How the Distribution of Anthropogenic Nitrogen Has Changed in Narragansett Bay (RI,USA) Following Major Reductions in Nutrient Loads     

Autumn Oczkowski  Courtney Schmidt  Emily Santos  Kenneth Miller  Alana Hanson  Donald Cobb  Jason Krumholz  Adam Pimenta  Leanna Heffner  Sandra Robinson  Joaquín Chaves  Rick McKinney 《Estuaries and Coasts》2018,41(8):2260-2276

Over the past decade, nitrogen (N) loads to Narragansett Bay have decreased by more than 50%. These reductions were, in large part, the direct result of multiple wastewater treatment facility upgrades to tertiary treatment, a process which employs N removal. Here, we document ecosystem response to the N reductions and assess how the distribution of sewage N in Narragansett Bay has changed from before, during, and shortly after the upgrades. While others have observed clear responses when data were considered annually, our seasonal and regional comparisons of pre- and post-tertiary treatment dissolved inorganic nitrogen (DIN) concentrations and Secchi depth data, from bay-wide surveys conducted periodically from the early 1970s through 2016, resulted in only a few subtle differences. Thus, we sought to use stable isotope data to assess how sewage N is incorporated into the ecology of the Bay and how its distribution may have changed after the upgrades. The nitrogen (δ¹⁵N) and carbon (δ¹³C) stable isotope measurements of particulate matter served as a proxy for phytoplankton, while macroalgae served as short-term integrators of water column bio-available N, and hard clams (Mercenaria mercenaria) as integrators of water column production. In contrast to other estuarine stable isotope studies that have observed an increased influence of isotopically lower marine N when sewage N is reduced, the opposite has occurred in Narragansett Bay. The tertiary treatment upgrades have increased the effluent δ¹⁵N values by at least 2‰. The plants and animals throughout Narragansett Bay have similarly increased by 1–2‰, on average. In contrast, the δ¹³C values measured in particulate matter and hard clams have declined by about the same amount. The δ¹⁵N results indicated that, even after the N reductions, sewage N still plays an important role in supporting primary and secondary production throughout the bay. However, the δ¹³C suggests that overall net production in Narragansett Bay has decreased. In the 5 years after the major wastewater treatment facilities came on-line for nutrient removal, oligotrophication has begun but sewage remains the dominant source of N to Narragansett Bay.  相似文献   

On the relationship between vegetation and climate in tropical and northern Africa     

Martin Schmidt  Doris Klein  Christopher Conrad  Stefan Dech  Heiko Paeth 《Theoretical and Applied Climatology》2014,115(1-2):341-353

Vegetation cover is a crucial component of the Earth’s climate system but, still, our understanding of the mechanisms governing the reciprocal influence between atmosphere and vegetation is limited. In this study, we investigate the unilateral atmospheric impact on vegetation cover in tropical and northern Africa, differentiated into regions with different circulation regimes and into detailed land-cover classes. In contrast to former studies, climate predictors from a regional climate model are used as input for a multiple regression model. Climate models provide consistent data without gaps at high spatial resolution, a considerably larger set of available climate variables and the perspective to transfer the statistical relationships to future projections, e.g., in the context of anthropogenic climate change. Indeed, robust climate predictors which drive up to 70 % of observed interannual vegetation variability could be extracted from the climate model. Besides precipitation and temperature, global radiation, and relative humidity play an important role. The statistical transfer functions are plausible in terms of the affected regions and land-cover classes and draw a rather complex picture of the atmosphere–vegetation relation in Africa.  相似文献   

Sunspots     

H. U. Schmidt 《地球物理与天体物理流体动力学》2013,107(1-4):249-270

Abstract

Some examples of research on structure and formation of sunspots are briefly recollected in historical sequence. They relate to many facets of sunspots, first: magnetic inhibition of convection, the conjecture of a fiat penumbra, the stratification beneath the umbra, the observable magnetic profile, the Evershed effect as syphon flow, the concept of a magnetopause; next: cooling by Alfven waves, evolution and stability, the “bright ring”, the observed change of umbra brightness with the phase of the sunspot cycle, the hypothetical cluster of separate flux strands underneath the umbra, the profile of the magnetopause, the structure of the penumbra and the inclination of its field and finally: the concept of a deep penumbra with volume currents, exchange convection and the concept of a second current sheet separating umbra and penumbra.

Of course, the rigorous theoretical modeling of local magnetoconvection is an essential tool for our understanding of all these processes. I do not deal with it here, but the reader has a fascinating review of magnetoconvection already in his hands (Weiss, 1991).  相似文献   

Erratum to: Nanoscale zero-valent iron flakes for groundwater treatment     

R. Köber  H. Hollert  G. Hornbruch  M. Jekel  A. Kamptner  N. Klaas  H. Maes  K.-M. Mangold  E. Martac  A. Matheis  H. Paar  A. Schäffer  H. Schell  A. Schiwy  K. R. Schmidt  T. J. Strutz  S. Thümmler  A. Tiehm  J. Braun 《Environmental Earth Sciences》2016,75(6):532

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Towards a Higher Comparability of Geothermometric Data obtained by Raman Spectroscopy of Carbonaceous Material. Part I: Evaluation of Biasing Factors   总被引：1，自引：0，他引：1  

Nils K. Lünsdorf  Istvan Dunkl  Burkhard C. Schmidt  Gerd Rantitsch  Hilmar von Eynatten 《Geostandards and Geoanalytical Research》2014,38(1):73-94

Raman spectroscopy of carbonaceous material (RSCM) is frequently used to determine metamorphic peak temperatures from the structural order of carbonaceous material enclosed in metasediments. This method provides a quick, robust and relatively cheap geothermometer. However, the comparability of the RSCM parameter is low as there are at least three major sources of biasing factors. These sources are the spectral curve‐fitting procedure, the sample characteristics itself and the experimental design including the used Raman system. To assess the impacts of the biasing factors on RSCM, a series of experiments was performed. The experiments showed that curve‐fitting is strongly influenced by individual operator‐bias and the degrees of freedom in the model, implying the need for a standardised curve‐fitting procedure. Due to the diversity of components (optics, light detection device, gratings, etc.) and their combinations within the Raman systems, different Raman instruments generally give differing results. Consequently, to estimate comparable metamorphic temperatures from RSCM data, every Raman instrument needs its own calibration. This demands a reference material series that covers the entire temperature calibration range. Although sample heterogeneity will still induce some variation, a reference material series combined with standardised curve‐fitting procedures will significantly increase the overall comparability of RSCM data from different laboratories.  相似文献   

Compositional mapping of planetary moons by mass spectrometry of dust ejecta     

Frank Postberg  Eberhard Grün  Mihaly Horanyi  Sascha Kempf  Harald Krüger  Jürgen Schmidt  Frank Spahn  Ralf Srama  Zoltan Sternovsky  Mario Trieloff 《Planetary and Space Science》2011,59(14):1815-1825

Classical methods to analyze the surface composition of atmosphereless planetary objects from an orbiter are IR and gamma ray spectroscopy and neutron backscatter measurements. The idea to analyze surface properties with an in-situ instrument has been proposed by Johnson et al. (1998). There, it was suggested to analyze Europa's thin atmosphere with an ion and neutral gas spectrometer. Since the atmospheric components are released by sputtering of the moon's surface, they provide a link to surface composition. Here we present an improved, complementary method to analyze rocky or icy dust particles as samples of planetary objects from which they were ejected. Such particles, generated by the ambient meteoroid bombardment that erodes the surface, are naturally present on all atmosphereless moons and planets. The planetary bodies are enshrouded in clouds of ballistic dust particles, which are characteristic samples of their surfaces. In situ mass spectroscopic analysis of these dust particles impacting onto a detector of an orbiting spacecraft reveals their composition. Recent instrumental developments and tests allow the chemical characterization of ice and dust particles encountered at speeds as low as 1 km/s and an accurate reconstruction of their trajectories. Depending on the sampling altitude, a dust trajectory sensor can trace back the origin of each analyzed grain with about 10 km accuracy at the surface. Since the detection rates are of the order of thousand per orbit, a spatially resolved mapping of the surface composition can be achieved. Certain bodies (e.g., Europa) with particularly dense dust clouds, could provide impact statistics that allow for compositional mapping even on single flybys. Dust impact velocities are in general sufficiently high at orbiters about planetary objects with a radius >1000 km and with only a thin or no atmosphere. In this work we focus on the scientific benefit of a dust spectrometer on a spacecraft orbiting Earth's Moon as well as Jupiter's Galilean satellites. This ‘dust spectrometer' approach provides key chemical and isotopic constraints for varying provinces or geological formations on the surfaces, leading to better understanding of the body's geological evolution.  相似文献   

Ra-partitioning between phlogopite and silicate melt and 226Ra/Ba–230Th/Ba isochrons     

Alessandro Fabbrizio  Max W. Schmidt  Detlef Günther  Jost Eikenberg 《Lithos》2010,114(1-2):121-131

In this study we experimentally determine phlogopite/melt partition coefficients of Ra and other trace elements in a lamproitic system. This work was achieved using an analytical technique (LA-ICP-MS) with low detection limits (~ 0.01 fg) permitting the measurement of the very low Ra concentrations feasible in experiments (~ 1 ppb). D_Ra^{phlogopite/melt} was determined to 2.28 ± 0.44 and 2.84 ± 0.47 in two experiments, the ratio D_Ra/D_Ba is around 1.6. The compatibility of Ra in phlogopite results from an ionic radius being close to the apex of the lattice strain parabola for earth alkalis in the large XII-coordinated interlayer site of phlogopite. A re-evaluation of D_Ra and D_Ra/D_Ba for magmatic minerals containing appreciable Ra, yields D_Ra^mineral/melt ranging from ~ 2.6 for phlogopite down to 2–3 ? 10^? 5 for pyroxenes, and D_Ra/D_Ba^mineral/melt from ~ 4 for leucite to 2 ? 10^? 2 for orthopyroxene. The influence of melt composition on D_Ra/D_Ba is less than 10%. All investigated minerals have different D_Ra/D_Ba, strongly fractionating Ra from Ba. Thus, for magmatic systems, (²²⁶Ra)/Ba in the various minerals is not constant, these minerals do not form a straight line in the (²²⁶Ra)/Ba–(²³⁰Th)/Ba system at the time of crystallization and thus, there is no (²²⁶Ra)/Ba–(²³⁰Th)/Ba isochron at t₀. ²²⁶Ra–²³⁰Th–Ba mineral dating is thus applicable only to model ages calculated from mineral–glass pairs with known D_Ra.  相似文献   

W. SPIESS: Erdnahe Raumstationen. Aufgaben,Entwurf, Kosten. Walter de Gruyter,Berlin, New York, 1973. — XI + 294 Seiten. Preis Ganzleinen DM 78.—.     

K.-H. Schmidt 《Astronomische Nachrichten》1975,296(1):47-47

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R. Jastrow,M. H. Thompsok : Astronomy: Fundamentals and Frontiers. (John Wiley & Sons,inc. New York,London, Sidney,Toronto 1973) XIX + 1-35 + 404 Seiten, 17 + 27.1 Abb., Preis £: 7.35     

K.-H. Schmidt 《Astronomische Nachrichten》1974,295(1):53-54

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Molecules in the Galactic Environment. Edited by M. A. Gordon and L. E. Snyder. John Wiley & Sons ltd., New York,London, Sydney,Toronto. 1973. XV + 475 pages. £ 9.50     

K.-H. Schmidt 《Astronomische Nachrichten》1974,295(5):241-242

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