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91.
92.
Chemical characterization and quantitative determination of dissolved low molecular weight carbohydrates in Mikawa Bay near Nagoya, Japan were conducted. The water samples were collected during the period of algal bloom of the dinoflagellate Prorocentrum minimum on 31 May 1980.Low molecular weight carbohydrates in seawater samples from depths of 1 and 6 m were first retained on a charcoal column and then eluted with aqueous ethanol. The carbohydrates obtained were permethylated and then isolated into each of the components by thin layer chromatography. The sugars isolated were characterized by gas chromatography (GC), combined gas chromatography and mass spectrometry (GC-MS), proton nuclear magnetic resonance spectroscopy (1H-NMR) and some chemical analyses. Laminaribiose, laminaritriose, sucrose, raffinose,
,
were fully characterized and quantified with ranges from 2.3 to 27.7 μg l−1 and from 0.5 to 17.8 μg l−1.These low molecular weight carbohydrates were also identified, with some difference in their relative abundance, in particulate matter consisting mainly of dinoflagellate cells collected on the same occasion from this bay. These results indicate that low molecular weight carbohydrates dissolved in seawater are directly derived from those of phytoplankton through extracellular release or cell lysis.  相似文献   
93.
Deep-sea benthic ecosystems are mainly sustained by sinking organic materials that are produced in the euphotic zone. “Benthic-pelagic coupling” is the key to understanding both material cycles and benthic ecology in deep-sea environments, in particular in topographically flat open oceanic settings. However, it remains unclear whether “benthic-pelagic coupling” exists in eutrophic deep-sea environments at the ocean margins where areas of undulating and steep bottom topography are partly closely surrounded by land. Land-locked deep-sea settings may be characterized by different particle behaviors both in the water column and in relation to submarine topography. Mechanisms of particle accumulation may be different from those found in open ocean sedimentary systems. An interdisciplinary programme, “Project Sagami”, was carried out to understand seasonal carbon cycling in a eutrophic deep-sea environment (Sagami Bay) with steep bottom topography along the western margin of the Pacific, off central Japan. We collected data from ocean color photographs obtained using a sea observation satellite, surface water samples, hydrographic casts with turbidity sensor, sediment trap moorings and multiple core samplings at a permanent station in the central part of Sagami Bay between 1997 and 1998. Bottom nepheloid layers were also observed in video images recorded at a real-time, sea-floor observatory off Hatsushima in Sagami Bay. Distinct spring blooms were observed during mid-February through May in 1997. Mass flux deposited in sediment traps did not show a distinct spring bloom signal because of the influence of resuspended materials. However, dense clouds of suspended particles were observed only in the spring in the benthic nepheloid layer. This phenomenon corresponds well to the increased deposition of phytodetritus after the spring bloom. A phytodetrital layer started to form on the sediment surface about two weeks after the start of the spring bloom. Chlorophyll-a was detected in the top 2 cm of the sediment only when a phytodetritus layer was present. Protozoan and metazoan meiobenthos increased in density after phytodetritus deposition. Thus, “benthic-pelagic coupling” was certainly observed even in a marginal ocean environment with undulated bottom topography. Seasonal changes in features of the sediment-water interface were also documented.  相似文献   
94.
Stability and phase relations of coexisting enstatite and H2 fluid were investigated in the pressure and temperature regions of 3.1–13.9 GPa and 1500–2000 K using laser-heated diamond-anvil cells. XRD measurements showed decomposition of enstatite upon heating to form forsterite, periclase, and coesite/stishovite. In the recovered samples, SiO2 grains were found at the margin of the heating hot spot, suggesting that the SiO2 component dissolved in the H2 fluid during heating, then precipitated when its solubility decreased with decreasing temperature. Raman and infrared spectra of the coexisting fluid phase revealed that SiH4 and H2O molecules formed through the reaction between dissolved SiO2 and H2. In contrast, forsterite and periclase crystals were found within the hot spot, which were assumed to have replaced the initial orthoenstatite crystals without dissolution. Preferential dissolution of SiO2 components of enstatite in H2 fluid, as well as that observed in the forsterite H2 system and the quartz H2 system, implies that H2-rich fluid enhances Mg/Si fractionation between the fluid and solid phases of mantle minerals.  相似文献   
95.
The Japanese National Large Telescope (JNLT) is a 7.5 m reflector with a monolithic thin meniscus main mirror, having the candidate construction site on the northwest cone of the Mauna Kea, Hawaii.The present concept of JNLT has the characteristics of a third generation infrared telescope, which should be capable of various observations of high spatial resolution in the optical-infrared region.Although the project is still under examination from the financial and administrative point of view, a wide range of technical studies were carried out by the JNLT Working Group with the collaboration of specialists from the academic and the industrial sectors.Paper presented at the symposium on the JNLT and Related Engineering Developments, Tokyo, November 29–December 2, 1988.  相似文献   
96.
We present a method to estimate the spatial distribution of dredged material disposed of at sea. Using both dredged sediments and samples of sea-bed sediment from near the Rame Head disposal site, Plymouth, UK, we applied entropy analysis to the <63 μm sediment fraction and combined the results with the trace metal data in the same fraction, to form a series of groups. We interpret the distribution of sediments in one group (F1) to approximate the distribution of material affected by the disposal site. This distribution includes locations close to the disposal site, and also locations <4 km to the SE and SW, <6 km to the NW and <2 km to the N. This approach demonstrates the feasibility of using trace metal analysis of particular grain size fractions to reduce uncertainty in interpreting the spatial distribution of impacts of dredge disposal.  相似文献   
97.
The relationship between permeability and vesicularity in volcanic rocks has been used to infer the degassing behavior of hydrous magma. Recent data on natural samples from various eruptions show a wide variation, fitting a power–law relationship of the percolation models with low (< 30%) critical vesicularity (ФC). In this study, we present data on permeability and pore-connectivity of juvenile rhyolitic pumice clasts in a pyroclastic flow around Onikobe volcano, NE Japan, and investigate their relationship with vesicularity developed in a single eruption event. The permeability of the pumices having a relatively low abundance of microlites and microphenocrysts shows a trend increasing by 4 orders of magnitude (from 10− 13.8 to 10− 10.1 m2) in a high and narrow vesicularity range (from 72 to 80%). This trend intersects at a high angle with the fit to the permeability–vesicularity data in the previous studies that has a low ФC, and is located on the extension of the trend for the products of isotropic decompression experiments. The two-dimensional (2D) connectivities of pores for the pumices were also measured from thin sections. From the point of view of percolation theory, connectivity provides information about the probability of percolation. They showed a steep increase from ca. 0 to 0.7 in an almost similar vesicularity range, as compared to their permeabilities. We attribute the increase in 2D connectivity to the increasing amount of ruptured bubble walls, which might have provided less-tortuous paths through larger apertures for gas flow. This, in turn, would cause an effective increase in the permeability. Aggregates of bubble-wall-shaped glass shards were found in the pumices, and their amount and degree of welding are higher in the pumices that have a higher abundance of microlites and microphenocrysts. These pumices have relatively high permeability and 2D connectivity at low vesicularity, which is accounted for by the existence of large irregularly shaped pores. These textural characteristics suggest that a series of partial fragmentation processes, including local rupturing of bubble walls and subsequent foam-collapse with permeable gas flow, might have occurred before the ultimate bulk fragmentation, thus resulting in the increase in permeability. We suggest that the 2D connectivity of pores is a useful parameter to quantify the degree of fragmentation of bubble walls and has the potential for use to assess their permeability.  相似文献   
98.
99.
To monitor land deformation in detail, we ran a large-scale field test in which an artificial landslide was induced by the application of a load to a natural slope. The measured landslide displacement was reproduced numerically through the use of finite element model analysis with a two-dimensional elasto-viscoplastic model. The analysis suggested that the strength of the sliding surface decreased as the landslide mass moved. We propose a simple method for estimating safety factors. The method involves back-calculation of shear strength parameters through reproduction of observed landslide displacements and calculating the ratio of driving force to resisting force acting on the sliding surface as modeled by joint elements. This ratio, the “stability index”, shows the same trend as safety factors calculated by a two-dimensional limit equilibrium method and a shear strength reduction method that use back-calculated shear strength parameters estimated from the limit equilibrium state. The results indicate that the stability index may be applicable to the assessment of slope stability.  相似文献   
100.
The Yamato (j), (k), (l), and (m) meteorites collected from near the Yamato Mountains in December, 1973, are respectively an H-4 and L-5 chondrite, a howardite, and an L-5 chondrite. Yamato (l), the howardite, is a polymict breccia of diogenite and eucrite clasts. Olivine in the chondrites ranges in composition from Fo75 to Fo80, whereas in the howardite, where it is rare, the composition is about Fo60. Pyroxenes in the chondrites are mostly orthopyroxenes and (En83), while the pyroxenes in the howardite are more complex, comprising orthopyroxene, pigeonite, augite, and rare clinohypersthene (in the order of decreasing abundance), with the range from En80 to En37. They form a definite trend, probably formed by the fractional crystallization of the parental magma of the achondrite, and later subjected to exsolution phenomena during the slow cooling. Plagioclase is high-temperature oligoclase in the chondrites, and anorthite in the howardite. Maskelynitization is sometimes observed. Other shock effects are also observed. Opaque phases consist mostly of nickel-iron, troilite, chromite, and rarely ilmenite. Intergrowth of these minerals are common. The accessory minerals comprise quartz, cristobalite, apatite, spinel, and rare uranium-bearing minerals. The bulk composition and genetic significance are discussed.  相似文献   
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