Comparison of organotin accumulation on the white-spotted charr Salvelinus leucomaenis between sea-run and freshwater-resident types     

Madoka Ohji  Hiroya Harino  Takaomi Arai 《Estuarine, Coastal and Shelf Science》2011

To examine the accumulation pattern of organotin compounds (OTs) in relation to the migration of diadromous fish, tributyltin (TBT) and triphenyltin (TPT) compounds and their derivatives were determined in the muscle tissue of both sea-run (anadromous) and freshwater-resident (nonanadromous) types of the white-spotted charr Salvelinus leucomaenis. There were generally no significant correlations between the TBT and TPT accumulation and various biological characteristics such as the total length (TL), body weight (BW), age and sex in S. leucomaenis. It is noteworthy that the TBT and TPT concentrations in sea-run white-spotted charr were significantly higher than in freshwater-resident individuals, although they are intraspecies. These results suggest that the sea-run S. leucomaenis has a higher ecological risk of TBT and TPT exposure than the freshwater-residents during their life history.  相似文献   

Petrology of the Yugu peridotites in the Gyeonggi Massif,South Korea: Implications for its origin and hydration process     

Shoji Arai  Akihiro Tamura  Satoko Ishimaru  Kazuyuki Kadoshima  Yong‐Il Lee  Ken‐ichiro Hisada 《Island Arc》2008,17(4):485-501

Peridotites exposed in the Yugu area in the Gyeonggi Massif, South Korea, near the boundary with the Okcheon Belt, exhibit mylonitic to strongly porphyroclastic textures, and are mostly spinel lherzolites. Subordinate dunites, harzburgites, and websterites are associated with the lherzolites. Amphiboles, often zoned from hornblende in the core to tremolite in the rim, are found only as neoblasts. Porphyroclasts have recorded equilibrium temperatures of about 1000°C, whereas neoblasts denote lower temperatures, about 800°C. Olivines are Fo_90–91 in lherzolites and Fo₉₁ in a dunite and a harzburgite. The Cr# (= Cr/(Cr + Al) atomic ratio) of spinels varies together with the Fo of olivines, being from 0.1 to 0.3 in lherzolites and around 0.5 in the dunite and harzburgite. The Na₂O content of clinopyroxene porphyroclasts is relatively low, around 0.3 to 0.5 wt% in the most fertile lherzolite. The Yugu peridotites are similar in porphyroclast mineral chemistry not to continental spinel peridotites but to sub‐arc or abyssal peridotites. Textural and mineralogical characteristics indicate the successive cooling with hydration from the upper mantle to crustal conditions for the Yugu peridotites. Almost all clinopyroxenes and amphiboles show the same U‐shaped rare earth element (REE) patterns although the level is up to ten times higher for the latter. The hydration was associated with enrichment in light REE, resulting from either a slab‐derived fluid or a fluid circulating in the crust. The mantle‐wedge or abyssal peridotites were emplaced into the continental crust as the Yugu peridotite body during collision of continents to form a high‐pressure metamorphic belt in the Gyeonggi Massif. The peridotites from the Gyeonggi Massif exhibit lower‐pressure equilibration than peridotites, with or without garnets, from the Dabie–Sulu Collision Belt, China, which is possibly a westward extension of the Gyeonggi Massif.  相似文献   

Early Cretaceous paleogeography of Korea and Southwest Japan inferred from occurrence of detrital chromian spinels     

Ken‐ichiro Hisada  Shizuka Takashima  Shoji Arai  Yong Il Lee 《Island Arc》2008,17(4):471-484

The Sindong Group was deposited in the north–south trending half‐graben Nakdong Trough, southern Korean peninsula. The occurrence of detrital chromian spinels from the Jinju Formation of the Sindong Group in the Gyeongsang Basin means that the mafic to ultramafic rocks were exposed in its provenance. The chromian spinels from the Jinju Formation are characterized by extremely low TiO₂ and Fe³⁺. Moreover, their range of Cr# is from 0.45 to 0.80 and makes a single trend with Mg#. The chemistry of chromian spinels implies that the source rocks for chromian spinels were peridotites or serpentinites, which originated in the mantle wedge. To more narrowly constrain their source rocks, the Ulsan and Andong serpentinites exposed in the Gyeongsang Basin were examined petrographically. Chromian spinels in the Andong serpentinite differ from those of the Jinju Formation and those in the Ulsan serpentinite partly resemble them. Furthermore, the Jinju chromian spinel suite is similar to the detrital chromian spinels from the Mesozoic sediments in the Circum‐Hida Tectonic zone, which includes the Nagato Tectonic zone in Southwest Japan and the Joetsu Belt in Northeast Japan. This suggests that the basement rocks, which were located along the main fault bounding the eastern edge of the Nakdong Trough, had exposures of peridotite or serpentinite. It is possible that the Nakdong Trough was directly adjacent to the Circum‐Hida Tectonic zone before the opening of the Sea of Japan (East Sea).  相似文献   

Magmatic unmixing in spinel from late Precambrian concentrically-zoned mafic–ultramafic intrusions, Eastern Desert, Egypt     

Ahmed Hassan Ahmed  Hassan Mohamed Helmy  Shoji Arai  Masako Yoshikawa 《Lithos》2008,104(1-4):85-98

Spinel is widespread in the ultramafic core rocks of zoned late Precambrian mafic–ultramafic complexes from the Eastern Desert of Egypt. These complexes; Gabbro Akarem, Genina Gharbia and Abu Hamamid are Precambrian analogues of Alaskan-type complexes, they are not metamorphosed although weakly altered. Each intrusion is composed of a predotite core enveloped by pyroxenites and gabbros at the margin. Silicate mineralogy and chemistry suggest formation by crystal fractionation from a hydrous magma. Relatively high Cr₂O₃ contents are recorded in pyroxenes (up to 1.1 wt.%) and amphiboles (up to 1.4 wt.%) from the three plutons. The chrome spinel crystallized at different stages of melt evolution; as early cumulus inclusions in olivine, inclusions in pyroxenes and amphiboles and late-magmatic intercumulus phase. The intercumulus chrome spinel is homogenous with narrow-range of chemical composition, mainly Fe³⁺-rich spinel. Spinel inclusions in clinopyroxene and amphibole reveal a wide range of Al (27–44 wt.% Al₂O₃) and Mg (6–13 wt.% MgO) contents and are commonly zoned. The different chemistries of those spinels reflect various stages of melt evolution and re-equilibration with the host minerals. The early cumulus chrome spinel reveals a complex unmixing structures and compositions. Three types of unmixed spinels are recognized; crystallographically oriented, irregular and complete separation. Unmixing products are Al-rich (Type I) and Fe³⁺-rich (Type II) spinels with an extensive solid solution between the two end members. The compositions of the unmixed spinels define a miscibility gap with respect to Cr–Al–Fe³⁺, extending from the Fe³⁺–Al join towards the Cr corner. Spinel unmixing occurs in response to cooling and the increase in oxidation state. The chemistry and grain size of the initial spinel and the cooling rate control the type of unmixing and the chemistry of the final products. Causes of spinel unmixing during late-magmatic stage are analogous to those in metamorphosed complexes. The chemistry of the unmixed spinels is completely different from the initial spinel composition and is not useful in petrogenetic interpretations. Spinels from oxidized magmas are likely to re-equilibrate during cooling and are not good tools for genetic considerations.  相似文献   

Compositional variations in spinel-hosted pargasite inclusions in the olivine-rich rock from the oceanic crust–mantle boundary zone     

Akihiro Tamura  Tomoaki Morishita  Satoko Ishimaru  Kaori Hara  Alessio Sanfilippo  Shoji Arai 《Contributions to Mineralogy and Petrology》2016,171(5):39

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Peridotite xenoliths from the Shiribeshi Seamount,Japan Sea: insights into mantle processes in a back-arc basin     

Yuji Ichiyama  Tomoaki Morishita  Akihiro Tamura  Shoji Arai 《Contributions to Mineralogy and Petrology》2016,171(10):86

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Influence of non-thermal plasma after-treatment technology on diesel engine particulate matter composition and NOx concentration     

M. Babaie  T. Kishi  M. Arai  Y. Zama  T. Furuhata  Z. Ristovski  H. Rahimzadeh  R. J. Brown 《International Journal of Environmental Science and Technology》2016,13(1):221-230

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Habitat use by the European eel Anguilla anguilla in Irish waters   总被引：2，自引：0，他引：2  

T. Arai  A. Kotake  T.K. McCarthy 《Estuarine, Coastal and Shelf Science》2006,67(4):569-578

The apparent use of marine and freshwater habitats by European eel Anguilla anguilla was examined by analyzing the strontium (Sr) and calcium (Ca) concentrations in otoliths of the eels collected from Irish coastal and fresh waters. The age and growth of eels were also examined using their otolith annuli. The sizes and ages of the female eels were greater than those of the males. The somatic growth rates ranged from 15 to 62 mm/year, which is typical for Ireland and other European countries. Analyses of Sr:Ca ratios along a life history transect in each otolith showed peaks (maximum more than 25 × 10⁻³) between the core and elver mark corresponding to the period of their leptocephalus and early glass eel stages in the ocean. Outside the elver mark, the Sr:Ca ratios indicated that eels had remained in different habitats that included freshwater (average Sr:Ca ratios, 0.98–1.78 × 10⁻³) and areas with relatively high salinities (average Sr:Ca ratios, 6.73–8.89 × 10⁻³). Some individuals showed clear evidence of shifts from sea to fresh waters. These findings suggest that Irish eels have the same behavioral plasticity regarding whether or not to enter freshwater or remain in marine environments as has been recently documented in this species and several other temperate anguillid species. However, patterns of habitat use in Irish waters were somewhat different than those previously reported for other habitats.  相似文献   

Comparison of organotin accumulation in the masu salmon Oncorhynchus masou accompanying migratory histories     

Madoka Ohji  Takaomi Arai  Nobuyuki Miyazaki 《Estuarine, Coastal and Shelf Science》2007,72(4):721-731

In order to examine the accumulation pattern of organotin compounds (OTs) accompanying the migration pattern in diadromous fish, tributyltin (TBT) and triphenyltin (TPT) compounds and their derivatives were determined in the liver, muscle, gill, and ovary tissues of both sea-run and freshwater-resident masu salmon, which are of the same species, Oncorhynchus masou. Their migratory histories were estimated using strontium (Sr) and calcium (Ca) analysis in the otolith. A significant difference in the mean Sr:Ca ratio from the core to the edge of the otolith was found between sea-run and freshwater-resident masu salmon. The TBT concentration in the liver was significantly higher than that in the other tissues in both sea-run and freshwater-resident fishes. In sea-run masu salmon, the TBT concentrations in all tissues except for the ovary were significantly higher than in those of freshwater-resident individuals. In the sea-run type, the percentage of TBT was higher than that of the freshwater-resident type. The TPT concentration in the liver of the sea-run type was also significantly higher than that in the other tissues, while that in the gill of the freshwater-resident type was significantly higher than that in the other tissues except for the ovary. The TPT concentrations found in the liver and muscle of the sea-run type were significantly higher than those in the freshwater-resident type, whereas the values of the gill in the sea-run type were significantly lower than those in the freshwater-resident fish examined. The percentage of TPT in the sea-run type was higher than that of the freshwater-resident type. These results suggest that the sea-run O. masou has a higher ecological risk of TBT and TPT exposure than the freshwater-residents during their life history.  相似文献   

Trace metals in Japanese eel Anguilla japonica in relation to ecological migratory types and growth stages     

Dung Quang Le  Naoko Chino  Kotaro Shirai  Takaomi Arai 《Estuarine, Coastal and Shelf Science》2010

In order to understand the metal concentrations in Japanese eel Anguilla japonica, nine elements were analyzed in the livers of different migratory types of eels collected from Tokushima region (south Japan). Migratory types were defined by examining the Sr:Ca ratio in otoliths. The results showed that there were significant differences in V, Cr, Cd, and Pb concentrations among the migratory types. Mature-sea-eels show a higher risk of metal accumulation than other migratory types of eels, and the concentrations of Mn, Cu, and Zn in mature eels were significantly higher than those in immature eels. The study suggests that the eel liver is a valuable bioindicator for trace metals; however, when using the eel as a bioindicator to reveal the pollutants in aquatic systems, life history analysis should be carried out for accurate interpretation of the results.  相似文献