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Katherine L. Pering 《Geochimica et cosmochimica acta》1973,37(3):401-417
A bitumen deposit in north Derbyshire, England, is described and studied using the techniques of gas chromatography, infra-red spectrophotometry and elemental analysis. The bitumens are associated with lead-zinc-fluorite ore minerals concentrated along an unconformable contact between the Carboniferous Limestone and the overlying shales. Three varieties of bitumen are distinguished and are compared with the dispersed bitumens in both the Carboniferous Limestone and the Edale Shales, with crude oils believed to be derived from these shales, and with inclusions in the hydrothermal mineral fiuorite, associated with the limestone-shale contact. One of the varieties recognized, a brittle brown solid, contains aliphatic hydrocarbons very similar to those of the shales and to those of the crude oils likely derived from these shales. The other two are a viscous oil and a brittle, black solid, which geologic evidence suggests were originally derived from the limestone. They contain a very complex mixture of aliphatic hydrocarbons quite different from those in the limestone, however. Aliphatic hydrocarbons isolated from fluorite, which is hydrothermally formed, in nearby massive deposits are almost identical to those of the limestone and shale. This observation indicates that alteration of the aliphatic hydrocarbons in the sediment by hydrothermal fluids is an unlikely explanation for the origin of the complex mixtures of hydrocarbons in the viscous oil and brittle, black solid. On the basis of indirect evidence of high nitrogen content, presence of unsaturated hydrocarbons, and suitability of the environment for bacterial growth, it is suggested that selective bacterial alteration of the aliphatic hydrocarbons is the main process responsible for their present composition. A geologic history for the deposit is postulated that involves a two-phase introduction of bitumens. Each phase is suggested to have begun as a pulse of warm saline fluids migrating along the shale-limestone unconformity passed through the topographic high at Windy Knoll. Microbial oxidation of the bitumens may have taken place during the deposition process or, more likely, as a recent secondary oxidation process. 相似文献
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Fast auroral waves have been recorded with an Image Intensifier-TV system and a new characteristic of this phenomenon has been revealed, namely, an abrupt transition from wave motion equatorwards to an E to W motion associated with an auroral band. For equatorward motion speeds ranged from 15 to 150 km/sec which is significantly lower than values previously reported. For the E to W motion speeds ranged from 20 to 90 km/sec. 相似文献
35.
Lam KK 《Marine pollution bulletin》2003,46(5):642-653
An experimental artificial reef was deployed in December 1993 at Hoi Ha Wan Marine Park, Hong Kong. This is the first study documenting natural scleractinian coral recruitment onto a stabilised pulverised fuel ash (PFA)-concrete artificial reef. Visible recruits were first recorded 9-10 months after the placement of reef blocks, i.e., in the autumn of 1994. Two scleractinians, Oulastrea crispata and Culicia japonica, were recruited. The recruit density of the former was much greater than the latter. The spatial recruitment pattern of the corals was observed to be affected by the orientation of the attaching surface. O. crispata settled predominantly on the undersides of the reef blocks. There was an edge effect on O. crispata recruitment. C. japonica, however, had a preference for exposed surfaces. O. crispata did not show a preference for block composition whereas C. japonica favoured blocks with high (75% by volume) PFA levels. This shows that PFA-concrete is a potential substratum for artificial reef construction, especially when such reefs aim at rehabilitating corals. 相似文献
36.
Richardson BJ Lam PK Zheng GJ McClellan KE De Luca-Abbott SB 《Marine pollution bulletin》2002,44(12):1372-1379
The outer layers of layflat, low density polyethylene plastic tubing (the principal component of semi-permeable membrane devices, SPMDs) were biofouled at a clean site in Hong Kong coastal waters for periods of 1–4 weeks. Following pre-fouling, triolein was added to the SPMDs and, along with control (unfouled) devices, they were exposed to a range of organochlorine pesticides (-HCH, aldrin, p,p′-DDT) and PAHs (anthracene, fluoranthene and benzo(a)pyrene) under laboratory conditions. Results showed that the uptake of contaminants by SPMDs was severely reduced by as much as 50% under fouling conditions in comparison to unfouled controls. The ultimate utility of SPMDs as passive monitors is thus reduced, although alternative measures, such as the use of permeability reference compounds may compensate, and allow for realistic evaluations of dissolved environmental concentrations in aquatic environments. However, due to the complexities involved in such procedures––especially as they need to be conducted on a case-by-case basis––the utility of SPMDs appears to be limited for estimates of bioavailability unless necessary calibrations are undertaken within each environment that the sampler is used. 相似文献
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Microbial ecology of the stratified water column of the Black Sea as revealed by a comprehensive biomarker study 总被引:2,自引:0,他引:2
Stuart G. Wakeham Rudi Amann Katherine H. Freeman Ellen C. Hopmans Bo Barker Jrgensen Isabell F. Putnam Stefan Schouten Jaap S. Sinninghe Damst Helen M. Talbot Dagmar Woebken 《Organic Geochemistry》2007,38(12):2070-2097
The stratified water column of the Black Sea is partitioned into oxic, suboxic, and euxinic zones, each characterized by different biogeochemical processes and by distinct microbial communities. In 2003, we collected particulate matter by large volume in situ filtration at the highest resolution to date for lipid biomarker analysis and bacterioplankton for enumeration of major prokaryotic groups. Abundances of several prokaryotic groups were estimated using CARD-FISH probes specific for Bacteria, Archaea (Crenarchaeota and Euryarchaeota), epsilonproteobacteria (mainly sulfide oxidizers) and sulfate reducing bacteria. We also measured a wide range of bacterial and archaeal lipid biomarkers. Depth distributions of diagnostic biomarkers are matched with zonation of microbial processes, including aerobic bacterial oxidation of methane, oxidation of ammonium by bacteria and archaea, metal reduction, and sulfide oxidation at the chemocline, and bacterial sulfate reduction and anaerobic oxidation of methane by archaea in the anoxic zone. Cell densities for archaea and sulfate reducing bacteria are estimated based on water column biomarker concentrations and compared with CARD-FISH results. 相似文献
40.
A cellular automata model of surface water flow 总被引:1,自引:0,他引:1
Previous cellular automata models of surface water flow have been constructed to reflect steady, gradually‐varied flow conditions. While these models are extremely important in showing the near‐equilibrium forms that result from the interactions of water and boundary material, highly dynamic forms and processes require models that represent unsteady flow conditions. In order to simulate unsteady flow in a cellular model of surface water flow, the conservation of mass and the Manning's equations are coupled with an algorithm to delay the movement of water from one pixel to the next until the correct timing is reached. This approach yields highly realistic flood wave hydrographs when compared with flood observations in the Walnut Gulch Experiment Watershed. Coupling this unsteady flow model with simple laws of sediment erosion, transport, and deposition should allow event‐based simulations of watershed and river channel geomorphologic change. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献