CZChemDB and EarthChem: Advancing management and access of critical zone geochemical data     

Xianzeng Niu  Kerstin A. Lehnert  Jennifer Williams  Susan L. Brantley 《Applied Geochemistry》2011

Multiple Critical Zone Observatories (CZO) have been established in recent years in the USA and other international settings to conduct collaborative research on processes that occur at and near Earth’s surface, also known as the Critical Zone (CZ). Data documentation and data sharing are two persistent problems facing the CZOs that impede the ability for cross-site comparisons and integrated analysis. In this study, a relational database was developed for CZ rock and regolith geochemical data – CZChemDB. There are a total of 24 interrelated tables in the database, each representing different aspects of CZ features. The main data group includes tables of locations, sites, samples, subsamples, preparation/treatments, laboratory-analysis and data values. The meta-data group includes tables of methods, references, and data quality. Lookup tables (variables, units, etc.) contain lists of “controlled” vocabularies. The CZChemDB is currently implemented in the MS Access database management system. It is expected to be integrated into the EarthChem portal by summer of 2011 for broader online accessibility and usability. This integration also complements the EarthChem’s global geochemistry database with CZ regolith data. The structure of the CZChemDB is simple, straightforward, and flexible so that it has potential to accommodate other chemical data collected from CZOs, such as pore fluid data. Furthermore, the development of CZChemDB represents the first attempt toward the standardization of geochemical data documentation and data sharing among CZOs. This effort will establish a model to bridge the connections between data acquisition, data management, data sharing, and data searching/discovering that are all essential but weak in terms of linkages within most geoscience research projects.  相似文献   

Provenance of Neoproterozoic and early Paleozoic siliciclastic rocks of the Teplá-Barrandian unit (Bohemian Massif): Evidence from U–Pb detrital zircon ages     

Kerstin Drost  Axel Gerdes  Teresa Jeffries  Ulf Linnemann  Craig Storey 《Gondwana Research》2011,19(1):213-231

New LA-ICP-MS U–Pb detrital zircon ages from Ediacaran and Paleozoic siliciclastic rocks are used to constrain provenance and paleogeographic affinities of the Teplá-Barrandian unit (TBU) in the centre of the Bohemian Massif (Central Europe, Czech Republic). The samples taken span the period from ≤ 635 Ma to ～ 385 Ma and permit recognition of provenance changes that reflect changes in geotectonic regime. Detrital zircon age spectra of two Ediacaran, one Lower Cambrian and three Upper Ordovician samples resemble the ages known from the NW African proportion of Gondwana, particularly the Trans-Saharan belt, while three rocks from higher Lower Cambrian to Lowermost Ordovician strata contain detritus that may have been derived exclusively from local sources. The age spectrum of the Devonian rock is a combination of the NW Gondwanan and local features. These new findings in combination with a wide range of published data are in agreement with a Neoproterozoic subduction-related setting at the margin of Gondwana followed by a Cambrian/Early Ordovician rifting stage and an Ordovician passive margin setting. Furthermore the data are in favour of a position of the TBU at the Gondwanan margin throughout pre-Variscan times.  相似文献   

The spatio-temporal development of Copenhagen’s bicycle infrastructure 1912–2013     

Trine Agervig Carstensen  Anton Stahl Olafsson  Nynne Marie Bech  Thea Schmidt Poulsen  Chunli Zhao 《Geografisk tidskrift / udgivet af Bestyrelsen for Det Kongelige danske geografiske selskab》2015,115(2):142-156

Cycling plays an important role in low-carbon transitions. Around the globe, cities are constructing bicycle infrastructure. The city of Copenhagen has a bicycle-friendly infrastructure celebrated for its fine-meshed network. This study documents the spatio-temporal development of Copenhagen’s bicycle infrastructure and explores how the development corresponds to other processes of urban transformation. The study builds on historical maps of bicycle infrastructure that are digitised into geographical information, which allows for a comprehensive analysis of the formation of the network. In search for identifying drivers, the study analyses the city’s spatial growth pattern, migration pattern, development of road network and changes in the transport culture. Analyses reveal that the bicycle infrastructure expanded at a relatively constant pace during distinct periods of urban transformation, including periods when the city suffered from spatial, economic and demographic decline, and dominance of car traffic. By discussing reasons and demands for constructing bicycle infrastructure, the study identifies four distinct periods in which bicycle infrastructure was constructed to enhance comfort and safety (first cycling city); the flow for cars (car city); urban liveability for soft transport (liveable city); and, finally, to improve the flow for cyclists as part a strategic re-design of urban space (liveable cycling city).  相似文献   

Heterogeneous timing of freshwater input into Kobbefjord,a low-arctic fjord in Greenland     

Jakob Abermann  Kirsty Langley  Sille M. Myreng  Kerstin Rasmussen  Dorthe Petersen 《水文研究》2021,35(11):e14413

The majority of freshwater input from Greenland to the global ocean stems from the Greenland Ice Sheet. Currently, almost a quarter of the freshwater flowing from Greenland is derived from catchments that are disconnected from the Greenland Ice Sheet. Despite their importance to the total freshwater flux and influence on fjord geochemistry, there is relatively little monitoring data available for those catchments and therefore the drivers of regional differences in export are largely unknown. We present a dataset of 12 years of discharge of four catchments less than 15 km apart, that are different in size (between 7 and 32 km²), local glacier coverage (4%–11%) and lake cover (0%–5%). They all drain into Kobbefjord, a well-studied fjord in West Greenland, near Greenland's capital Nuuk. Between catchments, the magnitude of discharge varies at annual, seasonal and sub-daily timescales, due to differences in physical catchment properties as well as local climate variability. We find that annual specific discharges vary greatly (between 1.2 and 1.9 m/year on a 12-year average) due to a longitudinal precipitation gradient from West to East caused by different amount of orographic precipitation shading. The seasonal cycle of discharge (amplitude, timing and minimum flow) differs among the sites mainly due to different exposure to solar radiation as a driver for major snowmelt; the small ice coverage in the catchments plays only a minor role in discharge variability. Dry years generally increase the relative differences in annual specific discharge and no significant temporal trends have been found in the studied catchments. On a sub-daily timescale, the difference in timing of maximum discharge during fair-weather days (>80% maximum solar radiation and no precipitation) ranged between 7 and 12 h, which is attributed to differences between the presence and elevation of lakes among the catchments. The response of discharge to major precipitation events is discussed, where a delay of between 5 and 7 h is found for the catchments that do not contain lakes near the gauge.  相似文献   

Discrete element simulation of geogrid-stabilised soil     

Michael Stahl  Heinz Konietzky  Lothar te Kamp  Hein Jas 《Acta Geotechnica》2014,9(6):1073-1084

A particle-based numerical simulation procedure is presented for the generation and calibration of geogrid-stabilised soil on the basis of experimental data. The paper describes how to simulate a biaxial geogrid depending on a specific particle and parallel bond model. Numerical and experimental pull-out tests have been performed to reproduce the pull-out force–strain behaviour of a biaxial geogrid specimen embedded in granular material under special consideration of the grain-size distribution, initial relative density, normal stress state as well as sample installation. Model analysis of soil mobilisation and geogrid deformation is presented to understand the significance of the interlocking effect as key mechanism for soil stabilisation. The procedure can be used for further investigations of the influence and effects of soil stabilisation depending on the significant properties of the interacting components (soils and geogrids).  相似文献   

Ecotones as Indicators of Changing Environmental Conditions: Rapid Migration of Salt Marsh–Upland Boundaries     

Kerstin Wasson  Andrea Woolfolk  Carla Fresquez 《Estuaries and Coasts》2013,36(3):654-664

Ecotones, the narrow transition zones between extensive ecological systems, may serve as sensitive indicators of climate change because they harbor species that are often near the limit of their physical and competitive tolerances. We investigated the ecotone between salt marsh and adjacent upland at Elkhorn Slough, an estuary in California, USA. Over a period of 10 years, we monitored movement of the ecotone–upland boundary, plant community structure, and physical factors likely to drive ecotone response. At three undiked sites, the ecotone boundary migrated about 1 m landward, representing a substantial shift for a transition zone that is only a few meters wide. Analysis of potential correlates of this upward migration suggests that it was driven by increased tidal inundation. Mean sea level did not increase during our study, but inundation at high elevations did. While the ecotone boundary responded dynamically to interannual changes in inundation at these undiked sites, the plant community structure of the ecotone remained stable. At two diked sites, we observed contrasting patterns. At one site, the ecotone boundary migrated seaward, while at the other, it showed no consistent trend. Diking appears to eliminate natural sensitivity of the ecotone boundary to interannual variation in oceanic and atmospheric drivers, with local factors (management of water control structures) outweighing regional ones. Our study shows that the marsh–upland ecotone migrated rapidly in response to environmental change while maintaining stable plant community structure. Such resilience, stability, and rapid response time suggest that the marsh–upland ecotone can serve as a sensitive indicator of climate change.  相似文献   

Spectroscopic studies of southern-hemisphere cepheids: WW Car,SX Car,UZ Car,UY Car,GX Car,HW Car,YZ Car     

I. A. Usenko  L. N. Berdnikov  V. V. Kravtsov  A. Yu. Kniazev  R. Chini  V. H. Hoffmeister  O. Stahl  H. Drass 《Astronomy Letters》2011,37(10):718-725

For seven faint southern Cepheids (WW Car, SX Car, UZ Car, UY Car, GX Car, HW Car, YZ Car), we have determined their atmospheric parameters and chemical composition for the first time based on ten high-resolution (R = 50 000) spectra taken with the 1.5-m Hexapod telescope at the Joint Observatory of the Northern Catholic University (Antofagasta, Chile) and the Ruhr University (Bochum, Germany). Six objects from the list demonstrate atmospheric parameters and chemical composition typical of Cepheids that have passed through the first dredge-up phase, while WW Car is probably an anomalous Cepheid. According to our preliminary estimates, it has an overabundance of CNO, a deficit of sodium and aluminum, and a slight deficit of magnesium, with iron and other elements being underabundant relative to the Sun.  相似文献   

Ultrafast, > 50 Hz LA‐ICP‐MS Spot Analysis Applied to U–Pb Dating of Zircon and other U‐Bearing Minerals     

David Chew  Kerstin Drost  Joseph A. Petrus 《Geostandards and Geoanalytical Research》2019,43(1):39-60

LA‐ICP‐MS U–Pb detrital zircon studies typically analyse 50–200 grains per sample, with the consequent risk that minor but geologically important age components (e.g., the youngest detrital zircon population) are not detected, and higher abundance age components are misrepresented, rendering quantitative comparisons between samples impossible. This study undertook rapid U–Pb LA‐ICP‐MS analyses (8 s per 18–47 μm diameter spot including baseline and ablation) of zircon, apatite, rutile and titanite using an aerosol rapid introduction system (ARIS). As the ARIS resolves individual single pulses at fast sampling rates, spot analyses require a high repetition rate (> 50 Hz) so the signal does not return to baseline and mass sweep times (> 80 ms) that span several laser pulses (i.e., major undersampling of the signal). All rapid U–Pb spot analyses employed 250–300 pulses, repetition rates of 53–65 Hz (total ablation times of 4.1–5.7 s) and low fluence (1.75–2.5 J cm^?2), resulting in pit depths of ca. 15 μm. Zircon, apatite, rutile and titanite reference material data yield an accuracy and precision (2s) of < 1% for pre‐Cenozoic reference materials and < 2% for younger reference materials. We present a detrital zircon data set from a Neoproterozoic tillite where > 1000 grains were analysed in < 3 h with a precision and accuracy comparable to conventional LA‐ICP‐MS analytical protocols, demonstrating the rapid acquisition of huge detrital data sets.  相似文献   

Interaction between warm Atlantic‐sourced waters and the East Greenland Current in northern Denmark Strait (68°N) during the last 10 600 cal a BP          下载免费PDF全文

Kerstin Perner  Anne E. Jennings  Matthias Moros  John T. Andrews  Lukas Wacker 《第四纪科学杂志》2016,31(5):472-483

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The distribution and relative toxic potential of organic chemicals in a PCB contaminated bay     

Sundberg H  Tjärnlund U  Kerman G  Blomberg M  Ishaq R  Grunder K  Hammar T  Broman D  Balk L 《Marine pollution bulletin》2005,50(2):195-207

For reliable monitoring of environmental improvement, the PCB contaminated bay Orserumsviken on Sweden's Baltic coast was investigated prior to remediation. We examined PCB congener patterns and the relative toxic potential of PCBs in extracts of three matrices: bottom sediment, settling particulate matter and the dissolved phase (obtained from semi-permeable membrane devices). Congener patterns were similar in all matrices. Three fractions were isolated from the extracts: (1) aliphatic and monocyclic aromatic compounds (MAC-fraction), (2) dicyclic aromatic compounds (DAC-fraction), including PCBs, and (3) polycyclic aromatic compounds (PAC-fraction), including PAHs. Total extracts and fractions were injected into newly fertilised rainbow trout eggs. At larval stage, hepatic EROD activities were quantified. Though high, the PCB contamination could explain only an estimated 1-5% of the total EROD induction. The order of EROD induction potential was: total extract > PAC-fraction > DAC-fraction > MAC-fraction in all matrices, suggesting that in Orserumsviken PACs made a larger contribution to the EROD induction potential than PCBs and other DACs.  相似文献