Effects of Selected Sampling Equipment and Procedures on the Concentrations of Trichloroethylene and Related Compounds in Ground Water Samples     

Kenneth A. Pearsall  David A. V. Eckhardt 《Ground Water Monitoring & Remediation》1987,7(2):64-73

Variations in concentrations of trichloroethylene and related compounds in ground water obtained from seven ground water samplers were used to compare the performance of three submersible pumps, a centrifugal pump, two peristaltic pumps, and a bailer. Two- and 4-inch diameter submersible pumps and a centrifugal pump produced samples whose trichloroethylene concentrations, on the average, did not differ significantly from each other. Ground water samples collected by using a peristaltic pump and silicone tubing had significantly lower trichloroethylene concentrations than samples from the submersible pumps. Concentrations of 1,2-dichloroethylene and trichloroethylene in ground water samples collected by using a bailer were indistinguishable from those in samples taken by a submersible pump when the concentrations were as much as 96 and 76 micrograms per liter, respectively, but were 15 and 12 percent lower when concentrations were as low as 29 and 23 micrograms per liter, respectively. Tests of different configurations of sampler placement in observation wells indicate that pump placement, rate of pumping, duration of pumping, and the uniformity of the vertical and lateral distribution of trichloroethylene in ground water near the well screen have a potentially significant influence on trichloroethylene concentrations in ground water samples and that these factors can have a greater effect than the type of sampler used.  相似文献   

Geothermometry of exsolved augites from the Laramie Anorthosite Complex,Wyoming     

Kenneth J. T. Livi 《Contributions to Mineralogy and Petrology》1987,96(3):371-380

Exsolved augite pyroxenes from the ferromonzonite border facies of the ferrosyenite in the Laramie Anorthosite Complex have been studied with the transmission electron microscope and the electron microprobe to determine their exsolution histories. The Lindsley and Andersen (1983) geothermometer gives initial crystallization temperatures of 1000° C for the bulk augite crystal (Wo₃₂ En₂₂ Fs₄₆). Exsolved lamellae are predominantly pigeonites with very low calcium contents (Wo_1–3 En_23–24 Fs_71–74) and have formation temperatures estimated to be in the range of 600 to 975° C. The uniform compositions of lamellae and hosts, despite the range in lamellar size and orientation, suggest that either 1) the ferromonzonite experienced an extended plateau in cooling or a reheating event at 600 to 650° C or 2) the pyroxenes recorded a blocking temperature. Two-feldspar geothermometry on exsolved feldspars also records 600° C and suggests that these low temperatures are not blocking temperatures.  相似文献   

A-type granites: geochemical characteristics,discrimination and petrogenesis   总被引：318，自引：3，他引：318  

Joseph B. Whalen  Kenneth L. Currie  Bruce W. Chappell 《Contributions to Mineralogy and Petrology》1987,95(4):407-419

New analyses of 131 samples of A-type (alkaline or anorogenic) granites substantiate previously recognized chemical features, namely high SiO₂, Na₂O+K₂O, Fe/Mg, Ga/Al, Zr, Nb, Ga, Y and Ce, and low CaO and Sr. Good discrimination can be obtained between A-type granites and most orogenic granites (M-, I and S-types) on plots employing Ga/Al, various major element ratios and Y, Ce, Nb and Zr. These discrimination diagrams are thought to be relatively insensitive to moderate degrees of alteration. A-type granites generally do not exhibit evidence of being strongly differentiated, and within individual suites can show a transition from strongly alkaline varieties toward subalkaline compositions. Highly fractionated, felsic I- and S-type granites can have Ga/Al ratios and some major and trace element values which overlap those of typical A-type granites.A-type granites probably result mainly from partial melting of F and/or Cl enriched dry, granulitic residue remaining in the lower crust after extraction of an orogenic granite. Such melts are only moderately and locally modified by metasomatism or crystal fractionation. A-type melts occurred world-wide throughout geological time in a variety of tectonic settings and do not necessarily indicate an anorogenic or rifting environment.Geological Survey of Canada contribution no. 18886  相似文献   

Contrasting styles of Archaean crustal evolution in parts of southern West Greenland     

Kenneth Coe  Steve Robertson 《Journal of Geodynamics》1984,1(3-5)

Aspects of the crustal evolution of three areas in the Archaean block of southern West Greenland are compared and new Rb and Sr isotope data are presented for one of them (inner Godthåbsfjord). It is concluded that major differences resulted from variations in crustal thickness with the early Archaean Amîtsoq gneisses controlling later events.  相似文献   

A detailed gravity study of the Chattolanee Baltimore Gneiss Dome,Maryland, U.S.A.     

Kenneth P. Kodama  David A. Chapin 《Earth and Planetary Science Letters》1984,68(2):286-296

A detailed gravity survey over the Chattolanee Baltimore Gneiss Dome in the Maryland Piedmont suggests that the dome is an arched recumbent fold. The Baltimore Gneiss, which cores the dome, has a negative density contrast with the surrounding Cambro-Ordovician marbles and schists and is coincident with a large minimum in the simple Bouguer gravity. Three north-south profiles, which cut across the east-west-trending surface exposure of the dome were modeled two-dimensionally. The models suggest that the Baltimore Gneiss is thickest and tightly folded in an inverted V shape to the east and thinner and broadly arched to the west. It is also possible to fit the gravity data with a mushroom-shaped body at the easternmost profile, which could suggest a diapiric origin for the dome, but this interpretation is not favored based on geological arguments. The Baltimore Mafic Complex, located to the south of the Chattolanee Dome, can be modeled as an approximately 1 km thick slab with a subhorizontal base, suggesting that it is a thrust sheet. By analogy with the Phoenix Baltimore Gneiss Dome, mapped by Crowley [2], the Cambro-Ordovician sediments surrounding the Chattolanee Dome may also be involved in the recumbent folding which would suggest that the dome was formed during the Ordovician Taconic orogeny.  相似文献   

The Topsails igneous terrane,Western Newfoundland: evidence for magma mixing     

Joseph B. Whalen  Kenneth L. Currie 《Contributions to Mineralogy and Petrology》1984,87(4):319-327

The Topsails igneous terrane of Western Newfoundland contains a diverse suite of igneous rocks, but consists mainly of Silurian alkaline to peralkaline granites and rhyolites. The terrane exhibits evidence for the coexistence of mafic and salic magmas in the form of composite dykes and flows, sinuous, boudined mafic dykes cutting granites and net vein complexes. Field data and major and trace element chemical data suggest that these magmas mixed to produce limited volumes of more or less homogeneous hydrids.Magma mixing, a process which has received recent prominence in petrogenetic models for calc-alkaline volcanic suites, has elicited less attention than restite separation and fractional crystallization as a cause of chemical dispersion in granites. Evidence from the Topsails igneous terrane suggests the possible importance of magma mixing to granite petrogenesis and a major role for transcurrent faulting in the origin and evolution of peralkaline magmas.  相似文献   

The lower Colorado River Valley: A Pleistocene desert     

Kenneth L. Cole 《Quaternary Research》1986,25(3)

A chronological sequence of plant macrofossil assemblages from twenty-five pack rat middens provides a record of desert scrub vegetation for most of the last 13,380 yr B.P. from a hyperarid portion of the lower Colorado River Valley. At the end of the late Wisconsin, and probably during much of the Quaternary, the Picacho Peak area, Imperial County, California, supported a typical Mohave Desert association of Larrea divaricata (creosote bush), Coleogyne ramosissima (blackbrush), Yucca brevifolia (Joshua tree), and Y. whipplei (Whipple yucca). Recent arrivals of Sonoran Desert plants such as Olneya tesota (ironwood) and Fouquieria splendens (ocotillo) suggest that the area supported relatively modern Sonoran desert scrub species for relatively short periods during interglaciations.  相似文献   

The role of interactions among environmental conditions in controlling historical fisheries variability     

J. Kevin Summers  Kenneth A. Rose 《Estuaries and Coasts》1987,10(3):255-266

We developed categorical time-series regression models to evaluate the roles of lagged stock abundance history, hydrographic variability, and anthropogenic factors in controlling the variation in abundance of striped bass and American shad in the Potomac, Delaware, and Hudson rivers. These models can be used to evaluate directly the role of interactions of variates to produce greater than average recruitment to commercial fish stocks. Whereas hydrographic factors dominate striped bass dynamics in all three estuaries for the period 1929–1976 compared to the pollution variables tested (i.e., sewage loading, dissolved oxygen, and biological oxygen demand), American shad shows strong dependence on the anthropogenic factors compared to hydrographic variates in all three estuaries.  相似文献   

The average molecular weight and shape of the “polymeric acids” found in Black Trona Water from the Green River Basin     

Roland E. Barden  Eugenia R. Logan  J.F. Branthaver  Kenneth E. Neet 《Organic Geochemistry》1984,5(4):217-225

Macromolecular organic material, called “polymeric acids”, has been isolated from Black Trona Water by exhaustive dialysis and characterized as the sodium salt in 0.10 M sodium carbonate, pH 10, by several physico-chemical methods. Analysis by gel filtration chromatography on Sepharose-CL 6B indicates that the “polymeric acids” are polydisperse and composed of species of relatively high molecular weight ( 4 × 10⁵, using proteins as standards). With this method, the range of molecular weights appears to be rather narrow. If “polymeric acids” are transferred from sodium carbonate, pH 10, into distilled water, selfassociation occurs and all species elute in the void volume. The weight-average molecular weight determined in 0.10 M sodium carbonate, pH 10, by the light scattering method is 1.7 × 10⁵. Sedimentation velocity analysis at 20°C with the analytical ultracentrifuge gives a value for S_20,w of 5.4 and the shape of the Schlieren patterns suggest a polydisperse sample with a relatively narrow range of sizes. Analysis of the molecular weight distribution by a sedimentation equilibrium method indicates that the range of molecular weights is 8 × 10⁴ to 2.1 × 10⁵. The partial specific volume ( ) of “polymeric acids” is 0.874 ml/g. Viscosity measurements yield a value for [η] of 2.5 ml/g, which indicates that the “polymeric acids” are compact (spherical or ellipsoidal) in shape.  相似文献   

Preface     

Robert J. Orth  Kenneth L. Heck  Michael P. Weinstein 《Estuaries and Coasts》1984,7(4):273-274

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