Carbonatites and ultrabasic-alkaline rocks of the maimecha-kotui region, N. Siberia     

Leonid S. Egorov 《Lithos》1970,3(4):341-359

The structural position, geology, petrography, petrochemistry, and petrogenesis of one of the world's greatest carbonatite provinces situated in North Siberia are recorded. Three groups of Late Permian-Early Triassic magmatites are briefly discussed: effusives, dikes, and intrusives of complex central type. Carbonatite and congenetic rocks are related to kimberlites, but are genetically unrelated to tholeiitic basalts and trachybasalts. The genetic development and diagnostic features of ultrabasic-alkaline rocks and carbonatites are formulated.  相似文献   

The eastern extent of the Barents–Kara ice sheet during the Last Glacial Maximum based on seismic-reflection data from the eastern Kara Sea     

Leonid Polyak  Frank Niessen  Valery Gataullin  & Valery Gainanov 《Polar research》2008,27(2):162-174

We present sub-bottom profiling (sparker and Parasound) results from the eastern Kara Sea, on the Eurasian Arctic margin, which enable the identification of the Last Glacial Maximum (LGM) ice extent. The analysed profiles show that glacigenic diamicton is ubiquitous at the seafloor, east of about 95°E and 78°N. The eastern margin of this diamicton is expressed in a conspicuous morainic ridge at the entrance to the Vilkitsky Strait, and to the south the diamicton projection aligns with the LGM limit mapped at the north-western Taymyr. The bottom of the Voronin Trough further north is also covered with diamicton and has numerous erosional bedforms, indicating a streamlined flow of grounded ice along the trough. Accurate dating of the diamicton is not attainable, but the correlation of pre-diamict sediments to well-dated sections in the Laptev Sea, and available ¹⁴C ages from sediments on top of the diamicton, indicate its LGM age. These results support the palaeogeographic reconstruction that assumes the extension of the LGM Barents–Kara ice sheet as far east as Taymyr. This configuration implies that LGM ice blocked the drainage of the Ob and Yenisey rivers on the Kara shelf. This inference is consistent with the presence of large (>100 km wide) lenses of basin infill adjacent to the southern margin of the diamicton. However, the limited distribution of the eastern Kara ice lobe, not extending on Severnaya Zemlya, suggests that the ice was fairly thin and short-lived: insufficient for the accumulation of the gigantic proglacial lakes that occurred during earlier glaciations.  相似文献   

In situ high-pressure study of FeP: Implications for planetary cores     

Tingting Gu  Xiang Wu  Shan Qin  Leonid Dubrovinsky 《Physics of the Earth and Planetary Interiors》2011,184(3-4):154-159

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Viability of pyrite pulled metabolism in the ‘iron-sulfur world’ theory: Quantum chemical assessment     

Andrea Michalkova  Dmytro Kosenkov  Leonid Gorb  Jerzy Leszczynski 《Geochimica et cosmochimica acta》2011,75(7):1933-1941

The viability of pyrite-pulled metabolism in the ‘iron-sulfur world’ theory was assessed using a simple model of iron-nickel sulfide (Fe-Ni-S) surface and data obtained from quantum chemical calculations. We have investigated how the individual reactions in the carbon fixation cycle (carboxylic acids formation) on an Fe-Ni-S surface could have operated to produce carboxylic acids from carbon oxide and water. The proposed model cycle reveals how the individual reactions might have functioned and provides the thermodynamics of each step of the proposed pathway. The feasibility of individual reactions, as well the whole cycle was considered. The reaction of acetic acid production from CH₃SH and CO on an Fe-Ni sulfide surface was revealed to be endergonic with a few partial steps having positive Gibbs free energy. On the other hand, the pyrite formation was found to be slightly exergonic. The significance of the catalytic activity of transition metal sulfides in generation of acetic acid was shown. The Gibbs free energy values indicate that the acetic acid synthesis is unfavorable to proceed on the studied Fe-Ni-S model under simulated conditions. The importance of these results in terms of a primordial chemistry on iron-nickel sulfide surfaces is discussed.  相似文献   

High-grade iron ore at Windarling, Yilgarn Craton: a product of syn-orogenic deformation, hypogene hydrothermal alteration and supergene modification in an Archean BIF-basalt lithostratigraphy   总被引：2，自引：0，他引：2  

Thomas Angerer  Steffen G. Hagemann  Leonid Danyushevsky 《Mineralium Deposita》2013,48(6):697-728

Banded iron formation (BIF)-hosted iron ore deposits in the Windarling Range are located in the lower greenstone succession of the Marda–Diemals greenstone belt, Southern Cross domain, Yilgarn Craton and constitute a total hematite–martite–goethite ore resource of minimum 52 Mt at 60 wt.% Fe (0.07 P). Banded iron formation is interlayered with high-Mg basalts at Windarling and precipitated during episodes of volcanic quiescence. Trace element content and the rare earth element (REE) ratios Y/Ho (42 to 45), Sm/Yb (1.5), together with positive La and Gd anomalies in ‘least-altered’ hematite–magnetite–metachert–BIF indicate the precipitation from Archean seawater that was fertilised by hydrothermal vent fluids with a basaltic HREE-Y signature. Hypogene iron ore in sub-greenschist facies metamorphosed BIF formed during three distinct stages: ore stage 1 was a syn- to post-metamorphic, syn-D₁, Fe–Ca–Mg–Ni–Co–P–REE metasomatism that produced local Ni–REE-rich Fe–dolomite–magnetite alteration in BIF. Hydrothermal alteration was induced by hot fluid flow controlled by brittle–ductile reactivation of BIF-basalt margins and crosscutting D₁ faults. The Ni–Co-rich content of dolomite and a shift in REE ratios in carbonate-altered BIF towards Archean mafic rock signature (Y/Ho to 31 to 40, Sm/Yb to 1 to 2 and Gd/Gd* to 1.2 to 1.4) suggest that high-Mg basalts in the Windarling Range were the primary source of introduced metals. During ore stage 2, a syn-deformational and likely acidic and oxidised fluid flow along BIF-basalt margins and within D₁ faults leached carbonate and precipitated lepidoblastic and anhedral/granoblastic hematite. High-grade magnetite–hematite ore is formed during this stage. Ore stage 3 hydrothermal specular hematite (spcH)–Fe–dolomite–quartz alteration was controlled by a late-orogenic, brittle, compressional/transpressional stage (D₄; the regional-scale shear-zone-related D₃ is not preserved in Windarling). This minor event remobilised iron oxides, carbonate and quartz to form veins and breccia but did not generate significant volumes of iron ore. Ore stage 4 involved Mesozoic(?) to recent supergene oxidation and hydration in a weathering environment reaching down to depths of ～100 to maximum 200 m below surface. Supergene ore formation involved goethite replacement of dolomite and quartz as well as martitisation. Important ‘ground preparation’ for supergene modification and upgrade were mainly the formation of steep D₁ to D₄ structures, steep BIF/basalt margins and particularly the syn-D₁ to syn-D₂ carbonate alteration of BIF that is most susceptible to supergene dissolution. The Windarling deposits are structurally controlled, supergene-modified hydrothermal iron ore systems that share comparable physical, chemical and ore-forming characteristics to other iron ore deposits in the Yilgarn Craton (e.g. Koolyanobbing, Beebyn in the Weld Range, Mt. Gibson). However, the remarkable variety in pre-, syn- and post-deformational ore textures (relative to D₁ and D₂) has not been described elsewhere in the Yilgarn and are similar to the ore deposits in high-strain zones, such as of Brazil (Quadrilátero Ferrífero or Iron Quadrangle) and Nigeria. The overall similarity of alteration stages, i.e. the sequence of hydrothermal carbonate introduction and hypogene leaching, with other greenstone belt-hosted iron ore deposits supports the interpretation that syn-orogenic BIF alteration and upgrade was crucial in the formation of hypogene–supergene iron ore deposits in the Yilgarn Craton and possibly in other Archean/Paleoproterozoic greenstone belt settings worldwide.  相似文献   

A Comparative Study of Five Reference Materials and the Lombard Meteorite for the Determination of the Platinum‐Group Elements and Gold by LA‐ICP‐MS     

Sarah Gilbert  Leonid Danyushevsky  Philip Robinson  Cora Wohlgemuth‐Ueberwasser  Norman Pearson  Dany Savard  Marc Norman  Jacob Hanley 《Geostandards and Geoanalytical Research》2013,37(1):51-64

A range of independently characterised reference materials (RMs) for LA‐ICP‐MS, used for the determination of the platinum‐group elements (PGE) and Au in a sulfide matrix, were analysed and compared: 8b, PGE‐A, NiS‐3, Po727‐T1, Po724‐T and the Lombard meteorite. The newly developed RM NiS‐3 was used as the RM for the calibration of all LA‐ICP‐MS analyses and the measured concentrations of the other RMs compared against their published concentrations. This data were also used to assess the consistency of concentrations calibrated against the different RMs. It was found that Po727‐T1 and 8b produced results that were comparable, within uncertainty, for all elements. Po727‐T1 also produced consistent results with NiS‐3 for all elements. All other RMs showed differences for some elements, especially Ru in Po724‐T, and Os, Ir and Au in PGE‐A. The homogeneity of the PGE and Au in each RM was assessed, by comparing the precision of multiple LA‐ICP‐MS spot analyses with the average uncertainty of the signal. Po724‐T, Po727‐T1 and the Lombard meteorite were found to be homogeneous for all elements, but 8b, PGE‐A and NiS‐3 were heterogeneous for some elements. This is the first direct comparison between a range of independently characterised PGE and Au LA‐ICP‐MS RMs.  相似文献   

A System of Sediment Reference Samples: Oo   总被引：2，自引：0，他引：2  

Leonid A. BERKOVITS  Valentina G. OBOLYANINOVA  Alexander K. PARSHIN  Albina R. ROMANOVSKAYA 《Geostandards and Geoanalytical Research》1991,15(1):85-109

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Textures,trace elements,and Pb isotopes of sulfides from the Haopinggou vein deposit,southern North China Craton: implications for discrete Au and Ag–Pb–Zn mineralization     

Zhan-Ke Li  Jian-Wei Li  David R. Cooke  Leonid Danyushevsky  Lejun Zhang  Hugh O’Brien  Yann Lahaye  Wen Zhang  Hai-Jun Xu 《Contributions to Mineralogy and Petrology》2016,171(12):99

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Parameterization of iron and manganese cycling in the Black Sea suboxic and anoxic environment     

Sergey Konovalov  Anatoliy Samodurov  Temel Oguz  Leonid Ivanov 《Deep Sea Research Part I: Oceanographic Research Papers》2004,51(12):273

New and published data on the distribution and speciation of manganese and iron in seawater are analyzed to identify and parameterize major biogeochemical processes of their cycling within the suboxic (15.6σ_t16.2) and anoxic layers (σ_t16.2) of the Black Sea. A steady-state transport-reaction model is applied to reveal layering and parameterize kinetics of redox and dissolution/precipitation processes. Previously published data on speciation of these elements in seawater are used to specify the nature of the transformations. Two particulate species of iron (Fe(III) hydroxide and Fe(II) sulfide) are necessary to adequately parameterize the vertical profile of suspended iron, while three particulate species (hydrous Mn(IV) oxide, Mn(II) sulfide, and Mn(II) carbonate) are necessary to describe the profile of suspended manganese. In addition to such processes as mixing and advection, precipitation, sinking, and dissolution of manganese carbonate are found to be essential in maintaining the observed vertical distribution of dissolved Mn(II). These results are used to interpret the observed difference in the form of vertical distribution for dissolved Mn(II) and Fe(II). Redox transformations of iron and manganese are coupled via oxidation of dissolved iron by sinking suspended manganese at σ_t16.2±0.2 kg m⁻³. The particulate manganese, necessary for this reaction, is supplied through oxidation of dissolved Mn(II). The best agreement with observations is achieved when nitrate, rather than oxygen, is set to oxidize dissolved Mn(II) in the lower part of the suboxic layer (15.90σ_t16.2). The results support the idea that, after sulfides of these metals are formed, they sink with particulate organic matter. The sinking rates of the particles and specific rates of individual redox and dissolved-particulate transformations have been estimated by fitting the vertical profile of the net rate.  相似文献   

Polarization of Microwave Radio Emission of Flare-Producing Solar Active Regions     

Vladimir M. Bogod  Leonid V. Yasnov 《Solar physics》2009,255(2):253-271

On the basis of our multiwavelength observations made with the one-dimensional RATAN-600 radio telescope, we study the inversion of the circular polarization in the solar microwave emission at different frequencies. The inversion is detected in the emission of flare-producing active regions (FPARs) at various stages of their development, starting from the pre-flare stage. During the latest 23rd solar cycle maximum, numerous FPARs revealed spectral inhomogeneities in their polarized microwave radiation (Bogod and Tokhchukova, 2003, Astron. Lett. 29, 263). Here, we discuss a particular case of such inhomogeneities, the frequency-dependent double inversion of the sign of circular polarization, which probably reflects some essential processes in FPARs. We consider several mechanisms for the double inversion: linear interaction of waves in the region of a quasitransverse magnetic field, the propagation of waves through a region of zero magnetic field, the scattering of radio waves on waves of high-frequency plasma turbulence, the influence of the current fibrils on the propagation of the radio emission, and the magnetic “dips,” in which the direction of magnetic field lines changes the sign relative to the observer. All of them have shortcomings, but the last mechanism explains the observations the best.  相似文献