Amino-acid racemizarion in Quaternary shell deposits at Willapa Bay,Washington     

Keith A. Kvenvolden  David J. Blunt  H.Edward Clifton 《Geochimica et cosmochimica acta》1979,43(9):1505-1520

Extents of racemization ($\text{d}\text{l}$ ratios) of amino acids in fossil Saxidomus giganteus (Deshayes) and Ostrea lurida Carpenter were measured on shell deposits exposed at 21 sites on the east side of Willapa Bay, Washington. Amino acids from Saxidomus show less variability in $\text{d}\text{Spl}$ ratios and, therefore, are of greater use in correlation and age estimation than are amino acids from Ostrea. Shells of two different ages, about 120,000 ± 40,000 yr old and about 190,000 ± 40,000 yr old, are present. These ages correspond to Stages 5 and 7 of the marine isotope record defined by Shackleton and Opdyke in 1973 and hence the shell deposits likely formed during two different high stands of sea level. The stratigraphic record at Willapa Bay is consistent with this interpretation.  相似文献   

Amino acid racemization dating of fossil bones,I. inter-laboratory comparison of racemization measurements     

Jeffrey L. Bada  E. Hoopes  D. Darling  Graham Dungworth  Henk J. Kessels  Keith A. Kvenvolden  David J. Blunt 《Earth and Planetary Science Letters》1979,43(2):265-268

Enantiomeric measurements for aspartic acid, glutamic acid, and alanine in twenty-one different fossil bone samples have been carried out by three different laboratories using different analytical methods. These inter-laboratory comparisons demonstrate that D/L aspartic acid measurements are highly reproducible, whereas the enantiomeric measurements for the other amino acids show a wide variation between the three laboratories. At present, aspartic acid measurements are the most suitable for racemization dating of bone because of their superior analytical precision.  相似文献   

A novel charge-transfer polymer for separating hydrocarbon fractions of crude oils     

Keith C.C. Bancroft  Susan B. Kendall  Michael M. Rhead  Gerard Hentic 《Marine pollution bulletin》1979,10(8):238-239

Hydrocarbon fractions in crude oil were separated by a new charge-transfer polymer in place of silver ions in Argentation TLC. The charge-transfer plates are cheaper than their silver nitrate equivalents, do not discolour, and store well. The polymer/silica gel mix can be re-used.  相似文献   

The Effect of Flyash Disposal on a Shallow Ground-Water System     

Douglas S. Cherkauer 《Ground water》1980,18(6):544-550

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Fore-arc evolution and continental growth: a general model     

Keith A.W Crook 《Journal of Structural Geology》1980,2(3):289-303

The extended evolution of fore-arc regions which leads to their eventual incorporation into stable kratonic continental crust is elucidated by a general model based upon observations from the modern circum-Pacific and the Palaeozoic Tasman Geosyncline.Fore-arc regions widen during subduction in the manner described by Karig & Sharman (1975). Their history, after subduction has ceased, depends upon the thickness of the accretionary prism formed during subduction. Where the prism is thick (ca. 20 km) kratonization is a single-step process. The fore-arc region remains above sea-level; post-arc silicic volcanics accumulate due to granitoid plutonism, the magmas being derived by melting of the subduction complex and from the oceanic lithosphere trapped beneath it. The volcanic arc subsides, becoming the site of a fore-deep.Intermediate-thickness accretionary prisms (ca. 16 km) are kratonized in a two-step process. They remain at shelf depths, while their associated volcanic arcs sink to comparable depths. Both acquire a post-arc shallow marine sequence of typical platform-cover facies. They are then deformed and intruded by granitoids when the crust attains critical thickness (ca. 20 km).Thin accretionary prisms (≤ 12 km) require a three-step process for kratonization. They and their associated arcs sink to bathyal depths. They are overwhelmed by prograding post-arc flysch deposits of continental origin. Deformation of the post-arc flysch and plutonism occur when critical crustal thickness (ca. 20 km) is attained. A transitional tectonic regime ensues, with molasse-like transitional basins preferentially sited over the extinct volcanic arcs and the thinner parts of buried accretionary prisms.The model satisfactorily explains the Late Proterozoic-Palaeozoic evolution of southeast Australia, where a 1000 km wide tract of continental crust was accreted to the Australian Kraton in 250–300 Ma, beginning as a S.W. Pacific-type oceanic terrain. It has been found useful for interpreting geosynclinal terrains in other continents.According to the model, the dynamic processes that contribute to kratonization are systematically causally connected. Kratonization is a unified, internally deterministic and self-sustaining phenomenon. The model has implications for the origin, ‘stratigraphy’ and composition of upper and lower continental crust; the origins and tectonic settings of ophiolites, granitoids, paired metamorphic belts and transitional basins; and for the nature and causes of orogenesis.  相似文献   

A Spectrum-Independent Procedure for Correcting Eddy Fluxes Measured with Separated Sensors   总被引：1，自引：0，他引：1  

Johannes Laubach  Keith G. McNAUGHTON 《Boundary-Layer Meteorology》1998,89(3):445-467

We investigate flux underestimates in eddy correlation measurements that are caused by horizontal separation of the sensors. A common eddy correlation setup consists of a sonic anemometer and a humidity sensor which, because of its bulk, must be placed some distance away from the sonic path, leading to a flux loss (of latent heat). Utilizing an additional fast temperature sensor placed near the humidity sensor, we develop a procedure for correcting for this loss. The procedure simultaneously corrects the sensible heat flux for the difference between true temperature and sonic temperature. Our correction procedure, which does not depend on the shape of the cospectrum, is then compared to the widely-used procedure following Moore (1986), which assumes a cospectral model ('Kansas Model). Both correction methods are applied to data collected within the internal boundary layer over a rice paddy, downwind of arid land. Under conditions of good fetch, they were found to agree well. Under poor fetch conditions, the model-based correction tended to be too small, while the spectrum-independent combined correction was robust. The latter is thus recommended for situations where the cospectral shape can be expected to deviate from the 'Kansas shape.  相似文献   

Rare earth element geochemistry of potassic lavas from the Birunga and Toro-Ankole regions of Uganda,Africa     

Roger H. Mitchell  Keith Bell 《Contributions to Mineralogy and Petrology》1976,58(3):293-303

Neutron activation determination of La, Ce, Sm, Eu, Tb, Yb, Lu, Ta, Hf, Sc, Co and Th in potassic lavas from the Birunga and Toro-Ankole regions show that the rocks are characterized by high rare earth element (REE) contents (161–754 ppm) and form two groups based upon differing La/Yb ratios. One group is made up of katungite, ugandite and mafurite with La/Yb =146–312, and the other of rocks of the leucitite and phonolitic tephrite series, La/Yb =30–56. The trace element content of the ugandite group is similar to that of kimberlites. The data do not indicate any trends of differentiation or simple relationships between the two groups of rocks, although katungite is unlikely to be parental to rocks of lower La/Yb ratios. It is unlikely that in terms of La/Yb ratios that partial melting of mica-garnet-lherzolite mantle can form katungite because of the very small amounts of partial melting required (0.2%), although the La/Yb ratios of 150–200 (ugandites, mafurites) and 30–60 (leucitites, phonolitic tephrites) can be accounted for by 0.3–1.5% and 1–9% melting respectively, if the REE are then concentrated without further La and Yb fractionation. Partial melting of mantle which has been metasomatized by alkaline earths and REE bearing fluids or mixing of carbonatite and nephelenite are also compatable with the observed geochemistry of the lavas. It is considered that gas transfer processes which selectively enrich the light REE may have obscured REE evidence pertaining to early partial melting and/or differentiation processes and therefore that REE geochemistry is of little use in determining the petrogenetic processes involved in the formation of potassic lavas.  相似文献   

Proceedings of the Fourth Conference on Origins of Life—Chemistry and Radioastronomy: edited by Lynn Margulis. Springer-Verlag,New York (1973) 291 pp, $17.20     

Keith A. Kvenvolden 《Geochimica et cosmochimica acta》1974,38(5):808

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Carbon and sulfur in the Swaziland sequence     

Carleton B Moore  Charles F Lewis  Keith A Kvenvolden 《Precambrian Research》1974,1(1):49-54

Sedimentary and igneous rocks of the Swaziland Sequence of South Africa (>3,200 my. old) contain total carbon (0.09–8.28%), organic carbon (0.04–1.95%) and sulfur (9–53,000 ppm). Amounts of organic carbon are generally high in the lower part of the Sequence (based on two samples from the Theespruit Formation). Sulfur content varies widely with no obvious correlations or trends. These rocks may contain clues to the early carbon and sulfur cycles on earth.  相似文献   

A discrete particle representation of hillslope hydrology: hypothesis testing in reproducing a tracer experiment at Gårdsjön,Sweden     

Jessica Davies  Keith Beven  Lars Nyberg  Allan Rodhe 《水文研究》2011,25(23):3602-3612

Despite the long history of the continuum equation approach in hydrology, it is not a necessary approach to the formulation of a physically based representation of hillslope hydrology. The Multiple Interacting Pathways (MIPs) model is a discrete realization that allows hillslope response and transport to be simultaneously explored in a way that reflects the potential occurrence of preferential flows and lengths of pathways. The MIPs model uses random particle tracking methods to represent the flow of water within the subsurface alongside velocity distributions that acknowledge preferential flows and transition probability matrices, which control flow pathways. An initial realization of this model is presented here in application to a tracer experiment carried out in Gårdsjön, Sweden. The model is used as an exploratory tool, testing several hypotheses in relation to this experiment. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献