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11.
Ratio measurements are commonly used to address a variety of analytical problems in environmental,forensic and pharmaceutical laboratories.In absorbance ratioing techniques,analytical chemists rely onthe spectral features of the analyte(s)of interest.The absorbances at two wavelengths are monitored andthe ratio of these two absorbances is computed.This ratio is then used to confirm the identity of theanalyte(s)of interest,the purity of a product or the overlap of chromatographic peaks.These decisionsoften have far-reaching consequences(e.g.the identification of the source,biogenic or petrogenic,ofhydrocarbons in biological tissues or water).Given the cost and the liabilities associated with suchdecisions,it is unfortunate that these ratios are seldom reported with any statistical confidence.Thepurpose of this study is to delineate the parameters that affect absorbance ratio measurements.Themodels that can be used to estimate the statistical confidence in these measurements are derived andevaluated experimentally.The results show that these models can estimate the relative standard deviationsin absorbance ratios accurately.They can also estimate the effect of signal-to-noise ratio and the choiceof wavelengths on the precision of absorbance ratios.  相似文献   
12.
Jellyfish blooms in pelagic systems appear to be increasing on a global scale because of anthropogenic impacts, but much less is known about the link between human activities and epibenthic jellyfish abundance. The aim of this study was to investigate whether the epibenthic jellyfish, Cassiopea spp., were found in greater abundance, and attained larger sizes, in coastal habitats adjacent to high human population densities compared to sites adjacent to uninhabited areas on Abaco Island, Bahamas. Cassiopea spp. were found to be significantly more dense and larger in areas with high human population densities. Ambient nutrient levels and nutrient content of seagrass were elevated in high human population density sites, and may be one mechanism driving higher abundance and size of Cassiopea spp. Cassiopea spp. may have important effects on community structure and ecosystem function in critical coastal ecosystems (e.g., seagrass beds), and their impacts warrant further study.  相似文献   
13.
秦岭洛南-栾川断裂带具有左旋斜向俯冲的运动学特征,其产状一般为107°/N∠65°。华南板块的俯冲方向为80°,俯冲角度为42°;华南板块运动方向为42°,运动方向与华北板块南部边界的夹角为65°,汇聚角25°。秦岭北缘强变形带内褶皱枢纽延伸方向为290°,与洛南-栾川断裂带存在15°的夹角。逆冲断层走向与褶皱的枢纽方向基本一致,大多数断层与洛南-栾川断裂带有相同的运动学极性,性质为左行平移逆断层。平移正断层走向主要为NE SW,断层性质、展布方向、运动学特征与板块汇聚的应力作用方式吻合;片理、片麻理走向117°,与洛南-栾川断裂带走向夹角为10°。在垂直剪切带的剖面上,系统观察岩石变形特征,测量面理产状,进行岩石有限应变测量,岩石非共轴递进变形分析结果表明:秦岭北缘强变形带内由南向北面理走向与剪切带走向的夹角逐渐增大,岩石剪应变量依次递减,造山带变形具有“三斜对称”特点。  相似文献   
14.
The penaeid prawns Fenneropenaeus indicus and Metapenaeus monoceros support shallow-water prawn fisheries in the south-west Indian Ocean. They are sympatric and have similar life histories, including developmental stages that depend on estuarine and marine habitats and a short dispersal duration. Nevertheless, M. monoceros juveniles display a more generalist habitat preference in estuaries and recruit to offshore habitats during a different season than F. indicus. We hypothesised that these differences would affect dispersal patterns, leading to dissimilar geographic genetic structure between the two taxa. Given their short dispersal phase, we also hypothesised that the Mozambique Channel would form a barrier to dispersal between the southeastern African mainland and Madagascar sites. Population differentiation was assessed based on analysis of mitochondrial DNA control-region sequences. Both species displayed high haplotype and low nucleotide diversity. Pairwise ?ST statistics supported the existence of admixed populations along the African mainland sites for both species, with geographic distance isolating populations at the extremes of the sampled range (Kenya and east coast of South Africa). The Madagascar population differed significantly from African mainland populations. The concordant patterns in population differentiation suggest that F. indicus and M. monoceros can be considered as single African stocks, or fisheries management units.  相似文献   
15.
西秦岭凤太矿集区丝毛岭金矿床地质地球化学特征   总被引:1,自引:0,他引:1  
西秦岭凤太矿集区丝毛岭金矿床位于八卦庙造山型金矿床西侧5km左右,是一个新探明的剪切带型金矿。其成矿作用过程可分为早期石英-绢云母-硫化物阶段、中期多金属-硫化物阶段和晚期碳酸盐阶段。对早、中期的石英流体包裹体测试结果表明,丝毛岭金矿床成矿流体以富CO2、中温、低盐度为特征,总体上属于中温低盐度CO2-H2O体系,流体包裹体类型的多样性是流体不混溶性的产物。从早阶段到主成矿阶段成矿流体的温度、压力和盐度均有降低,硫逸度增高,有利于金的沉淀富集。H、O、S、C同位素研究结果,以及与八卦庙金矿床的对比分析表明,二者的成矿流体具有相似性和同源性,都是以深部来源为主的多源流体。由于丝毛岭金矿床产出的层位高于八卦庙金矿床,其成矿环境相对开放。  相似文献   
16.
We use interferometric synthetic aperture radar (InSAR) and broadband seismic waveform data to estimate a source model of the 11th July, 2004 M W 6.2 Zhongba earthquake, Tibet of China. This event occurred within the seismically active zone of southwestern Tibetan Plateau where the east-west extension of the upper crust is observed. Because of limitations in one pair of InSAR data available, there are trade-offs among centroid depth, rupture area and amount of slip. Available seismic data tightly constrain ...  相似文献   
17.
The Owen Conglomerate comprises coarse-grained siliciclastics that were deposited in response to Late Cambrian extension. The identification of normal faults that host thickened accumulations of siliciclastics is used here to support interpretation of syn-fill extension. Local mapping and section construction have identified a series of north-trending, en échelon, segmented normal faults that exhibit changes in along-strike polarity. The Late Cambrian faults are adjacent to sedimentary packages that define half-graben geometries, with an unconformity that defines basal contacts with underlying Mt Read Volcanics and onlap geometries onto the opposing basin margin. Faults that were active during deposition of the Owen Conglomerate were subsequently reversed during D1 Middle Devonian deformation, with reverse displacement controlling the development of inversion structures defined by north-trending fold structures. Pervasive northwest-trending D2 deformation extensively overprints earlier deformation features, and has led to the spectacular development of type 1 interference patterns that largely control outcrop distributions along the West Coast Range. Field evidence is documented in support for a simple structural history that accounts for geometries associated with Late Cambrian extension, prior to Middle Devonian inversion (D1) and subsequent shortening (D2).  相似文献   
18.
Maintaining proper freshwater and marine inputs is essential for estuarine function. Alteration of freshwater flows into small tributaries that traverse the upland-estuarine margin may be especially problematic, e.g., by impacting the nursery areas for juvenile finfish and shellfish. We used stomach contents and stable isotope analysis (δ13C, δ15N) to examine effects of freshwater flow alterations on the trophic ecology of juvenile common snook (Centropomus undecimalis) in four mangrove creeks with different freshwater flow regimes. Diet diversity in less degraded creeks was greater than in more degraded creeks, and the importance (by % mass) of the top three preys was disproportionately higher in the more degraded creeks. Stable isotope measures of trophic diversity corroborate these trends, suggesting higher intraspecific trophic diversity in less degraded creeks. The difference in diet diversity of juvenile snook may be an indicator of an overall change in ecosystem function and these shifts in food web structure may affect the rate that juveniles of this and other species with similar habitat requirements successfully join the adult population.  相似文献   
19.
Classification and regression techniques are among the most used tools by chemometricians.Withclassification,the two classic methods are discriminant analysis and SIMCA.In this paper we discuss theconnection between these two methods and introduce two new ones of the same family:DASCO(discriminantanalysis with shrunken covariances)and RDA(regularized discriminant analysis).We demonstrate on bothsimulated and real data sets that their performance is superior to the old favorites.This is especially truein small-sample/high-dimension settings typical in chemistry.  相似文献   
20.
Coupled with a petrographical study, I carried out an ion probe study of rare earth element microdistributions in mineral phases of silicate inclusions from the Colomera ⅡE iron meteorite. Most mineral grains have homogeneous REEs, but show considerable inter-grain variations by a factor of 2 to 100. The whole rock REE abundances for Colomera, estimated by combining REE data with modal abundances, are relatively LREE-enriched with REEs of -10'CI, which suggest that Colomera silicates were highly differentiated and might represent a low degree partial melt (-10%) of a chondritic source. REE geochemistry of Colomera silicate inclusions points to an origin that involves differentiation, dynamic mixing, remelting, reduction, recrystallization, and subsequent rapid cooling near the surface of a planetary body.  相似文献   
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