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71.
We present the results of physical properties, petrography, bulk chemistry, mineral compositions, phase relations modelling and Noble gases study of the meteorite El Pozo. The petrography and mineral compositions indicate that the meteorite is an L5 chondrite with a low shock stage of S2-S3. Heterogenous weathering was preferentially along shock structures. Thermobarometric calculations indicate thermal equilibrium conditions between 768?°C and 925?°C at ~4 to 6?kb, which are substantially consistent with the petrological metamorphism type 5. A pseudosection phase diagram is relatively consistent with the mineral assemblage observed and PT conditions calculated. Temperature vs. fO2 diagram shows that plagioclase compositional stability is very sensitive to Tschermack substitution in orthopyroxene, clinopyroxene and XAn plagioclase during the high temperature metamorphic process. Based on noble gases He, Ne, Ar and K contents a cosmogenic exposure age CRE of 1.9?Myr was calculated. The 21Ne would be totally cosmogenic, with no primordial Ne. The 21Ne/22Ne value (0.97) is higher than solar value. According to the cosmogenic Ne content, we argue that El Pozo chondrite originally had a pre-atmospheric mass of 9–10?kg, which would have been produced by a later collision after the recognized collision of the L-chondrite parent body ~470?Ma ago.  相似文献   
72.

Spatially distributed values of the specific yield, a fundamental parameter for transient groundwater mass balance calculations, were obtained by means of three independent methods for the Crau plain, France. In contrast to its traditional use to assess recharge based on a given specific yield, the water-table fluctuation (WTF) method, applied using major recharging events, gave a first set of reference values. Then, large infiltration processes recorded by monitored boreholes and caused by major precipitation events were interpreted in terms of specific yield by means of a one-dimensional vertical numerical model solving Richards’ equations within the unsaturated zone. Finally, two gravity field campaigns, at low and high piezometric levels, were carried out to assess the groundwater mass variation and thus alternative specific yield values. The range obtained by the WTF method for this aquifer made of alluvial detrital material was 2.9– 26%, in line with the scarce data available so far. The average spatial value of specific yield by the WTF method (9.1%) is consistent with the aquifer scale value from the hydro-gravimetric approach. In this investigation, an estimate of the hitherto unknown spatial distribution of the specific yield over the Crau plain was obtained using the most reliable method (the WTF method). A groundwater mass balance calculation over the domain using this distribution yielded similar results to an independent quantification based on a stable isotope-mixing model. This agreement reinforces the relevance of such estimates, which can be used to build a more accurate transient hydrogeological model.

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73.
74.
In this work, we investigate the correlation between some magnetic parameters and the level of contamination by heavy metals in urban soils from Morelia city, western Mexico. The magnetic study was carried out on 98 urban soils samples belonging to distinct land uses. Most of analyzed samples contain ferrimagnetic minerals as the responsible for magnetization, most probably corresponding to the titanomagnetites/ titanomaghemites solid solutions. This is inferred from the susceptibility vs. temperature measurements and the isothermal remanent magnetization (IRM) experiments. These measurements also indicate that most of samples are almost completely saturated before 300 mT. Additionally, the S-200 values (S-200 = IRM-200/ SIRM, where IRM-200= Back-field of 200 mT after magnetic saturation) are between 0.7 and 1.0, characteristic of low coercivity magnetic minerals. The averaged saturation isothermal remanent magnetization (SIRM) curves can be used as an indicator of pollution level, as these curves show different saturation values according to the level of contamination by heavy metals: Cu, Ni, Cr and Sr. These associations of (titano)magnetite with heavy metals were observed by Scanning Electron Microscope revealing some complex aggregates rather than commonly detected spherules.  相似文献   
75.
A detailed characterization of the pore space is crucial for understanding of transport and element transfer in rocks. Here, the effect of differences in texture and content of secondary minerals on transport in pore systems was determined for two rocks of widespread occurrence, mid-ocean ridge basalts (MORB) and granites. Pore space characteristics were analyzed by Hg-porosimetry, intrusion of a molten alloy, and synchrotron-based X-ray tomographic microscopy. For evaluating the role of pore space characteristics for the prediction of diffusive transport, data on porosity, and the effective diffusion coefficient (D eff) were compared. Extended connective pore systems due to cracks and mineral dissolution are present in samples of both rocks, indicating high internal specific surface area. Uneven pore size distributions in altered MORB samples can be assigned to secondary minerals. Pore spaces determined by X-ray tomography, used to determine main direction of pores in the 3-D orthogonal system, suggest a slight anisotropy. In log–log plots, both rocks show roughly a linear dependence of D eff for H2O and compounds with comparable diffusivities (D2O, monovalent cations, and anions) on porosity, but at same porosity D eff is clearly higher in granitic than in basaltic samples. This difference is increasing with decreasing porosity, indicating that at low porosities the efficiency of element transport in basaltic samples is diminished, mainly inherited by the presence of small pores slowing down diffusion. The fact that diffusive transport in basaltic rocks is stronger dependent on porosity than in granitic rocks shows that also other rock characteristics such as pore size distribution and tortuosity of the pore network, highly affected by the alteration degree, can markedly affect transport and reactivity of pore solution.  相似文献   
76.
One way to reduce water consumption in urban areas is by using alternative sources of supply that can be provided by collecting rainwater and reusing wastewater for less restricted purposes. Thus, this study evaluated the characteristics of effluents produced by the wastewater treatment plant (WWTP) of São Paulo International Airport (SPIA), Brazil, in order to reuse it in non‐potable situations. The results achieved, indicated high efficiency in the biological system utilized by SPIA. The removal rates is equal to or >90% for most of the parameters analyzed, among them, fluoride, salinity, nitrite, nitrate, ammonium nitrogen, total nitrogen, phosphorus, sedimentable solids, turbidity, conductivity, apparent color, chemical oxygen demand, biochemical oxygen demand, total organic carbon, fecal coliforms, and oils and greases. Despite the final effluents were good enough to be launched in the local streams, they shall be submitted to a complementary treatment in order to fit some quality parameters to be reused for specific demands (landscape irrigation, toilet flushing, vehicle washing, fire fighting, and dust control).  相似文献   
77.
Organic matter is a fundamental factor in the biogeochemical cycle of carbon; it influences the chemical, physical, and biological properties of the soil. The aim of this paper is to determine the organic fractions in the three predominant morphologies of aggregates found in Typical Argiudolls of the Buenos Aires southeastern area and to link them to different soil uses, as possible indicators of soil quality. The study was carried out in the basin de Los Padres Pound (General Pueyrredón, Buenos Aires). We analyzed the first 5 cm of mollic epipedons of plots with different soil uses: (a) cultivated plots, (b) pine and eucalyptus forests, (c) pastures, and (d) a natural plot in the de Los Padres Pound Reserve as a reference. The percentage of soil organic carbon (SOC), light organic carbon (LOC), fulvic acids (FA), humic acids (HA), and humins (H) in elongated, quadrangular and spherical aggregates were determined. The results show slight variations in SOC (7.2–8.6%) in the spherical aggregates of all the plots and a greater variability in elongated and quadrangular aggregates (5.6–10% and 6.9–13.6%, respectively). HA are minimal in the agroecosystems with extreme values of 0.02% in the spherical aggregates of cultivated plots, and maximal in the elongated and quadrangular aggregates of natural plots (0.3–0.5%). Fulvic acids display a similar behavior, while H decrease slightly with the morphologies and the different practices. The substantial decrease of humic substances in cultivated plots translates into a lower biologic activity; this, in turn, influences the aggregation, thus lowering the structural stability of these plots, which have been under agro-horticultural management for more than 50 years.  相似文献   
78.
79.
High groundwater demand in the Great Metropolitan Area (GMA) of Costa Rica, combined with the presence of many septic systems, imposes the necessity to define adequate dimensions for setback distances or protection zones around wellheads to prevent contamination of aquifers by pathogenic organisms. Numerical 3-D simulations of transport of viruses under natural hydrogeological conditions of the northwest section of GMA were performed, considering both porous and fractured porous media with variable saturation. Based on the sensitivity analysis, principal transport parameters for the conditions in the study area are injection concentration, hydraulic conductivity, inactivation rate and attachment rate. Furthermore, a comparative analysis of the arrival of viruses to the water table and the modeling domain’s boundary was carried out using two approaches: maximum permissible concentration criteria and travel time criteria (TT) of 100 days frequently applied in Costa Rica for fractured rocks aquifers. The analysis indicates that under conditions of low mobility and high removal rates (typical for soils of volcanic origin), the TT approach overestimates the dimension of the protection zone. On the other hand, when conditions of high mobility and low removal rate are considered, the TT approach usually underestimates that dimension. It is recommended to perform more field and laboratory studies to obtain better representative parameters for soils of volcanic origin.  相似文献   
80.
In this research we evaluate the effects of the method used for estimating the potential surface available for benthic macroinvertebrates in macrophyte and unvegetated habitats on several metrics and habitat preference of aquatic macroinvertebrates in the upper catchment of the Henares River (Guadalajara, Central Spain). Three sampling sites were selected: a well-preserved stream (site A), a stream with no wood riparian vegetation (site B), and a straightened and deforested reach (site C). Two habitats were selected in each site: unvegetated habitat (i.e., substrata without macrophytes) and macrophyte habitat (i.e., substrata covered by macrophytes). In each habitat, six macroinvertebrate samples (including all macrophytes or mineral particles) were collected using a Hess sampler. Diversity and density of major families were referred to the surface of the Hess sampler (=Hess surface method) and to the actual surface of either mineral particles or macrophytes (=actual surface method). In general, for the actual surface method, biomass, richness, dominance, and diversity metrics were higher in the mineral habitat than in the macrophyte habitat. This trend was different for the Hess surface method. In general, densities turned out to be higher in the unvegetated habitat than in the macrophyte habitat when using the actual surface method, but the reverse occurred when using the Hess surface method. This fact is relevant for river biomonitoring, especially when reaches with different dominant substrates (macrophytes vs mineral) are compared using just one of the methods. It is concluded that the macrobenthic metrics and density values are influenced by the method used to estimate the potential available surface for aquatic macroinvertebrates.  相似文献   
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