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151.
A numerical method, which combines the boundary element method (BEM) and the volume of the fluid method (VOF method), has been presented to solve wave–structure interactions; the intense wave motion at the proximity of the structure is modeled by the VOF method and the rest of the fluid region is modeled by the BEM. The combined method can considerably reduce the time-consuming VOF domain, and thus practically makes it possible to apply the VOF method for random wave calculations, in which long time computations are usually required to obtain statistically meaningful results, and therefore the use of the single-VOF model often becomes prohibitive in terms of computational time and storage memories. A VOF model CADMAS-SURF, which is based on SMAC scheme and had been constructed by a number of VOF researchers in coastal engineering in Japan, is used in the combined BEM–VOF model. The two-way coupling treatment, which enables us to deal with bidirectional wave propagations, which was originally given for the SOLA-VOF model by Yan et al. (2003a) and later improved by Kim et al. (2007), was modified for the SMAC scheme. The coupling treatments are described in detail in the paper. The validity of the combined BEM–VOF model was investigated by comparing the numerical results with the theoretical results for the propagations of Stokes 5th order waves and random waves.  相似文献   
152.
Weathering rinds formed in Mesozoic sandstone and basalt cobbles buried in terrace deposits for up to 300 ka have been investigated. The aim was to determine the formation process and elemental mass balances during rind development. The ages of terraces distributed in the western part of Fukui prefecture, central Japan have been determined as 50 ka, 120 ka and 300 ka based on a tephro-stratigraphic method. Detailed investigations across the weathering rinds, consisting of microscopic observations, porosity measurements, and mineralogical and geochemical analyses using X-ray diffractometry (XRD), X-ray fluorescence (XRF), secondary X-ray analytical microscopy (SXAM), scanning electron microanalyser (SEM) and electron probe microanalysis (EPMA) have been carried out. The results revealed that the Fe concentrations in the weathering rind of a basalt cobble slightly decreased from the cobble’s surface (rim) towards the unweathered core. In contrast, in a sandstone cobble formed under the same environmental conditions over the same period of time there is an Fe-rich layer at some distance below the cobble’s surface. Elemental mass balances across the rinds were determined by using open system mass balance (τi,j) calculations and show that the Fe was precipitated as Fe-oxyhydroxides in the basalt cobbles, although Fe was slightly removed from the rims. In sandstone cobbles, on the other hand, Fe migrated along a Fe concentration gradient by diffusion and precipitated as Fe-oxyhydroxide minerals to form the weathering rinds. Presumably, precipitation was due to the relatively higher pH conditions caused by mineral dissolution within the pores, principally involving calcite, but probably also silicates including feldspar. The detailed characterization of the weathering rinds revealed the influence of lithology on the accumulation and dissolution of Fe-oxyhydroxides, causing weathering rinds with different characteristics to develop in different kinds of buried cobbles under the same conditions. Relatively large climatic changes in the study area did not cause discernable variations in the mean formation rates of the studied rinds, which were in the order of 10?8 m/a for both basalt and sandstone cobbles. These rates are 1–2 orders of magnitude slower than those reported for tropical areas elsewhere, most probably due to the lower rainfall in the studied area.  相似文献   
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Episyenite is a quartz-depleted vuggy rock resulting from hydrothermal alteration of granitic rocks. This is the first report of its existence in an island arc, which is identified in a deep drill core of the Toki Cretaceous granite distributed in central Japan. In order to understand the petrographical features of the episyenite, neutron porosity measurement, geochemical analysis, microscopic observation, and X-ray computed tomography scanning were carried out. The results show remarkably high porosity (35.4 %) due to interconnecting vugs and the removal of quartz, plagioclase, and biotite. The Rb–Sr isotopic results and the paragenetic sequence of secondary minerals in the vugs suggest that the hydrothermal alteration process can be divided into an episyenitization stage and a later hydrothermal stage. At the episyenitization stage (70.6 ± 3.1 Ma) ca. 6 million years after the emplacement of the unaltered granite (76.3 ± 1.5 Ma), dissolution of quartz, biotite, and plagioclase occurred and was followed by the precipitation of albite, vermicular chlorite, and platy calcite. The episyenitization is considered as a local alteration of the Toki granite in an isotopically closed system. At the later hydrothermal stage, illite and secondary quartz precipitated from circulating meteoric-derived water in the dissolution vugs. Superimposing alteration at the later hydrothermal stage is limited, which results in the preservation of the episyenite in an almost primitive condition.  相似文献   
156.
Lithium-rich brine in playas is a major raw material for lithium production. Recently, lithium isotopic ratios (δ7Li) have been identified as a tool for investigating water–rock interactions. Thus, to constrain the origin of lithium in playas by the use of its isotopes, we conducted leaching experiments on various lacustrine sediment and evaporite deposit samples collected from playas in Nevada, USA. We determined lithium and strontium isotopic ratios and contents and trace element contents of the leachate, estimated the initial δ7Li values in the water flowing into the playas, and examined the origin of lithium in playas by comparison with δ7Li values of the possible sources. In samples from the playas, δ7Li values show some variation, reflecting differences both in isotopic fractionation during mineral formation and in initial δ7Li value in water flowing into each playa. However, all δ7Li values in this study are much lower than those in river water and groundwater samples from around the world, but they are close to those of volcanic rocks. Considering the temperature dependence of lithium isotopic fractionation between solid and fluid, these results indicate that the lithium concentrated in playas in Nevada was supplied mainly through high-temperature water–rock interaction associated with local hydrothermal activity and not directly by low-temperature weathering of surface materials. This study, which is the first to report lithium isotopic compositions in playas, demonstrates that δ7Li may be a useful tracer for determining the origin of lithium and evaluating its accumulation processes in playas.  相似文献   
157.
The water content of low-K tholeiitic basalt magma from Iwate volcano, which is located on the volcanic front of the NE Japan arc, was estimated using multi-component thermodynamic models. The Iwate lavas are moderately porphyritic, consisting of ~8 vol.% olivine and ~20 vol.% plagioclase phenocrysts. The olivine and plagioclase phenocrysts show significant compositional variations, and the Mg# of olivine phenocrysts (Mg#78–85) correlates positively with the An content of coexisting plagioclase phenocrysts (An85–92). The olivine phenocrysts with Mg# > ~82 do not form crystal aggregates with plagioclase phenocrysts. It is inferred from these observations that the phenocrysts with variable compositions were primarily derived from mushy boundary layers along the walls of a magma chamber. By using thermodynamic calculations with the observed petrological features of the lavas, the water content of the Iwate magma was estimated to be 4–5 wt.%. The high water content of the magma supports the recent consensus that frontal-arc magmas are remarkably hydrous. Using the estimated water content of the Iwate magma, the water content and temperature of the source mantle were estimated. Given that the Iwate magma was derived from a primary magma solely by olivine fractionation, the water content and temperature were estimated to be ~0.7 wt.% and ~1,310 °C, respectively. Differentiation mechanisms of low-K frontal-arc basalt magmas were also examined by application of a thermodynamics-based mass balance model to the Iwate magma. It is suggested that magmatic differentiation proceeds primarily through fractionation of crystals from the main molten part of a magma chamber when it is located at <~200 MPa, whereas magma evolves through a convective melt exchange between the main magma and mushy boundary layers when the magma body is located at >~200 MPa.  相似文献   
158.
Abstract— The timing and processes of alteration in the CV parent body are investigated by the analysis of Sr isotopes, major and trace elements, and petrographic type and distribution of the secondary minerals (nepheline and sodalite) in 22 chondrules from the Allende (CV3) chondrite. The Sr isotopic compositions of the chondrules are scattered around the 4.0 Ga reference line on the 87Sr/86Sr evolution diagram, indicating that the chondrules have been affected by late thermal alteration event(s) in the parent body. The degree of alteration, determined for individual chondrules based on the distribution of nepheline and sodalite, is unrelated to the disturbance of the Rb‐Sr system, suggesting that the alteration process that produced nepheline and sodalite is different from the thermal process that disturbed the Rb‐Sr system of the chondrules. Considering the geochemical behavior of Rb and Sr, the main host phase of Sr in chondrules is likely to be mesostasis, which could be most susceptible to late thermal alteration. As there is a poor connection between the alteration degree determined from abundances of nepheline and sodalite and the disturbance of Rb‐Sr isotopic system, we consider the mesostasis to provide a constraint on the late parent body alteration process. From this point of view, 23 mesostasis‐rich chondrules, including those from literature data, were selected. The selected chondrules are closely correlated on the 87Sr/86Sr evolution diagram, with an inferred age of 4.36 ± 0.08 Ga. This correlation would represent an age of the final major Sr isotopic redistribution of the chondrules in the parent body.  相似文献   
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