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61.
Abstract— Transmission electron microscopic (TEM) and electron energy‐loss spectroscopic (EELS) study of the Ivuna and Orgueil (CI), and Tagish Lake (C2 ungrouped) carbonaceous chondrite meteorites shows two types of C‐clay assemblages. The first is coarser‐grained (to 1 μm) clay flakes that show an intense O K edge from the silicate together with a prominent C K edge, but without discrete C particles. Nitrogen is common in some clay flakes. Individual Orgueil and Tagish Lake meteorite clay flakes contain up to 6 and 8 at% C, respectively. The C K‐edge spectra from the clays show fine structure revealing aromatic, aliphatic, carboxylic, and carbonate C. The EELS data shows that this C is intercalated with the clay flakes. The second C‐clay association occurs as poorly crystalline to amorphous material occurring as nanometer aggregates of C, clay, and Fe‐O‐rich material. Some aggregates are dominated by carbonaceous particles that are structurally and chemically similar to the acid insoluble organic matter. The C K‐edge shape from this C resembles that of amorphous C, but lacking the distinct peaks corresponding to aliphatic, carboxylic, and carbonate C groups. Nanodiamonds are locally abundant in some carbonaceous particles. The abundance of C in the clays suggest that molecular speciation in the carbonaceous chondrites is partly determined by the effects of aqueous processing on the meteorite parent bodies, and that clays played an important role. This intricate C‐clay association lends credence to the proposal that minerals were important in the prebiotic chemical evolution of the early solar system.  相似文献   
62.
The wavelet transform (WT) is now recognized as a useful, flexible, and efficient technique to analyze intermittent, non-stationary and inhomogeneous signals as well as images which are obtained from experimental or in situ measurements. In this study, the two-dimensional continuous wavelet transform (2-D CWT) was introduced to analyze the spatial image of waves. The numerical algorithm of 2-D CWT was developed and testified in simulated wave field of regular and random waves. Some more simulated wave fields of various wave conditions and sea bed slopes were then assumed to verify the analytical accuracy of this new technique. The comparisons of estimations to theoretical values for several wave parameters show that the 2-D CWT is capable of identifying the directional spectra and wave properties in shallow water.  相似文献   
63.
The phase relationship between climate parameters during terminations gives insight into deglaciation mechanisms. By combining foraminiferal Mg/Ca and alkenone thermometers with planktonic and benthic foraminiferal δ18O, we determined the phase relationship between local sea surface temperature (SST) and global seawater δ18O changes in the Coral Sea in the Southwestern Pacific over the last 360 ka. The onset of the SST warming preceded the seawater δ18O change by several ka for Termination I, II and III. During Termination I, the SST warming started at 20 ka BP, earlier than atmospheric CO2 rise suggesting that the greenhouse effect was not the main trigger of this early warming. Compilation of 14C-dated SST records from the whole Pacific during Termination I reveals that the onset of the warming is generally earlier in the Southern and the tropical Pacific than in the North Pacific. This spatio-temporal warming pattern suggests linkage between the southern ocean and tropical Pacific. The early tropical warming could provide heat and moisture to the northern high latitudes, modifying radiative balance and precipitation over ice sheets at the onset of deglaciation.  相似文献   
64.
Using crowdsourcing techniques, the US Geological Survey’s (USGS) Volunteered Geographic Information (VGI) project known as “The National Map Corps (TNMCorps)” encourages citizen scientists to collect and edit data about man-made structures in an effort to provide accurate and authoritative map data for the USGS National Geospatial Program’s web-based The National Map. VGI is not new to the USGS, but past efforts have been hampered by available technologies. Building on lessons learned, TNMCorps volunteers are successfully editing 10 different structure types in all 50 states as well as Puerto Rico and the US Virgin Islands.  相似文献   
65.
Joint Cassini VIMS and RADAR SAR data of ∼700-km-wide Hotei Regio reveal a rich collection of geological features that correlate between the two sets of images. The degree of correlation is greater than anywhere else seen on Titan. Central to Hotei Regio is a basin filled with cryovolcanic flows that are anomalously bright in VIMS data (in particular at 5 μm) and quite variable in roughness in SAR. The edges of the flows are dark in SAR data and appear to overrun a VIMS-bright substrate. SAR-stereo topography shows the flows to be viscous, 100-200 m thick. On its southern edge the basin is ringed by higher (∼1 km) mountainous terrain. The mountains show mixed texture in SAR data: some regions are extremely rough, exhibit low and spectrally neutral albedo in VIMS data and may be partly coated with darker hydrocarbons. Around the southern margin of Hotei Regio, the SAR image shows several large, dendritic, radar-bright channels that flow down from the mountainous terrain and terminate in dark blue patches, seen in VIMS images, whose infrared color is consistent with enrichment in water ice. The patches are in depressions that we interpret to be filled with fluvial deposits eroded and transported by liquid methane in the channels. In the VIMS images the dark blue patches are encased in a latticework of lighter bands that we suggest to demark a set of circumferential and radial fault systems bounding structural depressions. Conceivably the circular features are tectonic structures that are remnant from an ancient impact structure. We suggest that impact-generated structures may have simply served as zones of weakness; no direct causal connection, such as impact-induced volcanism, is implied. We also speculate that two large dark features lying on the northern margin of Hotei Regio could be calderas. In summary the preservation of such a broad suite of VIMS infrared color variations and the detailed correlation with features in the SAR image and SAR topography evidence a complex set of geological processes (pluvial, fluvial, tectonic, cryovolcanic, impact) that have likely remained active up to very recent geological time (<104 year). That the cryovolcanic flows are excessively bright in the infrared, particularly at 5 μm, might signal ongoing geological activity. One study [Nelson, R.M., and 28 colleagues, 2009. Icarus 199, 429-441] reported significant 2-μm albedo changes in VIMS data for Hotei Arcus acquired between 2004 and 2006, that were interpreted as evidence for such activity. However in our review of that work, we do not agree that such evidence has yet been found.  相似文献   
66.
We have studied the chemical zoning of plagioclase phenocrysts from the slow-spreading Mid-Atlantic Ridge and the intermediate-spreading rate Costa Rica Rift to obtain the time scales of magmatic processes beneath these ridges. The anorthite content, Mg, and Sr in plagioclase phenocrysts from the Mid-Atlantic Ridge can be interpreted as recording initial crystallisation from a primitive magma (~11 wt% MgO) in an open system. This was followed by crystal accumulation in a mush zone and later entrainment of crystals into the erupted magma. The initial magma crystallised plagioclase more anorthitic than those in equilibrium with any erupted basalt. Evidence that the crystals accumulated in a mush zone comes from both: (1) plagioclase rims that were in equilibrium with a Sr-poor melt requiring extreme differentiation; and (2) different crystals found in the same thin section having different histories. Diffusion modelling shows that crystal residence times in the mush were <140 years, whereas the interval between mush disaggregation and eruption was ≤1.5 years. Zoning of anorthite content and Mg in plagioclase phenocrysts from the Costa Rica Rift show that they partially or completely equilibrated with a MgO-rich melt (>11 wt%). Partial equilibration in some crystals can be modelled as starting <1 year prior to eruption but for others longer times are required for complete equilibration. This variety of times is most readily explained if the mixing occurred in a mush zone. None of the plagioclase phenocrysts from the Costa Rica Rift that we studied have Mg contents in equilibrium with their host basalt even at their rims, requiring mixing into a much more evolved magma within days of eruption. In combination these observations suggest that at both intermediate- and slow-spreading ridges: (1) the chemical environment to which crystals are exposed changes on annual to decadal time scales; (2) plagioclase crystals record the existence of melts unlike those erupted; and (3) disaggregation of crystal mush zones appears to precede eruption, providing an efficient mechanism by which evolved interstitial melt can be mixed into erupted basalts.  相似文献   
67.
Io’s sublimation-driven atmosphere is modeled using the direct simulation Monte Carlo (DSMC) method. These rarefied gas dynamics simulations improve upon earlier models by using a three-dimensional domain encompassing the entire planet computed in parallel. The effects of plasma heating, planetary rotation, inhomogeneous surface frost, molecular residence time of SO2 on the exposed (non-volatile) rocky surface, and surface temperature distribution are investigated. Circumplanetary flow is predicted to develop from the warm dayside toward the cooler nightside. Io’s rotation leads to a highly asymmetric frost surface temperature distribution (due to the frost’s high thermal inertia) which results in circumplanetary flow that is not axi-symmetric about the subsolar point. The non-equilibrium thermal structure of the atmosphere, specifically vibrational and rotational temperatures, is also examined. Plasma heating is found to significantly inflate the atmosphere on both the dayside and nightside. The plasma energy flux causes high temperatures at high altitudes but plasma energy depletion through the dense gas column above the warmest frost permits gas temperatures cooler than the surface at low altitudes. A frost map (Douté, S., Schmitt, B., Lopes-Gautier, R., Carlson, R., Soderblom, L., Shirley, J., and the Galileo NIMS Team [2001]. Icarus 149, 107-132) is used to control the sublimated flux of SO2 which can result in inhomogeneous column densities that vary by nearly a factor of four for the same surface temperature. A short residence time for SO2 molecules on the “rock” component is found to smooth lateral atmospheric inhomogeneities caused by variations in the surface frost distribution, creating an atmosphere that looks nearly identical to one with uniform frost coverage. A longer residence time is found to agree better with mid-infrared observations (Spencer, J.R., Lellouch, E., Richter, M.J., López-Valverde, M.A., Jessup, K.L, Greathouse, T.K., Flaud, J. [2005]. Icarus 176, 283-304) and reproduce the observed anti-jovian/sub-jovian column density asymmetry. The computed peak dayside column density for Io assuming a surface frost temperature of 115 K agrees with those suggested by Lyman-α observations (Feaga, L.M., McGrath, M., Feldman, P.D. [2009]. Icarus 201, 570-584). On the other hand, the peak dayside column density at 120 K is a factor of five larger and is higher than the upper range of observations (Jessup, K.L., Spencer, J.R., Ballester, G.E., Howell, R.R., Roesler, F., Vigel, M., Yelle, R. [2004]. Icarus 169, 197-215; Spencer et al., 2005).  相似文献   
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70.
Remains of scaled chrysophytes, magnetic minerals and pollen were used to analyze the recent paleolimnological history of a small lake, Lake Waynewood, in the Pocono Mountains of Pennsylvania. Important shifts in all three variables were observed over the 133 years represented by the core. The most significant changes occurred near the turn of the century when the watershed was heavily logged. Before the logging event, species such asSynura sphagnicola, S. spinosa, Mallomonas galeiformis andM. duerrschmidtiae were co-dominant members of the flora. Subsequent to the deforestation of the watershed other taxa, includingM. crassisquama, M. caudata andS. petersenii, increased in relative importance. Concurrent with changes in the scaled chrysophytes was a six-fold increase in the concentrations of magnetic material, presumably the result of increased erosion caused by the logging. Changes in pollen grains also correlate well with the onset of the deforestation event. The scaled chrysophyte inferred specific conductivity of the lake has more than tripled, with the primary increase occurring concurrent with the commencement of logging and the increase in magnetic mineral material. The effects of other human-related disturbances are also discussed.  相似文献   
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