Arsenic(III) adsorption reactions are thought to play a critical role in the mobility of arsenic in the environment. It is the nature of the As(III) surface species that must be known on a wide variety of minerals and over a range of pH, ionic strength and surface coverage in order to be able to predict adsorption behavior. EXAFS and XANES spectroscopic studies have identified bidentate, binuclear inner-sphere surface species and/or an outer-sphere species, but only a few oxides have been examined. These results need to be integrated with a predictive surface complexation model in order to ascertain the environmental conditions under which the different surface species may be important on a wide range of solids. In the present study, the surface species information from XAFS and XANES studies has been built into a recent extension of the triple-layer model (ETLM) for the formation of inner-sphere complexes of anions that takes into account the electrostatics of water dipole desorption during ligand exchange reactions. The ETLM has been applied to regress surface titration, proton coadsorption, and As(III) adsorption data over extensive ranges of pH, ionic strength, electrolyte type and surface coverage for magnetite, goethite, gibbsite, amorphous hydrous alumina, hydrous ferric oxide (HFO), ferrihydrite, and amorphous iron oxide. Two principal reactions forming inner- and outer-sphere As(III) surface species,
Abstract– Enstatite chondrites (ECs) were subjected to noble gas analyses using stepped crushing and pyrolysis extraction methods. ECs can be classified into subsolar gas‐carrying and subsolar gas‐free ECs based on the 36Ar/84Kr/132Xe ratios. For subsolar gas‐free ECs, elemental ratios, and Xe isotopic compositions indicate that Q gas is the dominant trapped component, the Q gas concentration can be correlated with the petrologic type, reasonably explained by gas release from a common EC parental material during subsequent heating. Atmospheric Xe with sub‐Q elemental ratios is found in Antarctic E3s at 600–800 °C and through crushing. The 132Xe released in these fractions accounts for 30–60% of the bulk concentrations. Hence, the sub‐Q signature is generally due to contamination of elementally fractionated atmosphere. Subsolar gas is mainly released (up to 78% of the bulk 36Ar) at 1300–1600 °C and through crushing, suggesting that enstatite and friable phases are the host phases. Subsolar gas is isotopically identical to solar gas, but elementally fractionated. These observations are consistent with a previous study, which suggested that subsolar gas could be fractionated solar wind having been implanted into chondrule precursors ( Okazaki et al. 2001 ). Unlike subsolar gas‐free ECs, the primordial gas concentrations of subsolar gas‐carrying ECs are not simply correlated with the petrologic type. It is inferred that subsolar gas‐rich chondrules were heterogeneously distributed in the solar nebula and accreted to form subsolar gas‐carrying ECs. Subsequent metamorphic and impact‐shock heating events have affected noble gas compositions to various degrees. 相似文献
Abstract– The interior texture and chemical and noble gas composition of 99 cosmic spherules collected from the meteorite ice field around the Yamato Mountains in Antarctica were investigated. Their textures were used to classify the spherules into six different types reflecting the degree of heating: 13 were cryptocrystalline, 40 were barred olivine, 3 were porphyritic A, 24 were porphyritic B, 9 were porphyritic C, and 10 were partially melted spherules. While a correlation exists between the type of spherule and its noble gas content, there is no significant correlation between its chemical composition and noble gas content. Fifteen of the spherules still had detectable amounts of extraterrestrial He, and the majority of them had 3He/4He ratios that were close to that of solar wind (SW). The Ne isotopic composition of 28 of the spherules clustered between implantation‐fractionated SW and air. Extraterrestrial Ar, confirmed to be present because it had a 40Ar/36Ar ratio lower than that of terrestrial atmosphere, was found in 35 of the spherules. An enigmatic spherule, labeled M240410, had an extremely high concentration of cosmogenic nuclides. Assuming 4π exposure to galactic and solar cosmic rays as a micrometeoroid and no exposure on the parent body, the cosmic‐ray exposure (CRE) age of 393 Myr could be computed using cosmogenic 21Ne. Under these model assumptions, the inferred age suggests that the particle might have been an Edgeworth‐Kuiper Belt object. Alternatively, if exposure near the surface of its parent body was dominant, the CRE age of 382 Myr can be estimated from the cosmogenic 38Ar using the production rate of the 2π exposure geometry, and implies that the particle may have originated in the mature regolith of an asteroid. 相似文献
Existing thermal models of the oceanic lithosphere predict too sharp an increase of heat flow towards the ridge axis. A new mathematical model of a thickening lithosphere is presented. The temperature distribution is computed by the use of observed surface heat flow as a boundary condition. If observed heat flow values represent flow of heat from the mantle, the model predicts a rather rapid growth of the lithosphere within the first 30 m.y. and a nearly steady state after 100 m.y. Heat flow from the asthenosphere to the lithosphere shows a minimum near the ridge axis, suggesting a down-going convective flow in the asthenosphere at both sides of a spreading center. 相似文献
A study on the short term variability of the ocean and its effects on the distribution of fish shoals in the coastal area
of NE Japan has been conducted. The efforts have been made to detect the temporal changes of the Tsugaru Warm Current in summer
and autumn (i.e. fishing seasons) by using the satellite infrared images (NOAA7-9) and concurrent hydrographic observation
data. Also fish shoal (mackerel and sardine) distribution was investigated by echo-sounder and fishing fleets' operation data.
The satellite images revealed that the gyre of the Tsugaru Warm Current changed entirely in a short time, and sometimes the
gyre was devided into two parts. The time scale of this process was estimated to be 1–2 weeks. Corresponding to this process,
the fishing grounds changed rapidly. A part of the Tsugaru Warm Current flows from the gyre southward along the coast. The
flow has a temperature front against the Oyasio water intrusion, showing a wave-like perturbation propagating to the S. At
the perturbed frontal area, Mackerel fishing grounds formed frequently. The fish shoals distributed in the warmer side of
this frontal zone. By revealing the mechanism of the characteristic variability, the movement of fishing rounds may be predicted. 相似文献
High-Mg diorites that have similar whole rock composition to high-Mg andesites (HMAs) should not be simply interpreted as rocks solidified from the HMA magmas, because the high-Mg diorites may be mafic cumulates derived from a different magma from the HMAs.
The HMAs contain unique clinopyroxenes with higher Mg# and Si than those of other sub-alkaline series igneous rocks. The Mg# and Si are controlled by the source magma composition rather than its crystallized conditions such as pressure and temperature. The chemical composition of clinopyroxenes would present important information for the investigation of the source of high-Mg diorites.
We considered the source of Early Cretaceous high-Mg diorites on Kyushu Island, southwest Japan arc, based on their clinopyroxene and whole rock compositions. The clinopyroxenes have similar chemical characteristics to those in HMAs rather than those in other sub-alkaline rocks. Moreover, the whole rock compositions are equivalent to the sanukitic HMA and do not show features of mafic cumulates. This indicates that the high-Mg diorites solidified from sanukitic HMA magmas. It is generally believed that the sanukitic HMA magmas involve the subduction of a young and/or hot oceanic slab was situated in their genesis. Therefore, the occurrence of the high-Mg diorites suggests that Kyushu was situated in the tectonic setting of young and/or hot slab subduction in the Early Cretaceous. 相似文献
Two peculiar characteristics of the VAN method of short-term earthquake prediction are: (1) the existence of sensitive and insensitive sites to seismic electric signal (SES) and (2) the selective sensitivity of a sensitive station to SES from specific focal area(s). The process of their discovery, which so far has not been published adequately, is examined for the Ioannina (IOA) station. The sensitive site was discovered simply through repeatedly moving the temporary observation network. The selectivity map of the IOA station was made by first identifying the earthquake source areas with SESs which were considered to have been detected at IOA, and second by examining the direction of SESs from different such source areas. For the latter purpose, information from long dipoles appears to have been helpful. The selectivity map is empirically constructed and is updated regularly. We have independently tried to construct a selectivity map of IOA by examining VAN's raw SES records and by using the same criteria as VAN. The selectivity map we obtained was not exactly, but roughly similar to that of VAN. 相似文献
Since September 2017, the Kuroshio has taken a large-meander (LM) path in the region south of Japan. We examined characteristics of the 2017–present LM path in comparison with previous LM paths, using tide gauge, altimetric sea surface height, and bottom pressure data. The 2017–present LM path was formed from a path passing through a channel south of Hachijo-jima Island, while a typical LM path originated from a path through a channel north of Miyake-jima Island. The meander trough of this atypical path was found to be shifted far to the east and to vary on a timescale of months. These characteristics are different from those of a typical LM path but they are similar to those of the 1981–1984 LM path. Therefore, we identified two types of LM path; a stable and unstable LM paths. The 2017–present unstable type large meander has a zonal scale greater than that of the 2004–2005 stable type large meander and protrudes from the eastern boundary of the Shikoku Basin, i.e., Izu-Ogasawara Ridge. No significant bottom pressure depression was observed, associated with the formation of the 2017–present LM path, indicating that baroclinic instability was not important in the formation of this LM path. Due to no significant bottom steering, even during the 2017–present LM period, a mesoscale current path disturbance occurred southeast of Kyushu, propagated eastward, and amplified the offshore displacement of the Kuroshio.
