Cadmium stable isotope cosmochemistry   总被引：2，自引：0，他引：2  

Frank Wombacher  Mark Rehkämper  Klaus Mezger  Carsten Münker 《Geochimica et cosmochimica acta》2008,72(2):646-667

Cadmium stable isotope compositions are reported for a comprehensive suite of carbonaceous, ordinary, enstatite, and Rumuruti chondrites as well as achondrites and lunar samples (soils, breccias, pristine anorthosite). The Cd isotope analyses were performed by multiple collector ICP-MS with an external reproducibility of ±0.43‰ (2 sd) for δ^114/110Cd. None of the samples shows evidence of nucleosynthetic anomalies and cosmogenic isotope effects from neutron-capture by ¹¹³Cd were only observed for two lunar samples.The Cd stable isotope compositions of type 1, 2, and some type 3 carbonaceous chondrites, EH4 enstatite chondrites, eucrites, and the Earth are essentially identical at δ^114/110Cd ≈ 0.0 ± 0.4. This suggests that the portion of the solar nebula from which the inner solar system bodies accreted was homogeneous with respect to its Cd isotope composition. It also indicates that the primary volatile element depletion of the inner solar system did not involve partial kinetic Rayleigh evaporation or condensation. Furthermore no resolvable Cd isotope effects were generated during the accretion and initial differentiation of the planetary bodies.In contrast, the analyses reveal large Cd isotope effects for ordinary and some enstatite chondrites, which display δ^114/110Cd values between about −8 and +16. Smaller fractionations are observed for the Rumuruti and some type 3 to 5 carbonaceous chondrites. These Cd isotope variations are thought to reflect secondary depletion or redistribution of Cd, due to open system thermal metamorphism on the meteorite parent bodies.One CAI and chondrule separates from the Allende meteorite have unexpectedly high Cd concentrations and fractionated light Cd isotope compositions with δ^114/110Cd ≈ −1 to −4. These characteristics may have been established by the interaction of originally Cd-poor materials with a volatile-rich gas prior to the final accretion of the Allende parent body. The general Cd enrichment of the lunar soil and regolith mainly reflects early volcanic activity. However, decreasing Cd abundances in lunar soils correlate well with an enrichment of the heavy Cd isotopes. This relationship is best explained by suppressed Rayleigh fractionation in response to space weathering.  相似文献   

Geostandards and Geoanalytical Research Bibliographic Review 2007     

Klaus Peter Jochum  Stefanie M. Brueckner  Uwe Nohl  Brigitte Stoll  Ulrike Weis 《Geostandards and Geoanalytical Research》2008,32(4):509-514

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Biodegradation of the Antituberculosis Drug Isoniazid in the Aquatic Environment          下载免费PDF全文

Samuel Sasu  Jörg Metzger  Martin Kranert  Klaus Kümmerer 《洁净——土壤、空气、水》2015,43(2):166-172

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On the thick-disc exoplanet host subgiant HD 155358     

Klaus Fuhrmann  Jan Bernkopf † 《Monthly notices of the Royal Astronomical Society》2008,384(4):1563-1566

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On the dynamical origin of the ICM metallicity evolution     

Sofia A. Cora  Luca Tornatore  Paolo Tozzi  Klaus Dolag 《Monthly notices of the Royal Astronomical Society》2008,386(1):96-104

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Numerical simulation of a permittivity probe for measuring the electric properties of planetary regolith and application to the near‐surface region of asteroids and comets     

Klaus SPITZER  Frank SOHL  Martin PANZNER 《Meteoritics & planetary science》2008,43(6):997-1007

Abstract— We present a numerical simulation technique for the retrieval of the electric properties relative permittivity and conductivity of planetary, asteroid, and cometary regolith. Our simulation techniques aim at accompanying hardware development and conducting virtual experiments, e.g., to assess the response of arbitrary heterogeneous conductivity and permittivity distributions or to scrutinize possibilities for spatial reconstruction methods using inverse schemes. In a first step, we have developed a finite element simulation code on the basis of unstructured, adaptive triangular grids for arbitrary two‐dimensional axisymmetric distributions of conductivity and permittivity. The code is able to take into account the spatial geometry of the probe and allows for possible inductive effects. In previous studies, the non‐inductive approach has been used to convert potential and phase data into apparent material properties. By our simulations, we have shown that this approach is valid for the frequency range from 10² Hz to 10⁷ Hz and electric conductivities of 10^?8 S/m that are typical for the near‐surface region of asteroids and comets composed of chondritic materials and/or frozen volatiles such as H₂O and CO₂ ice. We prove the accuracy of our code to be better than 10%, using mixed types of boundary conditions and present a simulated vertical log through a horizontally stratified subsurface layer as a representative example of a heterogeneous distribution of the electrical properties. Resolution studies for the given electrode separation reveal that the material parameters of layers having thicknesses of less than about half the electrode spread are not reconstructible if only apparent quantities are considered. Therefore, spatial distributions of the complex sensitivity are presented having in mind a future data inversion concept that will permit the multi‐dimensional reconstruction of material parameters in heterogeneous environments.  相似文献   

Satellitenbild und Meereiserkundung     

Klaus Strübing 《Ocean Dynamics》1970,23(5):193-213

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Improved prediction of vegetation composition in NW European softwater lakes by combining location,water and sediment chemistry     

Cristina?PulidoEmail author  Kaj?Sand-Jensen  Esther?C.?H.?E.?T.?Lucassen  Jan?G.?M.?Roelofs  Klaus?P.?Brodersen  Ole?Pedersen 《Aquatic Sciences - Research Across Boundaries》2012,74(2):351-360

Isoetids, as indicators of near-pristine softwater lakes, have a high priority in national and international (European Water Directive Framework) assessments of ecological lake quality. Our main goal was to identify the most important environmental factors that influence the composition of plant communities and specifically determine the presence and abundance of the isoetid Lobelia dortmanna in NW European softwater lakes. Geographical position and composition of surface water, porewater, sediment and plant communities were examined in 39 lakes in four regions (The Netherlands, Denmark, West Norway and East Norway) distributed over a 1,200-km long distance. We confirmed that lake location was accompanied by significant changes in environmental variables between NW European lakes. Lake location was the single most important determinant of vegetation composition and it had significant individual contributions independent of the coupling to environmental variables. This influence of location was supported by a significant decline of community similarity with geographical distance between pairs of lakes at regional, inter-regional and international scales. Combining the geographical position with environmental variables for surface water, porewater and sediment significantly improved prediction of vegetation composition. Specifically, the combination of latitude, surface water alkalinity, porewater phosphate and redox potential offered the highest correlation (BIO ENV correlation 0.66) to vegetation composition. This complex analysis can also account for high sediment variability in the littoral zone of individual lakes, by using site-specific physico-chemical sediment factors, and offer better predictions of vegetation composition when lake water chemistry is relatively homogeneous among lakes within regions.  相似文献   

Photodegradation,Photocatalytic, and Aerobic Biodegradation of Sulfisomidine and Identification of Transformation Products by LC–UV‐MS/MS     

Faten Sleman  Waleed M. M. Mahmoud  Rolf Schubert  Klaus Kümmerer 《洁净——土壤、空气、水》2012,40(11):1244-1249

Much attention has recently been devoted to the fate and effects of pharmaceuticals in the water cycle. Removal of antibiotics in effluents by photo‐treatment or biodegradation is a topic currently under discussion. Degradation and removal efficiencies of sulfisomidine (SUI) by photodegradation and aerobic biodegradability were studied. SUI behavior was monitored during photolysis and photocatalysis (catalyst titanium dioxide) using 150‐W medium‐pressure Hg lamp. Also an aerobic bacterial degradation test from the OECD series (closed bottle test (CBT, OECD 301 D)) was performed. The primary elimination of SUI was monitored. Structures of photo‐degradation products were assessed by chromatographic separation on a C18 column with ultraviolet detection at 270 nm and ion trap MS. The results demonstrate that SUI is not readily biodegradable in CBT. Photo catalysis was more is effective than photolysis. SUI underwent photodegradation and several SUI photoproducts were identified. Accordingly, the photodegradation pathway of SUI was postulated. When reaching the aquatic environment, SUI and its photo products can constitute a risk to the environment.  相似文献   

Sensitivity of subglacial Lake Vostok's flow regime on environmental parameters     

Malte Thoma  Christoph Mayer  Klaus Grosfeld 《Earth and Planetary Science Letters》2008,269(1-2):242-247

Subglacial lakes provide unique habitats, but the exact nature of physical and geochemical conditions are still a matter of debate and await direct sampling of water. Due to its isolation from external atmospheric forcing other environmental parameters influence the flow characteristics within the lake. In this study we use an improved treatment of the physical processes at the ice–water boundary interface to identify and quantify the impact of (1) the geothermal heat flux, (2) the heat flux from the lake into the ice, (3) the influence of the salinity of the lake water, and (4) the ice thickness on the size of the freezing area and the freeze/melt rates. We show that the modelled basal mass imbalance (that is the produced melt water minus the re-frozen water) depends on the geothermal heating as well as the heat flux into the ice. The circulation and the temperature distribution within subglacial Lake Vostok are rather stable against variations of geothermal heat flux, heat flux into the ice sheet, salinity of the lake, and small changes of the ice thickness above the lake. However, the flow regime for any subglacial lake with less than 2000 m ice thickness above, will be substantially different from those that experience higher pressures. This is because the buoyancy–temperature relationship reverses at this depth.  相似文献