Sludge weathering and mobility of contaminants in soil affected by the Aznalcollar tailing dam spill (SW Spain)   总被引：3，自引：0，他引：3  

C. Domnech  C. Ayora  J. de Pablo 《Chemical Geology》2002,190(1-4):355-370

As a result of the collapse of the Aznalcollar mine tailings dam, a large extension of the Guadiamar valley in SW Spain was covered with a layer of pyrite sludge. Although most of the sludge was removed, a small amount remains in the soil, constituting a potential source of water pollution. A column experiment was carried out in order to determine the rate of sludge oxidation in the soil, and the existence of metal retention processes. The column was filled with a mixture of sludge and a sandy soil common in the region. At different time intervals, the column was leached with water and the resulting solution analysed.

The pH of the water dropped to values around 2 after 260 days and then remained constant due to the buffering role of silicate dissolution. The concentration of Zn, Cd and Co in the leachates matched the expected values from flow-through experiments at atmospheric oxygen pressure. This indicates that oxygen diffusion in the pores was complete. Moreover, no efficient processes existed for retaining Zn, Cd and Co, which formed soluble salts and were entirely incorporated into the infiltrating water. During the first 2 months of the experiment, when pH was higher than 4.5, the concentrations of Fe and Al were very low. Saturation indices showed that the solution was in equilibrium with amorphous Fe(OH)₃ and Al(OH)₃. Subsequently, at lower pH values, jarosite [(Na,K)Fe₃(SO₄)₂(OH)₆] formed. This solid phase was identified by X-ray diffraction (XRD) and Scanning Electron Microscopy (SEM). Jarosite was also responsible for the depletion of As, Pb, Sb and probably Tl in the water resulting from infiltration.  相似文献   

Burial of redox-sensitive metals and organic matter in the equatorial Indian Ocean linked to precession     

Delphine PaillerEdouard Bard  Frauke RostekYan Zheng  Richard MortlockAlexander van Geen 《Geochimica et cosmochimica acta》2002,66(5):849-865

Authigenic metals (uranium, cadmium, and molybdenum), organic carbon (OC) and total C₃₇ alkenone (totC₃₇) concentrations were measured for the last 350 kyr in core MD900963, located in the eastern equatorial Arabian Sea. Authigenic metal concentrations on a carbonate-free basis range between 1 and 17 ppm, 0.5 and 6 ppm, and 0.5 and 4 ppm for U, Cd, and Mo, respectively. The profiles are characterized by well-defined 23 kyr cycles between oxic and mildly suboxic conditions. The redox-sensitive metal profiles also follow variations in the concentrations of OC (0.2-0.9%) and alkenones (0.2-6.7 ppm). The coupled variations in inorganic and organic constituents are attributed to a 23-kyr cycle in primary production above site MD900963, as suggested by clear correlations with independent micropaleontologic proxies (primary productivity indices based on foraminifera and coccoliths and fragmentation of foraminiferal shells). The 23-kyr cycles do appear to be primarily driven by productivity rather than changes in bottom water oxygen. Comparison with other records indicates that if this interpretation is correct, productivity variations across much of the Indian Ocean have been dominated by precessional forcing, with high productivity in phase with low summer insolation in the Northern Hemisphere. This interpretation contrasts with the traditional attribution of enhanced productivity in the Indian Ocean with periods of high summer insolation.  相似文献   

Seismic buffer recognition using wavelet-based features and neural classification     

Alwyn Hoffman  Riaan Hoogenboezem  Theo van der Merwe  Tonie Tollig 《Geophysical Prospecting》2002,50(4):361-371

One of the first operations in a seismic signal processing system applied to earthquake data is to distinguish between valid and invalid records. Since valid signals are characterized by a combination of their time and frequency properties, wavelets are natural candidates for describing seismic features in a compact way. This paper develops a seismic buffer pattern recognition technique, comprising wavelet-based feature extraction, feature selection based on the mutual information criterion, and neural classification based on feedforward networks. The ability of the wavelet transform to capture discriminating information from seismic data in a small number of features is compared with alternative feature reduction techniques, including statistical moments. Three different variations of the wavelet transform are used to extract features: the discrete wavelet transform, the single wavelet transform and the continuous wavelet transform. The mutual information criterion is employed to select a relatively small set of wavelets from the time–frequency grid. Firstly, it is determined whether wavelets can capture more informative data in an equal number of features compared with other features derived from raw data. Secondly, wavelet-based features are compared with features selected based on prior knowledge of class differences. Thirdly, a technique is developed to optimize wavelet features as part of the neural network training process, by using the wavelet neural network architecture. The automated classification techniques developed in this paper are shown to perform similarly to human operators trained for this function. Wavelet-based techniques are found to be useful, both for preprocessing of the raw data and for extracting features from the data. It is demonstrated that the definition of wavelet features can be optimized using the classification wavelet network architecture.  相似文献   

The El Salvador earthquakes of January and February 2001: context, characteristics and implications for seismic risk     

J. J. Bommer  M. B. Benito  M. Ciudad-Real  A. Lemoine  M. A. Lpez-Menjívar  R. Madariaga  J. Mankelow  P. Mndez de Hasbun  W. Murphy  M. Nieto-Lovo  C. E. Rodríguez-Pineda  H. Rosa 《Soil Dynamics and Earthquake Engineering》2002,22(5)

The small Central American republic of El Salvador has experienced, on average, one destructive earthquake per decade during the last hundred years. The latest events occurred on 13 January and 13 February 2001, with magnitudes M_w 7.7 and 6.6, respectively. The two events, which were of different tectonic origin, follow the patterns of the seismicity of the region although neither event has a known precedent in the earthquake catalogue in terms of size and location. The earthquakes caused damage to thousands of traditionally built houses and triggered hundreds of landslides, which were the main causes of fatalities. The earthquakes have clearly demonstrated trends of increasing seismic risk in El Salvador due to rapid population expansion in areas of high shaking and landslide hazard, exacerbated by deforestation and uncontrolled urbanisation. The institutional mechanisms required for the control of land use and building practice are very weak and present a major obstacle to risk mitigation.  相似文献   

Modes of raising northeastern Tibet probed by explosion seismology   总被引：4，自引：0，他引：4  

Audrey GalvéAlfred Hirn  Jiang MeiJosep Gallart  Béatrice de VoogdJean-Claude Lépine  Jordi DiazWang Youxue  Qian Hui 《Earth and Planetary Science Letters》2002,203(1):35-43

New wide-angle reflection and refraction seismic data provide constraints on the structure of the upper lithosphere, and test models of its evolution to raise the northeastern part of the Tibetan Plateau. Amplitudes observed for reflections from the crust-mantle boundary are sufficiently large to suggest that there is no significant partial melt in the deep crust. The data show an increase of the crustal thickness between terranes from north of the Kun Lun Fault into the Qang Tang of central Tibet, and a contrast among their intracrustal images and compositions. In the north, P and S velocities are consistent with a dominantly felsic composition and show that only the upper crust thickened. South of the Kun Lun Fault a thicker crust made of two layers could result from the superposition of the originally thin crust of the Bayan Har terrane on the lower part of the crust of the domain to the north, which upper crust it shoved and thickened. Different modes of crustal thickening, either by thickening of individual layers or superpositions and imbrication among them appear to work jointly to raise the topography.  相似文献   

Use of Chemotaxonomy To Study the Influence of Benzalkonium Chloride on Bacterial Populations in Biodegradation Testing     

Klaus Kümmerer  Ali Al‐Ahmad  Almut Henninger 《洁净——土壤、空气、水》2002,30(4):171-178

Contradictory results are reported for the behaviour of quaternary ammonium compounds (QACs) in sewage treatment plants (STPs). QACs may sorb onto activated sludge. Only little information is available with respect to effects of QACs against bacteria in STPs. Only 5 to 15 % of bacteria present in sewage sludge can be detected by means of culture dependent microbiological methods. The shift of the bacterial populations due to effects of test compounds have not been studied up to now with culture independent methods. The microbial populations shift was studied in situ using culture independent chemotaxonomy profiling ubiquinones and polyamines. Additionally, toxic effects of QACs against bacteria present in the test vessels of the Zahn‐Wellens test (OECD 302 B) were assessed with a toxicity control in the test. The ubiquinone profiles representing changes in Gram‐negative populations mainly showed that the activated sludge was affected only in test vessels containing benzalkonium chloride. According to chemotaxonomy Acinetobacter or/and some members of Pseudomonas spp. have been selected by benzalkonium chloride after some adaptation period (8 to 12 days).  相似文献   

山西北部至晋冀蒙交界地区几次中强地震前4.0级地震活动的研究     

薛丁  徐建德  阎海滨  张晁军  朱学健 《山西地震》2002,(4):17-21

对山西北部至晋冀蒙交界地区中强地震前的 4 .0级地震进行了研究 ,得出其特征为异常增强—异常平静—信号地震的结论 ,认为该区某些 4 .0级地震活动似可作为某些中强地震的前兆地震而进行进一步的研究。  相似文献   

Establishment of a Non-Permanent GPS Network to Monitor the Recent NE-SW Deformation in the Granada Basin (Betic Cordillera,Southern Spain)     

Gil  A. J.  Rodríguez-Caderot  G.  Lacy  M. C.  Ruiz  A. M.  Sanz de Galdeano  C.  Alfaro  P. 《Studia Geophysica et Geodaetica》2002,46(3):395-410

The Granada Basin (Central Betic Cordillera), one of the most seismically active areas of the Iberian Peninsula, is currently subjected to NW-SE compression and NE-SW extension. The present day extension is accommodated by normal faults with various orientations but particularly with a NW-SE strike. At the surface, these active NW-SE normal faults are mainly concentrated on the NE part of the Basin. In this part we have selected a 15-km long segment where several active normal faults crop out. Using the marine Tortonian rocks as a reference, we have calculated a minimum extensional rate of 0.15-0.30 mm/year. The observed block rotation, the listric geometry of faults at depth and the distribution of seismicity over the whole Basin, indicate that this rate is a minimum value. In the framework of an interdisciplinary research project a non-permanent GPS-network has been established in the central sector of Betic Cordillera to monitor the crustal deformations. The first two observation campaigns were done in 1999 and 2000.  相似文献   

路南石林形态计量分析   总被引：3，自引：0，他引：3  

王在高  杨明德  梁虹  彭建  程星 《山地学报》2002,20(5):519-525

从流域地貌结构的角度，分析了路南石林形态的相似性和差异性，并根据对石林形态测量的数据，借助于SPSS软件，运用多元统计学的方法，对石林形态进行计量分析，从而揭示了石林形态大小的内在本质规律-石林的高度与宽度的比值符合P-Ⅲ型曲线分布模型。  相似文献   

Competitive Adjustment and Advancement in Global Commodity Chains II: The Case of the Singapore Garment Industry     

Leo van Grunsven  & Floor Smakman 《Singapore journal of tropical geography》2002,23(1):70-92

This is the second part of a contribution to the debate on the possibilities of leveraging economic globalisation — through incorporation in international production networks and global commodity chains (GCCs) — as a strategy for developing countries to industrialise and advance their position in the world economy. In the first part, we analysed the experience of the East Asian apparel industry and addressed the issues of sustaining positions, upgrading to more rewarding roles, and advancing to less dependent positions within production networks and GCCs. We developed an analytical framework at both the firm and industry levels, and subsequently identified alternative firm- and industry-level strategies and trajectories. The present paper deals with these issues in the context of the Singapore apparel industry. Based on extensive empirical research, we demonstrate that although the East Asian experience of upgrading and repositioning within the GCC is to some extent emulated in the case of the Singapore apparel industry, the outcomes have been less favourable in terms of the depth, extent and strength of these trajectories. The differing outcomes can be explained in terms of different (systemic) conditions in the Singapore business environment, including the agency of local players, the geography of sourcing networks, and the role of the state and prevailing business attitudes. Our conclusions merit continued attention in both research and policy circles on the development of capabilities at the firm level, and the role of local business and institutional environments in local industry development processes under globalisation.  相似文献