Monitoring the freely dissolved concentrations of polycyclic aromatic hydrocarbons (PAH) and alkylphenols (AP) around a Norwegian oil platform by holistic passive sampling     

Christopher Harman  Kevin V. Thomas  Knut Erik Tollefsen  Sonnich Meier  Olav Byum  Merete Grung 《Marine pollution bulletin》2009,58(11):1671-1679

In order to assess the environmental impact of aquatic discharges from the offshore oil industry, polar organic chemical integrative samplers (POCIS) and semipermeable membrane devices (SPMDs) were deployed around an oil platform and at reference locations in the North Sea. Exposure to polycyclic aromatic hydrocarbons (PAH) and alkylated phenols (AP) was determined from passive sampler accumulations using an empirical uptake model, the dissipation of performance reference compounds and adjusted laboratory derived sampling rates. Exposure was relatively similar within 1–2 km of the discharge point, with levels dominated by short chained C1–C3 AP isomers (19–51 ng L⁻¹) and alkylated naphthalenes, phenanthrenes and dibenzothiophenes (NPD, 29–45 ng L⁻¹). Exposure stations showed significant differences to reference sites for NPD, but not always for more hydrophobic PAH. These concentrations are several orders of magnitude lower than those reported to give both acute and sub-lethal effects, although their long term consequences are unknown.  相似文献   

The Meteoritical Bulletin,No. 105          下载免费PDF全文

Audrey Bouvier  Jérôme Gattacceca  Jeffrey Grossman  Knut Metzler 《Meteoritics & planetary science》2017,52(11):2411-2411

Meteoritical Bulletin 105 contains 2666 meteorites including 12 falls (Aouinet Legraa, Banma, Buritizal, Ejby, Kamargaon, Moshampa, Mount Blanco, Murrili, Osceola, Sariçiçek, Sidi Ali Ou Azza, Stubenberg), with 2244 ordinary chondrites, 142 HED achondrites, 116 carbonaceous chondrites, 37 Lunar meteorites, 20 enstatite chondrites, 20 iron meteorites, 20 ureilites, 19 Martian meteorites, 12 Rumuruti chondrites, 10 primitive achondrites, 9 mesosiderites, 5 angrites, 4 pallasites, 4 ungrouped achondrites, 2 ungrouped chondrites, 1 enstatite achondrite, and 1 relict meteorite, and with 1545 from Antarctica, 686 from Africa, 245 from Asia, 147 from South America, 22 from North America, 14 from Europe, 5 from Oceania, 1 from unknown origin. Note: 5 meteorites from Russia were counted as European. It also includes a list of approved new Dense Collection Areas and a nomenclature of the Aletai (IIIE‐an) iron meteorites from Xinjiang, China.  相似文献   

Shock metamorphism of planetary silicate rocks and sediments: Proposal for an updated classification system          下载免费PDF全文

Dieter Stöffler  Christopher Hamann  Knut Metzler 《Meteoritics & planetary science》2018,53(1):5-49

We reevaluate the systematics and geologic setting of terrestrial, lunar, Martian, and asteroidal “impactites” resulting from single or multiple impacts. For impactites derived from silicate rocks and sediments, we propose a unified and updated system of progressive shock metamorphism. “Shock-metamorphosed rocks” occur as lithic clasts or melt particles in proximal impactites at impact craters, and rarely in distal impactites. They represent a wide range of metamorphism, typically ranging from unshocked to shock melted. As the degree of shock metamorphism, at a given shock pressure, depends primarily on the mineralogical composition and the porosity of a rock or sediment sample, different shock classification systems are required for different types of planetary rocks and sediments. We define shock classification systems for eight rock and sediment classes which are assigned to three major groups of rocks and sediments (1) crystalline rocks with classes F, M, A, and U; (2) chondritic rocks (class C); and (3) sedimentary rocks and sediments with classes SR, SE, and RE. The abbreviations stand for felsic (F), mafic (M), anorthositic (A), ultramafic (U), sedimentary rocks (SR), unconsolidated sediments (SE), and regoliths (RE). In each class, the progressive stages of shock metamorphism are denominated S1 to Sx. These progressive shock stages are introduced as: S1–S7 for F , S1–S7 for M, S1–S6 for A , S1–S7 for U , S1–S7 for C , S1–S7 for SR , S1–S5 for SE , and S1–S6 for RE . S1 stands for “unshocked” and Sx (variable between S5 and S7) stands for “whole rock melting.” We propose a sequence of symbols characterizing the degree of shock metamorphism of a sample, i.e., F-S1 to F-S7 with the option to add the tabulated pressure ranges (in GPa) in parentheses.  相似文献   

Addendum to “Stöffler,D., Hamann,C., and Metzler,K., Shock metamorphism of planetary silicate rocks and sediments: Proposal for an updated classification system. Meteoritics & Planetary Science 53, 5–49, 2018”     

Dieter Stffler  Christopher Hamann  Knut Metzler 《Meteoritics & planetary science》2019,54(4):946-949

With this addendum we provide some correction and additional information regarding the above cited publication. It addresses the following two topics. (1) Clarification for a correct application of the criteria for certain shock stages of chondrites, in particular stage C‐S6. (2) Correction of a printing error in the table that contains the shock classification system of chondrites.  相似文献   

The L3–6 chondritic regolith breccia Northwest Africa (NWA) 869: (II) Noble gases and cosmogenic radionuclides     

Kees WELTEN  Marc W. CAFFEE  Luitgard FRANKE  A. J. Timothy JULL  Marlene D. LeCLERC  Knut METZLER  Ulrich OTT 《Meteoritics & planetary science》2011,46(7):970-988

Abstract– We measured cosmogenic radionuclides and noble gases in the L3–6 chondrite breccia Northwest Africa (NWA) 869, one of the largest meteorite finds from the Sahara. Concentrations of ¹⁰Be, ²⁶Al, and ³⁶Cl in stone and metal fractions of six fragments of NWA 869 indicate a preatmospheric radius of 2.0–2.5 m. The ¹⁴C and ¹⁰Be concentrations in three fragments yield a terrestrial age of 4.4 ± 0.7 kyr, whereas two fragments show evidence for a recent change in shielding, most likely due to a recent impact on the NWA meteoroid, approximately 10⁵ yr ago, that excavated material up to approximately 80 cm deep and exposed previously shielded material to higher cosmic‐ray fluxes. This scenario is supported by the low cosmogenic ³He/²¹Ne ratios in these two samples, indicating recent loss of cosmogenic ³He. Most NWA samples, except for clasts of petrologic type 4–6, contain significant amounts of solar Ne and Ar, but are virtually free of solar helium, judging from the trapped ⁴He/²⁰Ne ratio of approximately 7. Trapped planetary‐type Kr and Xe are most clearly present in the bulk and matrix samples, where abundances of ¹²⁹Xe from decay of now extinct ¹²⁹I are highest. Cosmogenic ²¹Ne varies between 0.55 and 1.92 × 10^?8 cm³ STP g^?1, with no apparent relationship between cosmogenic and solar Ne contents. Low cosmogenic (²²Ne/²¹Ne)_c ratios in solar gas free specimens are consistent with irradiation in a large body. Combined ¹⁰Be and ²¹Ne concentrations indicate that NWA 869 had a 4π cosmic‐ray exposure (CRE) age of 5 ± 1 Myr, whereas elevated ²¹Ne concentrations in several clasts and bulk samples indicate a previous CRE of 10–30 Myr on the parent body, most probably as individual components in a regolith. Unlike many other large chondrites, NWA 869 does not show clear evidence of CRE as a large boulder near the surface of its parent body. Radiogenic ⁴He concentrations in most NWA 869 samples indicate a major outgassing event approximately 2.8 Gyr ago that may have also resulted in loss of solar helium.  相似文献   

Multiproxy Analyses of Stratigraphy and Palaeoenvironment of the Late Palaeolithic Grabow Floodplain Site,Northern Germany     

Johann Friedrich Tolksdorf  Falko Turner  Knut Kaiser  Eileen Eckmeier  Mareike Stahlschmidt  Rupert A. Housley  Klaus Breest  Stephan Veil 《Geoarchaeology》2013,28(1):50-65

Changing river courses and fluctuations of the water table were some of the most fundamental environmental changes that humans faced during the Late Glacial, particularly as these changes affected areas intensively used for settlement and resource exploitation. Unfortunately, only a few stratigraphies have been documented in the North European plain that show the interaction between river development, vegetation history, and occupation by Late Palaeolithic humans. Here, we present the results of detailed stratigraphical studies (pedology, archaeology, chrono‐, tephra‐, and palynostratigraphy) at the Federmesser site Grabow 15 located in the broad Elbe River valley. The research aimed to produce a model of site formation based on a multiproxy approach, relating the local evidence to the palaeoenvironmental and settlement history of the wider region. After deposition of fluvial sands during the Late Pleniglacial in a braided setting, the river course developed locally toward a meandering system at the transition from the Older Dryas to the Allerød, while periodic flooding led to the deposition of floodplain sediments during the early Allerød. The floodplain was settled by people of the earliest “Federmessergruppen,” who are believed to have chosen this open floodplain area along the river for collecting and processing amber of local origin. Their artifacts became embedded in the aggrading floodplain sediments. In the late Allerød, floodplain sedimentation ceased and a Fluvisol‐type soil developed, indicating a trend toward geomorphic stability. The Fluvisol was then covered by silty floodplain sediments due to a rising water level during the late Younger Dryas resulting in the cessation of human occupation in the area. Subsequent organic‐rich Late Glacial/Holocene sediments preserved the settlement remains to the present.  相似文献   

Transferability of hydrological model parameter spaces in the estimation of runoff in ungauged catchments     

Mulugeta B. Zelelew  Knut Alfredsen 《水文科学杂志》2013,58(8):1470-1490

Abstract

In this study, transferability options of the Hydrologiska Byråns Vattenbalansavdelning (HBV) hydrological model parameter (MP) spaces were investigated to estimate ungauged catchment runoff. Three approaches were applied in the study: MP space transfer from single, neighbouring and all potential donor catchments. The model performance was evaluated by a jackknife procedure, where one catchment at a time was treated as if ungauged, and behavioural MP sets from candidate donor catchments were used to estimate the “ungauged” runoff. The results showed that ungauged catchment runoff estimation could not be guaranteed by transferring MP sets from a single physiographically nearest donor catchment. Integrating MP sets typically from one to six donor catchments supplemented the lack of effective MP sets and improved the model performance at the ungauged catchments. In addition, the analysis results revealed that the model performance converged to an average performance when the MP sets of all potential donor catchments were integrated.  相似文献   

The effects of hydropeaking on hyporheic interactions based on field experiments          下载免费PDF全文

Roser Casas‐Mulet  Knut Alfredsen  Byman Hamududu  Netra Prasad Timalsina 《水文研究》2015,29(6):1370-1384

Hydropeaking power production has the potential to pose serious challenges towards hydrology, water quality and ecology in the downstream water bodies. The effects of such abrupt changes of flow in hyporheic exchange have been explored in a few cases in the literature. This paper extends previous works with a study of finer time resolution in a river of a smaller size and with different climatic characteristics, adding to the current knowledge of peaking‐hyporheic interactions. A high‐frequency logging field experiment measuring hyporheic flow and temperature was conducted on a ~30 × 20 m gravel bar frequently exposed to dry conditions because of fast and abrupt flow changes. This study demonstrates that hyporheic processes are sensitive to hydropeaking with respect to rates of change, durations and temperature. Differences BETWEEN individual events, seasons, watering and dewatering processes and positions in the river bed that can be potentially relevant to ecology were investigated. Understanding the complexity of those processes at the fine scale from the physical point of view is both important for the judgement of potential ecological impacts and for the future management of such regulated systems. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Configuration,history and impact of the Norwegian Channel Ice Stream     

Hans Petter Sejrup  Eiliv Larsen  Haflidi Haflidason  Ida M. Berstad  Berit O. Hjelstuen  Hafdis E. Jonsdottir  Edward L. King  Jon Landvik  Oddvar Longva  Atle Nygrd  Dag Ottesen  Stle Raunholm  Leif Rise  Knut Stalsberg 《Boreas: An International Journal of Quaternary Research》2003,32(1):18-36

The Norwegian Channel between Skagerrak, in the southeast, and the continental margin of the northern North Sea, in the northwest, is the result of processes related to repeated ice stream activity through the last 1.1 m yr. In such periods the Skagerrak Trough (700 m deep) has acted as a confluence area for glacial ice from southeastern Norway, southern Sweden and parts of the Baltic. Possibly related to the threshold in the Norwegian Channel off Jæren (250 m deep), the ice stream, on a number of occasions over the last 400 ka, inundated the coastal lowlands and left an imprint of NW‐oriented ice directional features (drumlins, stone orientations in tills and striations). Marine interstadial sediments found up to 200 m a.s.l. on Jæren have been suggested to reflect glacial isostasy related to the Norwegian Channel Ice Stream (NCIS). In the channel itself, the ice stream activity is evidenced by mega‐scale glacial lineations on till surfaces. As a result of subsidence, the most complete sedimentary records of early phases of the NCIS are preserved close to the continental margin in the North Sea Fan region. The strongest evidence for ice stream erosion during the last glacial phase is found in the Skagerrak. On the continental slope the ice stream activity is evidenced by the large North Sea Fan, which is mainly a result of deposition of glacial‐fed debris flows. Northwards of the North Sea Fan, rapid deposition of meltwater plume deposits, possibly related to the NCIS, is detected as far north as the Vøring Plateau. The NCIS system offers a unique possibility to study ice stream related processes and the impact the ice stream development had on open ocean sedimentation and circulation.  相似文献   

Measurements of meteor smoke particles during the ECOMA-2006 campaign: 2. Results     

Irina Strelnikova  Markus Rapp  Boris Strelnikov  Gerd Baumgarten  Alvin Brattli  Knut Svenes  Ulf-Peter Hoppe  Martin Friedrich  Jörg Gumbel  Bifford P. Williams 《Journal of Atmospheric and Solar》2009,71(3-4):486-496

The first sounding rocket of the European ECOMA-project (ECOMA, Existence and Charge state Of Meteoric smoke particles in the middle Atmosphere) was launched on 8 September 2006. Measurements with a new particle detector described in the companion paper by Rapp and Strelnikova [2008. Measurements of meteor smoke particles during the ECOMA-2006 campaign: 1. Particle detection by active photoionization. Journal of Atmospheric and Solar-Terrestrial Physics, this issue, doi:10.1016/j.jastp.2008.06.002] clearly showed meteor smoke particle (MSP) signatures in both data channels. The data channels measure particles directly impacting on the detector electrode and photoelectrons from the particles actively created using ionization by the UV-photons of a xenon-flashlamp. Measured photoelectron currents resemble model expectations of the shape of the MSP layer almost perfectly, whereas derived number densities in the altitude range 60–90 km are larger than model results by about a factor of 5. Given the large uncertainties inherent to both model and the analysis of our measurements (e.g., the composition of the particles is not known and must be assumed) we consider this a satisfactory agreement and proof that MSPs do extend throughout the entire mesosphere as predicted by models. The measurements of direct particle impacts revealed a confined layer of negative charge between 80 and 90 km. This limited altitude range, however, is quantitatively shown to be the consequence of the aerodynamics of the rocket flight and does not have any geophysical origin. Measured charge signatures are consistent with expectations of particle charging given our own measurements of the background ionization. Unfortunately, however, a contamination of these measurements from triboelectric charging cannot be excluded at this stage.  相似文献