Can stable isotopes be used to monitor landfill leachate impact on surface waters?     

Jessica C. North  Russell D. Frew  Robert Van Hale 《Journal of Geochemical Exploration》2006,88(1-3):49

Bacterially mediated methanogenesis in municipal solid waste landfills has been shown to cause an enrichment of carbon stable isotope ratios of dissolved inorganic carbon and hydrogen stable isotope ratios of water in landfill leachate. In the present study, we investigate the universality of this enrichment in leachate obtained from four diverse landfill sites in New Zealand. At each site, surface water samples upstream and downstream of landfills were analysed to examine the applicability of stable isotope ratios as a tool for monitoring leachate contamination in landfill-associated streams. The design of leachate collection systems, operational history, and landfill location appeared to strongly influence leachate isotopic values and the effectiveness of isotope ratios as an environmental monitoring tool for surface water.  相似文献   

Modification of streaming potential by precipitation of calcite in a sand–water system: laboratory measurements in the pH range from 4 to 12     

Xavier Guichet  Laurence Jouniaux  Nicole Catel 《Geophysical Journal International》2006,166(1):445-460

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Spatial process and data models: Toward integration of agent-based models and GIS   总被引：8，自引：1，他引：8  

Daniel G. Brown  Rick Riolo  Derek T. Robinson  Michael North  William Rand 《Journal of Geographical Systems》2005,7(1):25-47

The use of object-orientation for both spatial data and spatial process models facilitates their integration, which can allow exploration and explanation of spatial-temporal phenomena. In order to better understand how tight coupling might proceed and to evaluate the possible functional and efficiency gains from such a tight coupling, we identify four key relationships affecting how geographic data (fields and objects) and agent-based process models can interact: identity, causal, temporal and topological. We discuss approaches to implementing tight integration, focusing on a middleware approach that links existing GIS and ABM development platforms, and illustrate the need and approaches with example agent-based models.  相似文献   

Editorial     

Raymond Michels  Laurence Mansuy  Marcel Elie  Pierre Faure  Vincent Huault  Luis Martinez  Jacques Pironon 《Organic Geochemistry》2002,33(12)

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Recent temperature and precipitation increases in West Siberia and their association with the Arctic Oscillation     

Karen E. Frey  Laurence C. Smith 《Polar research》2003,22(2):287-300

Surface air temperature and precipitation records for the years 1958-1999 from ten meteorological stations located throughout West Siberia are used to identify climatic trends and determine to what extent these trends are potentially attributable to the Arctic Oscillation (AO). Although recent changes in atmospheric variability are associated with broad Arctic climate change, West Siberia appears particularly susceptible to warming. Furthermore, unlike most of the Arctic, moisture transport in the region is highly variable. The records show that West Siberia is experiencing significant warming and notable increases in precipitation, likely driven, in part, by large-scale Arctic atmospheric variability. Because this region contains a large percentage of the world's peatlands and contributes a significant portion of the total terrestrial freshwater flux to the Arctic Ocean, these recent climatic trends may have globally significant repercussions. The most robust patterns found are strong and prevalent springtime warming, winter precipitation increases, and strong association of non-summer air temperatures with the AO. Warming rates for both spring (0.5-0.8 °C/decade) and annual (0.3-0.5°C/decade) records are statistically significant for nine often stations. On average, the AO is linearly congruent with 96% (winter), 19% (spring), 0% (summer), 67% (autumn) and 53% (annual) of the warming found in this study. Significant trends in precipitation occur most commonly during winter, when four of ten stations exhibit significant increases (4-13 %/decade). The AO may play a lesser role in precipitation variability and is linearly congruent with only 17% (winter), 13% (spring), 12% (summer), 1% (autumn) and 26% (annual) of precipitation trends.  相似文献   

河南濮阳西水坡新石器时代遗址瓣鳃类动物群的生态环境分析   总被引：1，自引：0，他引：1       下载免费PDF全文

郭书元  孙长虹 《古地理学报》2003,5(4):450-460

河南濮阳西水坡新石器时代遗址出土的瓣鳃类共有33种，其中31种组成了Lamprotula-Cuneopsis-Unio组合，称为西水坡丽蚌动物群，其时代为中全新世早期。据贝壳14C测年资料（6 465±45 a BP）和同层出土的陶器特征， 为仰韶文化早期（7 000～6 000 a BP）。该动物群与长江中,下游流域洞庭湖、鄱阳湖和太湖及其周围水域的现代丽蚌动物群组合特征非常接近，同属东洋界、中印亚界动物地理区， 亚热带湿热气候。根据该动物群反映的生态环境，仰韶文化早期该地区的古环境地处亚热带，气候湿热，雨量充沛，草木茂盛，河流成网，湖泊遍野，水质优良，水生生物丰富，优越的自然环境为先民提供了从事农耕、渔猎的生栖条件。  相似文献   

Preliminary data on chemical changes in the Aral Sea during low-level periods from the last 9000 years     

Laurence Le Callonnec  Alain Person  Maurice Renard  René Létolle  Nathalie Nebout  Leila Ben Khelifa  Ivan Rubanov 《Comptes Rendus Geoscience》2005,337(12):1035-1044

The withdrawal of the Aral Sea tributaries (Amu and Syr Daria) for cultures has led to significant falls of its level and an important increase in its salinity. During the Holocene, a succession of low and high water inputs occurred. Silty deposits correspond to the high levels and carbonates to the low levels. This study makes a distinction between the Syr Daria and the Amu Daria water inputs during low-level periods by using mineralogical and chemical compositions of the carbonates deposits. Waters from the Syr Daria are more sulphatic and have a low iron content in comparison with that of the Amu Daria. The Syr Daria was the major tributary around 7500, 4956 and 970 yr?BP, whereas around 6200 and 3610 yr?BP, inflow also from the Amu Daria is observed. To cite this article: L. Le Callonnec et al., C. R. Geoscience 337 (2005).  相似文献   

Isotopic compositions of oxygen, iron, chromium, and nickel in cosmic spherules: Toward a better comprehension of atmospheric entry heating effects     

Cécile Engrand  Kevin D. McKeegan  Gregory F. Herzog  Laurence E. Nyquist 《Geochimica et cosmochimica acta》2005,69(22):5365-5385

Large, correlated, mass-dependent enrichments in the heavier isotopes of O, Cr, Fe, and Ni are observed in type-I (metal/metal oxide) cosmic spherules collected from the deep sea. Limited intraparticle variability of oxygen isotope abundances, typically <5‰ in δ¹⁸O, indicates good mixing of the melts and supports the application of the Rayleigh equation for the calculation of fractional evaporative losses during atmospheric entry. Fractional losses for oxygen evaporation from wüstite, assuming a starting isotopic composition equal to that of air (δ¹⁸O = 23.5‰; δ¹⁷O = 11.8‰), are in the range 55%-77%, and are systematically smaller than evaporative losses calculated for Fe (69%-85%), Cr (81%-95%), and especially Ni (45%-99%). However, as δ¹⁸O values increase, fractional losses for oxygen approach those of Fe, Cr, and Ni indicating a shift in the evaporating species from metallic to oxidized forms as the spherules are progressively oxidized during entry heating. The observed unequal fractional losses of O and Fe can be reconciled by allowing for a kinetic isotope mass-dependent fractionation of atmospheric oxygen during the oxidation process and/or that some metallic Fe may have undergone Rayleigh evaporation before oxidation began.In situ measurements of oxygen isotopic abundances were also performed in 14 type-S (silicate) cosmic spherules, 13 from the Antarctic ice and one from the deep sea. Additional bulk Fe and Cr isotopic abundances were determined for two type-S deep-sea spherules. The isotopic fractionation of Cr isotopes suggest appreciable evaporative loss of Cr, perhaps as a sulfide. The oxygen isotopic compositions for the type-S spherules range from δ¹⁸O = −2‰ to + 27‰. The intraspherule isotopic variations are typically small, ∼5% relative, except for the less-heated porphyritic spherules which have preserved large isotopic heterogeneities in at least one case. A plot of δ¹⁷O vs. δ¹⁸O values for these spherules defines a broad parallelogram bounded at higher values of δ¹⁷O by the terrestrial fractionation line, and at lower values of δ¹⁷O by a line parallel to it and anchored near the isotopic composition of δ¹⁸O = −2.5‰ and δ¹⁷O = −5‰. Lack of independent evidence for substantial evaporative losses suggests that much of this variation reflects the starting isotopic composition of the precursor materials, which likely resembled CO, CM, or CI chondrites. However, the enrichments in heavy isotopes indicate that some mixing with atmospheric oxygen was probably involved during atmospheric entry for some of the spherules. Isotopic fractionation due to evaporation of incoming grain is not required to explain most of the oxygen isotopic data for type-S spherules. However spherules with barred olivine textures that are thought to have experienced a more intense heating than the porphyritic ones might have undergone some distillation. Two cosmic spherules, one classified as a radial pyroxene type and the other showing a glassy texture, show unfractionated oxygen isotopic abundances. They are probably chondrule fragments that survived atmospheric entry unmelted.Possible reasons type-I spherules show larger degrees of isotopic fractionation than type-S spherules include: a) the short duration of the heating pulse associated with the high volatile content of the type-S spherule precursors compared to type-I spherules; b) higher evaporation temperatures for at least a refractory portion of the silicates compared to that of iron metal or oxide; c) lower duration of heating of type-S spherules compared to type-I spherules as a consequence of their lower densities.  相似文献   

Environmental changes over the past 25 000 years in the southern Middle Atlas,Morocco          下载免费PDF全文

Jalal Tabel  Carla Khater  Ali Rhoujjati  Laurent Dezileau  Ilham Bouimetarhan  Matthieu Carre  Laurence Vidal  Abdelfattah Benkaddour  Majda Nourelbait  Rachid Cheddadi 《第四纪科学杂志》2016,31(2):93-102

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Quantifying flows along hydrological pathways by applying a new filtering algorithm in conjunction with master recession curve analysis          下载免费PDF全文

Ronan J. O'Brien  Bruce D. Misstear  Laurence W. Gill  Paul M. Johnston  Raymond Flynn 《水文研究》2014,28(26):6211-6221

Quantifying the proportion of the river hydrograph derived from the different hydrological pathways is essential for understanding the behaviour of a catchment. This paper describes a new approach using the output from master recession curve analysis to inform a new algorithm based on the Lyne and Hollick ‘one‐parameter’ signal analysis filtering algorithm. This approach was applied to six catchments (including two subcatchments of these) in Ireland. The conceptual model for each catchment consists of four main flow pathways: overland flow, interflow, shallow groundwater and deep groundwater. The results were compared with those of the master recession curve analysis, a recharge coefficient approach developed in Ireland and the semi‐distributed, lumped and deterministic hydrological model Nedbør‐Afstrømings‐Model. The new algorithm removes the ‘free variable’ aspect that is typically associated with filtering algorithms and provides a means of estimating the contribution of each pathway that is consistent with the results of hydrograph separation in catchments that are dominated by quick response pathways. These types of catchments are underlain by poorly productive aquifers that are not capable of providing large baseflows in the river. Such aquifers underlie over 73% of Ireland, ensuring that this new algorithm is applicable in the majority of catchments in Ireland and potentially in those catchments internationally that are strongly influenced by the quick‐responding hydrological pathways. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献