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21.
The sound velocity (V P) of liquid Fe–10 wt% Ni and Fe–10 wt% Ni–4 wt% C up to 6.6 GPa was studied using the ultrasonic pulse-echo method combined with synchrotron X-ray techniques. The obtained V P of liquid Fe–Ni is insensitive to temperature, whereas that of liquid Fe–Ni–C tends to decrease with increasing temperature. The V P values of both liquid Fe–Ni and Fe–Ni–C increase with pressure. Alloying with 10 wt% of Ni slightly reduces the V P of liquid Fe, whereas alloying with C is likely to increase the V P. However, a difference in V P between liquid Fe–Ni and Fe–Ni–C becomes to be smaller at higher temperature. By fitting the measured V P data with the Murnaghan equation of state, the adiabatic bulk modulus (K S0) and its pressure derivative (K S ) were obtained to be K S0 = 103 GPa and K S  = 5.7 for liquid Fe–Ni and K S0 = 110 GPa and K S  = 7.6 for liquid Fe–Ni–C. The calculated density of liquid Fe–Ni–C using the obtained elastic parameters was consistent with the density values measured directly using the X-ray computed tomography technique. In the relation between the density (ρ) and sound velocity (V P) at 5 GPa (the lunar core condition), it was found that the effect of alloying Fe with Ni was that ρ increased mildly and V P decreased, whereas the effect of C dissolution was to decrease ρ but increase V P. In contrast, alloying with S significantly reduces both ρ and V P. Therefore, the effects of light elements (C and S) and Ni on the ρ and V P of liquid Fe are quite different under the lunar core conditions, providing a clue to constrain the light element in the lunar core by comparing with lunar seismic data.  相似文献   
22.
Strontium contents of 232 sea water samples collected at various stations in the North Pacific and adjacent seas of Japan were measured by the atomic absorption spectrophotometry and strontium-chlorinity ratios were determined. Mean Sr concentration is 8.08 mg/kg and mean Sr/Cl ratio is 0.425 mg/kg/Contrary to some recent reports, regional and vertical variations of Sr/Cl ratios were statistically insignificant, and presence of particulate strontium was not confirmed.  相似文献   
23.
The distributions of CFC (chlorofluorocarbon) in the water column was determined twice in 2000 and 2001 in the northwestern Japan Sea. In 2000 the CFC-11 concentration decreased almost exponentially with depth from 6 pmol/kg at a few hundred m deep to 0.3 pmol/kg or less at the bottom of about 3400 m depth at three stations (40–41°N, 132–133°E) about 300 km off Vladivostok. In 2001 the CFC-11 concentration increased sharply up to 2 pmol/kg in the bottom water, while it did not increase at a station (42.0°N, 136.5°E) about 450 km away to the northeast. This is due to the renewal of the bottom water which is replaced by the surface water flowing down along the continental slope, as suggested by Tsunogai et al. (1999), who proposed the continental shelf pump. Furthermore, an increase in the CFC-11 concentration was observed throughout the entire water column above 3000 m depth, although the proportion of the increase was about 20%, which was one order of magnitude smaller than that in the bottom water. The increase in inventory is almost four times larger than that in the bottom water below 3000 m depth which is equivalent to about 1/6 of the total inventory found in 2000. The increase also means that 3% of the deep water was replaced by the recent surface water, or, if the turnover occurs every year, that the turnover time of the deep water to be about 30 years. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   
24.
239, 240Pu,137Cs and90Sr concentrations were determined in sea waters from the central and western North Pacific in 1980 and 1982. The results are consistent with those reported earlier for North Pacific waters. The profiles of90Sr and137Cs show a monotonic decrease with depth, whilst239, 240Pu shows a distinct subsurface maximum at a depth between 400 and 1,000 m. The calculated inventories of these nuclides significantly exceed the global mean fallout inputs for these latitudes. This may be due to local fallout input to the ocean at times of large-scale nuclear weapon tests in the equatorial North Pacific. The existence of measurable amounts of137Cs and239, 240Pu in deep waters suggests that these nuclides are transported by sinking particulate matter from the surface to the deep ocean.  相似文献   
25.
Based on the petrology of hydrothermally altered Archean basaltic greenstones, thermodynamic calculations of phase equilibria were conducted to estimate the composition of a high-temperature (∼350 °C) hydrothermal fluid in an Archean subseafloor basalt-hosted hydrothermal system. The results indicate that the hydrothermal fluid was highly alkaline attributed to the presence of calcite in the alteration minerals under a high-CO2 condition, and predict a generation of SiO2-rich, Fe-poor hydrothermal fluids in the Archean subseafloor hydrothermal system. The chemically reactive mixing zones between alkaline hydrothermal fluids and slightly acidic-neutral seawater are characterized by inverse pH and chemical polarity to modern hydrothermal systems, leading to extensive precipitation of silica and iron oxyhydroxides on/under the seafloor. Such processes can be responsible for the abiotic formation of voluminous chert and subseafloor silica dike, the mechanism of silicification, and the pH-controlled generation of banded iron formation that has been arising mainly from the redox chemistry in the Archean ocean. Such high-temperature alkaline fluids could have had a significant role not only in the early ocean geochemical processes but also in the early evolution of life.  相似文献   
26.
Zircon is resistant to alteration over a wide range of geological environments, and isotopic ratios within the mineral provide constraints on ages and their parental magmas. Trace element compositions in zircon are also expected to reflect those of their parent magmas, and have a potential as essential indicators for their host rocks. Because most detrital zircons that accumulate at river mouths are derived primarily from granitoids, the classification of zircon within granitoids is potentially meaningful. This study employs the conventional classification scheme of granites (I‐, S‐, M‐, and A‐types). To clarify geochemical characteristics of zircons in A‐type granites, trace element compositions of zircons extracted from the A‐type Ashizuri granitoids were examined. Zircons from the Ashizuri granitoids commonly show enrichments of heavy rare earth elements and positive Ce anomalies, indicating that these zircons were igneous in origin. In addition, zircons in these A‐type granites are characterized by enrichments of Nb, Y, Ta, Th, and U and strong negative Eu anomalies, which exhibit good positive correlations with those in their whole rocks. This fact indicates that these signatures in zircons reflect well those in their parental bodies and are useful in identifying zircons derived from A‐type granite. Based on compilations of available data, zircons from A‐type granites can be clearly discriminated from other‐types of granites within Nb/Sr–Eu anomaly, U/Sr–Eu anomaly, Nb/Sr–U/Sr, and Nb/Sr–Ta/Sr cross‐plots. All indices used in these diagrams were selected based on the geochemical features of both zircon and whole rock of A‐type granites. Application of these discrimination diagrams to detrital zircons will likely provide further insights. For example, some Hadean detrital zircons plot in similar fields to A‐type granites, implying the existence of A‐type magmatism in the Earth's earliest history.  相似文献   
27.
28.
In this study, the three‐dimensional (3‐D) microstructure of 48 Itokawa regolith particles was examined by synchrotron microtomography at SPring‐8 during the preliminary examination of Hayabusa samples. Moreover, the 3‐D microstructure of particles collected from two LL6 chondrites (Ensisheim and Kilabo meteorites) and an LL5 chondrite (Tuxtuac meteorite) was investigated by the same method for comparison. The modal abundances of minerals, especially olivine, bulk density, porosity, and grain size are similar in all samples, including voids and cracks. These results show that the Itokawa particles, which are surface materials from the S‐type asteroid Itokawa, are consistent with the LL chondrite materials in terms of not only elemental and isotopic composition of the minerals but also 3‐D microstructure. However, we could not determine whether the Itokawa particles are purely LL5, LL6, or a mixture of the two. No difference between the particles collected from Rooms A and B of the sample chamber, corresponding to the sampling sequence of the spacecraft's second and first touchdowns, respectively, was detected because of the statistically small amount of particles from Room B.  相似文献   
29.
It has been almost four decades since the first launch of geostationary meteorological satellite by Japan Meteorological Agency (JMA). The specifications of the geostationary meteorological satellites have shown tremendous progresses along with the generations, which are now entering their third generation. The third-generation geostationary meteorological satellites not only yield basic data for weather monitoring, but also globally observe the Earth’s environment. The development of multi-band imagers with improved spatial resolution onboard the third-generation geostationary meteorological satellites brings us meteorological data in larger size than those of the second-generation ones. Thus, new techniques for domestic and world-wide dissemination of the observational big data are needed. In this paper, we develop a web-based data visualization for Himawari-8 satellite sensed images in real time and with full resolution. This data visualization is supported by the ecosystems, which uses a tiled pyramid representation and parallel processing technique for terrain on an academic cloud system. We evaluate the performance of our techniques for domestic and international users on laboratory experiments. The results show that our data visualization is suitable for practical use on a temporal preview of observation image data for the domestic users.  相似文献   
30.
This study uses temperature and salinity time series acquired with taut-line moorings in the western equatorial Pacific to investigate water mass behavior on the thermocline layer. Basically, it is insufficient to trace water mass variation by the original discrete depth coordinate data because of relatively high variability of density at fixed depth near the thermocline. A reconstruction method based on the density surface motion caused by tidal forcing was used to derive continuous profiles of temperature and salinity from vertically discrete measurements at fixed depths. This method can represent detailed vertical salinity structures and their variation, especially along the potential density surface of 24.8σθ, where the salinity maximum of South Pacific tropical water (SPTW) appeared. Variability around the 24.8σθ surface at each site was as large as that observed at the surface, which suggests a strong influence of SPTW behavior. High salinity along the 24.8σθ surface within the equatorial band of the western Pacific appeared during boreal fall-winter at sites far from New Guinea. In contrast, high salinity appeared near New Guinea during the boreal spring-summer. These features suggest the influence of the New Guinea Coastal Undercurrent. Over longer time scales, several higher salinity events were observed. The most pronounced salinity event occurred during 2007–2008. Interannual variation of the salinity anomaly along the 24.8σθ surface was negatively correlated with the Niño 3.4 sea surface temperature anomaly. A long-term salinity anomaly shift from negative to positive occurred around the end of 2002. The relationship with decadal variation in subtropical cell transport is also discussed.  相似文献   
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