A tertiary fold and thrust belt in the Valle del Cauca Basin, Colombian Andes     

C.A. Alfonso  P.E. Sacks  D.T. Secor  J. Rine  V. Perez 《Journal of South American Earth Sciences》1994,7(3-4)

Surface geology and heophysical data, supplemented by regional structural interpretations, indicate that the Valle del Cauca basin and adjacent areas in west-central Colombia form a west-vergent, basement-involved fold and thrust belt. This belt is part of a Cenozoic orogen developed along the west side of the Romeral fault system. Structural analysis and geometrical constraints show that the Mesozoic ophiolitic basement and its Cenozoic sedimentary cover are involved in a “thick-skinned” west-vergent foreland style deformation. The rocks are transported and shortened by deeply rooted thrust faults and stacked in imbricate fashion. The faults have a NE---SW regional trend, are listric in shape, developed as splay faults which are interpreted as joining a common detachment at over 10 km depth. The faults carry Paleogene sedimentary strata and Cretaceous basement rocks westward over Miocene strata of the Valle del Cauca Basin. Fold axes trend parallel or sub parallel to the thrust faults. The folds are westwardly asymmetrical with parallel to kink geometry, and are interpreted to be fault-propagation folds stacked in an imbricate thrust system. Stratigraphic evidence suggests that the Valle del Cauca basin was deformed between Oligocene and upper Miocene time. The kinematic history outlined above is consistent with an oblique convergence between the Panama and South American plates during the Cenozoic.A negative residual Bouguer anomaly of 20–70 mgls in the central part of the Valle del Cauca basin indicates that a substantial volume of low density sedimentary rocks is concealed beneath the thrust sheets exposed at the land surface. The hydrocarbon potential of the Valle del Cauca should be reevaluated in light of the structural interpretations presented in this paper.  相似文献   

Comment on “The solubility of aragonite in seawater”     

Alfonso Mucci  Frank J. Millero  John W. Morse 《Geochimica et cosmochimica acta》1982,46(1):105-107

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The incorporation of Mg²⁺ and Sr²⁺ into calcite overgrowths: influences of growth rate and solution composition     

Alfonso Mucci  John W Morse 《Geochimica et cosmochimica acta》1983,47(2):217-233

The concentrations of Mg²⁺ and Sr²⁺ incorporated within calcite overgrowths precipitated from seawater and related solutions, determined at 25°C, were independent of the precipitation rate over approximately an order of magnitude. The saturation states used to produce this range of precipitation rates varied from 3 to 17 depending on the composition of the solution.The amount of Mg²⁺ incorporated in the overgrowths was not directly proportional to $\text{Mg}{}^{\mathrm{2+}}\text{Ca}{}^{\mathrm{2+}}$ in solution over the entire range (1–20) of ratios studied. Below a ratio of 7.5, the overgrowth was enriched in MgCO₃ relative to what is predicted by the constant distribution coefficient measured above a ratio of 7.5. This increased MgCO₃ correlates with the relative enrichment of adsorbed Mg²⁺. Above a ratio of 7.5 the concentration of MgCO₃ in the calcite overgrowths followed a classical thermodynamic behavior characterized by a constant distribution coefficient of 0.0123 (±0.008 std dev).The concentration of SrCO₃ incorporated in the overgrowths was linearly related to the MgCO₃ content of the overgrowths, and is attributed to increased solubility of SrCO₃ in calcite due to the incorporation of the smaller Mg²⁺ ions.The kinetic data indicate that the growth mechanism involves the adsorption of the cations on the surface of the calcite prior to dehydration and final incorporation. It is suggested that dehydration of cations at the surface is the rate controlling step.  相似文献   

Fog Formation Related to Gravity Currents Interacting with Coastal Topography     

Bardoel  Stef L.  Horna Muñoz  Daniel V.  Grachev  Andrey A.  Krishnamurthy  Raghavendra  Chamorro  Leonardo P.  Fernando  Harindra J. S. 《Boundary-Layer Meteorology》2021,181(2-3):499-521

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Radiocarbon Data on Lateglacial and Holocene Landslides in the Northern Apennines     

Giovanni Bertolini  Nicola Casagli  Leonardo Ermini  Claudio Malaguti 《Natural Hazards》2004,31(3):645-662

The Emilia Romagna slope of the Northern Apennines is strewnwith over 32,000 landslides, 5,000 of which are larger than 1 million cubic metres. They representthe remains of geomorphic agents that shaped the Apennines during the Holocene. Dating themby means of radiocarbon methods adds a contribution to the knowledge about the last periodof the geological geomorphological history of the Apennines. They can also be used to examinethe influence of Quaternary climatic changes on the instability of slopes and, for practicalor planning functions, to assess the periodicity of activity phases of the landslides. Thedating has been carried out on wood remnants buried under the landslide bodies. In some cases theentire tree trunk was found.In this paper we present radiocarbon dating of 20 casestudies in the Northern Apennines. Results range approximately from 13790–13670 cal y BP to950–790 cal`y BP. The oldest case is that of the Morsiano earth-flow, while the younger datedevent is represented by the Marano case that represents an example of how radiometric analysescan further enhance the available historical data. In the Cavola case, wood remnants of different ageswere found at different depths (from 9 to 45 m), allowing the dating of the first and followingperiods of activity of the landslide. The results are discussed and some considerations on the correlationbetween landslide occurrence and Holocene climate changes are proposed.  相似文献   

DFT study of the cation arrangements in the octahedral and tetrahedral sheets of dioctahedral 2:1 phyllosilicates     

Alfonso Hernández-Laguna  Elizabeth Escamilla-Roa  Vicente Timón  Martin T. Dove  C. Ignacio Sainz-Díaz 《Physics and Chemistry of Minerals》2006,33(10):655-666

Quantum mechanical calculations based on the density functional theory (DFT) are used to study the crystal structures of dioctahedral 2:1 phyllosilicates. The isomorphous cation substitution is investigated by exploring different substitutions of octahedral Al³⁺ by Mg²⁺ or Fe³⁺, tetrahedral substitution of Si⁴⁺ by Al³⁺, and different interlayer cations (IC) (Na⁺, K⁺, Ca²⁺, and Mg²⁺). Samples with different kinds of layer charges are studied: only tetrahedrally charged, only octahedrally charged, or mixed octahedral/tetrahedral charged. The effect of the relative arrangements of these substitutions on the lattice parameters and total energy is studied. The experimental observation of segregation tendency of Fe³⁺ and dispersion tendency of Mg²⁺ in the octahedral sheet is reproduced and explained with reference to the relative energies of the octahedral cation arrangements. These energies are higher than those due to the IC/tetrahedral and IC/octahedral relative arrangements. The tetrahedral and octahedral substitutions that generate charged layers also tend to be dispersed. The octahedral cation exchange potentials change with the IC-charge/ionic radius value.  相似文献   

Modeling endogenous learning and imperfect competition effects in climate change economics     

Laurent Viguier  Leonardo Barreto  Alain Haurie  Socrates Kypreos  Peter Rafaj 《Climatic change》2006,79(1-2):121-141

In this two-part paper we evaluate the effect of “endogenizing” technological learning and strategic behavior of agents in economic models used to assess climate change policies. In the first part we show the potential impact of R&D policies or demonstration and deployment (D&D) programs in the context of stringent stabilization scenarios. In the second part we show how game-theoretic methods can be implemented in climate change economic models to take into account three types of strategic interactions: (i) the market power of the countries benefiting from very low abatement costs on international markets for CO₂ emissions, (ii) the strategic behavior of governments in the domestic allocation of CO₂ emissions quotas, and (iii) the non-cooperative behavior of countries and regions in the burden sharing of CO₂ concentration stabilization. The two topics of endogenous learning and game-theoretic approach to economic modeling are two manifestations of the need to take into account the strategic behavior of agents in the evaluation of climate change policies. In the first case an R&D policy or a demonstration and deployment (D&D) program are put in place in order to attain a cost reduction through the learning effect; in the second case the agents (countries) reply optimally to the actions decided by the other agents by exploiting their strategic advantages. Simulations based on integrated assessment models illustrate the approaches. These studies have been conducted under the Swiss NCCR-Climate program.  相似文献   

Analytical Solutions for Free-Hydrocarbon Recovery Using Skimmer and Dual-Pump wells     

Russell T. Johns  Larry W. Lake  Abimbola B. Obigbesan  Leonardo Bermudez  M.R. Hassan  Randall J. Charbeneau 《Ground Water Monitoring & Remediation》2003,23(1):97-106

Accidental release of petroleum hydrocarbons to the subsurface may occur through spills around refineries, leaking pipelines, storage tanks, or other sources. If the spill is large, the hydrocarbon liquids may eventually reach a water table and spread laterally in a pancake-like lens. Hydrocarbons that exist as a separate phase are termed light nonaqueous phase liquids (LNAPLs). The portion of the LNAPL that is mobile, not entrapped as residual saturation, is termed "free product."
This paper presents new analytical solutions for the design of long-term free-product recovery from aquifers with skimmer, single- and dual-pump wells. The solutions are for steady-state flow, based on the assumption of vertical equilibrium, and include the effect of coning of LNAPL, air, and water on flow. The solutions are valid for soils of large hydraulic conductivity where the effect of capillary pressure on coning is small.
The results show how to estimate the maximum rate of inflow of LNAPL for skimmer wells, i.e., wells in which LNAPL is recovered with little or no water production. The paper also shows how to calculate the increase in LNAPL recovery when water is pumped by single- or dual-pump wells. A simple equation is given that can be used to adjust the water rate to avoid smearing of the LNAPL below the water table.  相似文献   

Late Neoproterozoic crustal growth in the European Variscides: Nd isotope and geochemical evidence from the Sierra de Córdoba Andesites (Ossa-Morena Zone, Southern Spain)     

Christian Pin  Eladio Lin  Emilio Pascual  Teodosio Donaire  Alfonso Valenzuela 《Tectonophysics》2002,352(1-2)

Because the Hercynian overprint was extremely weak, the Sierra de Córdoba (southeastern Ossa-Morena Zone, OMZ) provides an excellent opportunity to study the tectonic evolution of sequences deposited close to the Late Neoproterozoic–Early Palaeozoic boundary. In order to put constraints on the sources and geodynamic significance of the Late Proterozoic magmatism, a representative set of 18 igneous rocks, and 3 interbedded sedimentary rocks from the San Jerónimo Formation have been studied for major and trace element geochemistry and for the Sm–Nd isotopic systematics. The igneous rocks are generally porphyritic to microporphyritic andesites, with abundant plagioclase (±amphibole) phenocrysts. With the exception of two intrusive rocks, possibly not related to the Late Proterozoic episode, all the samples display positive _{Nd550 Ma} values, ranging from +2.9 to +7.6. Most of them, with +4<_{Nd550 Ma}<+6, exhibit LREE enrichment, high La/Nb ratios, and elevated Zr/Nb ratios ranging from 21 to 32. There is no obvious correlation between the shape of REE patterns, La/Nb ratios and _{Nd550 Ma} values, precluding simple models of late-stage interaction with typical crustal components having low _Nd and high LREE/HREE and La/Nb ratios. Based on their major element composition and enriched, continental crust-like trace element characteristics, combined with distinctly positive _Nd initial values, the Córdoba andesites document an episode of crustal growth through the addition of calc-alkaline magmas, extracted from a mantle reservoir which was strongly depleted in LREE on a time-integrated basis. The occurrence of interlayered sediments of continental provenance (negative _Nd values) does not favour a purely ensimatic arc setting, remote from continental land masses, for this subduction-related magmatism, but the geochemical data suggest an active margin environment located on relatively juvenile crust. In any case, the Córdoba andesites document the addition of materials chemically similar to the bulk continental crust which were extracted from mantle sources with strong time-integrated LREE depletion. Therefore, they provide evidence for crustal growth related to Cadomian orogenic events during Late Proterozoic times.  相似文献   

Geostatistical seismic Amplitude‐versus‐angle inversion          下载免费PDF全文

Leonardo Azevedo  Rúben Nunes  Amílcar Soares  Guenther Schwedersky Neto  Teresa S. Martins 《Geophysical Prospecting》2018,66(Z1):116-131

Seismic inversion plays an important role in reservoir modelling and characterisation due to its potential for assessing the spatial distribution of the sub‐surface petro‐elastic properties. Seismic amplitude‐versus‐angle inversion methodologies allow to retrieve P‐wave and S‐wave velocities and density individually allowing a better characterisation of existing litho‐fluid facies. We present an iterative geostatistical seismic amplitude‐versus‐angle inversion algorithm that inverts pre‐stack seismic data, sorted by angle gather, directly for: density; P‐wave; and S‐wave velocity models. The proposed iterative geostatistical inverse procedure is based on the use of stochastic sequential simulation and co‐simulation algorithms as the perturbation technique of the model parametre space; and the use of a genetic algorithm as a global optimiser to make the simulated elastic models converge from iteration to iteration. All the elastic models simulated during the iterative procedure honour the marginal prior distributions of P‐wave velocity, S‐wave velocity and density estimated from the available well‐log data, and the corresponding joint distributions between density versus P‐wave velocity and P‐wave versus S‐wave velocity. We successfully tested and implemented the proposed inversion procedure on a pre‐stack synthetic dataset, built from a real reservoir, and on a real pre‐stack seismic dataset acquired over a deep‐water gas reservoir. In both cases the results show a good convergence between real and synthetic seismic and reliable high‐resolution elastic sub‐surface Earth models.  相似文献