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71.
In this paper a novel series of field measurements are presented, which are the first to elucidate the processes influencing siltation in Botlek Harbour. Botlek Harbour is situated at the limit of saline water intrusion in the Rotterdam Waterway. Normally, after the ebb tide fresher river waters are found in the Rotterdam Waterway at the location of Botlek Harbour. On the flooding tide, the tip of the salt wedge is advected along the Rotterdam Waterway towards the mouth of Botlek Harbour. Hence on flood, a lock-exchange mechanism operates between Botlek Harbour and the Rotterdam Waterway. On the flood tide, when there is a supply of suspended particulate matter (SPM) associated with the presence of the estuarine turbidity maximum (ETM) at the mouth of the harbour, the survey data show exchange of SPM into the harbour. This lock-exchange process is found to be the dominant cause for SPM transport into the harbour. This is further substantiated by an analysis of the mass transport mechanisms. In this analysis, the vertical profiles of the instantaneous velocity, salinity and SPM concentration fields, recorded during the surveys, were decomposed into advective and dispersive transport components. The results of this analysis indicate that the correlation between the lock-exchange mechanism on the flood tide with the availability of SPM for exchange and efficient trapping, dominate the total exchange of SPM (97%). Hence, the increase in measured near-bed SPM concentration within the harbour is ascribed to tidal advection of saline water and the ETM along the Rotterdam Waterway. Tidal advection controls the density difference between the estuary and harbour, as well as the availability of SPM for exchange at the entrance to Botlek Harbour. The location of the ETM at the tip of the salt wedge is a key factor in supplying SPM to Botlek Harbour. Consequently the timing of the availability of SPM at the mouth of the harbour needs to be considered in siltation studies. The survey data suggest that Botlek Harbour basin has a 100% trapping efficiency. Analysis of 5 months of data, from a measuring rig located within the harbour, show excursions of the limit of the salt wedge and ETM. These excursions are likely to affect siltation of upstream harbours. Salinity-induced density gradients control the transport and subsequent trapping of SPM in the estuary in close proximity to the harbour entrance, the exchange of SPM between the estuary and harbour, and the trapping of SPM in the harbour basin.  相似文献   
72.
The coastal plain bordering the southern Venice Lagoon is a reclaimed lowland characterized by high subsidence rate, and ground level and water-table depth below sea level. In this agricultural region, where the surface hydrologic network is entirely artificially controlled by irrigation/drainage canals, salinization problems have long been encountered in soils and groundwaters. Here we use isotopic and geochemical tracers to improve our understanding of the origin of salinization and mineralization of the semi-confined aquifer (0–40 m), and the freshwater inputs to this hydrological system. Water samples have been collected at different seasons in the coastal Adriatic Sea, lagoon, rivers and irrigation canals, as well as in the semi-confined aquifer at depths between 12 and 35 m (14 boreholes), and in the first confined aquifer (three boreholes drilled between 40 and 80 m depth). Stable isotopes (δ18O and δD) and conductivity profiles show that direct saline intrusion from the sea or the lagoon is observed only in a restricted coastal strip, while brackish groundwaters are found over the entire topographic and piezometric depression in the centre of the study area. Fresh groundwaters are found only in the most western zone. The sharp isotopic contrast between the western and central regions suggests disconnected hydrological circulations between these two parts of the shallow aquifer. The border between these two regions also corresponds to the limits of the most strongly subsiding zone.Our results can be interpreted in terms of a four end-member mixing scheme, involving (1) marine water from the lagoon or the open sea, (2) alpine and pre-alpine regional recharge waters carried either by the main rivers Adige, Bacchiglione and Brenta (irrigation waters) or by the regional groundwater circulation, (3) local precipitation, and (4) evaporated waters infiltrated from the surface. Infiltration from the surface is also revealed by the stratification of the electrical conductivity profiles, showing that the brackish groundwaters are overlain by a shallow layer of less saline water all over the central depression. In the first confined aquifer, the groundwaters have isotopic compositions similar to the deep groundwaters of the Venetian confined aquifers (40–400 m depth). The isotopic data and the Br/Cl ratio show that the origin of the salinization of the phreatic aquifer can be ascribed to seawater intrusion alone, with no indication of the involvement of deep brines (identified at 450 m depth) in the process.The chemical composition of the saline and brackish groundwaters is characterized by an excess of sodium and a deficit of calcium compared to conservative mixing between fresh groundwaters and seawater. This suggests that the phreatic aquifer is progressively freshening, as a consequence of the beneficial influence of the extensive irrigation/drainage network, including raised canals acting as a hydraulic barrier along the coast. This freshening tendency may have been lasting since the reclamation in the mid-twentieth century, and has probably been accelerated by the ban on groundwater abstraction since the 1970s.  相似文献   
73.
The size and composition of microartifacts (objects less than 2 mm) and macroartifacts (objects greater than 2 mm) are utilized to interpret the formational processes of an archaeological site. Because grain-size distributions are known to reflect mode of transport and source, the attribute of size is examined by plotting each artifact class (unmodified rock, modified rock, ceramic, concretion, bone/shell, and metal) in size frequency diagrams. the plots allow the agent and mode of transport to be reconstructed, which in turn allows the formational processes of the site to be interpreted. the example used is the Pelts Site (23-DU-29) of southeastern Missouri. the site was chosen for this pilot study because the formation processes can be reconstructed from other data. the size distributions of each artifact class support those reconstructions and allow the proposed method to be evaluated as an interpretive method for other archaeological sites.  相似文献   
74.
The mineralogy and geochemistry of Ceres, as constrained by Dawn's instruments, are broadly consistent with a carbonaceous chondrite (CM/CI) bulk composition. Differences explainable by Ceres’s more advanced alteration include the formation of Mg‐rich serpentine and ammoniated clay; a greater proportion of carbonate and lesser organic matter; amounts of magnetite, sulfide, and carbon that could act as spectral darkening agents; and partial fractionation of water ice and silicates in the interior and regolith. Ceres is not spectrally unique, but is similar to a few other C‐class asteroids, which may also have suffered extensive alteration. All these bodies are among the largest carbonaceous chondrite asteroids, and they orbit in the same part of the Main Belt. Thus, the degree of alteration is apparently related to the size of the body. Although the ammonia now incorporated into clay likely condensed in the outer nebula, we cannot presently determine whether Ceres itself formed in the outer solar system and migrated inward or was assembled within the Main Belt, along with other carbonaceous chondrite bodies.  相似文献   
75.
Non-fishery use of artificial reefs has been given attention in recent years. The primary concern associated with non-fishery artificial reefs is their effects to the surrounding ecosystems. This study examined the infaunal communities around two non-fishery artificial reefs (the sunken vessels YO257 and Sea Tiger) in Mamala Bay, Hawaii. Infaunal community structures at these artificial reefs were relatively similar to one at a nearly natural patch reef. A large amount of basalt gravel around YO257 associated with its deployment operation possibly had an effect on the surrounding community by increasing pore space. Polychaete assemblages were compared with existing data throughout the bay, and this revealed that the variation in sediment grain sizes and depths seemed to play some role in structuring the polychaete communities. Nevertheless, the infaunal communities around the artificial reefs were typical and within the range of natural variation in Mamala Bay, supporting their beneficial uses in ecotourism.  相似文献   
76.
The Pleistocene ungulate communities from the western coastal plains of South Africa's Cape Floristic Region (CFR) are diverse and dominated by grazers, in contrast to the region's Holocene and historical faunas, which are relatively species-poor and dominated by small-bodied browsers and mixed feeders. An expansion of grassy habitats is clearly implied by the Pleistocene faunas, but the presence of ruminant grazers that cannot survive the summer dry season typical of the region today suggests other important paleoecological changes. Here we use dental ecometrics to explore the paleoecological implications of the region's Pleistocene faunas. We show that the dental traits (hypsodonty and occlusal topography) of the ungulates that occurred historically in the CFR track annual and summer aridity, and we use these relationships to reconstruct past aridity. Our results indicate that the Pleistocene faunas signal paleoenvironments that were on average less arid than today, including during the summer, consistent with other lines of evidence that suggest a higher water table and expansion of well-watered habitats. Greater water availability can be explained by lower temperature and reduced evapotranspiration during cooler phases of the Pleistocene, probably coupled with enhanced groundwater recharge due to increased winter precipitation.  相似文献   
77.
The relationship between climate change understanding and other variables, including risk perception, beliefs, and worldviews, is an important consideration as we work to increase public attention to climate change. Despite significant effort to develop rigorous mechanisms for measuring affective variables, measurement of climate change understanding is often relegated to unvalidated questions or question sets. To remedy this situation, we constructed and analyzed a climate change concept inventory using a suite of validity and reliability steps, including Rasch analysis. The resultant 21-item test has a high degree of validity and reliability for measuring understanding about basic climate change processes. Inventory scores along with other variables were included in a model of climate change risk perception, providing both concurrent validity for the test and new insight into the importance of understanding, worldview, and values on risk perception. We find that environmental beliefs and cultural cognition worldview play a larger role in predicting an individual’s risk perception than knowledge. Implications for addressing climate change are considered.  相似文献   
78.
Climate change is anticipated to influence all parts of agricultural production systems. However, the potential impacts on crop storage have rarely been assessed, even though storage is an important component of a grower’s marketing strategy and is essential for the continuous supply of a commodity for processors, exporters, and consumers. The Michigan chip-processing potato industry provides an example of the importance of crop storage. Michigan is the largest producer of chip-processing potatoes in the USA, and potatoes are stored on farms from September to June. We use an ensemble of climate projections developed for three future time slices (early, mid, and late century) from 16 climate models forced by three greenhouse gas concentration pathways to assess future changes in potato storage conditions. Our findings indicate an increased future demand for ventilation and/or refrigeration immediately after harvest and again in spring and early summer, even for the early-century time slice. Furthermore, the period of reliably cold storage temperatures during winter is anticipated, when averaged across all models, to shorten by 11–17 days in Michigan’s primary production area and 14–20 days in the more southern secondary area by mid-century, and by 15–29 days and 31–35 days, respectively, for the northern and southern production areas by late century. The level of uncertainty, as indicated by the ensemble range, is large, although the sign of the projected changes in storage parameters is consistent. This case study provides an example of the potentially large effects of climate change on the storage conditions for agricultural commodities.  相似文献   
79.
Clay-rich mine tailings from phosphate mine operations in Florida are a major environmental and economic problem. Options for reclamation and restoration for these tailings are very limited and are fundamentally restricted by poor physical properties such as low mechanical strength, low hydraulic conductivity, and heavy metal content. The major control on these bulk physical properties is the mineralogy of the materials. Eight continuous push borings were obtained to investigate stratigraphy, mineralogy, aspects of geochemistry, and bulk properties of a deposit of clay-rich mine tailings from a phosphate mine near Bartow, Florida that ceased operations in the early 1970s. Stratigraphy is dominated by laminated clay-rich sediment with minor units of silt and sand. An intact kaolinite liner occurs near the impoundment walls and the impoundment floor has approximately 4 m of relief. Moisture content varies from 4.35 to 57.40 wt% and organic content varies from 0.41 to 9.53 wt%. Bulk XRF investigation indicates that the P2O5 concentrations vary from approximately 4 to 21 wt%. A very strong correlation (r 2 = 0.92) between CaO and P2O5 indicates that apatite is a major control on the phosphate. The strong correlation (r 2 = 0.77) of Al2O3 and TiO2 suggests that the source materials for this deposit are comparatively uniform. A number of heavy metal elements and trace elements occur. Cr, V, Ni, Cu are interpreted to be in phosphate minerals, largely apatite. Sr and Pb are interpreted to be in both phyllosilicates and phosphate minerals. Two populations of apatite were observed in the clay-sized fraction, one that was Fe and Si- bearing and another that was only Si-bearing. Fe-bearing apatite had Fe2O3 contents that varied from 0.38 to 5.32 wt% and SiO2 contents that varied from 0.90 to 3.32 wt%. The other apatite population had a wider range of SiO2 contents that varied from 0.77 to 8.80 wt%. TEM imaging shows that apatite grains are dominantly single crystals with lesser amounts of aggregates. Wavellite commonly occurs as individual or clusters of lath-like crystals and the chemical composition differs from the pure aluminium phosphate end member with average concentrations of components being that of CaO (1.57 wt%), Fe2O3 (1.98 wt%), SiO2 (5.94 wt%). In the clay-sized phosphate minerals investigated no fluorine was found above detection limit (approximately 0.15 wt%), nor was any uranium, radium, heavy metal, or REE element detected. The phyllosilicate mineralogy of the deposit is dominated by smectite (montmorillonite with lesser amounts of nontronite), palygorskite, illite and kaolinite. No systematic variation in the relative proportions of phyllosilicates was observed in the clay deposit. Energy dispersive spectroscopy EDS analysis indicates that chemical compositions of phyllosilicates are somewhat typical but overall are enriched with respect to Fe compared to theoretical end members. The relative enrichment of Fe is interpreted to be a primary sedimentary feature. Ca content in smectite minerals is high and may inhibit stabilization using lime or similar methods. The high percentages of montmorillonite and palygorskite explain the high bulk water contents observed. This investigation provides fundamentally new details regarding clay tailing deposits from closed phosphate mines in central Florida which can be used in restoration and reclamation efforts.  相似文献   
80.
Rapid transport of anthropogenic lead through soils in southeast Missouri   总被引:1,自引:0,他引:1  
To investigate Pb transport and cycling, soils from the forest floor and cores from White Oaks (Quercus alba L.) were collected near a Pb smelter in SE Missouri at varying depths from the surface and varying distances. Lead concentrations in soil samples at the surface drop dramatically with distance from approximately 1500 mg/kg at less than 2 km from the smelter to around 100 mg/kg at localities greater than 2 km from the smelter. Lead contents in tree rings are below 0.5 mg/kg in samples dated prior to 1970, and rapidly increase in 1975–1990 samples. Isotopic compositions of soils and tree rings exhibit systematic variations of Pb isotopic compositions with depth and tree ring age. Distinguishable isotopic signatures for Pb sources allowed quantification of the contribution of smelter Pb to the soils. At depths where Pb concentrations decreased and approached constant values (10–25 cm, 10–30 mg/kg), 50–90%, 40–50% and 10–50% of the Pb could be derived from the smelter for the samples at locations less than 2, 2–4 and over 4 km from the smelter, respectively. The remaining portion was attributable to automobile emission and bedrock sources. Because the smelter operated from 1963 to 2003 and samples were collected in 1999, it is estimated that smelter Pb infiltrates at rates of 1 cm/yr (30 cm in 30 yr). At distances less than 1.5 km from the smelter, even though Pb concentrations become asymptotic at a depth of 30 cm, isotopic evidence suggests that Pb has migrated below this depth, presumably through exchange with naturally occurring Pb in the soil matrix. This implies that soils heavily polluted by Pb can exceed their Pb carrying capacity, which could have potential impacts on shallow groundwater systems and risk further exposure to human and ecological receptors.  相似文献   
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