EDAPHIC PROPERTIES AND FOLIAR ELEMENTAL CONCENTRATIONS FROM SAND PINE (PINUS CLAUSA) POPULATIONS THROUGHOUT FLORIDA     

Juliana K. Evans  Albert J. Parker  Kathleen C. Parker  David S. Leigh 《自然地理学》2013,34(3):219-241

Soil physical and chemical properties, plus foliar elemental concentrations, are reported for surface (5–10 cm) and subsurface (35–40 cm) soil and foliar tissue samples from 20 sand pine (Pinus clausa) populations, 9 from the Choctawhatchee variety on the Florida panhandle and 11 from the Ocala variety on the Florida peninsula. Sand pine occurred exclusively on sandy soils, with mean sand content >97%. Soils generally were low in organic carbon and soil elemental concentrations. Both K and P were below analytic detection limits, whereas Ca and Mg were present at only modest levels. Only soil Al and Fe were relatively abundant. Foliar elemental concentrations indicated pronounced bioconcentration of nutrients by sand pine. Macronutrients (Ca, K, Mg, and P) approached or exceeded levels typical of other southern pine species. Some contrasts in edaphic and foliar tissue properties were apparent between varieties, but contrasts were more pronounced between groups of populations based on both soil color (yellow-sand group) and variety (Choctawhatchee white-sand and Ocala white-sand groups). The yellow-sand group, dominated by inland Choctawhatchee sites on sediments of mixed marine/fluvial origin, possessed less well sorted sand grains, higher clay content, lower pH, and higher levels of soil Al and Fe. The Choctawhatchee white-sand group consisted primarily of coastal dune sites, with well-sorted sands that reflect an eolian substrate. The Ocala white-sand group ranged primarily along the interior sand ridges of central Florida and was intermediate in sedimentological character. Foliar elemental concentrations did not reflect soil elemental patterns. Whereas Ocala samples were significantly higher in P and Mg, Choctawhatchee samples were higher in K, and there were no signficant varietal differences in foliar Ca. [Key words: sand pine, soil elemental concentrations, foliar elemental concentrations, Florida.]  相似文献   

SPATIAL PATTERNS AND CAUSES OF MARBLE TOMBSTONE WEATHERING IN WESTERN PENNSYLVANIA     

Kathleen V. Schreiber  Thomas C. Meierding 《自然地理学》2013,34(3):173-188

A 9600 km² area of southwestern Pennsylvania with widely varying amounts of historic industrial air pollution contains enough old cemeteries (135) to permit high-resolution mapping of Vermont marble tombstone weathering rates. Mean vertical-slab surface recession rates are as much as eight times greater for urban/industrial areas (maximum 3.0 mm [100 yr]^-1) than for rural areas (minimum 0.4 mm [100 yr]^-1). A damage function relates mean weathering rates to long-term numbers of employees in nearby polluting industries, and shows that even small industrial operations significantly augmented local rates of weathering within several kilometers. Marble stones near short-smokestack industries are significantly more weathered than are those near tall-smokestack, coal-fired electrical power plants. The comparatively high mean rate of marble weathering in small town cemeteries (1.1 mm [100 yr]^-1) suggests that recent acidic precipitation may be dissolving the stones throughout the study region or that pollution from home coal and oil furnaces was high. [Key words: marble tombstone, weathering, industrial air pollution, Pennsylvania.]  相似文献   

Identity-based change: a foundation for spatio-temporal knowledge representation     

Kathleen Hornsby  Max J. Egenhofer 《International journal of geographical information science》2013,27(3):207-224

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Sea-level history of the past two interglacial periods: new evidence from U-series dating of reef corals from south Florida     

Daniel R. Muhs  Kathleen R. Simmons  R. Randall Schumann  Robert B. Halley 《Quaternary Science Reviews》2011,30(5-6):570-590

As a future warm-climate analog, much attention has been directed to studies of the Last Interglacial period or marine isotope substage (MIS) 5.5, which occurred ～120,000 years ago. Nevertheless, there are still uncertainties with respect to its duration, warmth and magnitude of sea-level rise. Here we present new data from tectonically stable peninsular Florida and the Florida Keys that provide estimates of the timing and magnitude of sea-level rise during the Last Interglacial period. The Last Interglacial high sea stand in south Florida is recorded by the Key Largo Limestone, a fossil reef complex, and the Miami Limestone, an oolitic marine sediment. Thirty-five new, high-precision, uranium-series ages of fossil corals from the Key Largo Limestone indicate that sea level was significantly above present for at least 9000 years during the Last Interglacial period, and possibly longer. Ooids from the Miami Limestone show open-system histories with respect to U-series dating, but show a clear linear trend toward an age of ～120 ka, correlating this unit with the Last Interglacial corals of the Key Largo Limestone. Older fossil reefs at three localities in the Florida Keys have ages of ～200 ka and probably correlate to MIS 7. These reefs imply sea level near or slightly above present during the penultimate interglacial period. Elevation measurements of both the Key Largo Limestone and the Miami Limestone indicate that local (relative) sea level was at least 6.6 m, and possibly as much as 8.3 m higher than present during the Last Interglacial period.  相似文献   

Influence of groundwater and topography on stream drying in semi-arid headwater streams     

Sara R. Warix  Sarah E. Godsey  Kathleen A. Lohse  Rebecca L. Hale 《水文研究》2021,35(5):e14185

Non-perennial streams comprise over half of the global stream network and impact downstream water quality. Although aridity is a primary driver of stream drying globally, surface flow permanence varies spatially and temporally within many headwater streams, suggesting that these complex drying patterns may be driven by topographic and subsurface factors. Indeed, these factors affect shallow groundwater flows in perennial systems, but there has been only limited characterisation of shallow groundwater residence times and groundwater contributions to intermittent streams. Here, we asked how groundwater residence times, shallow groundwater contributions to streamflow, and topography interact to control stream drying in headwater streams. We evaluated this overarching question in eight semi-arid headwater catchments based on surface flow observations during the low-flow period, coupled with tracer-based groundwater residence times. For one headwater catchment, we analysed stream drying during the seasonal flow recession and rewetting period using a sensor network that was interspersed between groundwater monitoring locations, and linked drying patterns to groundwater inputs and topography. We found a poor relationship between groundwater residence times and flowing network extent (R² < 0.24). Although groundwater residence times indicated that old groundwater was present in all headwater streams, surface drying also occurred in each of them, suggesting old, deep flowpaths are insufficient to sustain surface flows. Indeed, the timing of stream drying at any given point typically coincided with a decrease in the contribution from near-surface sources and an increased relative contribution of groundwater to streamflow at that location, whereas the spatial pattern of drying within the stream network typically correlated with locations where groundwater inputs were most seasonally variable. Topographic metrics only explained ~30% of the variability in seasonal flow permanence, and surprisingly, we found no correlation with seasonal drying and down-valley subsurface storage area. Because we found complex spatial patterns, future studies should pair dense spatial observations of subsurface properties, such as hydraulic conductivity and transmissivity, to observations of seasonal flow permanence.  相似文献   

YREE sorption on hydrous ferric oxide in 0.5 M NaCl solutions: A model extension     

Johan Schijf  Kathleen S. Marshall 《Marine Chemistry》2011,123(1-4):32-43

Distribution coefficients, _iK_Fe, were measured for sorption of yttrium and the rare earth elements (YREEs) on hydrous ferric oxide (HFO) in 0.5 M NaCl solutions over the pH range 3.9–8.4 (T = 25 °C). An existing, non-electrostatic model [Quinn, K.A., Byrne, R.H., Schijf, J., 2006. Sorption of yttrium and rare earth elements by amorphous ferric hydroxide: influence of pH and ionic strength. Mar. Chem. 99, 128–150] was modified to account for sorption of YREE–chloride complexes, as well as YREE–hydroxide complexes at elevated pH. The extended model, which allows calculation of _iK_Fe as a function of [H⁺], contains two parameters, _SK₁ and _SK₂, to describe the equilibrium between positive, neutral, and negative forms of the hydroxyl functional groups on the HFO surface. In addition, it contains several composite, conditional stability constants, A_n, that represent YREE bonding to the neutral groups with release of n protons and/or to the negatively charged groups with release of n ? 1 protons.In 0.5 M NaCl solutions, YREE sorption on HFO is weaker and less pH dependent, yielding only 0.7–0.9 protons per YREE cation on average, vs. about 1.5 at low ionic strength. This is due to enhanced deprotonation of the HFO surface (_SK₁ ~ 0, p_SK₂ = 6.16), leading to an increase in the proportion of negatively charged groups, which release fewer protons per YREE cation sorbed. On a logarithmic scale, _iK_Fe is a nearly linear function of pH, except at pH > 8 where cumulative sorption of YREE–hydroxide complexes causes it to rise more rapidly, especially for the heavy REEs. Both our own data and prior results from the literature are well described by the extended model, using only three adjustable parameters, A₁–A₃. The constant A₃, representing YREE bonding to the negatively charged groups with release of two protons, shows an excellent linear free-energy relation when plotted against the first YREE hydrolysis constant, β₁*. There is no evidence for YREE bonding to the positively charged groups (i.e., A₀ = 0).  相似文献   

The effect of global warming on mortality     

Jean Calleja-Agius  Kathleen England  Neville Calleja 《Chemie der Erde / Geochemistry》2011

There is a significant relationship between ambient temperature and mortality. In healthy individuals with no underlying co-morbid conditions, there is an efficient heat regulation system which enables the body to effectively handle thermal stress. However, in vulnerable groups, especially in elderly over the age of 65 years, infants and individuals with co-morbid cardiovascular and/or respiratory conditions, there is a deficiency in thermoregulation. When temperatures exceed a certain limit, being cold winter spells or heat waves, there is an increase in the number of deaths. In particular, it has been shown that at temperatures above 27 °C, the daily mortality rate increases more rapidly per degree rise compared to when it drops below 27 °C.This is especially of relevance with the current emergency of global warming. Besides the direct effect of temperature rises on human health, global warming will have a negative impact on primary producers and livestock, leading to malnutrition, which will in turn lead to a myriad of health related issues. This is further exacerbated by environmental pollution.Public health measures that countries should follow should include not only health-related information strategies aiming to reduce the exposure to heat for vulnerable individuals and the community, but improved urban planning and reduction in energy consumption, among many others. This will reduce the carbon footprint and help avert global warming, thus reducing mortality.  相似文献   

On regional dynamical downscaling for the assessment and projection of temperature and precipitation extremes across Tasmania, Australia     

Christopher J. White  Kathleen L. McInnes  Robert P. Cechet  Stuart P. Corney  Michael R. Grose  Gregory K. Holz  Jack J. Katzfey  Nathaniel L. Bindoff 《Climate Dynamics》2013,41(11-12):3145-3165

The ability of an ensemble of six GCMs, downscaled to a 0.1° lat/lon grid using the Conformal Cubic Atmospheric Model over Tasmania, Australia, to simulate observed extreme temperature and precipitation climatologies and statewide trends is assessed for 1961–2009 using a suite of extreme indices. The downscaled simulations have high skill in reproducing extreme temperatures, with the majority of models reproducing the statewide averaged sign and magnitude of recent observed trends of increasing warm days and warm nights and decreasing frost days. The warm spell duration index is however underestimated, while variance is generally overrepresented in the extreme temperature range across most regions. The simulations show a lower level of skill in modelling the amplitude of the extreme precipitation indices such as very wet days, but simulate the observed spatial patterns and variability. In general, simulations of dry extreme precipitation indices are underestimated in dryer areas and wet extremes indices are underestimated in wetter areas. Using two SRES emissions scenarios, the simulations indicate a significant increase in warm nights compared to a slightly more moderate increase in warm days, and an increase in maximum 1- and 5-day precipitation intensities interspersed with longer consecutive dry spells across Tasmania during the twenty-first century.  相似文献   

Impacts of agricultural irrigation recharge on groundwater quality in a basalt aquifer system (Washington, USA): a multi-tracer approach   总被引：1，自引：0，他引：1  

Kyle B. Brown  Jennifer C. McIntosh  Laura K. Rademacher  Kathleen A. Lohse 《Hydrogeology Journal》2011,19(5):1039-1051

Irrigation in semi-arid agricultural regions can have profound effects on recharge rates and the quality of shallow groundwater. This study coupled stable isotopes (²??, ¹⁸O), age-tracers (³H, CFCs, ¹⁴C), ⁸⁷Sr/⁸⁶Sr ratios, and elemental chemistry to determine the sources, residence times, and flowpaths of groundwater and agricultural contaminants (e.g. NO ₃ ^?C ) in the Saddle Mountains Basalt Aquifer in central Washington, USA, where over 80% of the population depend on groundwater for domestic use. Results demonstrate the presence of two distinct types of water: contaminated irrigation water and pristine regional groundwater. Contaminated irrigation water has high NO ₃ ^?C concentrations (11?C116? mg/l), ⁸⁷Sr/⁸⁶Sr ratios (0.70659?C0.71078) within range of nitrogen-based fertilizers, detectable tritium (2.8?C13.4 TU), CFC ages 20?C40?years, high ??¹⁸O values (?16.9 to ?13.5??), and ??100 percent modern ¹⁴C. Pristine regional groundwater has low NO ₃ ^?C concentrations (1?C5? mg/l), no detectable tritium (??0.8 TU), low ??¹⁸O values (?18.9 to ?17.3??) and ¹⁴C ages from ??15 to 33?ky BP. Nitrogen and oxygen isotopes of NO ₃ ^?C , combined with high dissolved oxygen values, show that denitrification is not an important process in the organic-poor basalt aquifers resulting in transport of high NO ₃ ^?C irrigation water to depths greater than 40?m in less than 30? years.  相似文献   

Water supply and sanitation of Costa Rica     

Kathleen M. Bower 《Environmental Earth Sciences》2014,71(1):107-123

Costa Rica is a developing country whose citizens pride themselves on care for the environment. Environmental care is only slowly spreading to include safe and reliable water supplies. Plentiful water resources are used for energy production, industry, municipal water supply, and agriculture. The amount and quality of water resources must be understood and protected for future sustainable use. Based on interviews and conversations, some Costarricense are aware of the need for protection of natural water resources through preservation of forests; other steps toward sustainable water use are not universally valued. Streams are not the preferred source of domestic water supply due to potential water contamination; mostly from untreated sewage, sediment and agricultural chemicals. Quantity and quality of ground water supplies, the current main source of domestic water, are being investigated by scientists of Costa Rica. While 99 % of the population has access to a known supply of domestic water, only 82 % of the population has consistent access to potable drinking water. The potable water supply is smaller in rural areas. Three percent of sewage in Costa Rica is treated before release to the environment. The Río Tárcoles water basin, underlying the largest urban area of Costa Rica, is probably the most polluted in Central America. More is spent for treatment of water-borne diseases than on water supply and sewage treatment. Other potential sources of water contamination are examined.  相似文献