Assessment of mercury mobility and bioavailability by fractionation method in sediments from coastal zone inundated by the 26 December 2004 tsunami in Thailand     

Leonard Boszke  Artur Kowalski  Witold Szczuciński  Grzegorz Rachlewicz  Stanisław Lorenc  Jerzy Siepak 《Environmental Geology》2006,51(4):527-536

The 26 December 2004 tsunami covered significant portion of a coastal zone with a blanket of potentially contaminated sediments. In this report are presented results on mercury concentrations in sediments deposited by the tsunami in a coastal zone of Thailand. Since the total mercury concentrations are insufficient to assess mercury mobility and bioavailability in sediment, its fractionation was applied. Sediments were sampled within 50 days after the event and analyzed by sequential extraction method. The procedure of sequential extraction involved five subsequent stages performed with solutions of chloroform, deionized water, 0.5 M HCl, 0.2 M NaOH, and aqua regia. The mean concentration of total mercury in sediments was 119 ± 50 ng g⁻¹ dry mass (range 66–230). The fractionation revealed that mercury is mainly bound to the least bioavailable sulphides 75 ± 6% (range 62–86), organomercury compounds 14 ± 7% (range 4–26), and humic matter 9 ± 7% (range 1–27). The lowest contributions bring fractions of water-soluble mercury 0.8 ± 1.0% (range 0.1–3.6) and acid soluble mercury 0.9 ± 0.5% (range 0.2–2.1). Although, the total mercury content is similar in a reference sample and in the tsunami sediments, the highly toxic organomercury fraction contribution is higher in the latter. The results were compared with chemical and sedimentological properties of the sediments but no significant correlations were obtained between them.  相似文献   

Ambiguity in Measuring Matrix Diffusion with Single-Well Injection/Recovery Tracer Tests   总被引：2，自引：0，他引：2  

Steven C. Lessoff  Leonard F. Konikow 《Ground water》1997,35(1):166-176

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Geochemical characteristics of mineral air particles emitted inside a clay atomisation plant which introduces waste recycling processes     

V Sanfelix  ET Gòmez  MM Jordán  T Sanfeliu  S Pallarés  AB Vicente 《Environmental Geology》2005,47(6):811-819

The objective of this work is to assess the concentrations of three factions of air particles (settable particles, TSP and PM10) and the levels of several toxic elements in a clay atomisation industry through aerosol sampling at several points inside an industrial plant. Mechanical activities, which produce diffuse emissions, are the main process of discharge of particles in both indoor and outdoor workplace environments in the atomisation plant. The levels of As, Cd, Pb, Zn, Ba and Ni increase in the zones with higher concentrations of particles and lower ventilation. The concentrations of As and F are not influenced by the recycling processes. The levels of Cd and Pb do not show great enrichment in air particles collected inside the atomisation plant although the content of both elements is associated with ceramic muck recycling. Finally, the content of B in waste water is mainly transferred in gaseous phase to the atmosphere during the process of drying by atomisation.  相似文献   

Groundwater depletion: A global problem   总被引：19，自引：6，他引：19  

Leonard F. Konikow  Eloise Kendy 《Hydrogeology Journal》2005,13(1):317-320

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West Nile virus in American crows (Corvus brachyrhynchos) in Canada: projecting the influence of climate change     

Benita Y. Tam  Leonard J. S. Tsuji 《GeoJournal》2016,81(1):89-101

The present study examined the influence of climate change on the spread of West Nile virus (WNV) in Canada among American crows (Corvus brachyrhynchos) by first identifying the significant climatic and environmental determinants of positive WNV cases in American crow specimens from 2009 to 2013. Using this information, we projected climate change scenarios on the potential spread of WNV in American crow species in Canada for three time periods: 2015–2039, 2040–2069, and 2070–2099. Using bird specimen, meteorological and land-use data, the statistical association between positive WNV cases in American crows and the environment was assessed by means of a general linear mixed model. Statistical results revealed that temperature and precipitation were significantly related to positive cases of WNV in American crows. Thus, climate change projections of summer mean temperature averages were projected for the three time periods. Climate change scenarios were created and imported into Quantum Geographic Information System (QGIS) and an algorithm was applied using the raster calculator to spatially delineate current and future areas of risk. Spatial analyses revealed that increased warming in the near future may increase the latitudinal extension of WNV in American crows in Canada.  相似文献   

Characterization of hard‐to‐differentiate dune stratification types in the Permian Coconino Sandstone (Arizona,USA)     

Sarah A. Maithel  Leonard R. Brand  John H. Whitmore 《Sedimentology》2021,68(1):238-265

Dune stratification types, which include grainfall, grainflow and ripple lamination, provide a record of the fine‐scale processes that deposited sediment on palaeo‐dune foresets. While these facies are relatively easy to distinguish in some cross‐bedded sandstones, for others – like the Permian Coconino Sandstone of northern and central Arizona – discrete stratification styles are hard to recognize at the bedding scale. Furthermore, few attempts have been made to classify fine‐scale processes in this sandstone, despite its renown as a classic aeolian dune deposit and Grand Canyon formation. To interpret depositional processes in the Coconino Sandstone, cross‐bed facies were characterized using a suite of sedimentary textures and structures. Bedding parameters were described at multiple scales via a combination of field and laboratory methods, including annotated outcrop photomosaics, strike and dip measurements, sandstone disaggregation and laser‐diffraction particle analysis, high‐resolution scans of thin sections, and scanning electron microscopy. Cross‐beds were observed to be laterally extensive along‐strike, with most dip angles ranging from the mid‐teens to mid‐twenties. While some cross‐bed sets are statistically coarser near their bases, others exhibit no significant vertical sorting trends. Both massive and laminated textures are visible in high‐resolution scans of thin sections, but laminae contacts are commonly indistinct, making normal and reverse grading difficult to define. Diagenetic features, such as stylolite seams and large pores, are also present in some samples and might indicate alteration of original textures like detrital clay laminae and carbonate minerals. Observed textures and sedimentary structures suggest that the cross‐beds may consist of grainflow and grainfall deposits, but these remain difficult to differentiate at outcrop and thin‐section scales. This characterization of fine‐scale processes will play a critical part in the development of depositional models for the Coconino Sandstone and elucidate interpretations for similar cross‐bedded formations.  相似文献   

A conduit-related genesis of the Lengshuiqing intrusive assemblage (Sichuan,SW China)     

Marian Munteanu  Allan H. Wilson  Yong Yao  Shao-Yong Jiang  Gordon Chunnett  Yaonan Luo  Leonard Mafurutu  Rofhiwa Phadagi 《Journal of Volcanology and Geothermal Research》2010,189(1-2):118-130

Lengshuiqing is part of the late Proterozoic igneous province from the western margin of the Yangtze craton. The Lengshuiqing area comprises five ultramafic–mafic intrusions, emplaced in the late Proterozoic Yanbian Group. The intrusions from Lengshuiqing contain cumulate ultramafic zones (peridotite + olivine pyroxenite), with cumulus olivine and Cr-spinel, and intercumulus pyroxenes, hornblende, phlogopite and plagioclase. Ni–Cu ore (pyrrhotite + pentlandite + chalcopyrite) is hosted in the ultramafic zones. Olivine-free diorite–quartz diorite ± gabbro and granite zones commonly occur above the ultramafic rocks. The genesis of the intrusions (conduit-related accumulation or differentiation from stagnant magma) was investigated. The amount of sulphides in the intrusions from Lengshuiqing is one order of magnitude bigger than the sulphides that can be dissolved by a volume of mafic magma similar with the volume of the intrusions. Most intrusions from Lengshuiqing have bulk composition (peridotite ± diorite ± granite) more magnesian (MgO = 21–22%; Mg# > 78) than the deduced composition of their parental magma (MgO = 9–11%; Mg# = 64–67). This indicates the accumulation of sulphide and mafic silicates from a volume of magma much bigger than the volume of the intrusions, which can be explained by the fractionation from magma ascending through the intrusions to shallower depths. A continuous supply and vent of magma is consistent with the lack of chilled margins, the melting of the wall rocks and the generation of high-temperature mineral assemblages (K-feldspar, diopside, and sillimanite) in the Yanbian Group. The intrusions from Lengshuiqing are seen as microchambers on conduits draining olivine-, Cr-spinel-, and sulphide-bearing mafic magma from a larger staging chamber.  相似文献   

Dynamics of epiphytic photoautotrophs and heterotrophs inZostera marina (eelgrass) microcosms: Responses to nutrient enrichment and grazing     

Hilary A. Neckles  Eric T. Koepfler  Leonard W. Haas  Richard L. Wetzel  Robert J. Orth 《Estuaries and Coasts》1994,17(3):597-605

The combined effects of nutrient enrichment and grazing by isopods and amphipods on abundances of seagrass epiphytes were tested inZostera marina L. (eelgrass) microcosms. Using epifluorescence microscopy, densities of epiphytic diatoms, cyanobacteria, heterotrophic flagellates, and heterotrophic bacteria were enumerated after 1 mo and 2 mo of treatment. In general, numbers of diatoms decreased, in the presence of grazers and showed little response to nutrient enrichment, whereas numbers of cyanobacteria increased with nutrient enrichment and showed little response to grazing. Thus, macrofaunal grazing maintained a photoautotrophic community domainated by cyanobacteria, particularly under nutrient enriched conditions. Following 2 mo of treatment, dense macroalgal growth under nutrient-enriched conditins with grazers absent appeared to limit populations of both epiphytic autotrophs. Patterns of abundance of heterotrophic bacteria suggested that the original bacteria population was nutrient limited. Bacteria populations may have been limited by organic carbon supplies at the end of the experiment. Abundances of heterotrophic flagellates and bacteria were strongly correlated on both sampling dates. Results suggest that heterotrophic flagellates might serve as a link between heterotrophic bacterial production and higher trophic levels in seagrass epiphyte food webs.  相似文献   

Spatial distributions of the softstem bulrush,Scirpus validus,across a salinity gradient     

Pamela J. Latham  Leonard G. Pearlstine  Wiley M. Kitchens 《Estuaries and Coasts》1991,14(2):192-198

Spatial distribution patterns ofScirpus validus were studied in tidal marshes of the lower Savannah River. The hypothesis that changes in spatial pattern forS. validus would accompany differences in environmental parameters was tested by sampling densities and biomass along environmental gradients of salinity and elevation. Coefficients of dispersion were calculated forS. validus and used to compare spatial patterns among freshwater, midly oligohaline, strongly oligohaline, and mesohaline tidal marshes. Results indicated significantly greater clumping ofS. validus in mesohaline marsh than in freshwater marsh. Only the mildly oligohaline site supported a random population ofS. validus, while the strongly oligohaline marsh supported a uniform spatial distribution. Spatial pattern and relative importance ofS. validus, as well as composition of co-occurring species, changed significantly with changing salinity. The relations between changes in relative importance ofS. validus and differences in soil organic matter and elevation were also significant.  相似文献   

On the role of evidence in physical and human geography     

Leonard Guelke 《Geoforum》1985,16(2):131-137

While physical geographers are united in a commitment to the scientific method with its emphasis on quantitative evidence, human geographers face a dilemma in deciding whether to adopt a scientific or humanistic approach in their research. The scientific approach offers a more secure, objective knowledge, but limits the scholar to a relatively narrow range of topics. The humanistic approach allows the scholar to explore a wide range of human experiences, but it lacks rigorous procedures of objective verification. The difficulty of the application of theoretical ideas to human societies can, to some extent, be avoided by adopting an historical approach, with an emphasis on the empirical investigation of human activity as a reflection of ideas. As long as human geographers have a commitment to basing their interpretations of geographical phenomena on objective evidence the possibility of a profitable co-operation exists among proponents of different philosophical approaches. A unified human geography embracing scholars of diverse views depends for its success on the identification of geographical problems that transcend philosophical and theoretical points of view.  相似文献