Spatial and temporal distribution of Fe, Ni, Cu and Pb along 140°E in the Southern Ocean during austral summer 2001/02     

Xiaodong Lai  Kazuhiro Norisuye  Michi Mikata  Tomoharu Minami  Andrew R. Bowie  Yoshiki Sohrin   《Marine Chemistry》2008,111(3-4):171-183

The distribution of dissolved (D) and acid-dissolvable (AD) Fe, Ni, Cu and Pb in the upper water column (0–300 m depth) was determined in the Australian sector of the Southern Ocean (140°E meridian) during three cruises conducted between November 2001 and March 2002. For Ni and Cu, there was no significant difference in concentration between dissolved and acid-dissolvable species. DNi and DCu showed significant (P = 0.01) positive correlations with silicate, phosphate and nitrate, reflecting their strong nutrient-type behaviour. For Fe and Pb, the acid-dissolvable concentration mostly exceeded the dissolved concentration, reflecting the importance of labile particulate species for these elements. DPb decreased between January and February in the Polar Frontal Zone and in Antarctic continental shelf water. ADPb maxima occurred in the Antarctic Zone, resulting in a maximum AD/D ratio of 7. The mean DFe concentration in the surface mixed layer was 0.3 nM in the sub-Antarctic zone, 0.4 nM in the Polar Frontal Zone, 0.5 nM in the Antarctic Zone and increased southward beyond the Antarctic Divergence and towards the continent. DFe did not show a clear temporal change in its horizontal distribution, which was in contrast to the other nutrients and trace metals. ADFe substantially increased in Antarctic continental shelf water where the AD/D ratio reached 11. The following conclusions can be drawn from these data. (1) Ni and Cu exist exclusively as dissolved species and their distributions are mainly controlled by their biogeochemical cycling, similar to those of the major nutrients. (2) Pb is dominated by particulate species. The distribution of DPb is temporally and spatially variable due to a sporadic source and strong scavenging. (3) DFe is rather a minor fraction of total Fe in Antarctic continental shelf water where shelf sediments and Antarctic sea-ice appear to be strong sources for Fe. There is substantial temporal variation in the supply of Fe to the upper water column. DFe in the mixed layer of the open Southern Ocean is maintained at low concentrations throughout summer due to uptake by phytoplankton and scavenging.  相似文献   

Upper Silurian and Devonian pelagic deep-water radiolarian chert from the Khangai–Khentei belt of Central Mongolia: Evidence for Middle Paleozoic subduction–accretion activity in the Central Asian Orogenic Belt     

Toshiyuki Kurihara  Kazuhiro Tsukada  Shigeru Otoh  Kenji Kashiwagi  Minjin Chuluun  Dorjsuren Byambadash  Bujinlkham Boijir  Sersmaa Gonchigdorj  Manchuk Nuramkhan  Masakazu Niwa  Tetsuya Tokiwa  Gen’ya Hikichi  Takafumi Kozuka 《Journal of Asian Earth Sciences》2009,34(2):209-225

Recent mapping projects undertaken in Central Mongolia have revealed the widespread occurrence of radiolarian chert within a Paleozoic accretionary complex. We present the results of the first detailed tectonostratigraphic and radiolarian biostratigraphic investigations of the Gorkhi Formation in the Khangai–Khentei belt of the Central Asian Orogenic Belt.The Gorkhi Formation consists of sandstone shale, alternating sandstone and shale of turbidite affinity and chert with small amounts of siliceous shale, basalt, limestone, and clast-bearing mudstone. Radiolarian chert that is completely devoid of terrigenous clastic material is commonly associated with underlying basalt (sedimentary contact) and with conformably overlying siliceous shale and turbidite deposits. The tectonic stacking of basalt–chert and chert–turbidite successions is the most remarkable structural feature of the formation.The recovery of moderately well-preserved radiolarians and conodonts from red chert led to the recognition of four radiolarian assemblages that have a combined age range from the latest Silurian (Pridolian) to the Late Devonian (Frasnian). No age control exists for the siliceous shale, shale, and sandstone, although they are considered to be latest Devonian or slightly younger on the basis of stratigraphic relationships with underlying chert.The Gorkhi Formation has previously been interpreted as a thick sedimentary basin deposit overlying an unexposed Archean–Neoproterozoic basement; however, the stratigraphy within individual tectonic slices clearly corresponds to that of an ocean plate stratigraphy of an accretionary complex generated by the trenchward movement of an oceanic plate. From the lowermost to uppermost units, the stratigraphy comprises ocean floor basalt, pelagic deep-water radiolarian chert, hemipelagic siliceous shale, and terrigenous turbidite deposits. The biostratigraphic data obtained in the present study provide corroborating evidence for the existence of an extensive deep-water ocean that enabled the continuous sedimentation of pelagic chert over a period of nearly 50 million years. These data, together with structural data characterized by tectonic repetition of the stratigraphy, indicate that these rocks formed as an accretionary wedge along an active continental margin, possibly that of the Angara Craton. The mid-oceanic chert was probably deposited in the Northern Hemisphere portion of the Paleo–Pacific Ocean that faced the Angara Craton and the North China–Tarim blocks. Thus, we propose that subduction–accretion processes along the Paleo–Pacific rim played an important role in the accretionary growth of the active continental margin of the Angara Craton, directly influencing the evolution of the Central Asian Orogenic Belt.  相似文献   

Erratum to: Stoichiometry among bioactive trace metals in seawater on the Bering Sea shelf     

Abigail Parcasio Cid  Syouhei Urushihara  Tomoharu Minami  Kazuhiro Norisuye  Yoshiki Sohrin 《Journal of Oceanography》2012,68(3):483-484

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Occurrence of water ponding on soil surfaces depending on infiltration rates on Mongolian rangeland          下载免费PDF全文

Katori Miyasaka  Sho Shiozawa  Kazuhiro Nishida  Siilegmaa Batsukh  Shuichiro Yoshida  Undarmaa Jamsran 《水文研究》2017,31(22):3996-4005

The occurrence of water ponding on soil surfaces during and after heavy rainfall produces surface run‐off or surface water accumulation in low‐lying areas, which might reduce the water supply to soils and result in a reduction of the soil water that plants can use, especially in arid climates. On Mongolian rangeland, we observed ponded water on the surface of a specific soil condition subjected to a heavy rainfall of 30 mm/hr. By contrast, ponded water was not observed for the same type of soil where livestock grazing had been removed for 6–8 years via a fence or for nearby soil containing less clay. We measured the infiltration rate (the saturated hydraulic conductivity of the surface soil, K_s) of the three sites by applying ponded water on the soil surface (an intake rate test). The results showed that K_s in the rangeland was lower than the rainfall intensity in the site where water ponded on the soil surface; however, K_s of the soil inside of the fence has recovered to 3 times that of the soil outside of the fence to exceed the rainfall intensity. Heavy rainfall that exceeds the infiltration rate occurs several times a year at the livestock grazing site where we observed ponded water. Slight water repellency of the soil reduces rain infiltration to increase the possibility of surface ponding for the soil.  相似文献   

Direct evidence for nitrogen isotope discrimination during sedimentation and early diagenesis in Lake Kasumigaura, Japan     

Ayato Kohzu  Akio ImaiToshihiro Miyajima  Takehiko FukushimaKazuo Matsushige  Kazuhiro KomatsuNobuyuki Kawasaki  Shingo MiuraTakayuki Sato 《Organic Geochemistry》2011,42(2):173-183

Sediment core samples from the center of Lake Kasumigaura, Japan, were collected from 1979 to 2007 at intervals of 1 month to 5 yr. We evaluated the degree of modification in N isotope composition during sedimentation and diagenesis. We estimated the degree of isotope discrimination during diagenesis by comparing historical changes in N isotope composition of the surface sediment (top 2 cm) against the vertical profile of the isotope composition of sediment core samples (15 cm depth). The degree of ¹⁵N enrichment during sedimentation appeared to be significant under the preferential N decomposition that occurred in the periods with low C/N ratio values of suspended particulate organic matter. We documented ¹⁵N depletion in sediment deeper than approximately 3 cm during diagenesis. The contrasting directions of N isotope discrimination during sedimentation and diagenesis suggest changing mechanisms of isotopic shift across an oxidation-reduction boundary.  相似文献   

Determination of reaction kinetics using grain size: An application for metamorphic zircon growth          下载免费PDF全文

Kazuhiro Miyazaki  Yasushi Mori  Tadao Nishiyama  Kenshi Suga  Miki Shigeno 《地学学报》2018,30(2):162-168

The reaction kinetics of metamorphic minerals can be subdivided into interface‐ and diffusion‐controlled kinetics. The discrimination of reaction kinetics is crucial for estimating reaction rates. Here, we propose a new and simple method for discriminating reaction kinetics. This method requires measuring only the initial and final grain sizes during growth. The reaction kinetics is inferred from different plotted arrays of initial vs. final grain sizes after the mineral growth. Using metamorphic zircon, we take detrital core sizes as the initial sizes and post‐metamorphic grain sizes as the final sizes. The application of the method to the subduction‐related high‐pressure Nagasaki metamorphic complex in Japan shows that this metamorphic zircon grew under interface‐controlled kinetics even at the relatively low temperature of 440°C. This method is potentially applicable to other minerals that have time‐markers, such as chemical zoning or internal structures that are captured at a given point in time during growth.  相似文献   

Radio imaging of the Subaru/XMM–Newton Deep Field – I. The 100-μJy catalogue, optical identifications, and the nature of the faint radio source population     

Chris Simpson  Alejo Martínez-Sansigre  Steve Rawlings  Rob Ivison  Masayuki Akiyama  Kazuhiro Sekiguchi  Tadafumi Takata  Yoshihiro Ueda  Mike Watson 《Monthly notices of the Royal Astronomical Society》2006,372(2):741-757

We describe deep radio imaging at 1.4 GHz of the 1.3-deg² Subaru/ XMM–Newton Deep Field (SXDF), made with the Very Large Array in B and C configurations. We present a radio map of the entire field, and a catalogue of 505 sources covering 0.8 deg² to a peak flux density limit of 100 μJy. Robust optical identifications are provided for 90 per cent of the sources, and suggested identifications are presented for all but 14 (of which seven are optically blank, and seven are close to bright contaminating objects). We show that the optical properties of the radio sources do not change with flux density, suggesting that active galactic nuclei (AGN) continue to contribute significantly at faint flux densities. We test this assertion by cross-correlating our radio catalogue with the X-ray source catalogue and conclude that radio-quiet AGN become a significant population at flux densities below 300 μJy, and may dominate the population responsible for the flattening of the radio source counts if a significant fraction of them are Compton-thick.  相似文献   

Field measurement and modeling of near-bed sediment transport processes with fluid mud layer in Tokyo Bay     

Nakagawa  Yasuyuki  Nadaoka  Kazuo  Yagi  Hiroshi  Ariji  Ryuichi  Yoneyama  Haruo  Shirai  Kazuhiro 《Ocean Dynamics》2012,62(10):1535-1544

Tokyo Bay is one of the estuaries in Japan with a high population of almost 26 million people in the basin area. One of the major concerns for the environment in this water area is the decreasing ecosystem functions including the deterioration of water and sediment qualities caused by various anthropogenic activities. Since the bottom sediments around almost the entire area of the inner bay consist of fine materials with a high organic content, which cause the deterioration of water quality through processes such as hypoxia, an understanding of the fine sediment dynamics in the Bay is crucial for an environmental assessment of the water area. This paper proposes a model for the key processes of fine sediment dynamics, which reflects field data about muddy bed structures and their dynamics obtained during the monitoring campaign in 2007. One of the specific features of the sediment in the Bay at present is the persistent existence of fluid mud layers (water content over 300 %) with a thickness of around a few decimeters, which might be caused by deposition of abundant organic particles due to eutrophication. The present study shows that diffusion flux model delivers quite reliable results for estimating erosion flux from the top of fluid mud layers after calibrating the model parameter against the time series data of vertical flux measured by an acoustic Doppler velocimeter system. This study also derives analytical solutions, based on the Bingham fluid concept, of advection flux in the fluid mud layer on which external shear stress force is applied.

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Long-term (36-year) observations on the dynamics of the fish-killing raphidophyte Chattonella in Harima-Nada,eastern Seto Inland Sea,Japan     

Tetsuya Nishikawa  Yutaka Hori  Satoshi Nagai  Kazutaka Miyahara  Yukinobu Nakamura  Kazuhiro Harada  Kuninao Tada  Ichiro Imai 《Journal of Oceanography》2014,70(2):153-164

Long-term changes of the fish-killing raphidophyte Chattonella spp. (Chattonella antiqua, Chattonella marina and Chattonella ovata) were examined in relation to environmental factors at 19 sampling stations in Harima-Nada, eastern Seto Inland Sea, Japan, for 36 years from 1973 to 2008. Long-term trends in the dynamics of Chattonella populations were considered to relate to environmental factors such as nutrient concentrations and water temperature. High nutrient levels during the period from the 1970s to the early 1980s have contributed to the high cell density and large-scale red tides of Chattonella spp. in Harima-Nada. However, nutrient levels exhibited a decreasing trend thereafter, and it is thought that Chattonella spp. cannot form large-scale blooms under the present conditions. After the mid-1990s, the occurrence period of vegetative cells of Chattonella spp. has been several weeks or 1 month earlier than that of the 1970s and early 1980s, and the appearance frequency of Chattonella spp. has increased in the northern coastal area, although the cell density and the spatial scale of the distribution have become lower and smaller than those in the previous decades. It is suggested that the timing of germination of Chattonella cysts has become earlier as a result of the increase in water temperature, and the chances of vegetative growth have also increased, especially at the northern coast where most of large rivers discharge into the Harima-Nada. In addition, the present results revealed that fewer diatoms were also one of the significant factors for the high abundance of Chattonella spp. in Harima-Nada.  相似文献   

Geological setting of basaltic rocks in an accretionary complex,Khangai–Khentei Belt,Mongolia     

Kazuhiro Tsukada  Yuki Nakane  Koshi Yamamoto  Toshiyuki Kurihara  Shigeru Otoh  Kenji Kashiwagi  Minjin Chuluun  Sersmaa Gonchigdorj  Manchuk Nuramkhaan  Masakazu Niwa  Tetsuya Tokiwa 《Island Arc》2013,22(2):227-241

We describe the mode of occurrence and geochemical characteristics of basalts, in the Khangai–Khentei belt in Mongolia, overlain by Middle Paleozoic radiolarian chert in an extensive accretionary complex. These basalts are greatly enriched in K, Ti, Fe, P, Rb, Ba, Th, and Nb in comparison to the composition of the mid‐ocean ridge basalts, indicative of within‐plate alkaline type. Ti/Y vs Nb/Y and MnO/TiO₂/P₂O₅ ratios of the basalts also suggest within‐plate affinities. Considering the geochemical characteristics as well as the conformable relationship with the overlying radiolarian chert, the alkaline basalts were clearly not continental but formed a pelagic oceanic island. The mode of occurrence and geochemistry of the basalts show that the alkaline basaltic volcanic activity had taken place to form an oceanic island in the Paleozoic pelagic region sufficiently far from continents to allow radiolarian ooze accumulation.  相似文献