Precise Determination of Ultra-Low (sub-ng g^-1) Level Rare Earth Elements in Ultramafic Rocks by Quadrupole ICP-MS     

Kentaro Nakamura  Qing Chang 《Geostandards and Geoanalytical Research》2007,31(3):185-197

We present a new method that determines precisely and accurately rare earth elements (REE) at the sub-ng g^-1 level in ultramafic rocks based on acid dissolution and quadrupole ICP-MS with systematic interference corrections on each sample. The method is demonstrated by analyses of the international geochemical reference materials, PCC-1 (peridotite), DTS-1 (dunite) and DTS-2 (dunite) provided by the United States Geological Survey (USGS), and JP-1 (peridotite) issued by the Geological Survey of Japan (GSJ). Detection limits, as rock equivalent, were calculated to be 0.01-0.08 ng g^-1 for our instrument, which is sufficiently low compared to the REE concentrations of ultramafic rocks. In addition, procedural blanks of the proposed method were 0.2-5 pg, which is negligible even for the ultra-low level REE determinations. Reproducibility obtained from separate dissolutions and measurements of USGS DTS-2 and GSJ JP-1 was 3-6%, which corresponds to the high-precision data obtained by ID-TIMS or magnetic sector field ICP-MS with a desolvating nebuliser. The REE data determined exhibit smooth chondrite-normalised REE patterns for all of the tested geochemical reference materials, and the abundances are in good agreement with recently published data.  相似文献   

Fisheries oceanography     

M. Ishino  T. Hirano  S. Hattori 《Journal of Oceanography》1971,27(6):287-294

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Ocean acidification and photic‐zone anoxia at the Toarcian Oceanic Anoxic Event: Insights from the Adriatic Carbonate Platform     

Nicholas P. Ettinger  Toti E. Larson  Charles Kerans  Alyson M. Thibodeau  Kelly E. Hattori  Sean M. Kacur  Rowan C. Martindale 《Sedimentology》2021,68(1):63-107

Severe global climate change led to the deterioration of environmental conditions in the oceans during the Toarcian Stage of the Jurassic. Carbonate platforms of the Western Tethys Ocean exposed in Alpine Tethyan mountain ranges today offer insight into this period of environmental upheaval. In addition to informing understanding of climate change in deep time, the effect of ancient carbon cycle perturbations on carbonate platforms has important implications for anthropogenic climate change; the patterns of early Toarcian environmental deterioration are similar to those occurring in modern oceans. This study focuses on the record of the early Toarcian Oceanic Anoxic Event (ca 183.1 Ma) in outcrops of the north‐west Adriatic Carbonate Platform in Slovenia. Amidst environmental deterioration, the north‐west Adriatic Platform abruptly transitioned from a healthy, shallow‐water environment with diverse metazoan ecosystems to a partially drowned setting with low diversity biota and diminished sedimentation. An organic carbon‐isotope excursion of ?2.2‰ reflects the massive injection of CO₂ into the ocean‐atmosphere system and marks the stratigraphic position of the Toarcian Oceanic Anoxic Event. A prominent dissolution horizon and suppressed carbonate deposition on the platform are interpreted to reflect transient shoaling of the carbonate compensation depth to unprecedentedly shallow levels as the dramatic influx of CO₂ overwhelmed the ocean’s buffering capacity, causing ocean acidification. Trace metal geochemistry and palaeoecology highlight water column deoxygenation, including the development of photic‐zone anoxia, preceding and during the Toarcian Oceanic Anoxic Event. Ocean acidification and reduced oxygen levels likely had a profoundly negative effect on carbonate‐producing biota and growth of the Adriatic Platform. These effects are consistent with the approximate doubling of the concentration of CO₂ in the ocean‐atmosphere system from pre‐event levels, which has previously been linked to a volcanic triggering mechanism. Mercury enrichments discovered in this study support a temporal and genetic link between volcanism, the Toarcian Oceanic Anoxic Event and the carbonate crisis.  相似文献   

Simultaneous seeing measurement through the Subaru Telescope in the visible and near-infrared bands for the wavelength dependence evaluation     

Shin Oya  Hiroshi Terada  Yutaka Hayano  Makoto Watanabe  Masayuki Hattori  Yosuke Minowa 《Experimental Astronomy》2016,42(1):85-98

Stellar images have been obtained under natural seeing at visible and near-infrared wavelengths simultaneously through the Subaru Telescope at Mauna Kea. The image quality is evaluated by the full-width at the half-maximum (FWHM) of the stellar images. The observed ratio of FWHM in the V-band to the K-band is 1.54 ± 0.17 on average. The ratio shows tendency to decrease toward bad seeing as expected from the outer scale influence, though the number of the samples is still limited. The ratio is important for simulations to evaluate the performance of a ground-layer adaptive optics system at near-infrared wavelengths based on optical seeing statistics. The observed optical seeing is also compared with outside seeing to estimate the dome seeing of the Subaru Telescope.  相似文献   

Compression mechanism and amorphization of portlandite, Ca(OH)2: structural refinement under pressure     

T. Nagai  T. Ito  T. Hattori  T. Yamanaka 《Physics and Chemistry of Minerals》2000,27(7):462-466

In order to investigate compression mechanism and the pressure-induced amorphization of portlandite, Ca(OH)₂, the crystal structure has been refined up to 9.7?GPa using Rietveld analysis. Angular-dispersive synchrotron X-ray powder diffraction experiments were performed using a diamond anvil cell and an imaging plate at BL-18C in the Photon Factory at KEK, Japan. Compression behavior is highly anisotropic and the c axis is approximately 2.5 times as compressible as the a axis (β_a=0.004, β_c=0.011?GPa^?1). Because the refined fractional coordinate, z, of the O atom increases linearly with pressure, compression along the c axis is due to the shortening of the interlayer spacing. The compression mechanism shows no change up to the amorphization pressure and is basically the same as that of brucite, Mg(OH)₂, observed below 10 GPa. The octahedral regularity of CaO₆ approaches a regular configuration with pressure. The interlayer O…O distance is expected to be about 2.75 Å at the amorphization pressure and should affect hydrogen bonding.  相似文献   

Alkalinization and acidification of stream water with changes in atmospheric deposition in a tropical dry evergreen forest of northeastern Thailand          下载免费PDF全文

Hiroyuki Sase  Jesada Luangjame  Hathairatana Garivait  Bopit Kietvuttinon  Thiti Visaratana  Masato Kamisako  Ryo Kobayashi  Seiichi Ohta  Junko Shindo  Kentaro Hayashi  Hideshige Toda  Kazuhide Matsuda 《水文研究》2017,31(4):836-846

Field surveys on atmospheric deposition and stream water chemistry were conducted in an evergreen forest in northeastern Thailand characterized by a tropical savanna climate with distinct dry and wet seasons. Atmospheric deposition of ion constituents by throughfall and stemflow was shown to increase in the beginning and end of the wet season, reflecting the precipitation pattern. The pH and electrical conductivity of stream water increased with alkalinity and base cation concentrations due to mineralization of organic matter by the first rain and retention of anions in soil during the start of the wet season. After initial alkalinization, the pH and alkalinity declined rapidly with the highest SO₄^2? concentration displayed in the middle towards the end of the wet season. The magnitude of peaks in SO₄^2? concentration (13.5–60.6 μmol_c/L) reflects deposition during the first 2 months of the wet season (March and April) in respective years (60.8–170 mol_c/ha). Release of SO₄^2? with H⁺, which is retained in soil during the early wet season, may cause acidification later in the season. The deposition and concentration of SO₄^2? declined over 6 years. However, the pH of stream water declined with increasing concentrations of SO₄^2? and other major ions. The release of materials accumulated in the ecosystem was facilitated by the decrease in SO₄^2? concentration/deposition and increased precipitation in the middle–late wet season. The retention‐release cycle of SO₄^2? largely contributed to both seasonal and interannual variations in stream water chemistry in the tropical savanna climate studied.  相似文献   

Stability of a circular tunnel in cohesive-frictional soil subjected to surcharge loading     

Kentaro Yamamoto  Andrei V. Lyamin  Daniel W. Wilson  Scott W. Sloan  Andrew J. Abbo 《Computers and Geotechnics》2011

The stability of circular tunnels in cohesive-frictional soils subjected to surcharge loading has been investigated theoretically and numerically assuming plane strain conditions. Despite the importance of this problem, previous research on the subject is very limited. At present, no generally accepted design or analysis method is available to evaluate the stability of tunnels/openings in cohesive-frictional soils. In this study, continuous loading is applied to the ground surface, and both smooth and rough interface conditions are modelled. For a series of tunnel diameter-to-depth ratios and material properties, rigorous lower- and upper-bound solutions for the ultimate surcharge loading are obtained by applying finite element limit analysis techniques. For practical use, the results are presented in the form of dimensionless stability charts with the actual tunnel stability numbers being closely bracketed from above and below. As an additional check on the solutions, upper-bound rigid-block mechanisms have been developed and the predicted collapse loads from these are compared with those from finite element limit analysis. Finally, an expression that approximates the ultimate surcharge load has been devised which is convenient for use by practising engineers.  相似文献   

Flux‐Free Fusion of Silicate Rock Preceding Acid Digestion for ICP‐MS Bulk Analysis     

Kenji Shimizu  Qing Chang  Kentaro Nakamura 《Geostandards and Geoanalytical Research》2011,35(1):45-55

We present a new method for the decomposition of silicate rocks by flux‐free fusion in preparation for whole‐rock trace element determination (Sc, Rb, Sr, Y, Zr, Nb, Cs, Ba, rare earth elements and Hf) that is especially applicable to zircon‐bearing felsic rocks. The method was verified by analyses of RMs of mafic (JB‐1a, JB‐2, JGb‐1) and felsic rocks (JG‐3, JR‐3, JSd‐1, GSP‐2, G‐2). Pellets of powdered sample (up to 500 mg) without flux were weighed and placed in a clean platinum crucible. The samples were then fused in a Siliconit® tube furnace and quenched to room temperature. The optimum condition for the fusion of granitic rock was determined to be heating for 2–3 min at 1600 °C. The fused glass in the platinum crucible after heating was decomposed using HF and HClO₄ in a Teflon® beaker. Decomposed and diluted sample solutions were analysed using a quadrupole inductively coupled plasma‐mass spectrometer. Replicate analyses (n = 4 or 5) of the RMs revealed that analytical uncertainties were generally < 3% for all elements except Zr and Hf (～ 6%) in JG‐3. These higher uncertainties may be attributed to sample heterogeneity. Our analytical results for the RMs agreed well with recommended concentrations and recently published concentrations, indicating complete decomposition of our rock samples during fusion.  相似文献   

Search for TeV Gamma-Rays from 3EG J1234-1318 with the Cangaroo-II Telescope     

Takahiro Hattori  Kyoshi Nishijima 《Astrophysics and Space Science》2005,297(1-4):327-334

We observed 3EG J1234-1318 with the CANGAROO-II telescope in March, 2002. This source is a steady unidentified EGRET gamma-ray source at high Galactic latitude which has been associated with a dynamically merging clusters of galaxies, and is therefore a candidate TeV source. TeV gamma-ray emission is also expected as a result of large-scale cosmological structure formation. We here report the resulting upper limit on the TeV gamma-ray emission from 3EG J1234-1318. For the CANGAROO Collaboration.  相似文献   

Measurement of evaporation from the forest floor in a deciduous forest throughout the year using microlysimeter and closed‐chamber systems     

Aiko Deguchi  Shigeaki Hattori  Kenichi Daikoku  Ho‐Teak Park 《水文研究》2008,22(18):3712-3723

Evaporation from the forest floor (E_FF) in a deciduous broadleaf forest was measured using microlysimeter and closed‐chamber systems. The microlysimeter was used at six points in the experimental basin, and measurements gave different E_FF values at different points. This could be attributed to the local photoenvironment of each sampling point, rather than to litter conditions, if the spatial variation in air temperature (Ta) or vapour pressure deficit (VPD) at the forest floor was small within this basin. A detachable microlysimeter measured condensation in the litter layer during the night, indicating that the litter layer, as well as the mulch layer, played a role in preventing evaporation from the soil layer. The closed‐chamber system made it possible to continuously measure long‐term E_FF. E_FF was closely related to VPD; even during the night, when solar radiation was zero, E_FF amounted to 14·0% of the daily E_FF. The daily E_FF was 0·20 ± 0·13 mm day^?1 during the study period, with two seasonal peaks: in late spring (0·31 mm day^?1 in April) and early fall (0·22 mm day^?1 in September). The former peak has been reported from two deciduous forests in Japan and is strongly related to the solar radiation reaching the forest floor when the trees are dormant. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献