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31.
ABSTRACT

This study assesses the performance of Fourier series in representing seasonal variations of the tropical rainfall process in Malaysia. Fourier series are incorporated into a spatial-temporal stochastic model in an attempt to make the model parsimonious and, at the same time, capture the annual variation of rainfall distribution. In view of Malaysia’s main rainfall regime, the model is individually fitted for two regions with distinctive rainfall profiles: one being an urban area receiving rainfall from convective activities whilst the other receives rainfall from monsoonal activities. Since both regions are susceptible to floods, the study focuses on the rainfall process at fine resolution. Fourier series equations are developed to represent the model’s parameters to describe their annual periodicity. The number of significant harmonics for each parameter is determined by inspecting the cumulative fraction of total variance explained by the significant harmonics. Results reveal that the number of significant harmonics assigned for the parameters is slightly higher in the region with monsoonal rains. The overall simulation results show that the proposed model is capable of generating tropical rainfall series from convective and monsoonal activities.
Editor D. Koutsoyiannis Associate editor K. Hamed  相似文献   
32.
Abstract

The Hulu Langat basin, a strategic watershed in Malaysia, has in recent decades been exposed to extensive changes in land-use and consequently hydrological conditions. In this work, the impact of Land Use and Cover Change (LUCC) on hydrological conditions (water discharge and sediment load) of the basin were investigated using the Soil and Water Assessment Tool (SWAT). Four land-use scenarios were defined for land-use change impact analysis, i.e. past, present (baseline), future and water conservation planning. The land-use maps, dated 1984, 1990, 1997 and 2002, were defined as the past scenarios for LUCC impact analysis. The present scenario was defined based on the 2006 land-use map. The 2020 land-use map was simulated using a cellular automata-Markov model and defined as the future scenario. Water conservation scenarios were produced based on guidelines published by Malaysia’s Department of Town and Country Planning and Department of Environment. Model calibration and uncertainty analysis was performed using the Sequential Uncertainty Fitting (SUFI-2) algorithm. The model robustness for water discharge simulation for the period 1997–2008 was good. However, due to uncertainties, mainly resulting from intense urban development in the basin, its robustness for sediment load simulation was only acceptable for the calibration period 1997–2004. The optimized model was run using different land-use maps over the periods 1997–2008 and 1997–2004 for water discharge and sediment load estimation, respectively. In comparison to the baseline scenario, SWAT simulation using the past and conservative scenarios showed significant reduction in monthly direct runoff and monthly sediment load, while SWAT simulation based on the future scenario showed significant increase in monthly direct runoff, monthly sediment load and groundwater recharge.
Editor D. Koutsoyiannis; Associate editor C. Perrin  相似文献   
33.
The suitability of groundwater quality for drinking and agricultural purposes was assessed in the rural areas of Delhi based on the various water quality parameters. A total of 50 ground water samples were collected randomly from different sources viz. hand pump, tube well, boring and analyzed for major ion chemistry to understand the operating mechanism of geochemical processes for ground water quality. The quality analysis is performed through the estimation of pH, EC, TDS, total hardness, total alkalinity, Na, K, Cl, NO3, SO4, DO, BOD, Cu, Cr, Cd, Ni, Zn and Pb. Hydrochemical facies were identified using Piper, Durov and Chadha diagram. Chemical data were also used for mathematical calculations (SAR, %Na, RSC, PI, KI, and chloroalkaline indices) for better understanding the suitability of ground water for irrigation purposes. The results of saturation index shows that all the water samples were supersaturated to undersaturated with respect to carbonate minerals and undersaturated with respect to sulphate and chloride minerals. According to USSL diagram, most of the samples fall in the field of C3S1, indicating medium salinity and low sodium water which can be used for almost all types of soil with little danger of exchangeable sodium. Assessment of water samples from various methods indicated that majority of the ground water in the study area is chemically suitable for drinking and agricultural uses.  相似文献   
34.
A field study was performed at rivers in Gunung Jerai forest reserve(Kedah,Malaysia) to assess seasonal changes in mayfly community structure and abundance in relation to altitude and water physicochemistry.Rivers at lower(Batu Hampar River) and higher(Teroi River) elevations were visited through dry and wet seasons in September 2007 to August 2008.Monthly visits were made to 20 sites on each river,and water and aquatic insects were sampled using D-pond aquatic nets.Water was warmer,more acid,and more turbid in Teroi River during wet season.Ammonia was the only nutrient exhibiting significant seasonal variations(greater during wet season).Chemical oxygen demand content was higher in Teroi River where biochemical oxygen demand content was low during wet season.Species richness was higher in Batu Hampar River,but displayed seasonal variations only in Teroi River.Among the eight families encountered,Baetidae was the commonest.Baetid abundance was usually high during wet season,and those belonging to the dominant genus(Baetis) were more abundant in Teroi River.Heptageniidae was the second commonest family;its predominant genus,Thalerospyrus was more abundant in Teroi River during dry season.Caenidae,Leptophlebiidae and Oligoneuriidae were only found in Batu Hampar River where their abundances peaked during dry season,i.e.,Habrophlebiodes sp.and Isonychia sp.Ephemerellidae and Teloganodidae occurred only in Teroi River,with the first found only during dry season.Mayflies were recorded under very distinct physicochemical conditions,illustrating their potential usefulness for assessing water quality.Caenids,leptophlebids,oligoneurids ephemerellids and teloganodids seem to be particularly sensitive to temperature,acidity,turbidity,chemical oxygen demand and biochemical oxygen demand,parameters that varied with river altitude.  相似文献   
35.
The effect of calcium-based stabilizers such as lime on the geotechnical properties of tropical soils has been reported by many researchers. However, the amount of literature available on the micro-structural, molecular, and leaching characteristics of lime and in particular phosphoric acid-stabilized lateritic clays has been limited. This research was carried out in an attempt to identify the time-dependent soil-chemical reactions. In addition, the possible mechanisms that contributed to the stabilization process were discussed in the light of various spectroscopic and microscopic techniques such as X-ray diffractometry (XRD), energy-dispersive X-ray spectrometry (EDAX), field emission scanning electron microscopy (FESEM), Fourier transform infrared spectroscopy (FTIR), and nuclear magnetic resonance spectroscopy (NMR) etc. Based on the results it was found that in lime-treated samples, the coating action of free iron oxides on clay particles imposed inhibitive effects on the dissolution of clay alumina. On the other hand, in phosphoric acid-stabilized soil, due to the increase in solubility of metal oxides and also the subsequent release of clay alumina the formation of cementitious compounds were more feasible. From engineering point of view, the phosphoric acid-stabilized lateritic soil showed the highest degree of improvement with an approximately threefold strength increase in comparison with the natural soil over an 8-month curing period.  相似文献   
36.
The separation of vanillin from the lignin of empty fruit bunch oil palm is presented in this study. The lignin was extracted from soda black liquor derived from oil palm empty fruit bunches (EFB) using 20% sulfuric acid. Nitrobenzene oxidation was carried out by adding 50 mg of dry EFB lignin into a mixture of 7 mL of 2 M NaOH and 4 mL of nitrobenzene in a 15 mL steel autoclave. The autoclave was sealed tightly with a screw cap fitted with a Teflon gasket and heated to 165°C for 3 h in a preheated thermostatic oil bath. High performance liquid chromatography (HPLC) was used to determine the concentration of each compound present in the lignin. There were eight compounds detected in the HPLC chromatogram. The crystallization process was then used as a method to separate vanillin from other compounds. Based on the solubility of vanillin in acetone, 15 mL of acetone was added to the residue of the oxidized products and heated to 60°C for 10 min. A yield of 1.6% vanillin was isolated from a 50 mg lignin sample. The isolated compound was analyzed with HPLC, Fourier transform infrared spectrophotometry (FT‐IR) and nuclear magnetic resonance (13C‐NMR) for structural verification. The results of the characterization studies proved that the isolated compound is vanillin.  相似文献   
37.
We are very aware of the importance of the ozone layer, without which life on the Earth would not have evolved in the way it has. Solar storms carry energetic protons into the Earth's upper atmosphere,where they boost production of nitrogen oxides which are known as ozone killers and which ultimately increase ultraviolet(UV) radiations. In the present study, we estimate the effects of solar energetic protons during super storms(Dst index -300 nT) over the total ozone column for the last 32 yr. We select a total of seven super storm events that occurred during solar cycles 22–24(for the last 32 yr) having Dst index -300 nT. To that end, we apply superposed epoch analysis(SEA) to verify the impact of storm events on the quantitative variation of total ozone column and on UV radiations during super storm events.After completing the empirical analysis, we conclude that the ozone column gets depleted significantly(22±6.8%) as proton density increases during super storm events and this decrement in the ozone level is further responsible for a substantial increase(26±11.2%) in peak UV radiation intensities.  相似文献   
38.
The impact of surface melt patterns and the Indian summer monsoon (ISM) is examined on the varying contributions of end member (snow, glacier ice, and rain) to proglacial streamflow during the ablation period (June–October) in the Chhota Shigri glaciated basin, Western Himalaya. Isotopic seasonality observed in the catchment precipitation was generally reflected in surface runoff (supraglacial melt and proglacial stream) and shows a shift in major water source during the melt season. Isotopically correlated (δ18O–δD) high deuterium intercept in the surface runoff suggests that westerly precipitation acts as the dominant source, augmenting the other snow- and ice-melt sources in the region. The endmember contributions to the proglacial stream were quantified using a three-component mixing. Overall, glacier ice melt is the major source of proglacial discharge. Snowmelt is the predominant source during the early ablation season (June) and the peak ISM period (August and September), whereas ice melt reaches a maximum in the peak melt period (July). The monthly contribution of rain is on the lower side and shows a steady rise and decline with onset and retreat of the monsoon. These results are persistent with the surface melt pattern observed in Chhota Shigri glacier, Upper Chandra basin. Moreover, the role of the ISM in Chhota Shigri glacier is unvarying to that observed in other glacierized catchments of Upper Ganga basin. Thus, this study augments the significant role of the ISM in glacier mass balance up to the boundary of the central-western Himalayan glaciated region.  相似文献   
39.
In this work, the X-ray Photoelectron Spectroscopy (XPS) technique is utilized to analyze the surface chemical composition of particulate matter (PM) which was collected from various locations at Jeddah, Saudi Arabia. The main elements found on the surface of PM are carbon (C), oxygen (O) and silicon (Si) with combined percentage of 89.4–94.9 while traces of nitrogen (N), calcium (Ca), aluminum (Al), sodium (Na), chlorine (Cl), manganese (Mg), and sulfur (S) were also present. The analyzed XPS chemical state of C, O and Si was further used to determine their bonding with other elements occurring over the surface of PM. Carbon was found in the form of carbides (18.86%), fluorides (2.39%) and carbonates (78.75%); oxygen was observed as oxides (21.05%) and hydroxides (73.42%) of other metals; and silicon was detected as silicones (12.16%), nitrides (82.53%) and silicates (5.25%). The particle size of a PM is also of great concern for health issues, and thus has been investigated by the Field Emission Scanning Electron Microscope (FESEM). The Energy Dispersive X-ray Spectroscopy (EDS) was employed for cross verification of detected elements by XPS.  相似文献   
40.
The existence of intra-plate deformation of the Sundaland platelet along its eastern edge in North Borneo, South-East Asia, makes it an interesting area that still is relatively understudied. In addition, the motion of the coastal area of North-West Borneo is directed toward a frontal fold-and-thrust belt and has been fueling a long debate on the possible geophysical sources behind it. At present this fold-and-thrust belt is not generating significant seismic activity and may also not be entirely active due to a decreasing shelfal extension from south to north. Two sets of Global Positioning System (GPS) data have been used in this study; the first covering a time period from 1999 until 2004 (ending just before the Giant Sumatra–Andaman earthquake) to determine the continuous Sundaland tectonic plate motion, and the second from 2009 until 2011 to investigate the current deformations of North Borneo. Both absolute and relative positioning methods were carried out to investigate horizontal and vertical displacements. Analysis of the GPS results indicates a clear trend of extension along coastal regions of Sarawak and Brunei in North Borneo. On the contrary strain rate tensors in Sabah reveal that only insignificant and inconsistent extension and compression occurs throughout North-West Borneo. Moreover, station velocities and rotation rate tensors on the northern part of North Borneo suggest a clockwise (micro-block) rotation. The first analysis of vertical displacements recorded by GPS in North-West Borneo points to low subsidence rates along the western coastal regions of Sabah and inconsistent trends between the Crocker and Trusmadi mountain ranges. These results have not been able to either confirm or reject the hypothesis that gravity sliding is the main driving force behind the local motions in North Borneo. The ongoing Sundaland–Philippine Sea plate convergence may also still play an active role in the present-day deformation (crustal shortening) in North Borneo and the possible clockwise rotation of the northern part of North Borneo as a micro-block. However, more observations need to be collected to determine if the northern part of North Borneo indeed is (slowly) moving independently.  相似文献   
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