Stochastic riming of plate-like and columnar ice crystals     

Klaus D. Beheng 《Pure and Applied Geophysics》1980,119(4):820-830

Riming growth of ice particles is simulated by numerically solving the stochastic collection equations, simultaneously considering coagulation of water droplets. By introducing a special criterion which defines the habit of a riming particle, the influence of this habit on the growth of several kinds of ice particles assumed to be formed during riming was investigated.It was found that (i) hexagonal rimed ice plates are growing more efficiently than lump graupel or rimed columns, (ii) the use of different collection kernels for the lump graupel evolution leads to widely differing results and that (iii) the time dependent decrease of liquid water substance and the size of the resulting ice particles were more strongly influenced by the initial ice crystal concentration than by the initial ice crystal size and the habit of the ice particles. By decreasing the number density of ice crystals gradually a critical ice crystal concentration was found at which the present liquid water was not completely consumed by the riming process even after 1800 s model time, causing large drops of radii >100 m to be formed in appreciable concentrations.  相似文献   

The genesis of the methane in Lake Kivu (Central Africa)     

Dr. Klaus Tietze  Dr. Mebus Geyh  Dr. Helmut Müller  Dr. Lothar Schröder  Dr. Wolfgang Stahl  Dr. Hermann Wehner 《International Journal of Earth Sciences》1980,69(2):452-472

Large amounts of methane and carbon dioxide, among other gases, are dissolved in the deep water of Lake Kivu. There is no dispute about the primarily magmatic origin of the carbon dioxide, but models of the genesis of the methane have been contradictory up to now. They have been based on too few and partly too inaccurate data.On the basis of new measurements obtained from gas and sediment samples, some of the old concepts have been further developed to a new model. According to this model, the methane is generated mainly by bacteria from the organic carbon of the sediment. It probably also contains minor amounts of thermocatalytic methane.About 70% of the organic carbon of the upper sediment is derived from mainly magmatic carbon dioxide (old carbon), which enters the biozone of the lake from the deep water by eddy diffusion and is assimilated there. The remaining 30% comes from atmospheric carbon dioxide (young carbon) assimilated in the biozone. But because methane also migrates into the lake from deeper sediment, the¹⁴C-content in the methane dissolved in the lake water is not 30% modern but only ca. 10% modern.More isotopic measurements on plankton, methane, carbon dioxide and sediment samples are necessary to support this model.

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Zusammenfassung Im Tiefenwasser des Kivusees sind u. a. große Mengen an Methan und Kohlendioxid gelöst. Während über den hauptsächlich magmatischen Ursprung des Kohlendioxids weitgehend Einigkeit besteht, sind die bisherigen Modellvorstellungen zur Genese des Methans widersprüchlich. Sie beruhen auf zu wenigen und zum Teil zu ungenauen Meß-daten.Mit Hilfe neuer Meßergebnisse an Gas- und Sedimentproben des Kivusees wurden einige der alten Vorstellungen zu einem neuen Modell weiterentwickelt. Danach ist das Methan hauptsächlich bakteriell aus dem organischen Kohlenstoff des Sediments entstanden. Wahrscheinlich enthält es auch geringe Beimengungen thermokatalytischen Methans.Der organische Kohlenstoff des oberen Sediments stammt zu rd. 70% aus dem vorwiegend magmatischen Kohlendioxid (alter Kohlenstoff), das aus dem Tiefenwasser durch turbulenten Austausch in die Biozone des Sees gelangt und dort assimiliert wird. Die restlichen 30% stammen aus dem in der Biozone assimilierten atmosphärischen Kohlendioxid (junger Kohlenstoff). Weil jedoch auch Methan aus tieferen Sedimentschichten in den See wandert, beträgt der¹⁴C-Gehalt des im Seewasser gelösten Methans nicht 30% modern, sondern nur ca. 10% modern.Weitere Isotopenuntersuchungen an Plankton-, Methan-, Kohlendioxid- und Sedimentproben sind notwendig, um das Modell abzusichern.

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Résumé De grandes quantités de méthane et d'oxyde carbonique sont dissoutes dans les eaux profondes du Lac Kicu. Alors qu'on est en général d'accord sur l'origine surtout magmatique de l'oxyde carbonique, les modèles devant représenter la genése du méthane sont contradictoires. Ils reposent sur des données trop peu nombreuses et en partie trop inexactes.A l'aide de nouveaux résultats de mesures faites sur des échantillons de gaz et du sédiment, on a développé un nouveau modèle, à partir des anciennes représentations. D'après celui-ci, le méthane provient pour sa plus grande part du carbone organique du sédiment, transformé par des bactéries. Il contient probablement des traces d'un méthane de thermocatalyse.Le carbone organique du sédiment supérieur provient pour 70% de l'oxyde carbonique surtout magmatique (carbone »ancien«), des eaux profondes parvenu, par échanges turbulents, dans la biozone du lac, où l'oxyde carbonique est assimilé. Les 30% restant proviennent de l'oxyde carbonique atmosphérique (carbone »jeune«) assimilé dans la biozone. Le méthane des couches profondes du sédiment migrant dans le lac, la teneur en¹⁴C de méthane dissous dans les eaux du lac n'est pas de 30% modernes, mais de 10% modernes.D'autres recherches sur les isotopes d'échantillons du plancton, du méthane, de l'oxyde carbonique et du sédiment du Lac Kivu seront nécessaires pour confirmer ce modéle.

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The nature and origin of ureilites     

John L. Berkley  G.Jeffrey Taylor  Klaus Keil  George E. Harlow  Martin Prinz 《Geochimica et cosmochimica acta》1980,44(10):1579-1597

Ureilites are carbon-bearing olivine-pigeonite achondrites which constitute a unique achondrite type. We performed a comprehensive mineralogical and petrological study on eight ureilites (Kenna, Novo Urei, Goalpara, Haverö, Dingo Pup Donga, Dyalpur, North Haig, and ALHA77257) the results of which were used to construct a hypothesis for the origin of ureilites. This hypothesis suggests that ureilites are primarily olivine-pigeonite cumulates which crystallized from a silicate liquid that also contained suspended solid carbon phases, mainly graphite. This carbon caused reduction of the melt and influenced ureilite mineral compositions. Carbonaceous material was trapped by settling cumulus mafic silicates along with other intercumulus material to form the carbon-rich ‘veins’ common to ureilites. Petrofabric analyses show that mafic silicates are oriented in lineated and foliated patterns characteristic of cumulate rocks, specifically adcumulates. Strain state of silicates suggests that ureilites were deformed subsequent to lithification by mild tectonic stress as well as by moderate to severe shock. The latter event caused the formation of micron-sized diamonds and lonsdaleite from graphite and carbon-induced reduction of silicate grain margins during temporal shock-heating.  相似文献   

Microscope-photometric methods for non-destructive Fe²⁺ – Fe³⁺ determination in chloritoids (Fe²⁺, Mn²⁺, Mg)₂ (Al,Fe³⁺)₄ Si₂O₁₀(OH)₄     

Ulf Hålenius  Klaus Langer 《Lithos》1980,13(3):291-294

Six natural chloritoid crystals with Fe²⁺ and Fe³⁺ contents ranging from 4.15 to 12.81 and from 0.411 to 0.849g-atoms/l, respectively, as determined by means of microprobe and Mössbauer techniques, served as reference material to develop non-destructive microscope-spectrophotometric methods for quantitative Fe²⁺ – Fe³⁺ determinations in chloritoids from unpolarized spectra of (001) platelets. Fe²⁺ concentrations in g-atom/l can be obtained from [ [Fe³⁺]=C₁xD₁/t where D₁ = log₁₀(I_0/I at 28,000 cm^-1 and t=crystal thickness in cm; C₁ is a conttant that may be influenced somewhat by experimental conditions and is found to be 0.002289 with the experimental set-up used in this study. Fe²⁺ concentrations in g-atom/l can be obtained from [Fe²⁺]=C₁xD₁/D₁-C₃ with D₂=log₁₀(I₀/I) at 16,300 cm^?1 and constants C₄ = 45.36 and C₅ = 3.540. Due to the uncertainties in absorbance measurements, D₁ and D₂ and the thickness measurements, the accuracies are ±0.05 and ±0.15 g-atom/l for [Fe³⁺] and [Fe²⁺], respectively. The determinations may be carried out on chloritoid grains in normal thin sections with an areal resolution of ～10 μm.  相似文献   

Faziesverzahnung von diamantführenden Konglomeraten und Bändererzen (BIF) in der südlichen Serra do Espinhaço (Minas Gerais,Brasilien)     

Dr. Klaus Paternoster 《International Journal of Earth Sciences》1980,69(2):437-451

Zusammenfassung Die untersuchten Gesteine wurden im Altproterozoikum als Schelfsedimente vorwiegend in Flachwasserfazies abgelagert. In ihrer Verbreitung sind Unterschiede zwischen Bildungen turbulenter Bereiche (Sande, Konglomerate und vereinzelte Breccien) und Stillwasserbildungen (Hämatitquarzit, Itabirit und Phyllit) festzustellen. Im Übergangsbereich beider Faziesbereiche kam es zu Verzahnungen von klastischen mit chemischen Sedimenten. Die chemisch gefällten Bändererze sind in zwei Typen zu trennen, zum einen in klastisch beeinflußte aus Bereichen unruhiger Sedimentationsbedingungen, zum anderen in klastisch nicht beeinflußte aus ruhigen Bereichen. Klastische Beeinflussung und intraformationale Aufarbeitung der BIF fand während allen Stadien der Verfestigung statt. Intraformationale Aufarbeitungsprodukte der Bändererze treten gemeinsam mit Konglomeraten großer Gerölldurchmesser entlang einer Nord-Süd streichenden Zone auf, wo sie sich lateral mit ungestörten chemischen Eisenerzen verzahnen. Konglomerate und BIF wurden zeitgleich sedimentiert. Charakteristisch für diese Zone sind außerdem synsedimentär aufgedrungene Vulkanite, deren Vorkommen einen Bereich tektonischer Unruhe nachzeichnet.

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The investigated rocks were deposited as shelf-sediments during the lower Proterozoic, predominantly in a shallow marine environment. It can be distinguished between sediments formed under turbulent conditions (sands, conglomerates and occasional breccias) and sediments of undisturbed environments (hematite-quartzite, itabirite and phyllite). In the transition of both facies-zones detritic and chemical sediments are interfingering. The chemically precipitated banded iron ores can be separated into two types — clastically influenced BIF formed in areas of agitated sedimentary conditions, and BIF with no clastic admixtures formed in quiet regions. Banded iron ores were clastically influenced and intraformationally reworked during all states of lithification. Products of intraformationally reworked BIF appear together with conglomerates of large diameters along a north-south-striking zone where they interfinger laterally with undisturbed chemically precipitated iron ores. Conglomerates and BIF were deposited here at the same time. Significant for this zone are also synsedimentary volcanites accentuating the presence of a tectonically active zone.

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Resumo Os metasedimentos aqui analisados foram predominantemente depositados em ambientes plataformais do Proterozoico inferior. Na sua distribuição constata-sc depósitos de águas calmas (hematita-quartzitos, itabiritos e filitos) e turbulentas) areias, conglomerados e esporadicamente brechas). Na zona de transição entre as duas facies sedimentares ocorreu interdigatação de sedimentos clásticos e químicos. Os minérios bandeados de ferro (BIF), quimicamente precipitados, podem ser classificados em dois grupos: o primeiro com interferência clástica, típico de ambientes agitados de sedimentação; o segundo sem componentes clásticos e característico de ambientes calmas. Interferência clástica como retrabalhamento intraformational ocorreu durante todos os estágios de processo sedimentar e de consolidação de BIF. Produtos do retrabalhamento intraformacional dos minérios bandeados ocorrem simultaneamente com conglomerados (seixos de diámetros grandes) ao longo de uma faixa Norte-Sul e interdigitados lateralmente com sedimentos químicos não perturbados. Conglomerados e BIF foram sedimentados concomitantemente. Característico para esta faixa são vulcanitos de extrusão sinsedimentar cuja presença tipifica um ambiente de instabilidade tectônica.

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, , . . ., — , — — .: , . . : . . - , , . , , . , , .

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Elemental abundances in chondrules from unequilibrated chondrites: Evidence for chondrule origin by melting of pre-existing materials     

James L. Gooding  Klaus Keil  Takaaki Fukuoka  Roman A. Schmitt 《Earth and Planetary Science Letters》1980,50(1):171-180

Bulk abundances of Na, Mg, Al, Ca, Sc, V, Cr, Mn, Fe, Co, Ni, Zn, La, Sm, Eu, Yb, Lu, Ir, and Au were determined by neutron activation analysis of chondrules separated from unequilibrated H-, L-, and LL-chondrites (Tieschitz, Hallingeberg, Chainpur, Semarkona) and correlated with chondrule petrographic properties. Despite wellknown compositional differences among the whole-rock chondrites, the geometric mean compositions of their respective chondrule suites are nearly indistinguishable from each other for many elements. Relative to the condensible bulk solar system (approximated by the Cl chondrite Orgueil), chondrules are enriched in lithophile and depleted in siderophile elements in a pattern consistent with chondrule formation by melting of pre-existing materials, preceded or attended by silicate/metal fractionation. Relative to nonporphyritic chondrules, porphyritic chondrules are enriched in refractory and siderophile elements, suggesting that these two chondrule groups may have formed from different precursor materials.  相似文献   

Calcmylonites and solution transfer in a Devonian reef at Warstein,Germany   总被引：1，自引：1，他引：0  

Jacob de Roo  Johannes Duyster  Klaus Weber 《International Journal of Earth Sciences》1992,81(2):333-346

Massive limestone complexes of Late Palaeozoic age are scattered across the allochthonous foreland of the Hercynides in Germany. One of these complexes is situated at Warstein. Stratigraphic facies studies have represented the Warstein complex as a reef in a coastal shelf. Our study emphasizes that at least part of the reef consists of a pile of calcmylonites.The calcmylonites have a strong foliation (S_m) and lineation (L_m) and a structural asymmetry indicating non-coaxial deformation. X-ray textures and calcite microstructures show that the mylonitization involved intracrystalline deformation and dynamic recrystallization. These processes competed with solution transfer, as the mylonites are corroded at S_m-parallel stylolites and contain carbonate veins. Cathodoluminescopy shows that some veins are parallel to S_m and have been recrystallized, whereas others are normal to S_m and retain a fibrous crackseal microstructure. The latter type created limestones showing a pair of preferred grain boundary orientations; one normal to S_m, one in S_m. This orthogonal boundary fabric is distinct from crystalplastic fabrics: the latter show only one preferred grain boundary orientation (in S_m).

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Zusammenfassung Massenkalkkomplexe spätpaläozoischen Alters liegen verstreut über das allochthone Vorland des Variszischen Gebirges in Deutschland. Einer dieser Komplexe liegt bei Warstein. Stratigraphische Faziesstudien haben den Warsteiner Komplex als ein Riff in einem küstennahen Schelf dargestellt. Die vorliegende Arbeit betont, daß wenigstens ein Teil des Riffes aus einer Stapelung von Kalkmyloniten besteht.Die Kalkmylonite haben eine starke Foliation (S_m) und Lineation (L_m), und eine strukturelle Asymmetrie die auf nicht-koaxiale Verformung hinweist. Röntgentexturen und Calcitmikrostrukturen zeigen, daß die Mylonitisierung intrakristalline Verformung und dynamische Rekristallisation beinhaltet. Diese Prozesse müssen mit Lösungstransport konkurriert haben, da die Mylonite an S_m-parallelen Styloliten korrodiert sind und Karbonatgänge erhalten. Kathodolumineskopie zeigt, daß einige Gänge (parallel zu S_m) rekristallisiert sind, während andere (senkrecht zu S_m) eine faserige crack-seal Mikro-Struktur enthalten. Der letzte Typ ist verbunden mit Konformgefügen. Diese unterscheiden sich von kristallplastischen Kornformgefügen, da sie eine zweite bevorzugte Korngrenzorientierung aufweisen, die senkrecht zur ersten (in S_m) einfällt.

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Résumé Les complexes de calcaires massifs de l'Âge paléozoîque supérieure sont repandus sur l'avantpays allochthone des Hercynides en Allemagne. Un de ces complexes est situé à Warstein. Les Études de faciès stratigraphiques ont répresenté le complexe à Warstein comme un Récif littoral. Notre étude montre que au moins partie de ce «Récif» consiste en un empilement des calcmylonites.Les calcmylonites ont une foliation (S_m) et linéation (L_m) fort, et une asymmetrie structurale indiquant de la déformation non-coaxiale. Les textures röntgenographiques et les microstructures calcitiques montrent que la mylonitization était incluse de déformation intracristalline et récristallisation dynamique. Ces processus auront été en compétition avec dissolution-cristallization («solution transfer»), car les mylonites sont corrodées aux stylolites parallel à S_m et contient des veines carbonatiques. La cathodoluminescopie montre que quelques veines (parallel à S_m) sont récristallisées, pendant que les autres (perpendiculaire à S_m) ont retenu une microstructure fibreuse («crack-seal»). Le dernier type est lié avec des fabriques de forme des grains. Ils se sont distingués des fabriques de plasticité cristalline par la présence d'une deuxième orientation préférentielle des bordures des grains, perpendiculaire à la première (dans S_m).

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. Warstein'a. , . , , , »« . (S_m) (L_m), , . , - , . , .. , S_m, . , , S_m, , , S_m, = »crack-seal«. : , S_m.

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Temperature-jump induced cation exchange kinetics in (Co<Subscript>0.1</Subscript>Mg<Subscript>0.9</Subscript>)<Subscript>2</Subscript>SiO<Subscript>4</Subscript> olivine: an in situ optical spectroscopic study     

Jianmin Shi  Stefan G. Ebbinghaus  Klaus Dieter Becker 《Physics and Chemistry of Minerals》2008,35(1):1-9

In the olivine crystal structure, cations are distributed over two inequivalent octahedral sites, M1 and M2. Kinetics of cation exchange between the two octahedral sites in (Co_0.1Mg_0.9)₂SiO₄ single crystal have been studied in the temperature range from 600 to 800°C by monitoring the time evolution of the absorbance of Co²⁺ ions in M1 or M2 sites using optical spectroscopy after rapid temperature jumps. It was found from such temperature-jump induced relaxation experiments that with increasing temperature the absorbance of Co²⁺ ions in the M1 site decreases while that in the M2 site increases. This indicates a tendency of Co²⁺ cations to populate the M2 site with increasing temperatures and vice versa. The experimental relaxation data can be modeled using a triple exponential equation based on theoretical analysis. Activation energies of 221 ± 4 and 213 ± 10 kJ/mol were derived from relaxation experiments on the M2 site and M1 site, respectively, for the cation exchange processes in (Co_0.1Mg_0.9)₂SiO₄ olivine. Implications for cation diffusion at low temperatures are discussed.  相似文献   

Cadmium stable isotope cosmochemistry   总被引：2，自引：0，他引：2  

Frank Wombacher  Mark Rehkämper  Klaus Mezger  Carsten Münker 《Geochimica et cosmochimica acta》2008,72(2):646-667

Cadmium stable isotope compositions are reported for a comprehensive suite of carbonaceous, ordinary, enstatite, and Rumuruti chondrites as well as achondrites and lunar samples (soils, breccias, pristine anorthosite). The Cd isotope analyses were performed by multiple collector ICP-MS with an external reproducibility of ±0.43‰ (2 sd) for δ^114/110Cd. None of the samples shows evidence of nucleosynthetic anomalies and cosmogenic isotope effects from neutron-capture by ¹¹³Cd were only observed for two lunar samples.The Cd stable isotope compositions of type 1, 2, and some type 3 carbonaceous chondrites, EH4 enstatite chondrites, eucrites, and the Earth are essentially identical at δ^114/110Cd ≈ 0.0 ± 0.4. This suggests that the portion of the solar nebula from which the inner solar system bodies accreted was homogeneous with respect to its Cd isotope composition. It also indicates that the primary volatile element depletion of the inner solar system did not involve partial kinetic Rayleigh evaporation or condensation. Furthermore no resolvable Cd isotope effects were generated during the accretion and initial differentiation of the planetary bodies.In contrast, the analyses reveal large Cd isotope effects for ordinary and some enstatite chondrites, which display δ^114/110Cd values between about −8 and +16. Smaller fractionations are observed for the Rumuruti and some type 3 to 5 carbonaceous chondrites. These Cd isotope variations are thought to reflect secondary depletion or redistribution of Cd, due to open system thermal metamorphism on the meteorite parent bodies.One CAI and chondrule separates from the Allende meteorite have unexpectedly high Cd concentrations and fractionated light Cd isotope compositions with δ^114/110Cd ≈ −1 to −4. These characteristics may have been established by the interaction of originally Cd-poor materials with a volatile-rich gas prior to the final accretion of the Allende parent body. The general Cd enrichment of the lunar soil and regolith mainly reflects early volcanic activity. However, decreasing Cd abundances in lunar soils correlate well with an enrichment of the heavy Cd isotopes. This relationship is best explained by suppressed Rayleigh fractionation in response to space weathering.  相似文献   

Geostandards and Geoanalytical Research Bibliographic Review 2007     

Klaus Peter Jochum  Stefanie M. Brueckner  Uwe Nohl  Brigitte Stoll  Ulrike Weis 《Geostandards and Geoanalytical Research》2008,32(4):509-514

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