The energetics and structure of the hydrogarnet defect in grossular: A computer simulation study   总被引：1，自引：0，他引：1  

Kate Wright  R. Freer  C. R. A. Catlow 《Physics and Chemistry of Minerals》1994,20(7):500-503

We have used computer simulation methods to model the structure and energetics of the hydrogarnet defect in grossular. The predicted structure is in good agreement with experimental data. The calculated energy for the reaction of water with grossular to form the hydrogarnet defect is 1.02 Ev (98 kJ mol^-1). This low energy of reaction suggests that such defects will be common in garnets where they could play an important role in effecting processes such as atomic transport.  相似文献   

Adapting to climate change: Public water supply in England and Wales   总被引：1，自引：0，他引：1  

Nigel W. Arnell  E. Kate Delaney 《Climatic change》2006,78(2-4):227-255

This paper describes an assessment of the ways in which water supply companies in England and Wales are adapting to climate change, evaluated in the context of a model of the adaptation process. The four components of the model are (i) awareness of and concern about the potential impacts of climate change, (ii) adaptation strategy, (iii) the concept of an adaptation space from which options are selected, and (iv) the notion that three groups of factors influence awareness, strategy and option selection: susceptibility to change, internal characteristics of the organisation, and regulatory and market context.Public water supply in England and Wales is provided by private sector companies, subject to environmental and economic regulation. Hydrological simulations suggest that climate change has the potential to reduce the reliability of supply sources over the next few decades. The industry in December 2004 completed a review of investment requirements over the next five years.Awareness of climate change is high in the water industry, but by developing assessment procedures and incorporating them into the investment review the regulators forced companies to consider explicitly the potential impacts of climate change in a consistent and rigorous manner. These analyses combined climate change with other pressures on water resources, and in practice companies did not attribute specific investment decisions or proposals to climate change or indeed any other individual drivers. The broad strategy adopted by all water supply companies – to maintain standards of service – is determined by regulatory controls and market considerations, but the degree of concern about the impacts of climate change and precise adaptation options necessary to address supply-demand imbalances varied between water supply companies, reflecting local geographic conditions. The water supply companies and regulators have different perspectives on the relative merits of supply-side and demand-side measures, reflecting different organisational priorities.The 2004 investment review determined that no specific actions were necessary to deal with future climate change, but that measures set in place – in terms of methodologies and investment in investigations into specific resource developments – provided a sound foundation for more specific actions in the next investment review in five years time. The paper concludes by summarising the factors assisting and constraining adaptation over the next few decades.  相似文献   

Detection of iodine monoxide radicals in the marine boundary layer using laser induced fluorescence spectroscopy     

Lisa K. Whalley  Kate L. Furneaux  Tom Gravestock  Helen M. Atkinson  Catherine S. E. Bale  Trevor Ingham  William J. Bloss  Dwayne E. Heard 《Journal of Atmospheric Chemistry》2007,58(1):19-39

A Laser Induced Fluorescence (LIF) instrument has been developed to detect iodine monoxide (IO) radicals in the atmosphere. An all solid-state Nd:YAG pumped Ti:Sapphire laser operating at approximately 445 nm was used to excite the (2,0) band of the IO A²Π_3/2 ← X²Π_3/2 electronic transition, with off-resonance fluorescence in the (2,5) band detected at 521 nm. The sensitivity of the instrument was determined by calibration. IO (between 10 and 150 pptV) was generated following the 184.9 nm photolysis of N₂O/CF₃I/N₂ mixtures with O₃ actinometry used to determine the photolysis flux. The detection limit was determined to be 0.3 pptV for a 300 s integration period, with an uncertainty of 23% (1σ). The instrument was deployed in August/September 2006 during the RHaMBLe (Reactive Halogens in the Marine Boundary Layer) campaign in Roscoff, France. Located on a small jetty, a few metres from the water’s edge at high tide, the instrument measured significant levels of IO on 11 days, with a maximum of 27.6 ± 3.2 pptV observed on one day (averaged over 10 s) representing the highest IO mixing ratio recorded in the marine boundary layer to date. IO displayed a clear diurnal profile with a maximum at low tide during the daytime. These results represent the first point measurements of IO in the atmosphere by LIF.  相似文献   

Development of a benthic index to assess sediment quality in the Tampa Bay Estuary   总被引：1，自引：0，他引：1  

Malloy KJ  Wade D  Janicki A  Grabe SA  Nijbroek R 《Marine pollution bulletin》2007,54(1):22-31

The identification, remedial treatment, and monitoring of contaminated sediments are among the priorities for managers of the Tampa Bay Estuary. Tampa Bay, as an urbanized estuary, is subject to the input of watershed sources of chemical contaminants, including metals, pesticides, and organic chemicals. Although the use of biological indicators and their incorporation into multi-metric indices is not new, the refinement and applications of such techniques for determining environmental condition still require further development and exploration. We present a single Tampa Bay Benthic Index (TBBI) that was developed specifically for Tampa Bay. Stepwise discriminant analysis was applied to a comprehensive list of potential benthic metrics. Results from the stepwise procedure identified the metrics that best discriminated between "healthy" and "degraded" conditions, as defined by sediment contaminant effect levels and dissolved oxygen. Discriminant analysis was then applied to the resultant three variables to determine the linear combination for the index.  相似文献   

Clumped isotope thermometry of carbonatites as an indicator of diagenetic alteration   总被引：2，自引：0，他引：2  

Kate J. Dennis  Daniel P. Schrag 《Geochimica et cosmochimica acta》2010,74(14):4110-7131

We measure the clumped isotopic signature of carbonatites to assess the integrity of the clumped isotope paleothermometer over long timescales (10⁷-10⁹ years) and the susceptibility of the proxy to closed system re-equilibration of isotopes during burial diagenesis. We find pristine carbonatites that have primary oxygen isotope signatures, along with a Carrara marble standard, do not record clumped isotope signatures lighter than 0.31‰ suggesting atoms of carbon and oxygen freely exchange within the carbonate lattice at temperatures above 250-300 °C. There is no systematic trend in the clumped isotope signature of pristine carbonatites with age, although partial re-equilibration to lower temperatures can occur if a carbonatite has been exposed to burial temperatures for long periods of time. We conclude that the solid-state re-ordering of carbon and oxygen atoms is sufficiently slow to enable the use of clumped isotope paleothermometry on timescales of 10⁸ years, but that diagenetic resetting can still occur, even without bulk recrystallization. In addition to the carbonatite data, an inorganic calibration of the clumped isotope paleothermometer for low temperature carbonates (7.5-77 °C) is presented and highlights the need for further inter-lab standardization.  相似文献   

“I’m an imaginary figure”: Unravelling the mobility and marginalisation of Scottish Gypsy Travellers     

Sergei Shubin  Kate Swanson 《Geoforum》2010,41(6):919-929

Gypsy Travellers have a long history of marginalisation in Scotland, but their mobility remains an issue of particular contention. Drawing upon a series of interviews with Gypsy Travellers in the North-East of Scotland, this paper uncovers how power and politics permeate discourses on movement to legitimise the spatial ordering of this traditionally nomadic group. The paper begins by exploring the more hidden and subtle aspects of mobility, such as the emotional and imaginative ties to travel. It then shifts to document how Gypsy Travellers’ geographies have been compromised by discriminatory policies and practices, which demonstrate a misunderstanding of the heterogeneity of their mobility. Consequently, increasingly punitive policies have pushed many Gypsy Travellers to abandon their travelling ways to move into “fixed” housing, while others have been forced into states of perpetual motion. The overall goal of the paper is to unravel the discursive constructions of movement in the context of institutionalised power and to document the spatial ordering of Gypsy Travellers’ lives, whose marginality has been legitimised by laws, ideologically sustained and reproduced in policy documents.  相似文献   

Lithological and geochemical record of mining-induced changes in sediments from Macquarie Harbour,southwest Tasmania,Australia     

Paul Augustinus  Charles E. Barton  Atun Zawadzki  Kate Harle 《Environmental Earth Sciences》2010,61(3):625-639

Macquarie Harbour in southwest Tasmania, Australia, has been affected severely by the establishment of mines in nearby Queenstown in the 1890s. As well as heavy metal-laden acid rock drainage from the Mount Lyell mine area, over 100 Mt of mine tailings and slag were discharged into the Queen and Ring Rivers, with an estimated 10 Mt of mine tailings building a delta of ca. 2.5 km² and ca. 10 Mt of fine tailings in the harbour beyond the delta. Coring of sediments throughout Macquarie Harbour indicated that mine tailings accreted most rapidly close to the King River delta source with a significant reduction in thickness of tailings and heavy metal contamination with increasing distance from the King River source. Close to the King River delta the mine tailings are readily discriminated from the background estuarine sediments on the basis of visual logging of the core (laminations, colour), sediment grain size, sediment magnetic susceptibility and elemental geochemistry, especially concentrations of the heavy metals Cu, Zn and Pb. The high heavy metal concentrations are demonstrated by the very high contamination factors (CF > 6) for Cu and Zn, with CF values mostly >50 for Cu for the mine-impacted sediments. Although the addition of mine waste into the King River catchment has ceased, the catchment continues to be a source of these heavy metals due to acid rock drainage and remobilisation of mine waste in storage in the river banks, river bed and delta. The addition of heavy metals to the harbour sourced from the Mount Lyell mines preceded the advent of direct tailings disposal into the Queen River in 1915 with the metals probably provided by acid rock drainage from the Mount Lyell mining area.  相似文献   

Ice caps existed throughout the Lateglacial Interstadial in northern Scotland     

Tom Bradwell  Derek Fabel  Martyn Stoker  Hannah Mathers  Lanny McHargue  John Howe 《第四纪科学杂志》2008,23(5):401-407

We constrain, in detail, fluctuations of two former ice caps in NW Scotland with multibeam seabed surveys, geomorphological mapping and cosmogenic ¹⁰Be isotope analyses. We map a continuous sequence of 40 recessional moraines stretching from ～10 km offshore to the Wester Ross mountains. Surface‐exposure ages from boulders on moraine ridges in Assynt and the Summer Isles region show that substantial, dynamic, ice caps existed in NW Scotland between 13 and 14 ka BP. We interpret this as strong evidence that large active glaciers probably survived throughout the Lateglacial Interstadial, and that during the Older Dryas period (ca. 14 ka BP) ice caps in NW Scotland were thicker and considerably more extensive than in the subsequent Younger Dryas Stadial. By inference, we suggest that Lateglacial ice‐cap oscillations in Scotland reflect the complex interplay between changing temperature and precipitation regimes during this climatically unstable period (ca. 15–11 ka BP). © Natural Environment Research Council (NERC) copyright 2008. Reproduced with the permission of NERC. Published by John Wiley & Sons, Ltd.  相似文献   

Submillimetre observations of z > 6 quasars     

Ian Robson  Robert S. Priddey  Kate G. Isaak  Richard G. McMahon 《Monthly notices of the Royal Astronomical Society》2004,351(2):L29-L33

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Water quality monitoring: a combined approach to investigate gradients of change in the Great Barrier Reef, Australia     

Udy J  Gall M  Longstaff B  Moore K  Roelfsema C  Spooner DR  Albert S 《Marine pollution bulletin》2005,51(1-4):224-238

For the managers of a region as large as the Great Barrier Reef, it is a challenge to develop a cost effective monitoring program, with appropriate temporal and spatial resolution to detect changes in water quality. The current study compares water quality data (phytoplankton abundance and water clarity) from remote sensing with field sampling (continuous underway profiles of water quality and fixed site sampling) at different spatial scales in the Great Barrier Reef north of Mackay (20 degrees S). Five transects (20-30 km long) were conducted from clean oceanic water to the turbid waters adjacent to the mainland. The different data sources demonstrated high correlations when compared on a similar spatial scale (18 fixed sites). However, each data source also contributed unique information that could not be obtained by the other techniques. A combination of remote sensing, underway sampling and fixed stations will deliver the best spatial and temporal monitoring of water quality in the Great Barrier Reef.  相似文献