Chemical and structural characterization of As immobilization by nanoparticles of mackinawite (FeS_m)     

Devon Renock  Tanya Gallegos  Satoshi Utsunomiya  Kim Hayes  Rodney C. Ewing  Udo Becker 《Chemical Geology》2009,268(1-2):116-125

The mobility and availability of arsenite, As(III), in anoxic environments is largely controlled by adsorption onto iron sulfides and/or precipitation of arsenic in solid phases. The interaction of As(III) with synthetic mackinawite (FeS_m) in pH 5 and 9 suspensions was investigated using high-angle annular dark field (HAADF) scanning transmission electron microscopy (STEM), STEM elemental mapping, high resolution TEM, and X-ray photoelectron spectroscopy (XPS). At pH 5, arsenic sulfide phases precipitate among the FeS_m particles as discrete particles that are an amorphous hydrous phase of arsenic sulfide. The oxidation state of As in the surface layers of the arsenic sulfide precipitates is ‘realgar-like’ based on XPS results showing that > 75% of the As 3d peak area is due to As with oxidation states between 0 and 2+. Discrete, arsenic sulfide precipitates are absent at pH 9, but elemental mapping in STEM-EDX mode shows that arsenic is uniformly distributed on the FeS_m, suggesting that uptake is caused by the sorption of As(III) oxyanions and/or the precipitation of highly dispersed arsenic sulfides on FeS_m. XPS also revealed that the FeS_m that equilibrated without As(III) has a more oxidized surface composition than the sample at pH 9, as indicated by the higher concentration of O ( three times greater than that at pH 9) and the larger fraction of Fe(III) species making up the total Fe (2p_3/2) peak. These findings provide a better understanding of redox processes and phase transitions upon As(III) adsorption on iron sulfide substrates.  相似文献   

Elemental and isotopic abundances of lithium in chondrule constituents in the Allende meteorite     

Seiji Maruyama  Masaki Watanabe  Tak Kunihiro  Eizo Nakamura 《Geochimica et cosmochimica acta》2009,73(3):778-793

Elemental and isotopic abundances of lithium in chondrule constituents in the Allende CV3 meteorite were determined using secondary ion mass spectrometry. Olivines and mesostasis dominated by a feldspathic phase are depleted in Li ( and , respectively). In contrast, low-Ca pyroxenes and mesostasis dominated by a Na-rich phase are enriched in Li ( and , respectively) and the interchondrule matrix is generally enriched in Li ( on average). The Li isotopic abundance of olivine ranges from to 21. The spatial distributions of elemental and isotopic abundances of Li in olivines within individual chondrules exhibit no systematic pattern. This suggests that the distribution of Li in olivine was not disturbed during aqueous alteration or thermal metamorphism on the Allende meteorite parent body. Although mesostasis is the last crystallizing phase from a chondrule melt and is expected to be enriched in Li, in the Allende meteorite it is generally depleted in Li. We suggest that during aqueous alteration on the CV asteroid, Li in mesostasis was leached out by aqueous fluids. The Li-enriched Na-rich mesostasis was probably produced later by infiltration of Na-rich fluids. It seems likely that aqueous fluids sequestered alkali elements from the Allende-chondrite region in the CV parent asteroid, although significant amounts of Li are preserved in ferrous olivine in the interchondrule matrix.  相似文献   

The relationship among meteorological,agricultural, and in situ news-generated big data on droughts     

Lee  Ji-Wan  Jung  Chung-Gil  Chung  Jee-Hun  Kim  Seong-Joon 《Natural Hazards》2019,98(2):765-781

Natural Hazards - The purpose of this study is to evaluate the effectiveness of agricultural drought risk management using news media data (NMD) by elucidating the relationships among the...  相似文献   

Sediment distribution and depositional processes along the fluvial to marine transition zone of the Mekong River delta,Vietnam     

Marcello Gugliotta  Yoshiki Saito  Van Lap Nguyen  Thi Kim Oanh Ta  Toru Tamura 《Sedimentology》2019,66(1):146-164

The area of coastal rivers with a combination of fluvial, tidal and wave processes is defined as the fluvial to marine transition zone and can extend up to several hundreds of kilometres upstream of the river mouth. The aim of this study is to improve the understanding of sediment distribution and depositional processes along the fluvial to marine transition zone using a comprehensive dataset of channel bed sediment samples collected from the Mekong River delta. Six sediment types were identified and were interpreted to reflect the combined action of fluvial and marine processes. Based on sediment‐type associations, the Mekong fluvial to marine transition zone could be subdivided into an upstream tract and a downstream tract; the boundary between these two tracts is identified 80 to 100 km upstream of the river mouth. The upstream tract is characterized by gravelly sand and sand and occasional heterolithic rhythmites, suggesting bed‐load supply and deposition mainly controlled by fluvial processes with subordinate tidal influence. The downstream tract is characterized by heterolithic rhythmites with subordinate sand and mud, suggesting suspended‐load supply and deposition mainly controlled by tidal processes with subordinate fluvial influence. Sediment distributions during wet and dry seasons suggest significant seasonal changes in sediment dynamic and depositional processes along the fluvial to marine transition zone. The upstream tract shows strong fluvial depositional processes with subordinate tidal influence during the wet season and no deposition with weak fluvial and tidal processes during the dry season. The downstream tract shows strong coexisting fluvial and tidal depositional processes during the wet season and strong tidal depositional processes with negligible fluvial influence during the dry season. Turbidity maxima are present along the downstream tract of the fluvial to marine transition zone during both wet and dry seasons and are driven by a combination of fluvial, tidal and wave processes.  相似文献   

Imaging the Yellow Sea Bottom Cold Water from multichannel seismic data     

Hye-Jin Moon  Han-Joon Kim  Chung-Ho Kim  Seonghoon Moon  Su-hwan Lee  Jin Soo Kim  Chung-Kyun Jeon  Gwang Hoon Lee  Sang Hoon Lee  YoungSook Baek  Hyeong-Tae Jou 《Journal of Oceanography》2017,73(5):701-709

The Yellow Sea Bottom Cold Water (YSBCW) is a large cold water mass lying in the deep part of the Yellow Sea during the warm season. We acquired multichannel seismic (MCS) data using an air gun source to image the structure of the YSBCW. The MCS data recorded reflections from sea water. The recognition of these reflections was confirmed by finite-difference seismic modeling in the frequency-domain. The seismic section from MCS data enabled discrimination of water masses distinctly separated by reflecting horizons. The structure of the water masses is fairly consistent with temperature-depth variations obtained using expandable bathythermograph (XBT) casts. The YSBCW is imaged as the lowermost water mass, maximally 40 m thick, that extends as a lens-like form along the sea bottom under the warm mixed layer. The correlation of XBT measurements and the seismic section indicates a rapid decrease in temperature from around 11 to 8 °C in the uppermost part of the YSBCW. A transition zone between the mixed layer and the underlying YSBCW is also defined. This transition zone has fairly uniform thickness of 14–18 m and marks an interval of rapid temperature drop, indicating vigorous thermal mixing. Our study demonstrates that MCS profiling is a useful and reliable tool for imaging fine structures in the shallow Yellow Sea.  相似文献   

Dissolved iron and zinc in Sagami Bay and the Izu-Ogasawara Trench     

Hajime Obata  Jun Nishioka  Taejin Kim  Kazuhiro Norisuye  Shigenobu Takeda  Yohei Wakuta  Toshitaka Gamo 《Journal of Oceanography》2017,73(3):333-344

Using a clean seawater sampling system for trace metals onboard the R. V. Shinsei-Maru, newly launched in 2013, we investigated the vertical distributions of dissolved iron and zinc in Sagami Bay and the Izu-Ogasawara Trench. We applied appropriate clean sampling and filtering processes for trace metals, so that uncontaminated seawater samples were successfully collected. The distribution of zinc in the trench area was similar to that of silicate and the same as that previously reported in the subtropical North Pacific. There were spatial variations in the iron (Fe) distribution in the trench areas. We used previously reported information about biogeochemical cycling in the trench area, and found that Fe has a residence time of 29 years in the water column. The short residence time of Fe (29 years) corresponds to the vertical variations of dissolved Fe in the water column.  相似文献   

Gap size effect on the tribological characteristics of the roller for deep-sea mining robot     

Jae-Won Oh  Hyung-Woo Kim  Sup Hong  Ki-Young Sung  Dae-Sung Bae 《Marine Georesources & Geotechnology》2017,35(1):120-126

To design the deep-sea mining robot, it is essential to analyze the tribological characteristics of its roller. In this study, we introduced the dynamic simulation model to analyze the tribological characteristics of the roller for deep-sea mining robot, considering the temperature, viscosity, viscous damping force, and gap size between the inner and outer rib seals. Effective viscosity changes with gap size in micro/nanoscale while the effective viscosity is equal to the kinematic viscosity in macroscale. For the stable operation of the roller, the effective viscosity must be less than the critical viscosity. As the gap size decreases, the effective viscosity increases while the critical viscosity decreases. This study shows that the gap size between the inner and outer rib seals of roller is the most dominant factor in designing the roller for deep-sea mining robot to use at relatively low temperatures that are found in the deep-sea environments.  相似文献   

Static pullout resistance of anchor chains in cohesionless soil—laboratory testing     

Byeongwan Kim  Osoon Kwon  BooHyun Nam 《Marine Georesources & Geotechnology》2017,35(6):780-787

This paper investigates the static pullout resistance of anchor chains embedded into cohesionless soil. The anchor chains, which are made of steel, were buried into Jumunjin sand whose relative density was set to approximately 60%. The anchor chains were horizontally pulled out through a displacement of 70?mm in laboratory model tests. Three different embedment depths and seven different numbers of chain links were adopted. The pullout resistance of the anchor chains was found to increase with increasing embedment depth and the number of anchor chain links. The measured resistance was significantly higher than the calculated frictional resistance, implying that the passive resistance at the front of the anchor chain significantly contributes to the pullout resistance. The contribution of the passive resistance tends to decrease with increasing number of chain links.  相似文献   

Impact of estuary barrage construction on fish assemblages in the lower part of a river and the role of fishways as a passage     

Ju-Duk Yoon  Jeong-Hui Kim  Sang-Hyeon Park  Eve Kim  Min-Ho Jang 《Ocean Science Journal》2017,52(1):147-164

The construction of an estuary barrage, an instream structure in the lower reaches of a river, causes significant physical changes in water flow patterns and river morphology, and results in altered environmental conditions. Here, we examined the impact of the Geum River estuary barrage, completed in 1990, on fish assemblages by using a literature search and fresh surveys of fishways in the barrage. We found that fish assemblages upstream and downstream of the barrage were altered following its completion. After construction, more species were found in the freshwater area, with a particularly great increase in freshwater species. Conversely, estuarine and marine species were only consistently caught in the downstream salt-water area, although the number of species increased. In total, 15,829 fish from 47 species and 20 families were identified at the three types (pool and weir, rubble type, and boat passage) of fishways in the barrage. The dominant species were Chelon haematocheilus, an estuarine species, Coilia nasus, a diadromous species, and Erythroculter erythropterus, a freshwater species. The mean total length of fish (101.9 ± 76.0 mm) in the boat passage fishway was approximately 100 mm lesser than those in the pool and weir (207.2 ± 112.8 mm) and rubble type (205.8 ± 112.7 mm) fishways. The boat passage fishway was the most efficient for fish movements. The current fishway system is not sufficient for fish migration, and thus additional ways are required to improve the system such as the boat passage. Few estuarine or diadromous species were found in both freshwater and salt-water areas, but freshwater fishes that accidently moved to salt-water area actively used fishways. Therefore, fishway management in the Geum River estuary barrage has to focus on freshwater fish; however, this may need to change to a focus on migratory fishes depending on ecological life cycles of migratory fish.  相似文献   

Growth and reproduction of the Japanese mantis shrimp, <Emphasis Type="Italic">Oratosquilla oratoria</Emphasis> (De Haan 1844) in the coastal area of Tongyeong,Korea     

SeongEun Kim  HanJu Kim  HoJin Bae  Hyeong-Gi Kim  Chul-Woong Oh 《Ocean Science Journal》2017,52(2):257-265

Growth and reproduction of the Japanese mantis shrimp, Oratosquilla oratoria, were investigated in the Tongyeong, Korea from July 2014 to August 2015. A total of 2,621 samples (1,380 females and 1,241 males) were collected during the study period. Females were observed more frequently than males. The mean body length (BL) was 128.5 ± 0.38 mm in females and 126.9 ± 0.42 mm in males. The mean body weight (BW) was 31.2 ± 0.28 g in females and 31.1 ± 0.32 g in males. There was a significant difference in the length-frequency distribution between females and males. The relationship between BL and BW was lnBW = 2.85 × lnBL - 10.43 for females and lnBW = 2.87 × lnBL -10.52 for males. The gonadosomatic index (GSI) varied on a monthly basis. The GSI reached a maximum in May and a minimum in November. The highest values of the GSI coincided with the spawning period of O. oratoria. Larger individuals of O. oratoria have their spawning season earlier than smaller ones. The size at sexual maturity of females was estimated as 96.5 mm. The Von Bertalanffy growth function parameters were BL_∞ = 184.5 mm, K = 0.72 year^?1, C = 0.36 and WP = 0.45 for females and BL_∞ = 183.75 mm, K = 0.82 year^?1, C = 0.38 and WP = 0.22 for males. The growth of males was slightly faster than females. The present study will help with the fisheries management of O. oratoria based on ecological parameters.  相似文献