A study on the interaction between ferric ion and silicic acid in hydrosphere: Si-containing ferruginous deposits formed in neutral hot spring waters     

Gaowa Naren  Akane Miyazaki  Motoyuki Matsuo  BAI Shuqin  Kotaro Yonesu  Yoshihiro Okaue  Takushi Yokoyama 《中国地球化学学报》2013,32(1):27-34

Five ferruginous deposit samples formed from neutral hot springs were analyzed to determine whether they consisted of a mixture of silica, hydrous iron oxide or iron silicate by differential thermal analysis (DTA), infrared (IR) spectroscopy, powder X-ray diffraction (XRD), and 57Fe Mssbauer spectroscopy. The Si/Fe atomic ratios of the deposits ranged from 0.25 to 0.45, and were smaller than those of hisingerite (12), but apparently close to those of siliceous ferrihydrite (0.250.5). Si was confirmed to be present as monomeric or oligomeric silicate from the Si-O stretching vibration frequencies on the IR spectra. Judging from the results of DTA, which minerals starting to produce after heating, and a relationship between Si-O stretching vibration frequency and Si/Fe atomic ratio proposed by Henmi et al. (1981), all the deposits in this study were concluded to be mixtures of various siliceous ferri-hydrites with low and high Si/Fe atomic ratios. Moreover, by comparing the chemical properties of hot spring waters, the formation conditions of siliceous ferrihydrite were also discussed.  相似文献   

http://www.sciencedirect.com/science/article/pii/S1674987112001302     

Jun＇ichi Okuno  Hideki Miura 《地学前缘(英文版)》2013,4(6):623-632

We present relative sea level （RSL） curves in Antarctica derived from glacial isostatic adjustment （GIA）predictions based on the melting scenarios of the Antarctic ice sheet since the Last Glacial Maximum （LGM）given in previous works.Simultaneously,Holocene-age RSL observations obtained at the raised beaches along the coast of Antarctica are shown to be in agreement with the GIA predictions.The differences from previously published ice-loading models regarding the spatial distribution and total mass change of the melted ice are significant.These models were also derived from GIA modelling; the variations can be attributed to the lack of geological and geographical evidence regarding the history of crustal movement due to ice sheet evolution.Next,we summarise the previously published ice load models and demonstrate the RSL curves based on combinations of different ice and earth models.The RSL curves calculated by GIA models indicate that the model dependence of both the ice and earth models is significantly large at several sites where RSL observations were obtained.In particular,GIA predictions based on the thin lithospheric thickness show the spatial distributions that are dependent on the melted ice thickness at each sites.These characteristics result from the short-wavelength deformation of the Earth.However,our predictions strongly suggest that it is possible to find the average ice model despite the use of the different models of lithospheric thickness.By sea level and crustal movement observations,we can deduce the geometry of the post-LGM ice sheets in detail and remove the GIA contribution from the crustal deformation and gravity change observed by space geodetic techniques,such as GPS and GRACE,for the estimation of the Antarctic ice mass change associated with recent global warming.  相似文献   

Cathodoluminescence microscopy and spectroscopy of forsterite from Kaba meteorite: An application to the study of hydrothermal alteration of parent body     

Arnold Gucsik  Taro Endo  Hirotsugu Nishido  Kiyotaka Ninagawa  Masahiro Kayama  Szaniszló Bérczi  Szabolcs Nagy  Péter Ábrahám  Yuki Kimura  Hitoshi Miura  Ildikó Gyollai  Irakli Simonia  Péter Rózsa  József Posta  Dániel Apai  Krisztián Mihályi  Mihály Nagy  Ulrich Ott 《Meteoritics & planetary science》2013,48(12):2577-2596

Highly forsteritic olivine (Fo: 99.2–99.7) in the Kaba meteorite emits bright cathodoluminescence (CL). CL spectra of red luminescent forsterite grains have two broad emission bands at approximately 630 nm (impurity center of divalent Mn ions) in the red region and above 700 nm (trivalent Cr ions) in the red–IR region. The cores of the grains show CL blue luminescence giving a characteristic broad band emission at 400 nm, also associated with minor red emissions related to Mn and Cr ions. CL color variation of Kaba forsterite is attributed to structural defects. Electron probe microanalyzer (EPMA) analysis shows concentrations of Ca, Al, and Ti in the center of the forsterite grain. The migration of diffusible ions of Mn, Cr, and Fe to the rim of the Kaba meteoritic forsterite was controlled by the hydrothermal alteration at relatively low temperature (estimated at about 250 °C), while Ca and Al ions might still lie in the core. A very unusual phase of FeO (wüstite) was also observed, which may be a terrestrial alteration product of FeNi‐metal.  相似文献   

Compound chondrule formation in the shock-wave heating model: Three-dimensional hydrodynamics simulation of the disruption of a partially-molten dust particle     

Seiji Yasuda  Hitoshi Miura 《Icarus》2009,204(1):303-315

We carried out three-dimensional hydrodynamics simulations of the disruption of a partially-molten dust particle exposed to high-speed gas flow to examine the compound chondrule formation due to mutual collisions between the fragments (fragment-collision model; [Miura, H., Yasuda, S., Nakamoto, T., 2008a. Icarus194, 811-821]).In the shock-wave heating model, which is one of the most plausible models for chondrule formation, the gas friction heats and melts the surface of the cm-sized dust particle (parent particle) and then the strong gas ram pressure causes the disruption of the molten surface layer. The hydrodynamics simulation shows details of the disruptive motion of the molten surface, production of many fragments and their trajectories parting from the parent particle, and mutual collisions among them. In our simulation, we identified 32 isolated fragments extracted from the parent particle. The size distribution of the fragments was similar to that obtained from the aerodynamic experiment in which a liquid layer was attached to a solid core and it was exposed to a gas flow. We detected 12 collisions between the fragments, which may result in the compound chondrule formation. We also analyzed the paths of all the fragments in detail and found the importance of the shadow effect in which a fragment extracted later blocks the gas flow toward a fragment extracted earlier. We examined the collision velocity and impact parameter of each collision and found that 11 collisions should result in coalescence. It means that the ratio of coalescent bodies to single bodies formed in this disruption of a parent particle is R_coa=11/(32-11)=0.52. We concluded that compound chondrule formation can occur just after the disruption of a cm-sized molten dust particle in shock-wave heating.  相似文献   

Diverse mineralogical and oxygen isotopic signatures recorded in CV3 carbonaceous chondrites     

Hatsumi Ishida  Tomoki Nakamura  Hitoshi Miura  Yuki Kakazu 《Polar Science》2012,6(3-4):252-262

We describe the petrography and mineralogy of six CV3 carbonaceous chondrites. LAP02206, LAP02228, LAP04843, and GRA06101 are classified as oxidized Allende-like chondrites (CV3_oxA). RBT04143 and QUE97186 are classified as members of the reduced subtype (CV3_red). Chondrules in the CV3_oxA chondrites show extensive Fe–Mg zoning. Fe-rich olivine in the rims of the CV3_oxA chondrules are ¹⁶O-poor relative to Mg-rich olivine in the cores, suggesting that in addition to Fe and Mg, oxygen was exchanged between chondrules and matrix during weak thermal metamorphism. The CV3_red chondrites appear to have formed through various processes. QUE97186 shows chondrule flattening with a preferred orientation, which is interpreted to have resulted from shock impact at a pressure of ～20 GPa. The post-shock residual heat (～1000 °C) is likely to be responsible for the restricted Fe/Mg ratios of matrix olivine. Based on the degree of Fe–Mg homogenization of matrix olivines, we estimate the spatial scale of the shock-heated region to be ～1 m. RBT04143 is a breccia containing many clasts of two types of lithologies: reduced-type material and very weakly altered material.  相似文献   

Quasi-static slip on the plate boundary associated with the 2003 M8.0 Tokachi-oki and 2004 M7.1 off-Kushiro earthquakes, Japan     

Naoki Uchida  Satoshi Yui  Satoshi Miura  Toru Matsuzawa  Akira Hasegawa  Yoshinobu Motoya  Minoru Kasahara 《Gondwana Research》2009,16(3-4):527-533

We analyzed small repeating earthquakes recorded over a 13-year period and GPS data recorded over an 8-month period to estimate interplate quasi-static slip associated with the 2003 Tokachi-oki earthquake (M8.0) and the 2004 off-Kushiro earthquake (M7.1). The repeating-earthquake analysis revealed that the slip rate near the source region of the Tokachi-oki earthquake was relatively low (< 5 cm/year) prior to the earthquake; however, in the last 3 years leading up to the event, a minor acceleration in slip occurred upon the deeper extension of the coseismic slip area of the earthquake. Repeating-earthquake and GPS data indicate that large amounts of afterslip occurred around the rupture area following the earthquake; the afterslip mainly propagated to the east of the coseismic slip area. We also infer that the occurrence of the 2004 off-Kushiro earthquake, located about 100 km northeast of the epicenter of the Tokachi-oki earthquake, was advanced by the afterslip associated with the Tokachi-oki earthquake.  相似文献   

Observations of molecular clouds in nearby galaxies with ALMA     

Nario Kuno  Akihiko Hirota  Tomoka Tosaki  Rie Miura 《Astrophysics and Space Science》2008,313(1-3):293-296

We present recent results of the observations of giant molecular clouds in nearby galaxies with the Nobeyama 45 m telescope and Millimeter Array. We give some brief comments about observations of GMCs in nearby galaxies with ALMA.  相似文献   

Fragment-collision model for compound chondrule formation: Estimation of collision probability     

Hitoshi Miura  Seiji Yasuda  Taishi Nakamoto 《Icarus》2008,194(2):811-821

We propose a new scenario for compound chondrule formation named as “fragment-collision model,” in the framework of the shock-wave heating model. A molten cm-sized dust particle (parent) is disrupted in the high-velocity gas flow. The extracted fragments (ejectors) are scattered behind the parent and the mutual collisions between them will occur. We modeled the disruption event by analytic considerations in order to estimate the probability of the mutual collisions assuming that all ejectors have the same radius. In the typical case, the molten thin () layer of the parent surface will be stripped by the gas flow. The stripped layer is divided into about 200 molten ejectors (assuming that the radius of ejectors is 300 μm) and then they are blown away by the gas flow in a short period of time (). The stripped layer is leaving from the parent with the velocity of depending on the viscosity, and we assumed that the extracted ejectors have a random velocity Δv of the same order of magnitude. Using above values, we can estimate the number density of ejectors behind the parent as . These ejectors occupy ∼9% of the space behind the parent in volume. Considering that the collision rate (number of collisions per unit time experienced by an ejector) is given by Rcoll=σcollneΔv, where σcoll is the cross-section of collision [e.g., Gooding, J.K., Keil, K., 1981. Meteoritics 16, 17-43], we obtain by substituting above values. Since most collisions occur within the short duration () before the ejectors are blown away, we obtain the collision probability of Pcoll∼0.36, which is the probability of collisions experienced by an ejector in one disruption event. The estimated collision probability is about one order of magnitude larger than the observed fraction of compound chondrules. In addition, the model predictions are qualitatively consistent with other observational data (oxygen isotopic composition, textural types, and size ratios of constituents). Based on these results, we concluded that this new model can be one of the strongest candidates for the compound chondrule formation. It should be noted that all collisions do not necessarily lead to the compound chondrule formation. The formation efficiency and the future works which should be investigated in the forthcoming paper are also discussed.  相似文献   

Geology and Skarn Cu–Bi–Au Mineralization at Shwe Min Bon Area,Kalaw Township,Southern Shan State,Myanmar     

Nyein N. Sint  Kotaro Yonezu  Thomas Tindell  May T. Aye  Htay Win  Akira Imai  Koichiro Watanabe 《Resource Geology》2019,69(1):85-106

The Shwe Min Bon Cu–Au skarn deposit lies within one of the largest Au–Cu belts in Myanmar. The deposit is situated along the Shan scarp zone, which marks the boundary between the Myanmar central basin to the west and the Shan plateau to the east. The Shwe Min Bon deposit comprises skarn‐type metasomatic alteration, and the Cu–Au mineralization occurs along the contact face between the Nwabangyi Dolomite and Shweminbon Formation and the Cretaceous dioritic rocks. The metasomatic process resulted in pro‐ and retrograde mineral assemblages in exoskarn. Hydrothermal activities in the Shwe Min Bon deposit are classified into prograde, retrograde stage I, and retrograde stage II. The prograde skarn is classified into a proximal garnet skarn with minor clinopyroxene and a distal wollastonite skarn. Chlorite, epidote, and tremolite–actinolite were formed during the retrograde stage I. Cu–Au mineralization mainly occurred in retrograde stage I, which was characterized by moderate temperatures (260–320 °C) and fluid with a moderate salinity (5.0–6.0% NaCl equiv.). Low temperature (180–200 °C) and low salinity (2.0–3.0% NaCl equiv.) were responsible for retrograde stage II. Au mineralization is mainly associated with chalcopyrite and tennantite in retrograde stage I and with tellurobismuthite in retrograde stage II.  相似文献   

Geochemical characteristics of pelagic chert sequences across the Permian-Triassic boundary in southwest Japan   总被引：1，自引：0，他引：1  

Hroaki  Ishiga  Kotaro  Ishida  Kaori  Dozen Makoto  Musashino 《Island Arc》1996,5(2):180-180

Abstract Geochemical characteristics, mainly of major and trace elements and REE (rare earth elements) of bedded chert and shale/mudstone sequences, across the Permian/Triassic boundary in southwest Japan are examined. The boundary is characterized by the disappearance of bedded cherts, and the interval between the Upper Permian cherts and Lower Triassic (probably Smithian) cherts comprises siliceous shales and organic black mudstones. Bedded cherts are characterized by a gradual depletion of chemical elements from Middle to Upper Permian. However, overlying siliceous shales exhibit a clear enrichment in some elements, especially alkaline metals (such as K, Rb and Cs) and Ti, Th, Y, P₂O₅, and REE in comparison with elements of the PAAS (post Archean Australian shales). This indicates that average components of the upper continental crust were transported in the boundary interval, possibly caused by volcanic activity. Ce-negative shifting in NASC (North American Shales Composite)-normalized REE patterns is characteristic of this interval, and could be related to the deposition of siliceous rocks in Ce-depleted seawater. This was probably caused by an invasion of water mass with a Ce-negative anomaly into the previously existing water mass of the Paleo-Tethys. Weak negative Eu-anomalies in this interval are suggestive of plagioclase fractionation caused by acid volcanisms and the LREE/HREE ratios in the interval show a slightly light-REE enrichment. Organic black mudstones are characteristically intercalated in the interval. These rocks are usually regarded as a product of oceanic deterioration, but in pelagic conditions, organic materials were formed by high primary production that resulted from the active upwelling of ocean floor water currents with rich nutrients. This may have been caused by the inferred mixing of water masses of the Paleo-Tethys and of the Panthalassa in Early Triassic time which was regarded as an event synchronous with an increase in volcanic activity on highly matured island arcs and/or continents.  相似文献