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991.
Cordieritites and highly peraluminous granites within the ElPilón granite complex, Sierras Pampeanas, Argentina,were emplaced during a medium-P, high-T metamorphic event duringthe initial decompression of a Cambrian orogen along the southwesternmargin of Gondwana. Very fresh orbicular and massive cordierititebodies with up to 90% cordieritite are genetically associatedwith a cordierite monzogranite pluton and a larger body of porphyriticgranodiorite. The petrogenesis of this association has beenstudied using petrographical, mineralogical, thermobarometric,geochemical, geochronological and isotope methods. The graniticmagmas were formed by anatexis of mid-crustal metamorphic rocksformed earlier in the Pampean orogeny. The cordieritites appearat the top of feeder conduits that connected the source regionlocated at  相似文献   
992.
ABSTRACT The depositional organization and architecture of the middle–late Devonian Yangdi rimmed carbonate platform margin in the Guilin area of South China were related to oblique, extensional faulting in a strike‐slip setting. The platform margin shows two main stages of construction in the late Givetian to Frasnian, with a bioconstructed margin evolving into a sand‐shoal system. In the late Givetian, the platform margin was rimmed with microbial buildups composed mainly of cyanobacterial colonies (mostly Renalcis and Epiphyton). These grew upwards and produced an aggradational (locally slightly retrogradational) architecture with steep foreslope clinoforms. Three depositional sequences (S3–S5) are recognized in the upper Givetian strata, which are dominated by extensive microbialites. Metre‐scale depositional cyclicity occurs in most facies associations, except in the platform‐margin buildups and upper foreslope facies. In the latest Givetian (at the top of sequence S5), relative platform uplift (± subaerial exposure) and associated rapid basin subsidence (probably a block‐tilting effect) caused large‐scale platform collapse and slope erosion to give local scalloped embayments along the platform margin and the synchronous demise of microbial buildups. Subsequently, sand shoals and banks composed of ooids and peloids and, a little later, stromatoporoid buildups on the palaeohighs, developed along the platform margin, from which abundant loose sediment was transported downslope to form gravity‐flow deposits. Another strong tectonic episode caused further platform collapse in the early Frasnian (at the top of sequence S6), leading to large‐scale breccia release and the death of the stromatoporoid buildups. Siliceous facies (banded cherts and siliceous shales) were then deposited extensively in the basin centre as a result of the influx of hydrothermal fluids. The platform‐margin sand‐shoal/bank system, possibly with gullies on the slope, persisted into the latest Frasnian until the restoration of microbial buildups. Four sequences (S6–S9), characterized by abundant sand‐shoal deposits on the margin and gravity‐flow and hemipelagic deposits on the slope, are distinguished in the Frasnian strata. Smaller‐scale depositional cyclicity is evident in all facies associations across the platform–slope–basin transect. The distinctive depositional architecture and evolution of this Yangdi Platform are interpreted as having been controlled mainly by regional tectonics with contributions from eustasy, environmental factors, oceanographic setting, biotic and sedimentary fabrics.  相似文献   
993.
Abstract River avulsions are commonly considered to be driven by the aggradation and growth of alluvial ridges, and the associated increase in cross‐valley slope relative to either the down‐channel slope or the down‐valley slope (the latter is termed the slope ratio in the present paper). Therefore, spatial patterns of overbank aggradation rate over stratigraphically relevant time scales are critical in avulsion‐dominated models of alluvial architecture. Detailed evidence on centennial‐ to millennial‐scale floodplain deposition has, to date, been largely unavailable. New data on such long‐term overbank aggradation rates from the Rhine–Meuse and Mississippi deltas demonstrate that the rate of decrease of overbank deposition away from the channel belt is much larger than has been supposed hitherto, and can be similar to observations for single overbank floods. This leads to more rapid growth of alluvial ridges and more rapid increase in slope ratios, potentially resulting in increased avulsion frequencies. A revised input parameter for overbank aggradation rate was used in a three‐dimensional model of alluvial architecture to study its effect on avulsion frequency. Realistic patterns of avulsion and interavulsion periods (≈1000 years) were simulated with input data from the Holocene Rhine River, with avulsions occurring when the slope ratio is in the range 3–5. However, caution should be practised with respect to uncritical use of these numbers in different settings. Evidence from the two study areas suggests that the avulsion threshold cannot be represented by one single value, irrespective of whether critical slope ratios are used, as in the present study, or superelevation as has been proposed by other investigators.  相似文献   
994.
The left-lateral Amanos Fault follows a 200-km-long and up to 2-km-high escarpment that bounds the eastern margin of the Amanos mountain range and the western margin of the Karasu Valley in southern Turkey, just east of the northeastern corner of the Mediterranean Sea. Regional kinematic models have reached diverse conclusions as to the role of this fault in accommodating relative motion between either the African and Arabian, Turkish and African, or Turkish and Arabian plates. Local studies have tried to estimate its slip rate by K–Ar dating Quaternary basalts that erupted within the Amanos Mountains, flowed across it into the Karasu Valley, and have since become offset. However, these studies have yielded a wide range of results, ranging from 0.3 to 15 mm a−1, which do not allow the overall role and significance of this fault in accommodating crustal deformation to be determined. We have used the Cassignol K–Ar method to date nine Quaternary basalt samples from the vicinity of the southern part of the Amanos Fault. These basalts exhibit a diverse chemistry, which we interpret as a consequence varying degrees of partial melting of their source combined with variable crustal contamination. This dating allows us to constrain the Quaternary slip rate on the Amanos fault to 1.0 to 1.6 mm a−1. The dramatic discrepancies between past estimates of this slip rate are partly due to technical difficulties in K–Ar dating of young basalts by isotope dilution. In addition, previous studies at the key locality of Hacılar have unwittingly dated different, chemically distinct, flow units of different ages that are juxtaposed. This low slip rate indicates that, at present, the Amanos Fault takes up a small proportion of the relative motion between the African and Arabian plates, which is transferred southward to the Dead Sea Fault Zone. It also provides strong evidence against the long-standing view that its slip continues offshore to the southwest along a hypothetical left-lateral fault zone located south of Cyprus.  相似文献   
995.
The Gulf of Corinth in central Greece is an active normal fault zone with particularly clear evidence of isostatic footwall uplift, constrained by Quaternary marine terraces, and hanging-wall subsidence and sedimentation. It is bounded to the south by a Pliocene to Early Pleistocene sedimentary basin, which is now eroding into the Gulf. Previous work has suggested that the relief across this region has increased dramatically since the Early Pleistocene, due to the isostatic response to increased rates of footwall erosion and hanging-wall sedimentation. It is indeed assumed here that incision accompanying the draw-down of global sea-level at 0.9 Ma, during the first major Pleistocene glaciation, initiated the erosion of the basin south of the Gulf of Corinth and so abruptly increased the sedimentation rate in the Gulf. The resulting transient thermal and isostatic response to these changes is modelled, with the subsiding depocentre and eroding sediment source coupled by flow in the lower continental crust. The subsequent enhancement of relief, involving an increase in bathymetry from near zero to 900 m and 500 m of uplift of the eroding land surface in the sediment source, is shown to be a direct consequence of this change. The model is sensitive to the effective viscosity of the lower crust, and can thus resolve this parameter by matching observations. A value of 6×1019 Pa s is indicated, suggesting a viscosity at the Moho no greater than 1018 Pa s. Similar transient topographic effects caused by increased rates of sedimentation and erosion are likely to be widespread within the geological record, suggesting that this coupling process involving flow in the weak lower crust may be of major geological and geomorphological importance.  相似文献   
996.
We have collected about 150 magnetotelluric (MT) soundings in northeastern Nevada in the region of the Ruby Mountains metamorphic core complex uplift and southern Carlin mineral trend, in an effort to illuminate controls on core complex evolution and deposition of world-class gold deposits. The region has experienced a broad range of tectonic events including several periods of compressional and extensional deformation, which have contributed to the total expression of electrical resistivity. Most of the soundings reside in three east–west profiles across increasing degrees of core uplift to the north (Bald Mountain, Harrison Pass, and Secret Pass latitudes). One short cross-line was also taken to assess an east–west structure to the north of the northern profile. Model resistivity cross-sections were derived from the MT data using a 2-D inversion algorithm, which damps departures of model parameters from an a priori structure. Geological interpretation of the resistivity combines previous seismic, potential field and isotope models, structural and petrological models for regional compression and extension, and detailed structural/stratigraphic interpretations incorporating drilling for petroleum and mineral exploration. To first order, the resistivity structure is one of a moderately conductive, Phanerozoic sedimentary section fundamentally disrupted by intrusion and uplift of resistive crystalline rocks. Late Devonian and early Mississippian shales of the Pilot and Chainman Formations together form an important conductive marker sequence in the stratigraphy and show pronounced increases in conductance (conductivity–thickness product) from east to west. These increases are attributed to graphitization caused by Elko–Sevier era compressional shear deformation and possibly by intrusive heating. The resistive crystalline central massifs adjoin the host stratigraphy across crustal-scale, steeply dipping fault zones. The zones provide pathways to the lower crust for heterogeneous, upper crustal induced, electric current flow. Resistive core complex crust appears steeply bounded under the middle of the neighboring grabens and not to deepen at a shallow angle to arbitrary distances to the west. The numerous crustal breaks imaged with MT may contribute to the low effective elastic thickness (Te) estimated regionally for the Great Basin and exemplify the mid-crustal, steeply dipping slip zones in which major earthquakes nucleate. An east–west oriented conductor in the crystalline upper crust spans the East Humboldt Range and northern Ruby Mountains. The conductor may be related to nearby graphitic metasediments, with possible alteration by middle Tertiary magmatism. Lower crustal resistivity everywhere under the profiles is low and appears quasi one-dimensional. It is consistent with a low rock porosity (<1 vol.%) containing hypersaline brines and possible water-undersaturated crustal melts, residual to the mostly Miocene regional extension. The resistivity expression of the southern Carlin Trend (CT) in the Pinon Range is not a simple lineament but rather a family of structures attributed to Eocene intrusion, stratal deformation, and alteration/graphitization. Substantial reactivation or overprinting by core complex uplift or Basin–Range extensional events seems likely. We concur with others that the Carlin Trend may result in part from overlap of the large Eocene Northeast Nevada Volcanic Field with Precambrian–Paleozoic deep-water clastic source rocks thickening abruptly to the west of the Pinon Range, and projecting to the north–northwest.  相似文献   
997.
998.
 We have investigated a well-ordered sample of natural Cr-bearing dickite from Nowa Ruda (Lower Silesia, Poland) using electron paramagnetic resonance (EPR) at X- and Q-band frequencies (9.42 and 33.97 GHz, respectively) and optical diffuse reflectance spectroscopy. The observation of the spin-forbidden transitions at 15500 and 14690 cm−1 allows us to unambiguously identify the major contribution of octahedrally coordinated Cr3+ ions in the optical spectrum. The X- and Q-band EPR spectra show two superposed Cr3+ signals. The corresponding fine-structure parameters were determined at room temperature and 145 K. These results suggest the substitution of Cr3+ for Al3+ in equal proportions in the two unequivalent octahedral sites of the dickite structure. In kaolin group minerals, the distortion around Cr3+ ions (λ≈ 0.2–0.4) in Al sites is significantly less rhombic than that observed around Fe3+ ions (λ≈ 0.6–0.8). Received: 29 June 2001 / Accepted: 22 October 2001  相似文献   
999.
 The heat capacity of paranatrolite and tetranatrolite with a disordered distribution of Al and Si atoms has been measured in the temperature range of 6–309 K using the adiabatic calorimetry technique. The composition of the samples is represented with the formula (Na1.90K0.22Ca0.06)[Al2.24Si2.76O10nH2O, where n=3.10 for paranatrolite and n=2.31 for tetranatrolite. For both zeolites, thermodynamic functions (vibrational entropy, enthalpy, and free energy function) have been calculated. At T=298.15 K, the values of the heat capacity and entropy are 425.1 ± 0.8 and 419.1 ±0.8 J K−1 mol−1 for paranatrolite and 381.0 ± 0.7 and 383.2 ± 0.7 J K−1 mol−1 for tetranatrolite. Thermodynamic functions for tetranatrolite and paranatrolite with compositions corrected for the amount of extraframework cations and water molecules have also been calculated. The calculation for tetranatrolite with two water molecules and two extraframework cations per formula yields: C p (298.15)=359.1 J K−1 mol−1, S(298.15) −S(0)=362.8 J K−1 mol−1. Comparing these values with the literature data for the (Al,Si)-ordered natrolite, we can conclude that the order in tetrahedral atoms does not affect the heat capacity. The analysis of derivatives dC/dT for natrolite, paranatrolite, and tetranatrolite has indicated that the water- cations subsystem within the highly hydrated zeolite may become unstable at temperatures above 200 K. Received: 30 July 2001 / Accepted: 15 November 2001  相似文献   
1000.
A novel method for synthesis of aluminium hematites, based upon the homogeneous precipitation of Fe and Al oxinates in various proportions, is presented. The precursor precipitates are heated in air at 700?°C. X-ray diffraction, thermal analyses, BET, FTIR, optical reflection analysis, TEM and Mössbauer spectroscopy at room temperature and 80?K of the resulting products indicate that single-phase hematites are formed with structural Al substitution of up to 10 at%. Interestingly, the particle size (>100?nm) is not substantially reduced by the Al content. Although it remains difficult to obtain a homogeneously distributed Al substitution in the final hematite, this processing line offers a unique opportunity to separate the effects of grain size and Al substitution on the Morin transition temperature (T M) of Al hematite. From the comparison between the present hematites and a series of Al-substituted hematites with lepidocrocite as precursor, it could be shown that the effect on T M, associated with a change of a factor 10 in grain size, is about 1/3 of the effect caused by a change of 10 in the degree of substitution. Finally, it is suggested that proper thermal treatments under different conditions of the same precursors are likely to produce spinel phases.  相似文献   
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