done with low computational effort, without absolute positioning capability of the sensor, and with less input information than required by quantitative approaches. 相似文献
77.
An interdisciplinary approach is necessary for flood risk assessment. Questions are often raised about which factors should
be considered important in assessing the flood risk in an area and how to quantify these factors. This article defines and
quantitatively evaluates the flood risk factors that would affect the Day River Flood Diversion Area in the context of integrated
flood management in the Red River Delta, Vietnam. Expert analysis, in conjunction with field survey and Analytical Hierarchy
Process (AHP), is applied to define and quantify parameters (indicators, subcomponents, and components) that contribute to
flood risk. Flood duration is found to be the most prominent indicator in determining flood hazard. Residential buildings,
population, and pollution are other fairly significant indicators contributing to flood vulnerability from the economic, social,
and environmental perspectives, respectively. The study results will be useful in developing comprehensive flood risk maps
for policy-makers and responsible authorities. Besides, local residents will also be able to implement suitable measures for
reducing flood risk in the study area. 相似文献
78.
Activity and stability phases as well as geomorphic processes within the Critical Zone are well known. Erosion and deposition of sediments represent activity; soils represent geomorphic stability phases. Data are presented from a 4 m deep sediment section that was dated by luminescence techniques. Upslope erosion and resulting sedimentation started in the late Pleistocene around 18 ka until 12 ka. Conditions at the study site then changed, which led to the formation of a well-developed soil. Radiocarbon dating of the organic matter yielded ages between 8552 and 8995 cal. BP. From roughly 6.2 to 5.4 ka another activity phase accompanied by according sediment deposition buried the soil and a new soil, a Cambisol, was formed at the surface. The buried soil is a strongly developed Luvisol. The black colors in the upper part of the buried soil are not the result of pedogenic accumulation of normal organic matter within an A-horizon. Nuclear magnetic resonance spectroscopy clearly documents the high amount of aromatic components (charcoal), which is responsible for the dark color. This indicates severe burning events at the site and the smaller charcoal dust (black carbon) was transported to deeper parts of the profile during the process of clay translocation. 相似文献
79.
加蓬海岸盆地主要分为南加蓬次盆和北加蓬次盆,是典型的西非被动大陆边缘含盐盆地,盐岩的分布具有一定规律性和差异性,并且对盆地内油气成藏具有重要的控制作用。分析了加蓬海岸盆地的构造演化与沉积充填特征、基本石油地质条件、盐岩的分布特征及其对盆地烃源岩特征、储层分布、圈闭特征、封盖条件、油气成藏,以及油气藏储量等各方面的影响与控制作用,并指出,由于加蓬海岸盆地的绝大多数油气成藏都与盐岩密不可分,因此深化盆地内盐岩展布特征的研究,对进一步评价北加蓬次盆的盐下层系及南次盆登泰尔地堑的勘探潜力具有重要意义。 相似文献
80.
Du Duc Tien Thanh Ngo-Duc Hoang Thi Mai Chanh Kieu 《Meteorology and Atmospheric Physics》2013,122(1-2):55-64
This study examines the dependence of the tropical cyclone (TC) intensity errors on the track errors in the Weather Research and Forecasting (WRF-ARW) model. By using the National Centers for Environmental Prediction global final analysis as the initial and boundary conditions for cloud-resolving simulations of TC cases that have small track errors, it is found that the 2- and 3-day intensity errors in the North Atlantic basin can be reduced to 15 and 19 % when the track errors decrease to 55 and 76 %, respectively, whereas the 1-day intensity error shows no significant reduction despite more than 30 % decrease of the 1-day track error. For the North-Western Pacific basin, the percentage of intensity reduction is somewhat similar with the 2- and 3-day intensity errors improved by about 15 and 19 %, respectively. This suggests that future improvement of the TC track forecast skill in the WRF-ARW model will be beneficial to the intensity forecast. However, the substantially smaller percentages of intensity improvement than those of the track error improvement indicate that ambient environment tends to play a less important role in determining the TC intensity as compared to other factors related to the vortex initialization or physics representations in the WRF-ARW model. 相似文献