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71.
The “North American shale composite”: Its compilation,major and trace element characteristics 总被引:6,自引:0,他引:6
L.Peter Gromet Larry A. Haskin Randy L. Korotev Robert F. Dymek 《Geochimica et cosmochimica acta》1984,48(12):2469-2482
The compilation and major element composition of the “North American shale composite” (NASC) are reported for the first time, along with redeterminations for the REE and selected other elements by modern, high precision analytical methods. The NASC is not strictly of North American origin; 5 of the constituent samples are from Africa and Antarctica, and 15 are from unspecified locations. The major element composition of the NASC compares quite closely with other average shale compositions. New analyses of the NASC document that significant portions of the REE and some other trace elements are contained in minor phases (zircon and possibly other minerals) and that their uneven distribution in the NASC powder appears to have resulted in heterogeneity among analyzed aliquants. The results of this study show that the REE distributions of detrital sediments can be dependent to some extent on their minor mineral assemblages and the sedimentological factors that control these assemblages. Consequently, caution should be exercised in the interpretation of the REE distributions of sediment samples as they may be variable and biased relative to average REE distribution of the crustal rocks supplying detritus. These effects appear to be largely averaged out in sediment composites, with the result that their REE distributions are more likely to be representative of their provenances. 相似文献
72.
Micro computers have been demonstrated to be a most valuable, cost-effective means of long- and short-term data acquisition for ground water investigations and installations. A system can readily be assembled for the cost of labor saved in the field, or for the same cost as other conventional instruments, which perform only a fraction of the functions of the computer system
Documented in this article are systems which have been developed and used for simultaneous monitoring of several wells during aquifer tests, and systems installed for long-term monitoring of piezometric surface fluctuations. Both systems can be contained in a small suitcase or insulated cooler. Specific features of the systems include multiple channel capacity, one-month maintenance period, variable computer controlled reading intervals, magnetic tape data storage, data reduction and analysis capabilities while maintaining monitoring, graphic display of time and measurements, hard copy capability and barometric pressure change corrections.
Other applications are examined for the complete control of pumping tests, including pumping rate; in situ permeability tests; monitoring changes; and even strain. The pressure transducer system may also be applied for river gauging and current measurement. 相似文献
Documented in this article are systems which have been developed and used for simultaneous monitoring of several wells during aquifer tests, and systems installed for long-term monitoring of piezometric surface fluctuations. Both systems can be contained in a small suitcase or insulated cooler. Specific features of the systems include multiple channel capacity, one-month maintenance period, variable computer controlled reading intervals, magnetic tape data storage, data reduction and analysis capabilities while maintaining monitoring, graphic display of time and measurements, hard copy capability and barometric pressure change corrections.
Other applications are examined for the complete control of pumping tests, including pumping rate; in situ permeability tests; monitoring changes; and even strain. The pressure transducer system may also be applied for river gauging and current measurement. 相似文献
73.
Larry W. Finger Robert M. Hazen Anne M. Hofmeister 《Physics and Chemistry of Minerals》1986,13(4):215-220
High-pressure crystal structures and compressibilities have been determined by x-ray methods for MgAl2O4 spinel and its isomorph magnetite, Fe3O4. The measured bulk moduli, K, of spinel and magnetite (assuming K′=4) are 1.94±0.06 and 1.86±0.05 Mbar, respectively, in accord with previous ultrasonic determinations. The oxygen u parameter, the only variable atomic position coordinate in the spinel structure (Fd3m, Z=8), decreases with pressure in MgAl2O4, thus indicating that the magnesium tetrahedron is more compressible than the aluminum octahedron. In magnetite the u parameter is unchanged, and both tetrahedron and octahedron display the 1.9 Mbar bulk modulus characteristic of the entire crystal. This behavior contrasts with that of nickel silicate spinel (γ-Ni2SiO4), in which the u parameter increases with pressure because the silicon tetrahedron is relatively incompressible compared to the nickel octahedron. 相似文献
74.
The temporal and spatial distributions of salinity, dissolved oxygen, suspended particulate material (SPM), and dissolved nutrients were determined during 1983 in the Choptank River, an estuarine tributary of Chesapeake Bay. During winter and spring freshets, the middle estuary was strongly stratified with changes in salinity of up to 5‰ occurring over 1 m depth intervals. Periodically, the lower estuary was stratified due to the intrusion of higher salinity water from the main channel of Chesapeake Bay. During summer this intrusion caused minimum oxygen and maximum NH4 + concentrations at the mouth of the Choptank River estuary. Highest concentrations of SPM, particulate carbon (PC), particulate nitrogen (PN), total nitrogen (TN), total phosphorous (TP) and dissolved inorganic nitrogen (DIN) occurred in the upper estuary during the early spring freshet. In contrast, minimum soluble reactive phosphate (SRP) concentrations were highest in the upper estuary in summer when freshwater discharge was low. In spring, PC:PN ratios were >13, indicating a strong influence by allochthonous plant detritus on PC and PN concentrations. However, high concentrations of PC and PN in fall coincided with maximum chlorophyll a concentrations and PC:PN ratios were <8, indicating in situ productivity controlled PC and PN levels. During late spring and summer, DIN concentrations decreased from >100 to <10 μg-at l?1, resulting mainly from the nonconservative behavior of NO3 ?, which dominated the DIN pool. Atomic ratios of both the inorganic and total forms of N and P exceeded 100 in spring, but by summer, ratios decreased to <5 and <15, respectively. The seasonal and spatial changes in both absolute concentrations and ratios of N and P reflect the strong influence of allochthonous inputs on nutrient distributions in spring, followed by the effects of internal processes in summer and fall. 相似文献
76.
Krystyna W. Semkow Ronald A. Rizzo Larry A. Haskin David J. Lindstrom 《Geochimica et cosmochimica acta》1982,46(10):1879-1889
Cyclic voltammetry has been done for Ni2+, Co2+, and Zn2+ in melts of diopside composition in the temperature range 1425 to 1575°C. Voltammetric curves for all three ions excellently match theoretical curves for uncomplicated, reversible charge transfer at the Pt electrode. This implies that the neutral metal atoms remain dissolved in the melt. The reference electrode is a form of oxygen electrode. Relative to that reference assigned a reduction potential of 0.00 volt, the values of standard reduction potential for the ions are , , and . The electrode reactions are rapid, with first order rate constants of the order of 10?2 cm/sec. Diffusion coefficients were found to be 2.6 × 10?6 cm2/sec for Ni2+, 3.4 × 10?6 cm2/sec for Co2+, and 3.8 × 10?6 cm2/sec for Zn2+ at 1500°C. The value of (, diopside) is a linear function of temperature over the range studied, with values of ?0.35 V at 1425°C and ?0.29 V at 1575°C. At constant temperature the value of ) was not observed to vary with composition over the range CaO · MgO · 2SiO2 to CaO·MgO·3SiO2 or from 1.67 CaO·0.33MgO·2SiO2 to 0.5 CaO·1.5MgO·2SiO2. The value for the diffusion coefficient for Ni2+ decreased by an order of magnitude at 1525°C over the compositional range CaO · MgO · 1.25SiO2 to CaO · MgO · 3SiO2. This is consistent with a mechanism by which Ni2+ ions diffuse by moving from one octahedral coordination site to another in the melt, with the same Ni2+ species discharging at the cathode regardless of the SiO2 concentration in the melt. 相似文献
77.
Seismic coupling and uncoupling at subduction zones 总被引:1,自引:0,他引:1
Seismic coupling has been used as a qualitative measure of the “interaction” between the two plates at subduction zones. Kanamori (1971) introduced seismic coupling after noting that the characteristic size of earthquakes varies systematically for the northern Pacific subduction zones. A quantitative global comparison of many subduction zones reveals a strong correlation of earthquake size with two other variables: age of the subducting lithosphere and convergence rate. The largest earthquakes occur in zones with young lithosphere and fast convergence rates, while zones with old lithosphere and slow rates are relatively aseismic for large earthquakes. Results from a study of the rupture process of three great earthquakes indicate that maximum earthquake size is directly related to the asperity distribution on the fault plane (asperities are strong regions that resist the motion between the two plates). The zones with the largest earthquakes have very large asperities, while the zones with smaller earthquakes have small scattered asperities. This observation can be translated into a simple model of seismic coupling, where the horizontal compressive stress between the two plates is proportional to the ratio of the summed asperity area to the total area of the contact surface. While the variation in asperity size is used to establish a connection between earthquake size and tectonic stress, it also implies that plate age and rate affect the asperity distribution. Plate age and rate can control asperity distribution directly by use of the horizontal compressive stress associated with the “preferred trajectory” (i.e. the vertical and horizontal velocities of subducting slabs are determined by the plate age and convergence velocity). Indirect influences are many, including oceanic plate topography and the amount of subducted sediments.All subduction zones are apparently uncoupled below a depth of about 40 km, and we propose that the basalt to eclogite phase change in the down-going oceanic crust may be largely responsible. This phase change should start at a depth of 30–35 km, and could at least partially uncouple the plates by superplastic deformation throughout the oceanic crust during the phase change. 相似文献
78.
79.
Issues pertaining to a mechanism whereby long internal waves in shallow seas may give rise to enhanced rates of resuspension of sedimentary material are addressed. The proposed mechanism is intimately related to the creation of conditions in the bottom boundary layer which are favorable for flow separation and spontaneous onset of global instability. It is shown that long waves generated by topographic resonance and propagating upstream against the oncoming current, especially a sheared current, have a strong tendency to release a coherent, pulsating dynamics in their footprint. The passage-through-resonance problem for a sheared, stratified flow is considered, conditions for topographic resonance in the flow model are defined, and preliminary results for the unsteady dynamics in the boundary layer under the footprint of a long wave packet are presented. 相似文献
80.