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111.
112.
The size, shape, and magmatic history of the most recently discovered shield volcano in the Hawaiian Islands, Mahukona, have been controversial. Mahukona corresponds to what was thought to be a gap in the paired sequence (Loa and Kea trends) of younger Hawaiian volcanoes (<4?Ma). Here, we present the results of marine expeditions to Mahukona where new bathymetry, sidescan sonar, gravity data, and lava samples were collected to address these controversies. Modeling of bathymetric and gravity data indicate that Mahukona is one of the smallest Hawaiian volcanoes (~6,000?km3) and that its magmatic system was not focused in a long-lived central reservoir like most other Hawaiian volcanoes. This lack of a long-lived magmatic reservoir is reflected by the absence of a central residual gravity high and the random distribution of cones on Mahukona Volcano. Our reconstructed subsidence history for Mahukona suggests it grew to at least ~270?m below sea level but probably did not form an island. New 40Ar–39Ar plateau ages range from 350 to 654?ka providing temporal constraints for Mahukona’s post-shield and shield stages of volcanism, which ended prematurely. Mahukona post-shield lavas have high 3He/4He ratios (16–21?Ra), which have not been observed in post-shield lavas from other Hawaiian volcanoes. Lava compositions range widely at Mahukona, including Pb isotopic values that straddle the boundary between Kea and Loa sequences of volcanoes. The compositional diversity of Mahukona lavas may be related to its relatively small size (less extensive melting) and the absence of a central magma reservoir where magmas would have been homogenized.  相似文献   
113.
We reviewed joint inversion studies of the rupture processes of significant earthquakes, using the definition of a joint inversion in earthquake source imaging as a source inversion of multiple kinds of datasets (waveform, geodetic, or tsunami). Yoshida and Koketsu (Geophys J Int 103:355–362, 1990), and Wald and Heaton (Bull Seismol Soc Am 84:668–691, 1994) independently initiated joint inversion methods, finding that joint inversion provides more reliable rupture process models than single-dataset inversion, leading to an increase of joint inversion studies. A list of these studies was made using the finite-source rupture model database (Mai and Thingbaijam in Seismol Res Lett 85:1348–1357, 2014). Outstanding issues regarding joint inversion were also discussed.  相似文献   
114.
To identify water with an excess nitrate concentration to phosphate ratio and its potential source, the nutrient concentrations in the Tsushima Strait (TSS) were investigated over ten cruises in August and September 2007–2014, excluding 2010. On the basis of the Redfield ratio, water with an excess nitrate concentration of >1 μM (positive ExNOx water) was identified below the surface mixed layer during four cruises in 2011–2013. Positive ExNOx water was present mainly in less-saline (<34) waters with a density of 22–25 σ θ , and 25–75 m depth. However, in August 2012, positive ExNOx was detected in dense (25–25.5 σ θ ) and deep (50–110 m depth) waters near the salinity maximum, although the salinity during this period was significantly lower than that in other years. The horizontal length of positive ExNOx water was >100 km across the TSS during two cruises in August 2012 and September 2013, respectively. According to multi-regression analysis conducted on the silicate concentration, temperature, and salinity, the silicate concentration was increased in the less-saline subsurface water. The required amount of original freshwater was 108–9 m3 day?1 based on the excess nitrate concentration. This evidence indicates that the positive ExNOx water originated from large river waters such as the Changjiang. Thus, discharged water from the rivers of the East Asia is contributing to the increased N:P ratio in the Tsushima Warm Current, southern Japan Sea.  相似文献   
115.
Underground developments such as subways and shopping facilities have been increasing in number and magnitude in the relatively shallow subsurface of many urban areas where the earth materials commonly are composed of marine sediments. Marine sediments can contain significant amounts of toxic trace elements such as arsenic, boron, and lead. Changes in the subsurface environment caused by excavation and construction in underground developments could potentially cause these toxic elements to be dissolved into pore water of the sediments, which might lead to groundwater pollution. The purpose of this study is to investigate correlations among chemical properties of marine sediments, such as pH and electrical conductivity (EC), concentrations of toxic trace elements, and stratigraphic characteristics of the sediments. We selected three sites with different stratigraphic settings in the southern Kanto Plain around the Tokyo Metropolis. We collected core samples from shallow strata at a site in the Arakawa Lowland, southern Saitama, and at two sites in the Musashino Upland, Middle Tokyo. All sites have both marine and non-marine sediments up to 50–60 m in thickness. We determined trace element concentrations in the pore water, pH, EC, and loss on ignition. The results show that (1) the marine sediments tend to have low pH, high EC, and high sulfur concentration compared to the non-marine sediments (2) the concentration of most of the soluble heavy metals vary depending on the concentration of sulfate, the pH, and the formation processes of the strata, (3) the arsenic concentration is not related to sulfur concentration but apparently to Fe and Al concentrations, (4) the boron concentration is not related to any other properties implying that the boron level is independent of and cannot be predicted by common chemical properties, and (5) for all three sites, concentrations of most of the trace elements, EC, pH, and sulfate concentration were correlated with each other. This study shows that the concentration and potential mobilization of many toxic trace elements in marine sediments could be predicted by easily measurable pore water chemical properties such as pH and EC. This could be useful for predicting and avoiding the risk of groundwater pollution during underground development projects.  相似文献   
116.
The Miocene Kitami rhyolite, consisting of orthopyroxene and plagioclase-phyric lavas and dikes, occurs on the back-arc side of the Kuril arc with coeval basalts and Fe-rich andesites. Temperatures estimated from orthopyroxene–ilmenite pairs exceed 900°C. Although the whole rock compositions of the Kitami rhyolite correspond to S-type granites (i.e., high K, Al, large ion lithophile elements, and low Ca and Sr), Sr–Nd isotope compositions are remarkably primitive, and similar to those of the coeval basalts and andesites. They are distinct from those of lower crustal metamorphic rocks exposed in the area. Comparison of chondrite-normalized rare earth element (REE) patterns between the rhyolite and the basalts and andesites show that the rhyolite is more light REE enriched, but has similar heavy REE contents than the basalts. All rhyolites show negative Eu anomalies. The geochemical data suggest that did not formed by simple dehydration melting of basaltic rocks or fractional crystallization of basaltic magmas. The features of slab-derived fluids expected from recent high pressure experimental studies indicates that mantle wedge is partly metasomatized with “rhyolitic” materials from subducted slabs; it is more likely that very low degree partial melting of the metasomatized mantle wedge formed the rhyolite magma.  相似文献   
117.
Based on the in situ and temperature-quench X-ray measurements, the back transformation in the (Mg, Fe)2SiO4-spinels has been characterized in terms of the transformation temperature (T r ),mechanism and kinetics of the transformation, and of the end product(s), with specific emphasis on the effect of oxygen on this transformation. The in situ measurements were conducted to 900° C in vacuum (10-4 to 10-5 torr) and to 600° C in air using synchrotron radiation (SR) at Stanford Synchrotron Radiation Laboratory (SSRL). In the quench-type measurements, samples were heated in air to 1100° C, quenched and examined at ambient conditions using the conventional X-ray diffraction facilities. Important results are (1) in vacuum, all the spinels convert back into the olivine phase, with their T r decreasing with increasing iron content; (2) the spinel olivine back transformation is a nucleation and growth type of transformation and can be described quantitatively using the Avrami equation; (3) in air, the (Mg, Fe)2SiO4-spinels with 0.2 mole fraction Fe or more are all oxidized, and the composition and phase of the end products depend upon the temperature and the starting composition; and (4) the oxidation of the iron-rich (Mg, Fe)2SiO4-spinels in air occurs at 350–400° C, which is significantly lower than its T r ( 300° C) in vacuum.  相似文献   
118.
 A new and detailed bathymetric map of the Myojinsho shallow submarine volcano provides a framework to interpret the physical volcanology of its 1952–1953 eruption, especially how the silicic pyroclasts, both primary and reworked, enlarged the volcano and were dispersed into the surrounding marine environment. Myojinsho, 420 km south of Tokyo along the Izu–Ogasawara arc, was the site of approximately 1000 phreatomagmatic explosions during the 12.5-month eruption. These explosions shattered growing dacite domes, producing dense clasts that immediately sank into the sea; minor amounts of pumice floated on the sea surface after some of these events. The Myojinsho cone has slopes of almost precisely 21° in the depth range 300–700 m.We interpret this to be the result of angle-of-repose deposition of submarine pyroclastic gravity flows that traveled downslope in all directions. Many of these gravity flows resulted from explosions and associated dome collapse, but others were likely triggered by the remobilization of debris temporarily deposited on the summit and steep upper slopes of the cone. Tephra was repeatedly carried into air in subaerial eruption columns and fell into the sea within 1–2 km of the volcano's summit, entering water as deep as 400 m. Because the fall velocity of single particles decreased by a factor of ∼30 in passing from air into the sea, we expect that the upper part of the water column was repeatedly choked with hyperconcentrations of fallout tephra. Gravitational instabilities within these tephra-choked regions could have formed vertical density currents that descended at velocities greater than those of the individual particles they contained. Upon reaching the sea floor, many of these currents probably continued to move downslope along Myojinsho's submarine slopes. Fine tephra was elutriated from the rubbly summit of the volcano by upwelling plumes of heated seawater that persisted for the entire duration of the eruption. Ocean currents carried this tephra to distal areas, where it presumably forms a pyroclastic component of deep-sea sediment. Received: 5 December 1996 / Accepted: 17 September 1997  相似文献   
119.
Summary Stress concentration at the bottom of a borehole due to the corners with small radius of curvature in an axial section and its effect on the azimuth of breakout was studied. To this end, a 3-D finite element analysis was conducted and the stress around the borehole was examined for boreholes arbitrarily oriented to three principal axes of remote stress. Results show that, in the case of high strength rock, compressive failure resulting in spalling of a borehole may occur only at the bottom of the borehole. The spalling can occur continuously with drilling, and results in continuous spalling with depth, i.e., a breakout. This type of breakout tends to form on one side of the borehole and its orientation is approximately perpendicular to the orientation of standard breakouts, inferred from the stress concentration due to the cylindrical shape of the borehole.  相似文献   
120.
During surveillance on the toxicity of invertebrates such as bivalves inhabiting the coasts of Hiroshima Bay in 2001 and 2002, the carnivorous gastropod rapa whelk Rapana venosa collected in the estuary of Nikoh River, was found to contain toxins which showed paralytic actions in mice; the maximum toxicities (as paralytic shellfish poison, PSP) were 4.2 MU/g (May 2001) and 11.4 MU/g (April 2002). Their total toxicities were 224 and 206 MU/viscera of one specimen throughout the monitoring period. Attempts were made to identify the toxic principle in the gastropod. The viscera were extracted with 80% ethanol acidified with acetic acid, followed by defatting with dichloromethane. The aqueous layer obtained was treated with activated charcoal and then applied to a Sep-Pak C18 cartridge. The unbound toxic fraction was analyzed by high-performance liquid chromatography techniques. The gastropod toxin was rather unexpectedly identified as PSP. It was comprised of high toxic component (gonyautoxin-3; GTX3, GTX2, saxitoxin; STX) as the major components, which accounted for approximately 91 mol% of all components along with C1 and C2, which are N-sulfocarbamoyl derivatives. Judging from their toxin patterns, it is suggested that the PSP toxification mechanism of the gastropod that PSP toxins produced by phytoplankton such as Alexandrium tamarense, are transferred to and accumulated in plankton feeders such as the short-necked clam, and then transferred to this carnivorous rapa whelk R. venosa through predation.  相似文献   
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