Isotopic fractionation of Mg(aq), Ca(aq), and Fe(aq) with carbonate minerals     

James R. Rustad  William H. Casey  Qing-Zhu Yin  Andrew R. Felmy  Virgil E. Jackson 《Geochimica et cosmochimica acta》2010,74(22):6301-6323

Density-functional electronic structure calculations are used to compute the equilibrium constants for ²⁶Mg/²⁴Mg and ⁴⁴Ca/⁴⁰Ca isotope exchange between carbonate minerals and uncomplexed divalent aquo ions. The most reliable calculations at the B3LYP/6-311++G(2d,2p) level predict equilibrium constants K, reported as 10³ln (K) at 25 °C, of −5.3, −1.1, and +1.2 for ²⁶Mg/²⁴Mg exchange between calcite (CaCO₃), magnesite (MgCO₃), and dolomite (Ca_0.5Mg_0.5CO₃), respectively, and Mg²⁺(aq), with positive values indicating enrichment of the heavy isotope in the mineral phase. For ⁴⁴Ca/⁴⁰Ca exchange between calcite and Ca²⁺(aq) at 25 °C, the calculations predict values of +1.5 for Ca²⁺(aq) in 6-fold coordination and +4.1 for Ca²⁺(aq) in 7-fold coordination. We find that the reduced partition function ratios can be reliably computed from systems as small as and embedded in a set of fixed atoms representing the second-shell (and greater) coordination environment. We find that the aqueous cluster representing the aquo ion is much more sensitive to improvements in the basis set than the calculations on the mineral systems, and that fractionation factors should be computed using the best possible basis set for the aquo complex, even if the reduced partition function ratio calculated with the same basis set is not available for the mineral system. The new calculations show that the previous discrepancies between theory and experiment for Fe³⁺-hematite and Fe²⁺-siderite fractionations arise from an insufficiently accurate reduced partition function ratio for the Fe³⁺(aq) and Fe²⁺(aq) species.  相似文献   

Proceedings of the conference ‘the abiotic environment‐evaluation of changes and hazards‐case studies’, edited by Katarzyna Jarmolowicz‐Szulc,Polish Geological Institute Special Papers 24, Warszawa, 2008. No. of pages: 136. ISSN 1507‐9791     

Trevor A. Jackson 《Geological Journal》2010,45(1):117-117

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The tectonic and geomagnetic significance of paleomagnetic observations from volcanic rocks from central Afar, Africa     

Gary D. Acton  Abera Tessema  Michael Jackson  Roger Bilham 《Earth and Planetary Science Letters》2000,180(3-4):225-241

Deformation throughout Afar over the past 2 myr has been characterized by widespread and intense crustal fragmentation that results from inhomogeneous extension across the region. In eastern Afar, this situation has evolved to localized extension associated with the westward propagation of the Gulf of Aden/Gulf of Tadjurah seafloor spreading system into the Asal–Ghoubbet Rift. During the gradual process of rift propagation and localization, crustal blocks in eastern Afar sustained clockwise rotations of 11°. To better understand the processes of rift propagation and localization and how they affect the rest of Afar, we have collected and analyzed over 400 oriented paleomagnetic samples from 67 lava flows from central and southern Afar. Unlike eastern Afar, the mean paleomagnetic direction from central Afar indicates that vertical-axis rotations are statistically insignificant (3.6°±4.4°), though small clockwise rotations (<8°) are permitted. Thus, propagation and localization in central Afar have not had the same influence in causing crustal block rotations or, perhaps more likely, have not reached the same stage of evolution as seen in eastern Afar. In addition, several of the lava flows record intriguing geomagnetic field behavior associated with polarity transitions, excursions, or large secular variation events. Interestingly, the transitional or anomalous virtual geomagnetic poles (VGPs) tend to cluster in two nearly antipodal regions, one in the northern Pacific Ocean and the other in the southwest Indian Ocean. One lava flow has recorded both of the antipodal transitional components, with the two components residing in magnetic minerals with unblocking temperatures above and below 500°C, respectively. Reheating and partial remagnetization by the overlying flow cannot explain either of the transitional directions because both differ significantly from that of the reversely magnetized overlying flow. The high-temperature component gives a VGP in the northern Pacific, whereas the lower-temperature component gives a nearly antipodal VGP south of Cape Town, South Africa. Hence, the configuration of the geomagnetic field appears to have jumped nearly instantaneously from a northern-hemisphere transitional state to a southern-hemisphere one during this normal-to-reverse polarity transition.  相似文献   

Evaluation of criteria for predicting erosion and accretion on an estuarine sand beach, Delaware Bay, Jew Jersey     

Nancy L. Jackson 《Estuaries and Coasts》1999,22(2):215-223

Predicting erosion and accretion of sand beaches in estuaries is important to managing shoreline development and identifying potential relationships between biological productivity and beach change. Wave, sediment and profile data, gathered over twenty-nine days on an estuarine sand beach in Delaware Bay, New Jersey, were used to evaluate the performance of four criteria that predict beach erosion and accretion due to wave-induced cross-shore sediment movement (Dean 1973; Sunamura and Horikawa 1974; Hattori and Kawamata 1980; Kraus et al. 1991). Each criterion defines a relation, between a wave and sediment parameter, and includes a coefficient that discriminates beach erosion and accretion events. Relations, based on small-scale laboratory and field data, were evaluated for predicting erosion or accretion at the study site. Significant wave heights at the study site, monitored near high water, ranged from 0.08 to 0.52 m with periods of 2.4 to 12.8 s. Median grain sizes of sediments on the beach foreshore, gathered at low water, ranged from 0.33 to 0.73 mm. All four criteria showed a clustering of erosion and accretion events. Relations derived from small-scale laboratory data were better predictors of erosion on the profile at the field site than those derived from field data gathered on exposed ocean environments. The planar profile and dominance of incident waves of low height and short period are similar to laboratory conditions characterized by initial planar beach slopes and monochromatic waves. Decreasing the value of the empirical coefficient to account for the differences in the magnitude of wave energy and grain size increases the performance of the criteria tested to predict erosion of the profile.  相似文献   

Effects of a high rise building on wind flow and beach characteristics at Atlantic City, NJ, USA     

Karl F. Nordstrom  Nancy L. Jackson 《Ocean & Coastal Management》1998,39(3):245-263

This study assesses the effects of a high rise building on the beach and dune at an intensively developed shoreline through field investigation of geomorphological and sedimentological characteristics and wind tunnel investigation of wind speed and direction. Results indicate that wind speed is increased close to the building, where wind is often deflected to a more onshore direction. Obliquely offshore northwesterly winds are the most dramatically altered and cause onshore flows (with pronounced upward flows) in the landward portion of the beach near the building. Onshore deflections in wind direction cause besanding of the boardwalk and create highly localized scour and deposition zones. A dune on the backbeach breaks up zones of sediment transport and scour and diminishes the likelihood that scour areas will cause increased hazard to landward buildings as a result of flooding. Generic large-scale studies are required to develop criteria for communities to use to specify optimum dimensions, locations and shapes of landforms that are modified or created by high rise structures.  相似文献   

High-Resolution Characterization of a Chlorinated Solvent Impacted Aquifer Using a Passive Profiler     

Haley A. Schneider  W. Andrew Jackson Ph.D.  P.E.  Paul B. Hatzinger Ph.D  Charles E. Schaefer Ph.D 《Ground Water Monitoring & Remediation》2020,40(4):27-43

A direct-drive high-resolution passive profiler (HRPP) was developed to quantify and delineate concentrations of chlorinated volatile organic compounds (CVOCs), geochemical indicators and CVOC-degrading microorganisms/genes, as well as to perform compound-specific stable isotope analysis (CSIA) of CVOCs and estimate interstitial velocity at <30-cm resolution. The profilers can be coupled together to provide a continuous sample interval and advanced to depths up to approximately 9 m below-ground surface (bgs) within saturated media where direct-push techniques are feasible. The HRPP was field tested in a previous dense nonaqueous phase liquid (DNAPL) source zone at the former Naval Air Station in Alameda, CA. HRPP data sets were compared to the following traditional groundwater data sets: CVOC and anion concentrations in standard and multilevel monitoring well water samples, CVOC concentrations in soil core samples, qualitative contaminant profiles delineated with a membrane interface probe (MIP), microbial community and CSIA profiles from Bio-Traps® deployed in wells, groundwater velocity from passive flux meters (PFMs), lithologic profiles correlated with MIP electrical conductivity (EC), and velocity estimates based on permeability profiles measured with a Geoprobe hydraulic profiling tool (HPT). In some cases, the HRPP data were equivalent to traditional techniques and, in other cases, the HRPP data were more representative of local variability rather than bulk aquifer conditions. Overall the results support the use of the HRPP to provide high-resolution data on concentrations, velocity, and microbial activity in temporary direct-push deployments without well installation, providing a new tool to better assess source zones and contaminated groundwater plumes, even in low permeability media, and to increase the fidelity of site transport models.  相似文献   

Beach recovery from extreme storm activity during the 2013–14 winter along the Atlantic coast of Europe     

Guillaume Dodet  Bruno Castelle  Gerd Masselink  Timothy Scott  Mark Davidson  France Floc'h  Derek Jackson  Serge Suanez 《地球表面变化过程与地形》2019,44(1):393-401

The storm sequence of the 2013–14 winter left many beaches along the Atlantic coast of Europe in their most eroded state for decades. Understanding how beaches recover from such extreme events is essential for coastal managers, especially in light of potential regional increases in storminess due to climate change. Here we analyse a unique dataset of decadal beach morphological changes along the west coast of Europe to investigate the post-2013–14 winter recovery. We show that the recovery signature is site specific and multi-annual, with one studied beach fully recovered after 2 years, and the others only partially recovered after 4 years. During the recovery phase, winter waves primarily control the timescales of beach recovery, as energetic winter conditions stall the recovery process whereas moderate winter conditions accelerate it. This inter-annual variability is well correlated with climate indices. On exposed beaches, an equilibrium model showed significant skill in reproducing the post-storm recovery and thus can be used to investigate the recovery process in more detail. © 2018 John Wiley & Sons, Ltd.  相似文献