Geotechnical sealing material for coastal disposal facility for soils and wastes contaminated by radioactive cesium     

Takashi Tsuchida  Hiroki Murakami  Ooki Kurihara  A. M. R. G. Athapaththu  Yuichi Tanaka  Kazuhiko Ueno 《Marine Georesources & Geotechnology》2017,35(4):481-495

Safe disposal of wastes produced due to the process of decontamination in and around Fukushima No. 1 nuclear power plant is an urgent requirement. The purpose of this study was to develop a sealing material which can be used as an engineered barrier for a final disposal facility for the soils and wastes contaminated by radioactive cesium. The analyses conducted based on 4-m-thick sealing layer revealed that the hydraulic conductivity of the sealing material needs to be kept below 5.0?×?10^?10?m/s to avoid the seepage of contaminants below the environmentally safe limits. Sealing material was developed using marine clay–bentonite mixture and the engineering characteristics were examined. The results of laboratory experiments showed that, with the addition of bentonite, the hydraulic conductivity equal to or less than 5.0?×?10^?10?m/s was achieved when the effective consolidation stress is equal to or more than 27?kPa. From the tests for adsorption properties for cesium, it was found that the sealing material showed the significant capacity of adsorption for cesium in seawater. It was concluded that the construction of waste disposal facility on the sandy seafloor is feasible using the sealing layer proposed in this study.  相似文献   

Sealevel history recorded in the Pleistocene carbonate sequence in IODP Hole 310‐M0005D,off Tahiti     

Yasufumi Iryu  Yasunari Takahashi  Kazuhiko Fujita  Gilbert Camoin  Guy Cabioch  Hiroki Matsuda  Tokiyuki Sato  Kaoru Sugihara  Jody M. Webster  Hildegard Westphal 《Island Arc》2010,19(4):690-706

Material cored during the Integrated Ocean Drilling Program (IODP) Expedition 310 ‘Tahiti Sea Level’ revealed that the fossil reef systems around Tahiti are composed of two major stratigraphic sequences: (i) a last deglacial sequence; and (ii) an older Pleistocene sequence. The older Pleistocene carbonate sequence is composed of reef deposits associated with volcaniclastic sediments and was preserved in Hole 310‐M0005D drilled off Maraa. Within an approximately 70‐m‐thick older Pleistocene sequence (33.22–101.93 m below seafloor; 92.85–161.56 m below present sealevel) in this hole, 11 depositional units are defined by lithological changes, sedimentological features, and paleontological characteristics and are numbered sequentially from the top of the hole downward (Subunits P1–P11). Paleowater depths inferred from nongeniculate coralline algae, combined with those determined by using corals and larger foraminifers, suggest two major sealevel rises during the deposition of the older Pleistocene sequence. Of these, the second sealevel rise is associated with an intervening sealevel drop. It is likely that the second sealevel rise corresponds to that during Termination II (TII, the penultimate deglaciation, from Marine Isotope Stages 6 to 5e). Therefore, the intervening sealevel drop can be correlated with that known as the ‘sealevel reversal’ during TII. Because there are limited data on the Pleistocene reef systems in the tropical South Pacific Ocean, this study provides important information about Pleistocene sealevel history, the evolution of coral reef ecosystems, and the responses of coral reefs to Quaternary climate changes.  相似文献   

Tetrahedral occupancy of ferric iron in (Mg,Fe)O: Implications for point defects in the Earth's lower mantle     

Kazuhiko Otsuka  Catherine A. McCammon  Shun-ichiro Karato 《Physics of the Earth and Planetary Interiors》2010,180(3-4):179-188

We investigated the concentration and site occupation of ferric iron (Fe³⁺) in (Mg,Fe)O to understand the influence of point defects on transport properties such as atomic diffusion, electrical conductivity and viscosity. We conducted Mössbauer spectroscopy of (Mg_0.8Fe_0.2)O single crystals synthesized at temperatures from 1673 to 2273 K and pressures from 5 to 15 GPa with Re–ReO₂ and Mo–MoO₂ oxygen fugacity buffers. The isomer shift of the Mössbauer spectra suggests that Fe³⁺ occupies mostly the tetrahedral site at reduced conditions and both the octahedral and tetrahedral sites at oxidized conditions. We formulate a thermodynamic model of point defect dissolution in (Mg,Fe)O which suggests that unassociated tetrahedral Fe³⁺ is more stable than unassociated octahedral Fe³⁺ at high-pressure and low oxygen fugacity due to the effect of configurational entropy. The pressure dependence of Fe³⁺ concentration indicates a change in the dominant site occupancy of Fe³⁺: (1) Fe³⁺ in the tetrahedral site, (2) Fe³⁺ in the octahedral site, and (3) defect clusters of Fe³⁺ and cation vacancy, in the order of increasing oxygen fugacity and decreasing pressure. This is in reasonable agreement with previously reported experiments on Fe³⁺ concentration, Mg–Fe interdiffusivity and electrical conductivity. We consider it plausible that (Mg,Fe)O accommodates Fe³⁺ in the tetrahedral site down to the lower mantle. Based on our results and available experimental data, we discuss the solubility competition between Fe³⁺ and protons (H⁺), and its implications for transport properties in the lower mantle.  相似文献   

Chemical composition of Coscinodiscus wailesii and the implication for nutrient ratios in a coastal water, Seto Inland Sea, Japan     

Ono A  Tada K  Ichimi K 《Marine pollution bulletin》2008,57(1-5):94-102

Chemical compositions of Coscinodiscus wailesii were determined for four samples of natural cells. Results revealed that the cellular Si:N ratio of C. wailesii cell was 2.4:1.0-5.2:1.0. The impacts of C. wailesii on surrounding coastal water were evaluated from hydrographic observations, in which C. wailesii cell density, nutrients concentrations and temperature were monitored from November 2001 to February 2005 in Harima-Nada, the Seto Inland Sea, Japan. In low temperature periods, from October to December, two peaks of C. wailesii cell density were observed and nutrient concentrations were depleted. The draw-down ratio of Si(OH)(4) and DIN (Si(OH)(4):DIN ratio) in the water column were similar to the cellular Si:N ratio of C. wailesii cells, which have high Si contents. In addition the effects of different Si(OH)(4):DIN ratio were determined for in situ bottle incubation experiments. In the culture experiments, picoplankton (0.2-2.0 microm) which consisted of small flagellates became dominant under low Si(OH)(4):DIN ratios. These results suggested that the sizes distribution shifted to small size and the phytoplankton community was changed to small flagellates after the C. wailesii bloom. These changes would influence predators at higher trophic levels in its coastal ecosystem.  相似文献   

Control law for variable damping device defined by a non-linear differential equation     

Kazuhiko Yamada 《地震工程与结构动力学》1999,28(5):529-541

This paper proposes a non-linear control law for a variable damping device (VDD) aimed at reducing structural seismic responses. The VDD is attached to the structure by an auxiliary spring element composing a non-linear Maxwell element. The VDD's damping coefficient is adjusted to control the reactive internal force in the non-linear Maxwell element. A large controlled force is thus produced with little external power required to adjust the VDD's damping coefficient. The proposed control law defines the rate or increment of the VDD's damping coefficient at a certain moment by a differential equation or its discretized form. The controlled force vs. deformation relation plots parallelogram-like hysteretic curves, which indicates quick action and energy dissipation. Fundamental characteristics of an SDOF model with the VDD controlled by the proposed law are examined for impulse, sin and seismic excitations. The law for the SDOF model is extended to one for an MDOF model. The control effect for a 3DOF model is examined by numerical experiments. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

Depositional environments of well‐sorted detrital limestone from the Minatogawa Formation in the southern part of Okinawa Island,the Ryukyu Archipelago,Japan          下载免费PDF全文

Kazuhiko Fujita  Kayo Aruga  Marc Humblet  Koichi Nagai 《Island Arc》2018,27(3)

Well‐sorted detrital limestone is one of the typical lithofacies of the latest interval of the Pleistocene Ryukyu Group, which is exposed in the Ryukyu Archipelago in southwestern Japan. The depositional environments of the limestone are interpreted to be extremely shallow and to include back‐reef lagoons or moats and subaerial sand dunes. However, detailed micropaleontological analyses have not been performed on this limestone. In this study, the interpretation of the depositional environments and paleo‐water depths was improved by quantitative examination of foraminiferal assemblages for the well‐sorted detrital limestone of the Minatogawa Formation in the southern part of Okinawa Island. Thin sections of limestone collected from the Minatogawa (Horikawa) quarry were subjected to sedimentological and foraminiferal analyses. Comparison with modern foraminiferal distribution within the Ryukyu Archipelago indicates that back‐reef and fore‐reef dwelling foraminifers characterize the fossil assemblages from the well‐sorted detrital limestone (bioclastic grainstone). Three ratios of indicator foraminiferal taxa (ratios of back‐reef to fore‐reef taxa, planktonic foraminifers to Amphistegina lobifera and Amphistegina lessonii, and Calcarina gaudichaudii to other Calcarina species), as well as multivariate analyses suggest that the well‐sorted detrital limestone was deposited in fore‐reef setting shallower than 40 m in water depth. A comparable depth range was reconstructed from the coral assemblage in the associated coral limestone, suggesting that the Minatogawa Formation was deposited in a gently inclined ramp setting with patch reefs and/or fringing reefs. Stratigraphic changes in paleo‐water depth, together with evidence of several unconformities associated with paleosol layers suggest that there were repeated transgressions and regressions, with an amplitude up to several tens of meters, when the Minatogawa Formation was deposited.  相似文献   

Influence of non-photosynthetic pigments on light absorption and quantum yield of photosynthesis in the western equatorial Pacific and the Subarctic North Pacific     

Anil Kumar Vijayan  Takashi Yoshikawa  Shigeki Watanabe  Hiroaki Sasaki  Kazuhiko Matsumoto  Sei-Ichi Saito  Shigenobu Takeda  Ken Furuya 《Journal of Oceanography》2009,65(2):245-258

Regional variations in the contribution of non-photosynthetic pigments (ā _np^*) to the total light absorption of phytoplankton (ā _ph^*) and its influence on the maximum quantum yield of photosynthesis (φ _m) were investigated. In the western equatorial Pacific, the surface ā _np^* : ā _ph^* ratio was higher in the western warm pool than that in the upwelling region. This difference appears to be attributable to severe nitrate depletion and higher percentage of prokaryotes, which can accumulate very high concentrations of zeaxanthin in the western warm pool. In the subarctic North Pacific, the ā _np^* : ā _ph^* ratio was expected to be higher in the Alaskan Gyre where the thermocline is sharper and iron limitation may possibly be more severe than in the Western Subarctic Gyre. However, the ratio was actually higher in the Western Subarctic Gyre, contradictory to our expectations. This east-west variation appears to be attributable to changes in the taxonomic composition; cyanobacteria were more abundant in the Western Subarctic Gyre. The values of ā _np^* : ā _ph^* and its vertical variations were relatively small in the subarctic North Pacific compared to those in the western equatorial Pacific. These inter-regional variations appear to be attributable to the lower solar radiation intensity, smaller percentage of cyanobacteria, and relatively strong vertical mixing in the subarctic North Pacific. The spatial variations in ā _np^* : ā _ph^* significantly influence φ _m. In comparison with φ _m based on the total light absorption (φ _{m ph}), the values corrected for the contribution of non-photosynthetic pigments (φ _{m ps}) showed an increase in both the western equatorial Pacific and the subarctic North Pacific.  相似文献   

Evidence of microphytobenthic roles on coastal shallow water of the Seto Inland Sea,Japan   总被引：1，自引：0，他引：1  

Nattapong Loassachan  Kazuhiko Ichimi  Kuninao Tada 《Journal of Oceanography》2009,65(3):361-372

This study describes the temporal variation of microphytobenthic biomass and its controlling factors, as well as the impact of microphytobenthic activities on coastal shallow sediment in the eastern Seto Inland Sea, Japan. The chlorophyll a (Chl a), phaeopigments and sedimentary biophilic element (C, N, P and Si) contents in surface sediments, as well as nutrient concentrations at the sediment-water interface (overlying water and pore water) were observed monthly during November 2003 to May 2005 at one site in Shido Bay (water depth ca. 7 m) and at one site in Harima-Nada (35 m). No correlation was observed between the sedimentary biophilic elements and other parameters. The maximum chlorophyll a content of 48.2 μg g^–1 was found in surface sediments under the photon flux reaching the seafloor of 537 μmol photon m^–2 s^–1 during the winter period when water transparency was the highest at station S (Shido Bay). Our results suggest that higher chlorophyll a content in surface sediment was due to the fresh microphytobenthic biomass (mainly benthic diatom). We also found a significant negative correlation between Chl a and inorganic nutrients in pore water during the low temperature period, especially silicic acid. This result suggests that the silicic acid was assimilated largely during the increase of microphytobenthic biomass in surface sediment. This study suggests that the microphytobenthic roles may have a great effect on nutrient budgets during the large supply of irradiance (winter periods) for their photosynthetic growth in shallow coastal waters.  相似文献   

Species diversity of the genus <Emphasis Type="Italic">Skeletonema</Emphasis> (Bacillariophyceae) in the industrial harbor Dokai Bay,Japan     

Machiko Yamada  Eri Katsuki  Mayuko Otsubo  Mayumi Kawaguchi  Kazuhiko Ichimi  Hideki Kaeriyama  Kuninao Tada  Paul J. Harrison 《Journal of Oceanography》2010,66(6):755-771

Seven Skeletonema species were identified at one station in the industrial harbor Dokai Bay, Japan, in October 2007 and then monthly from January 2008 to December 2009 by morphological scanning electron microscopy observations and molecular analyses of mainly the large subunit (LSU) rDNA. We refer to one species identified as S. dohrnii using LSU rDNA, but as S. marinoi using the small subunit (SSU) rDNA and consequently we use the term S. marinoi-dohrnii complex. This is the first time that S. ardens, S. costatum s.s., and S. pseudocostatum have been recorded in Japan and that S. menzelii and S. tropicum have been identified by molecular methods in Japan. The S. marinoi-dohrnii complex was isolated with high frequency all year-round, and S. japonicum was also isolated with high frequency but not so in summer. S. Tropicum was isolated from September to December, but S. ardens and S. costatum s.s. were isolated only when the water temperature exceeded 20°C. S. pseudocostatum bloomed just once, in summer, but S. menzelii was isolated in May and again in October. The continuous year-round occurrence of S. costatum s.l. in the bay is supported by the succession of these seven species. Six of the species, except S. menzelii, were important components of algal blooms in the bay. One to four species of Skeletonema were isolated every month. Monthly species diversity was higher when S. ardens, S. costatum s.s., and S. tropicum that are usually associated with tropical or subtropical waters, were isolated. In general, species diversity of the genus Skeletonema was very high in Dokai Bay.  相似文献   

Multiple‐indicator study of groundwater flow and chemistry and the impacts of river and paddy water on groundwater in the alluvial fan of the Tedori River,Japan          下载免费PDF全文

Yumi Iwasaki Yoshioka  Kimihito Nakamura  Takanori Nakano  Haruhiko Horino  Ki‐Cheol Shin  Satoko Hashimoto  Shigeto Kawashima 《水文研究》2016,30(16):2804-2816

To investigate the source, flow paths, and chemistry of rich resources of high‐quality, shallow groundwater in the alluvial fan between the Tedori and Sai rivers in central Japan, we analysed stable isotope ratios of H, O, and Sr and concentrations of major dissolved ions and trace elements in groundwater, river water, and paddy water. The ⁸⁷Sr/⁸⁶Sr ratios of the groundwater are related to near‐surface geology: groundwater in sediment from the Tedori River has high ⁸⁷Sr/⁸⁶Sr ratios (>0.711), whereas that from the Sai River in the north of the fan has low ⁸⁷Sr/⁸⁶Sr ratios (<0.711). δ²H and δ¹⁸O values and ⁸⁷Sr/⁸⁶Sr ratios indicate that groundwater in the central and southern fans is recharged by the Tedori River, whereas recharge in the north is from the Sai River. Mg²⁺, Ca²⁺, Sr²⁺, HCO₃^?, and SO₄^2? concentrations and δ²H and δ¹⁸O values in the groundwater are high in the central fan and, except for the northern area, tend to increase with distance from the Tedori River. There are linear relationships between ⁸⁷Sr/⁸⁶Sr ratio and the reciprocal concentrations of Sr²⁺, Mg²⁺, and Ca²⁺. These geochemical characteristics suggest that as groundwater recharged from the Tedori River flows towards the central fan, it mixes with waters derived from precipitation and paddy water that have become enriched in these components during downward infiltration. These results are consistent with our hydrological analysis and numerical simulation of groundwater flow, thus verifying the validity of the model we used in our simulation of groundwater flow. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献