Dolomitization of the Waulsortian Limestone (Lower Carboniferous) in the Irish Midlands   总被引：1，自引：0，他引：1  

Jay M. Gregg  Kevin L. Shelton  Aaron W. Johnson  Ian D. Somerville  & Wayne R. Wright 《Sedimentology》2001,48(4):745-766

The Waulsortian Limestone (Lower Carboniferous) of the southern Irish Midlands is dolomitized pervasively over a much larger region than previous studies have documented. This study indicates a complex, multistage, multiple fluid history for regional dolomitization. Partially and completely dolomitized sections of Waulsortian Limestones are characterized by finely crystalline (0·01–0·3 mm) planar dolomite. Planar replacive dolomite is commonly followed by coarse (≥0·5 mm) nonplanar replacive dolomite, and pervasive void‐filling saddle dolomite cement is frequently associated with Zn–Pb mineralization. Planar dolomite has average δ¹⁸O and δ¹³C values (‰ PDB) of –4·8 and 3·9 respectively. These are lower oxygen and slightly higher carbon isotope values than averages for marine limestones in the Waulsortian (δ¹⁸O=–2·2, δ¹³C=3·7). Mean C and O isotope values of planar replacive dolomite are also distinct from those of nonplanar and saddle dolomite cement (–7·0 and 3·3; –7·4 and 2·4 respectively). Fluid inclusions indicate a complex history involving at least three chemically and thermally distinct fluids during dolomite cementation. The petrography and geochemistry of planar dolomites are consistent with an early diagenetic origin, possibly in equilibrium with modified Carboniferous sea water. Where the Waulsortian was exposed to hydrothermal fluids (70–280 °C), planar dolomite underwent a neomorphic recrystallization to a coarser crystalline, planar and nonplanar dolomite characterized by lower δ¹⁸O values. Void‐filling dolomite cement is isotopically similar to nonplanar, replacive dolomite and reflects a similar origin from hydrothermal fluids. This history of multiple stages of dolomitization is significantly more complex than earlier models proposed for the Irish Midlands and provides a framework upon which to test competing models of regional vs. localized fluid flow.  相似文献   

Material flow analysis for an industry—A case study in packaging     

Kevin Sandgren 《Natural Resources Research》1996,5(4):235-247

The basic materials used in packaging are glass, metals (primarily aluminum and steel), an ever-growing range of plastics, paper and paperboard, wood, textiles for bags, and miscellaneous other materials (such as glues, inks, and other supplies). They are fabricated into rigid, semirigid, or flexible containers. The most common forms of these containers include cans, drums, bottles, cartons, boxes, bags, pouches, and wraps. Packaging products are, for the most part, low cost, bulky products that are manufactured close to their customers. There is virtually no import or export of packaging products. A material flow analysis can be developed that looks at all inputs to an industrial sector, inventories the losses in processing, and tracks the fate of the material after its useful life. An example is presented that identifies the material inputs to the packaging industry, and addresses the ultimate fate of the materials used.Correspondence should be directed to Earle B. Amey, U.S. Geological Survey, National Center 983, Reston, Virginia 20192.  相似文献   

Scales of nutrient-limited phytoplankton productivity in Chesapeake Bay   总被引：1，自引：0，他引：1  

Thomas C. Malone  Daniel J. Conley  Thomas R. Fisher  Patricia M. Glibert  Lawrence W. Harding  Kevin G. Sellner 《Estuaries and Coasts》1996,19(2):371-385

The scales on which phytoplankton biomass vary in response to variable nutrient inputs depend on the nutrient status of the plankton community and on the capacity of consumers to respond to increases in phytoplankton productivity. Overenrichment and associated declines in water quality occur when phytoplankton growth rate becomes nutrient-saturated, the production and consumption of phytoplankton biomass become uncoupled in time and space, and phytoplankton biomass becomes high and varies on scales longer than phytoplankton generation times. In Chesapeake Bay, phytoplankton growth rates appear to be limited by dissolved inorganic phosphorus (DIP) during spring when biomass reaches its annual maximum and by dissolved inorganic nitrogen (DIN) during summer when phytoplankton growth rates are highest. However, despite high inputs of DIN and dissolved silicate (DSi) relative to DIP (molar ratios of N∶P and Si∶P>100), seasonal accumulations of phytoplankton biomass within the salt-intruded-reach of the bay appear to be limited by riverine DIN supply while the magnitude of the spring diatom bloom is governed by DSi supply. Seasonal imbalances between biomass production and consumption lead to massive accumulations of phytoplankton biomass (often>1,000 mg Chl-a m^?2) during spring, to spring-summer oxygen depletion (summer bottom water <20% saturation), and to exceptionally high levels of annual phytoplankton production (>400 g m^?2 yr^?1). Nitrogen-dependent seasonal accumulations of phytoplankton biomass and annual production occur as a consequence of differences in the rates and pathways of nitrogen and phosphorus cycling within the bay and underscore the importance of controlling nitrogen inputs to the mesohaline and lower reaches of the bay.  相似文献   

External nutrient sources,internal nutrient pools,and phytoplankton production in Chesapeake Bay     

Robert E. Magnien  Robert M. Summers  Kevin G. Sellner 《Estuaries and Coasts》1992,15(4):497-516

External nutrient loadings, internal nutrient pools, and phytoplankton production were examined for three major subsystems of the Chesapeake Bay Estuary—the upper Mainstem, the Patuxent Estuary, and the 01 Potomac Estuary—during 1985–1989. The atomic nitrogen to phosphorus ratios (TN:TP) of total loads to the 01 Mainstem, Patuxent, and the Potomac were 51, 29 and 35, respectively. Most of these loads entered at the head of the estuaries from riverine sources and major wastewater treatment plants. Approximately 7–16% for the nitrogen load entered the head of each estuary as particulate matter in contrast to 48–69% for phosphorus. This difference is hypothesized to favor a greater loss of phosphorus than nitrogen through sedimentation and burial. This process could be important in driving estuarine nitrogen to phosphorus ratios above those of inputs. Water column TN: TP ratios in the tidal fresh, oligohaline, and mesohaline salinity zones of each estuary ranged from 56 to 82 in the Mainstem, 27 to 48 in the Patuxent, and 72 to 126 in the Potomac. A major storm event in the Potomac watershed was shown to greatly increase the particulate fraction of nitrogen and phosphorus and lower the TN:TP in the river-borne loads. The load during the month that contained this storm (November 1985) accounted for 11% of the nitrogen and 31% of the phosphorus that was delivered to the estuary by the Potomac River during the entire 60-month period examined here. Within the Mainstem estuary, salinity dilution plots revealed strong net sources of ammonium and phosphate in the oligohaline to upper mesohaline region, indicating that these areas were sites of considerable internal recycling of nutrients to surface waters. The sedimentation of particulate nutrient loads in the upper reaches of the estuary is probably a major source of these recycled nutrients. A net sink of nitrate was indicated during summer. A combination of inputs and these internal recycling processes caused dissolved inorganic N to P ratios to approach 16:1 in the mesohaline zone of the Mainstem during late summer; this ratio was much higher at other times and in the lower salinity zones. Phytoplankton biomass in the mesohaline Mainstem reached a peak in spring and was relatively constant throughout the other seasons. Productivity was highest in spring and summer, accounting for approximately 33% and 44%, respectively, of the total annual productivity in this region. In the Patuxent and Potomac, the TN:TP ratios of external loads documented here are 2–4 times higher than those observed over the previous two decades. These changes are attributed to point-source phosphorus controls and the likelihood that nitrogen-rich nonpoint source inputs, including contributions from the atmosphere, have increased. These higher N:P ratios relative to Redfield proportions (16:1) now suggest a greater overall potential for phosphorus-limitation rather than nitrogen-limitation of phytoplankton in the areas studied.  相似文献   

Short-Period Waves That Heat the Corona Detected at the 1999 Eclipse     

Pasachoff  Jay M.  Babcock  Bryce A.  Russell  Kevin D.  Seaton  Daniel B. 《Solar physics》2002,207(2):241-257

As a part of a study of the cause of solar coronal heating, we searched for high-frequency (1 Hz) intensity oscillations in coronal loops in the [Fexiv] coronal green line. We summarize results from observations made at the 11 August 1999 total solar eclipse from Râmnicu-Vâlcea, Romania, through clear skies. We discuss the image reduction and analysis through two simultaneous series of coronal CCD images digitized at 10 Hz for a total time of about 140 s. One series of images was taken through a 3.6 Å filter isolating the 5303 Å[Fexiv] coronal green line and the other through a 100 Å filter in the nearby K-corona continuum. Previous observations, described in Pasachoff et al. (2000), showed no evidence for oscillations in the [Fexiv] green line at a level greater than 2% of coronal intensity. We describe several improvements made over the 1998 eclipse that led to increased image clarity and sensitivity. The corona was brighter in 1999 with the solar maximum, further improving the data. We use Fourier analysis to search in the [Fexiv] channel for intensity oscillations in loops at the base of the corona. Such oscillations in the 1-Hz range are predicted as a result of density fluctuations from the resonant absorption of MHD waves. The dissipation of a significant amount of mechanical energy from the photosphere into the corona through this mechanism could provide sufficient energy to heat the corona. A Monte Carlo model of the data suggests the presence of enhanced power, particularly in the 0.75–1.0 Hz range, and we conclude that MHD waves remain a viable method for coronal heating.  相似文献   

Fresh Ammonia Ice Clouds in Jupiter: I. Spectroscopic Identification, Spatial Distribution, and Dynamical Implications     

Kevin H. BainesRobert W. Carlson  Lucas W. Kamp 《Icarus》2002,159(1):74-94

We report the first spectroscopic detection of discrete ammonia ice clouds in the atmosphere of Jupiter, as discovered utilizing the Galileo Near-Infrared Mapping Spectrometer (NIMS). Spectrally identifiable ammonia clouds (SIACs) cover less than 1% of the globe, as measured in complete global imagery obtained in September 1996 during Galileo's second orbit. More than half of the most spectrally prominent SIACs reside within a small latitudinal band, extending from 2° to 7° N latitude, just south of the 5-μm hot spots. The most prominent of these are spatially correlated with nearby 5-μm-bright hot spots lying 1.5°-3.0° of latitude to the north: they reside over a small range of relative longitudes on the eastward side of hot spots, about 37% of the longitudinal distance to the next hot spot to the east. This strong correlation between the positions of hot spots and the most prominent equatorial SIACs suggests that they are linked by a common planetary wave. Good agreement is demonstrated between regions of condensation predicted by the Rossby wave model of A. J. Friedson and G. S. Orton (1999, Bull. Am. Astron. Assoc31, 1155-1156) and the observed longitudinal positions of fresh ammonia clouds relative to 5-μm hot spots. Consistency is also demonstrated between (1) the lifetime of particles as determined by the wave phase speed and cloud width and (2) the sedimentation time for 10-μm radius particles consistent with previously reported ammonia particle size by T. Y. Brooke et al. (1998, Icarus136, 1-13). A young age (<two days) for most SIAC cloud particles is indicated. To the south, the most prominent SIACs are located to the northwest of the Great Red Spot, in a region where a westward flow of jovian air, diverted approximately 10° of latitude northward by the Great Red Spot, encounters a large eastward flow. SIACs have been observed repeatedly by NIMS at this location during Galileo's first four years in Jupiter orbit. It is speculated that due to the three-dimensional interactions of these flows, relatively large amounts of ammonia gas are steadily transported from the sub-cloud troposphere (below the ∼600-mbar level) to the high troposphere, nearly continuously forming fresh ammonia ice clouds to the northwest of the Great Red Spot.  相似文献   

Thematic Section: Dynamic sedimentation in forearc basins: Results from the Choshi and Sagara drilling projects     

Hiroshi Kitazato  Hideki Wada  Kevin T. Pickering  Asahiko Taira 《Island Arc》2006,15(3):283-284

  相似文献   

The Enso-Fire Dynamic in Insular Southeast Asia     

Douglas O. fuller  Kevin Murphy 《Climatic change》2006,74(4):435-455

We examined the spatiotemporal patterns of fire in insular Southeast Asia from July 1996 to December 2001 using a set of consistent, nighttime fire observations provided by the Along Track Scanning Radiometer (ATSR) sensor. Monthly ATSR fire counts were analyzed relative to georeferenced climatic and land-cover data from a variety of sources. We found that fires were strongly correlated with Southern Oscillation Index (SOI) (r = ?0.75) and Niño 3.4 index (r = 0.72) in forested land-cover types within the equatorial belt (5.5^°S–5.5^°N). Cross-correlation analysis revealed that detrended SOI was modestly correlated (r = 0.42) with detrended monthly fire count with a positive lag of four months. However, our analysis also revealed that fire counts reached their maximum 6 months before the absolute maximum of SOI. Annual sums of SOI (∑_SOI) and fire counts revealed linearity for ∑_SOI≤ 0. Overall, the results suggest that ENSO indices may have limited predictive utility at a monthly time scale, but that temporal aggregation and additional fire observations may enhance our capacity to forecast fires in different cover types based on ENSO data.  相似文献   

Electron tunneling properties of outer-membrane decaheme cytochromes from Shewanella oneidensis     

Nicholas S. Wigginton  Kevin M. Rosso  Liang Shi 《Geochimica et cosmochimica acta》2007,71(3):543-555

We have characterized the outer-membrane decaheme cytochromes OmcA and MtrC from Shewanella oneidensis MR-1 at the single-molecule level using scanning tunneling microscopy (STM) and tunneling spectroscopy (TS). These cytochrome proteins are of great interest because they are thought to mediate bacterial electron transfer reactions in anoxic waters that control the reductive dissolution of oxide minerals. In our study, to characterize the electron transfer properties of these proteins on a model surface, the purified cytochromes were chemically immobilized as molecular monolayers on Au(111) substrates via a recombinant tetra-cysteine sequence as verified by X-ray photoelectron spectroscopy. Atomic force microscopy images confirm the monolayer films were ∼5-8 nm thick which is consistent with the apparent lateral dimensions of individual cytochrome molecules obtained with STM. Current-voltage TS of single cytochrome molecules revealed that OmcA and MtrC have different abilities to mediate tunneling current despite having otherwise very similar molecular and biochemical properties. These observations suggest that, based on their electron tunneling properties, the two cytochromes could have specific roles during bacterial metal reduction. Additionally, this study establishes single-molecule STM/TS as an effective means for revealing insights into biogeochemical redox processes in the environment.  相似文献   

Living and working in urban working class communities     

Kevin Ward  Colette Fagan 《Geoforum》2007,38(2):312-325

Much has been written on the apparent urban renaissance in UK cities and the new lifestyle arrangements, working time patterns, economic activities and the more general reordering of work and life that appears to accompany it. Certainly, recent decades have witnessed a range of economic, social and cultural changes in the lives of those living and working in cities and surrounding suburbs. Much of the attention in this work has focused on those groups for whom the changes have appeared most profound: the high-income earners returning to live in the city - the gentrifiers - or those who suffer multiple deprivations as a result of economic restructuring. Seemingly absent from many accounts of urban change are those places where, at first glance, the effects of change have been less pronounced: low-income, working class neighbourhoods where most people continue to get by, albeit in the context of a harsher, and less secure political economic context. In light of this apparent silence, this paper draws on interviews from Wythenshawe in South Manchester, to examine how low-income mothers cope, live and labour, in a rapidly changing city, as they perform paid work at the same time as ensuring the social reproduction of the household.  相似文献