Back-arc basin basalt systematics   总被引：7，自引：0，他引：7  

Brian Taylor  Fernando Martinez 《Earth and Planetary Science Letters》2003,210(3-4):481-497

The Mariana, east Scotia, Lau, and Manus back-arc basins (BABs) have spreading rates that vary from slow (<50 mm/yr) to fast (>100 mm/yr) and extension axes located from 10 to 400 km behind their island arcs. Axial lava compositions from these BABs indicate melting of mid-ocean ridge basalt (MORB)-like sources in proportion to the amount added of previously depleted, water-rich, arc-like components. The arc-like end-members are characterized by low Na, Ti and Fe, and by high H₂O and Ba/La; the MORB-like end-members have the opposite traits. Comparisons between basins show that the least hydrous compositions follow global MORB systematics and an inverse correlation between Na8 and Fe8. This is interpreted as a positive correlation between the average degree and pressure of mantle melting that reflects regional variations in mantle potential temperatures (Lau/Manus hotter than Mariana/Scotia). This interpretation accords with numerical model predictions that faster subduction-induced advection will maintain a hotter mantle wedge. The primary compositional trends within each BAB (a positive correlation between Fe8, Na8 and Ti8, and their inverse correlation with H₂O(8) and Ba/La) are controlled by variations in water content, melt extraction, and enrichments imposed by slab and mantle wedge processes. Systematic axial depth (as a proxy for crustal production) variations with distance from the island arc indicate that compositional controls on melting dominate over spreading rate. Hydrous fluxing enhances decompression melting, allowing depleted mantle sources just behind the island arc to melt extensively, producing shallow spreading axes. Flow of enriched mantle components around the ends of slabs may augment this process in transform-bounded back-arcs such as the east Scotia Basin. The re-circulation (by mantle wedge corner flow) to the spreading axes of mantle previously depleted by both arc and spreading melt extraction can explain the greater depths and thinner crust of the East Lau Spreading Center, Manus Southern Rifts, and Mariana Trough and the very depleted lavas of east Scotia segments E8/E9. The crust becomes mid-ocean ridge (MOR)-like where the spreading axes, further away from the island arc and subducted slab, entrain dominantly fertile mantle.  相似文献   

Comparative geochemistry of cadmium, rhenium, uranium, and molybdenum in continental margin sediments     

BjØrn Sundby  Philippe Martinez  Charles Gobeil 《Geochimica et cosmochimica acta》2004,68(11):2485-2493

The concentrations of authigenic phases of Cd, Re, U, and Mo increase with depth in four 45-cm-long sediment box cores collected along the axis of the Laurentian Trough, Gulf of St. Lawrence. Average authigenic accumulation rates, estimated from element inventories, are similar to rates in other continental margin environments. Strong regional variations in sediment accumulation rate and sulfide concentration have little influence on the accumulation rates of Cd and Re. This suggests that slow precipitation kinetics controls the accumulation of Cd and Re in these sediments. The accumulation rate of authigenic U is more variable; it may be tied to the kinetics of microbially mediated U reduction and be controlled by the availability of reactive organic matter. Authigenic Mo is distinguished by a sharp subsurface concentration minimum, above which Mo cycles with manganese. Mo released to pore water upon reduction of Mn oxides diffuses downward and enriches the subsurface sediment. Mo accumulates most rapidly in the sediment with the highest sulfide content. Slow conversion of molybdate to thiomolybdate may explain the much slower Mo accumulation rate in the less sulfidic sediments. A component of authigenic Mo accumulates with pyrite in an approximately constant Mo:Fe ratio. The accumulation rate of pyrite and associated Mo is insensitive to AVS abundance. Pyrite formation may be limited by the reactivity of iron oxide minerals.  相似文献   

Spectroscopic investigation of U(VI) sorption at the calcite-water interface     

Evert J. Elzinga  C. Drew Tait  Kirk D. Rector  David E. Morris 《Geochimica et cosmochimica acta》2004,68(11):2437-2448

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The pulsating λ Bootis star HD 105759     

Peter Martinez    C. Koen    G. Handler  & E. Paunzen 《Monthly notices of the Royal Astronomical Society》1998,301(4):1099-1103

We present spectroscopic and multisite time series photometric observations of the star HD 105759 which confirm that this is a new pulsating λ Bootis star. Our spectroscopy indicates an overall metallicity of [Z] = log Z − log Z_⊙ = −1 and that T _eff = 8000 ± 300 K and log  g  = 4.0 ± 0.2. The photometric data reveal that this star pulsates with at least five frequencies: 8.62, 12.69, 20.15, 21.27 and 23.66 d⁻¹. These frequencies do not all match those found in an earlier single-site study, indicating that the pulsation spectrum changes with time.  相似文献   

Non‐linear analysis of a collapsed reinforced concrete chimney     

Wei Huang  Phillip L. Gould  Raul Martinez  Gayle S. Johnson 《地震工程与结构动力学》2004,33(4):485-498

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Free Radicals and Fast Photochemistry during BERLIOZ   总被引：4，自引：0，他引：4  

U. Platt  B. Alicke  R. Dubois  A. Geyer  A. Hofzumahaus  F. Holland  M. Martinez  D. Mihelcic  T. Klüpfel  B. Lohrmann  W. Pätz  D. Perner  F. Rohrer  J. Schäfer  J. Stutz 《Journal of Atmospheric Chemistry》2002,42(1):359-394

The free radicals OH, HO₂, RO₂, and NO₃ are known to be the driving force for most chemical processes in the atmosphere. Since the low concentration of the above radicals makes measurements particularly difficult, only relatively few direct measurements of free radical concentrations have been reported to date.We present a comprehensive set of simultaneous radical measurements performed by Laser Induced Fluorescence (LIF), Matrix Isolation –Electron spin Resonance (MI-ESR), Peroxy Radical Chemical Amplification (PERCA), and Differential Optical Absorption Spectroscopy (DOAS) during the BERLIner OZonexperiment (BERLIOZ) during July and August of 1998 near Berlin, Germany. Most of the above radical species were measured by more than one technique and an intercomparison gave good agreement. This data set offered the possibility to study and quantify the role of each radical at a rural, semi-polluted site in the continental boundary layer and to investigate interconnections and dependencies among these free radicals.In general (box) modelled diurnal profiles of the different radicals reproduced the measurements quite well, however measured absolute levels are frequently lower than model predictions. These discrepancies point to disturbing deficiencies in our understanding of the chemical system in urban air masses.In addition considerable night-time peroxy radical production related to VOC reactions with NO₃ and O₃ could be quantified.  相似文献   

Retardation of Dissolved Oxygen Due to a Trapped Gas Phase in Porous Media   总被引：2，自引：0，他引：2  

Virginia A. Fry  Jonathan D. Istok  Lewis Semprini  Kirk T. O'Reilly  Timothy E. Buscheck 《Ground water》1995,33(3):391-398

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A comparison of dimension-adjusted catch data methods for assessment of fish and crab abundance in intertidal salt marshes     

Lyle M. Varnell  Kirk J. Havens 《Estuaries and Coasts》1995,18(2):319-325

Sample collection methods and data standardization techniques accounting for marsh physiography were tested for mobile aquatic fauna in two intertidal pocket salt marshes in Sarah’s Creek, a tributary to the York River in Virginia. Fish and blue crab populations were described and compared as numbers per cubic meter of total marsh volume and numbers per square meter of total marsh area. These methods increase the accuracy of the analyses of sampled populations by relying on fewer assumptions than traditionals random sampling methods. Depending upon the season and the species compared, statistical differences were observed between dimension-adjusted data within the same sampled populations. Our data suggest that accurate population profiles can be determined if collection methods and data adjustments are based on the ecology, behavior, and life-history stage of the target species.  相似文献   

The genetic structure of Pandalus borealis in the Northeast Atlantic determined by RAPD analysis     

Martinez  Iciar; Aschan  Michaela; Skjerdal  Taran; Aljanabi  Salah M. 《ICES Journal of Marine Science》2006,63(5):840-850

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Three-dimensional SeaMARC II,gravity, and magnetics study of large-offset rift propagation at the Pito Rift,Easter microplate   总被引：1，自引：0，他引：1  

Fernando Martinez  David F. Naar  Thomas B. Reed IV  Richard N. Hey 《Marine Geophysical Researches》1991,13(4):255-285

We present results from a SeaMARC II bathymetry, gravity, and magnetics survey of the northern end of the large-offset propagating East Rift of the Easter microplate. The East Rift is offset by more than 300 km from the East Pacific Rise and its northern end has rifted into approximately 3 Ma lithosphere of the Nazca Plate forming a broad (70–100 km) zone of high (up to 4 km) relief referred to as the Pito Rift. This region appears to have undergone distributed and asymmetric extension that has been primarily accommodated tectonically, by block faulting and tilting, and to a lesser degree by seafloor spreading on a more recently developed magmatic accretionary axis. The larger fault blocks have dimensions of 10–15 km and have up to several km of throw between adjacent blocks suggesting that isostatic adjustments occur on the scale of the individual blocks. Three-dimensional terrain corrected Bouguer anomalies, a three-dimensional magnetic inversion, and SeaMARC II backscatter data locate the recently developed magmatic axis in an asymmetric position in the western part of the rift. The zone of magmatic accretion is characterized by an axis of negative Bouguer gravity anomalies, a band of positive magnetizations, and a high amplitude magnetization zone locating its tip approximately 10 km south of the Pito Deep, the deepest point in the rift area. Positive Bouguer gravity anomalies and negative magnetizations characterize the faulted area to the east of the spreading axis supporting the interpretation that this area consists primarily of pre-existing Nazca plate that has been block faulted and stretched, and that no substantial new accretion has occurred there. The wide zone of deformation in the Pito Rift area and the changing trend of the fault blocks from nearly N-S in the east to NW-SE in the west may be a result of the rapidly changing kinematics of the Easter microplate and/or may result from ridge-transform like shear stresses developed at the termination of the East Rift against the Nazca plate. The broad zone of deformation developed at the Pito Rift and its apparent continuation some distance south along the East Rift has important implications for microplate mechanics and kinematic reconstructions since it suggests that initial microplate boundaries may consist in part of broad zones of deformation characterized by the formation of lithospheric scale fault blocks, and that what appear to be pseudofaults may actually be the outer boundaries of tectonized zones enclosing significant amounts of stretched pre-existing lithosphere.  相似文献