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141.
Besides granites of the ilmenite series, in which the anisotropy of magnetic susceptibility (AMS) is mainly controlled by paramagnetic minerals, the AMS of igneous rocks is commonly interpreted as the result of the shape-preferred orientation of unequant ferromagnetic grains. In a few instances, the anisotropy due to the distribution of ferromagnetic grains, irrespective of their shape, has also been proposed as an important AMS source. Former analytical models that consider infinite geometry of identical and uniformly magnetized and coaxial particles confirm that shape fabric may be overcome by dipolar contributions if neighboring grains are close enough to each other to magnetically interact. On these bases we present and experimentally validate a two-grain macroscopic numerical model in which each grain carries its own magnetic anisotropy, volume, orientation and location in space. Compared with analytical predictions and available experiments, our results allow to list and quantify the factors that affect the effects of magnetic interactions. In particular, we discuss the effects of (i) the infinite geometry used in the analytical models, (ii) the intrinsic shape anisotropy of the grains, (iii) the relative orientation in space of the grains, and (iv) the spatial distribution of grains with a particular focus on the inter-grain distance distribution. Using documented case studies, these findings are summarized and discussed in the framework of the generalized total AMS tensor recently introduced by Cañon-Tapia (Cañon-Tapia, E., 2001. Factors affecting the relative importance of shape and distribution anisotropy in rocks: theory and experiments. Tectonophysics, 340, 117–131.). The most important result of our work is that analytical models far overestimate the role of magnetic interaction in rock fabric quantification. Considering natural rocks as an assemblage of interacting and non-interacting grains, and that the effects of interaction are reduced by (i) the finite geometry of the interacting clusters, (ii) the relative orientation between interacting grains, (iii) their heterogeneity in orientation, shape and bulk susceptibility, and (iv) their inter-distance distribution, we reconcile analytical models and experiments with real case studies that minimize the role of magnetic interaction onto the measured AMS. Limitations of our results are discussed and guidelines are provided for the use of AMS in geological interpretation of igneous rock fabrics where magnetic interactions are likely to occur.  相似文献   
142.
Estimating concentrations or flow rates along a stream network requires specific models. Two classes of models, recently proposed in the literature, are generalized, to the intrinsic case in particular. We present a global construction by ‘streams’, i.e. on the whole set of paths between sources and outlet. Combining stationary or intrinsic one-dimensional random functions leads to stationary or intrinsic models on segments, with discontinuities at the forks. A construction from outlet to sources, leads to stationary or intrinsic models on each stream, without any discontinuity at the forks. The linear variogram is found as a particular case. The extension to the linear model of coregionalization is immediate, allowing a multivariate modelling of concentrations. To cite this article: C. de Fouquet, C. Bernard-Michel, C. R. Geoscience 338 (2006).  相似文献   
143.
In 2005 Geostandards and Geoanalytical Research embarked upon a new initiative for its readers. Key researchers in various fields of geoanalytical technique development and their application were identified and invited to provide reviews pertinent to their expertise. As noted in the first of these publications "…instead of revisiting the historical context or decades of development in each analytical technique, the goal here has been to capture a snapshot of "hot topics" across a range of fields as represented in the… literature" (Hergt et al . 2005). Rather than prepare an annual review, a decision was taken earlier this year to provide a biennial summary of progress and accomplishments, in this case for the years 2004–2005. The principal techniques employed in Earth and environmental sciences are covered here, and include laser ablation and multicollector ICP-MS, ICP-AES, thermal ionisation and secondary ion mass spectrometry, as well as neutron activation analysis, X-ray fluorescence and atomic absorption spectrometry. A comprehensive review of the development of reference materials, often essential to these techniques, is also provided. The contributions assembled serve both to keep readers informed of advances they may be unfamiliar with, but also as a means of showcasing examples of the breadth and depth of work being conducted in these fields.  相似文献   
144.
This review gives an overview of the use and development of reference materials of geochemical and environmental interest in the literature of the years 2004 and 2005. In these years the performance of existing methods has been improved and new geochemical applications using new techniques have been developed. Accordingly, there was an increasing need for new reference materials, especially for in situ microanalysis and for precise stable isotope measurements. In addition, there was a notable trend for further characterisation of existing reference materials, mainly for the platinum-group elements. This review focuses on five topics: reference materials for platinum-group elements, reference glasses for in situ microanalysis, zircon reference materials, isotopic reference materials, and the development and certification of reference materials.  相似文献   
145.
Precambrian fluvial systems, lacking the influence of rooted vegetation, probably were characterised by flashy surface runoff, low bank stability, broad channels with abundant bedload, and faster rates of channel migration; consequently, a braided fluvial style is generally accepted. Pre-vegetational braided river systems, active under highly variable palaeoclimatic conditions, may have been more widespread than are modern, ephemeral dry-land braided systems. Aeolian deflation of fine fluvial detritus does not appear to have been prevalent. With the onset of large cratons by the Neoarchaean–Palaeoproterozoic, very large, perennial braided river systems became typical. The c. 2.06–1.88 Ga Waterberg Group, preserved within a Main and a smaller Middelburg basin on the Kaapvaal craton, was deposited largely by alluvial/braided-fluvial and subordinate palaeo-desert environments, within fault-bounded, possibly pull-apart type depositories.

Palaeohydrological data obtained from earlier work in the Middelburg basin (Wilgerivier Formation) are compared to such data derived from the correlated Blouberg Formation, situated along the NE margin of the Main basin. Within the preserved Blouberg depository, palaeohydrological parameters estimated from clast size and cross-bed set thickness data, exhibit rational changes in their values, either in a down-palaeocurrent direction, or from inferred basin margin to palaeo-basin centre. In both the Wilgerivier and Blouberg Formations, calculated palaeoslope values (derived from two separate formulae) plot within the gap separating typical alluvial fan gradients from those which characterise rivers (cf. [Blair, T.C., McPherson, J.G., 1994. Alluvial fans and their natural distinction from rivers based on morphology, hydraulic processes, sedimentary processes, and facies assemblages. J. Sediment. Res. A64, 450–489.]). Although it may be argued that such data support possibly unique fluvial styles within the Precambrian, perhaps related to a combination of major global-scale tectono-thermal and atmospheric–palaeoclimatic events, a simpler explanation of these apparently enigmatic palaeoslope values may be pertinent. Of the two possible palaeohydrological formulae for calculating palaeoslope, one provides results close to typical fluvial gradients; the other formula relies on preserved channel-width data. We suggest that the latter will not be reliable due to problematic preservation of original channel-widths within an active braided fluvial system. We thus find no unequivocal support for a unique fluvial style for the Precambrian, beyond that generally accepted for that period and discussed briefly in the first paragraph.  相似文献   

146.
147.
Many Precambrian granulite-facies metamorphic complexes contain so-called straight gneisses, which are massive rocks with a clearly pronounced blastomylonitic texture, lineation, and gneissosity. These rocks occur exclusively in high-temperature ductile shear zones, which can develop either during the primary exhumation of rock complexes or during the overprinting by high-temperature dynamometamorphism. The main criterion for distinguishing between these two types of straight gneisses is the configuration of their P-T trajectories, which are recorded in the mineral assemblages in these rocks and their host gneisses. Ductile shear zones developed in Archean granulite gneisses simultaneously with their exhumation, and, hence, their P-T trajectories are segments of decompression and/or isobaric cooling paths. Straight gneisses in Proterozoic polymetamorphic complexes commonly compose high-temperature ductile shear zones overprinted on Archean granulite complexes, and the P-T paths of these rocks are Z-shaped. This means that, at a constant pressure in the middle part of the continental crust, the T min of the older P-T trajectory corresponded to T max of the younger trajectory, and often T maxT min > 100°C. Such ductile shear zones commonly have a strike-slip morphology and can be easily seen in aerial photographs and discerned during structural geological surveying. These zones can overprint older gneisses without any notable thermal effect on the latter. Relations of this type were identified in the granulite complexes of Limpopo in South Africa, Sharyzhalgai in the southwestern Baikal area, and Lapland in the Kola Peninsula. The results of our research propose a solution for the well-known problem of the significant discrepancies between the isotopic ages in high-temperature-high-pressure complexes and the partial or complete distortion of radiogenic isotopic systems under the effect of a newly inflowing metamorphic fluid. The application of geochronologic techniques to these situations is senseless, and only P-T trajectories provide insight into the actual age relations between the discrete tectono-metamorphic stages. It is thus expedient to conduct not only structural studies of metamorphic complexes but also their detailed petrological examination and the calculation of their P-T paths before geochronologic dating.  相似文献   
148.
The origin of the hypersaline fluids (magmatic or basinal brine?), associated with iron oxide (Cu–U–Au–REE) deposits, is controversial. We report the first chlorine and strontium isotope data combined with Cl/Br ratios of fluid inclusions from selected iron oxide–copper–gold (IOCG) deposits (Candelaria, Raúl–Condestable, Sossego), a deposit considered to represent a magmatic end member of the IOCG class of deposit (Gameleira), and a magnetite–apatite deposit (El Romeral) from South America. Our data indicate mixing of a high δ 37Cl magmatic fluid with near 0‰ δ 37Cl basinal brines in the Candelaria, Raúl–Condestable, and Sossego IOCG deposits and leaching of a few weight percent of evaporites by magmatic-hydrothermal (?) fluids at Gameleira and El Romeral. The Sr isotopic composition of the inclusion fluids of Candelaria, Raúl–Condestable, and El Romeral confirms the presence of a non-magmatic fluid component in these deposits. The heavy chlorine isotope signatures of fluids from the IOCG deposits (Candelaria, Raúl–Condestable, Sossego), reflecting the magmatic-hydrothermal component of these fluids, contrast with the near 0‰ δ 37Cl values of porphyry copper fluids known from the literature. The heavy chlorine isotope compositions of fluids of the investigated IOCG deposits may indicate a prevailing mantle Cl component in contrast to porphyry copper fluids, an argument also supported by Os isotopes, or could result from differential Cl isotope fractionation processes (e.g. phase separation) in fluids of IOCG and porphyry Cu deposits.  相似文献   
149.
Planning for source water protection in Ontario   总被引:2,自引:0,他引:2  
Ontario began developing a drinking water source protection planning process in 2000, after a rural community's water supply was contaminated by pathogens from agricultural runoff. An expert committee report has recommended legislating a new source protection “sphere of jurisdiction” for municipalities; however, no specific new municipal tools or authorities have been proposed as yet. This paper reports findings from an evaluation of the extent to which existing institutional arrangements for land use planning and water management facilitate or constrain source protection by municipalities. A case study of the Regional Municipality of Waterloo suggests there is the potential to link land use planning more strongly to water management through creative use of existing tools, forgoing the need for major institutional changes.  相似文献   
150.
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