A Field Evaluation of In-Situ Biodegradation of Chlorinated Ethenes: Part 3, Studies of Competitive Inhibition   总被引：1，自引：0，他引：1  

Lewis Semprini  Gary D. Hopkins  Paul V. Roberts  Dunja Grbic-Galic  Perry L McCarty 《Ground water》1991,29(2):239-250

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An evaluation of flow-stratified sampling for estimating suspended sediment loads     

Robert B. Thomas  Jack Lewis 《Journal of Hydrology》1995,170(1-4):27-45

Flow-stratified sampling is a new method for sampling water quality constituents such as suspended sediment to estimate loads. As with selection-at-list-time (SALT) and time-stratified sampling, flow-stratified sampling is a statistical method requiring random sampling, and yielding unbiased estimates of load and variance. It can be used to estimate event yields or to estimate mean concentrations in flow classes for detecting change over time or differences from water quality standards. Flow-stratified sampling is described and its variance compared with those of SALT and time-stratified sampling. Time-stratified sampling generally gives the smallest variance of the three methods for estimating storm yields. Flow-stratified sampling of individual storms may fail to produce estimates in some short-lived strata because they may have sample sizes of zero. SALT will tend to give small samples and relatively high variances for small stroms. For longer and more complex hydrographs, having numerous peaks, flow-stratified sampling gives the lowest variance, and the SALT variance is lower than that of time-stratified sampling unless the sample size is very large. A desirable feature of flow-stratified sampling is that the variance can be reduced after sampling by splitting strata, particularly high flow strata that have been visited just once, and recalculating the total and variance. SALT has the potential to produce the lowest variance, but cannot be expected to do so with an auxiliary variable based on stage.  相似文献   

A chemical survey of the Mississippi estuary     

Lewis E. Fox  Frederick Lipschultz  Lee Kerkhof  Steven C. Wofsy 《Estuaries and Coasts》1987,10(1):1-12

A “snap shot” survey of the Mississippi estuary was made during a period of low river discharge, when the estuarine mixing zone was within the deltaic channels. Concentrations of H⁺, Ca²⁺, inorganic phosphorus and inorganic carbon suggest that the waters of the river and the low salinity (<5‰) portion of the estuary are near saturation with respect to calcite and sedimentary calcium phosphate. An input of oxidized nitrogen species and N₂O was observed in the estuary between 0 and 4‰ salinity. The concentrations of dissolved NH₄ ⁺ and O₂, over most of the estuary, appeared to be influenced by decomposition of terrestrial organic matter in bottom sediments. The estuarine bottom also appears to be a source of CH₄ which has been suggested to originate from petroleum shipping and refining operations. Estuarine mixing with offshore Gulf waters was the dominant influence on distributions of dissolved species over most of the estuary (i.e., from salinities >5‰). The phytoplankton abundance (measured as chlorophylla) increased as the depth of the mixed layer decreased in a manner consistent with that expected for a light-limited ecosystem. Fluxes of NO₃ ^?+NO₂ ^? and soluble inorganic phosphorus to the Gulf of Mexico were estimated to be 3.4±0.2×10³ g N s^?1 and 1.9±0.2 g P s^?1 respectively, at the time of this study.  相似文献   

Sorption of noble gases by solids,with reference to meteorites. I. Magnetite and carbon     

Jongmann Yang  Roy S. Lewis  Edward Anders 《Geochimica et cosmochimica acta》1982,46(6):841-860

To simulate trapping of meteoritic noble gases by solids, 18 samples of Fe₃O₄ were synthesized in a noble gas atmosphere at 350–720 K by the reactions: 3Fe + 4H₂O → Fe₃O₄ + 4H₂ (Ne, Ar, Kr, Xe) 3Fe + 4CO → Fe₃O₃ + 4C + carbides (Xe only) Phases were separated by selective solvents (HgCl₂, HCl). Noble gas contents were analyzed by mass spectrometry, or, in runs where 36 d Xe¹²⁷ tracer was used, by γ-counting. Surface areas, as measured by the BET method, ranged from 1 to 400 m²/g. Isotopic fractionations were below the detection limit of 0.5%/m.u.Sorption of Xe on Fe₃O₄ and C obeys Henry's Law between $\text{1 × 10}{}^{\mathrm{?8}}$ and $\text{4 × 10}{}^{\mathrm{?5}}$ atm, but shows only a slight temperature dependence between 650 and 720 K ($\text{ΔH}{}_{\mathrm{sol}}\text{= ?4 ± 2}\text{kcal/mole}$). The mean distribution coefficient K_Xe is $\text{0.28 ± 0.09}$ cc STP/g atm for Fe₃O₄ and only a factor of $\text{1.2 ± 0.4}$ greater for C; such similarity for two cogenetic phases was predicted by Lewis et al. (1977). Stepped heating and etching experiments show that 20–50% of the total Xe is physically adsorbed and about 20% is trapped in the solid. The rest is chemisorbed with $\text{ΔH}{}_{\mathrm{s}}\text{? ?13}\text{kcal/mole}$. The desorption or exchange half-time for the last two components is >10² yr at room temperature.Etching experiments showed a possible analogy to “Phase $\text{Q}$” in meteorites. A typical carbon + carbide sample, when etched with HNO₃, lost 47% of its Xe but only 0.9% of its mass, corresponding to a ~0.6 Å layer. Though this etchable, surficial gas component was more thermolabile than $\text{Q}$ (release $\text{T}$ below 1000°C, compared to 1200–1600°C), another experiment shows that the proportion of chemisorbed Xe increases upon moderate heating (1 hr at 450°C). Apparently adsorbed gases can become “fixed” to the crystal, by processes not involving volume diffusion (recrystallization, chemical reaction, migration to traps, etc.). Such mechanisms may have acted in the solar nebula, to strengthen the binding of adsorbed gases.Adsorbed atmospheric noble gases are present in all samples, and dominate whenever the noble gas partial pressure in the atmosphere is greater than that in the synthesis. Many of the results of Lancet and Anders (1973) seem to have been dominated by such an atmospheric component; others are suspect for other reasons, whereas still others seem reliable. When the doubtful samples of Lancet and Anders are eliminated or corrected, the fractionation pattern—as in our samples—no longer peaks at Ar, but rises monotonically from Ne to Xe. No clear evidence remains for the strong temperature dependence claimed by these authors.  相似文献   

Water movement within lac du bonnet batholith as revealed by detailed thermal studies of three closely-spaced boreholes     

Malcolm J. Drury  Trevor J. Lewis   《Tectonophysics》1983,95(3-4)

Successive temperature logs have been obtained over a period of two years in three closely-spaced boreholes in the Lac du Bonnet batholith of the Superior Province of the Canadian Shield. Two of the boreholes, of depth 450 m and 830 m, intersect a dipping fracture zone at 435–450 m. In both holes water is flowing from near the surface to the fracture zone at approximately 1.5–1.9·10⁻⁵ m³ s⁻¹, the flow being inferred from analysis of the temperature logs. Below 25 m, temperatures in these two holes are 0.22–0.28 K lower than those in the third, 145 m, hole.The temperature data have been combined with over 200 thermal conductivity measurements on core samples to produce heat flow values. In the deepest hole heat flow above the fracture zone is 16% higher than that below the zone. This indicates that water is flowing up the fracture zone. The flow rate is approximately 0.3 g s⁻¹ m⁻¹, and the flow has existed for thousands of years.Observation of thermal effects of water flow in massive, relatively unfractured plutons in a region having little topographic relief causes one to be concerned about the reliability of heat flow values measured in similar environments.The regional heat flow is taken to be 50 mW m⁻² after correction for glaciation effects. The average value of 24 determinations of radioactive heat generation in granitic core samples is 5.23 ± 1.11 μW m⁻³, which is more than three times higher than expected for such a heat flow in the Superior Province. This implies that the layer of high radioactive heat generation is thin, being not more than 4 km and probably about 1.3 km thick.  相似文献   

The role of choke points in the ocean context     

Lewis M. Alexander 《GeoJournal》1992,26(4):503-509

Choke points are narrow international waterways where three characteristics are present. The waterway should be narrow and capable of being closed off to both commercial and military snipping. There should be no readily available maritime route to utilize in the event of closure. Finally, the choke point should be of considerable significance to at least several States. This article identifies seven “primary” choke points which seem to satisfy these criteria. These are Gibraltar, Bab el Mandeb, Hormuz, the Danish and Turkish Straits, and the Suez and Panama Canals. It also identifies eleven “secondary” choke points, where at least one of the reouired characteristics is missing. The eleven include Dover, Bering and Magellan Straits, as well as Malacca-Singapore and a number of others in the Western Pacific. Turning to a consideration of the status of choke points in a Post-Cold War era, the article notes four basic assumptions: (1) the intense military rivalry between the United States and the Soviet Union will be reduced in coming years; (2) for many countries marine-related environmental concerns may be increasing considerably; (3) as the Cold War recedes, regional contests and confrontations will grow more intense; and (4) the overall densities of water-borne traffic will undergo change as the relative economic growth of regional centers changes. The article then considers the potential impact of these trends on the future role of choke points.  相似文献   

Reducing global warming — The role of rice     

Heinz-Ulrich Neue  Lewis H. Ziska  Robin B. Matthews  Qiujie Dai 《GeoJournal》1995,35(3):351-362

Activities to provide energy for an expanding population are increasingly disrupting and changing the concentration of atmospheric gases that increase global temperature. Increased CO₂ and temperature have a clear effect on growth and production of rice as they are key factors in photosynthesis. Rice yields could be increased with increased levels of CO₂, however, the rise of CO₂ may be accompanied by an increase in global temperature. The effect of doubling CO₂ levels on rice production was predicted using rice crop models. They showed different effects of climate change in different countries. A simulation of the Southeast Asian region indicated that a doubling of CO₂ increases yield, whereas an increase in temperature decreases yield.Enhanced UV-B radiation resulting for stratographic ozone depletion has been demonstrated to significantly reduce plant height, leaf area and dry weight of two rice cultivars under glasshouse conditions. Data are still insufficient, however, for conclusive results on the effect of UV-B radiation on rice growth under field conditions.Rice production itself has a significant effect on global warming and atmospheric chemistry through methane emission from flooded ricefields. Water regime, soil properties and the rice plant are major factors controlling the flux of methane in ricefields. Global and regional estimates of methane emission rates are still highly uncertain and tentative. Integration of mechanistic modeling of methane fluxes with geographic information systems of factors controlling these processes are required to improve estimates and predictions.  相似文献   

Isotopic composition of strontium in three basalt-andesite centers along the Lesser Antilles arc     

Carl E. Hedge  John F. Lewis 《Contributions to Mineralogy and Petrology》1971,32(1):39-47

Si⁸⁷/Sr⁸⁶ ratios have been determined for lavas and py lastic rocks from three basalt-andesite centers along the Lesser Antilles arc—Mt. Misery on the island of St. Kitts, Soufriere on the island of St. Vincent, and Carriacou, an island of The Grenadines. The average Si⁸⁷/Sr⁸⁶ content of these rocks is 0.7038 for Mt. Misery, 0.7041 for Soufriere, and 0.7053 for Carriacou. All the Sr⁸⁷/Sr⁸⁶ values from each center are the same within analytical uncertainty (±0.0002). The constancy of strontium isotopic data within each center supports the hypothesis that basalts and andesites for each specific center investigated are generated from the same source — in agreement with petrographic and major- and minor-element data. Strontium isotopic compositions and elemental concentrations, particularly of strontium and nickel, indicate that this source was mantle peridotite and that the relationship between the respective basalts and andesites is probably fractional crystallization.Publication authorized by the Director, U.S. Geological Survey.  相似文献   

Reversed Partial Thermo-Magnetic Remanence in Natural and Synthetic Titano-Magnetites   总被引：1，自引：0，他引：1  

A. D. Havard  M. Lewis 《Geophysical Journal International》1965,10(1):59-68

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Morphology of HCN and CN in Comet Hale-Bopp (1995 O1)     

L.M. Woodney  M.F. A'HearnDavid G. Schleicher  Tony L. FarnhamJ.P. McMullin  M.C.H. WrightJ.M. Veal  Lewis E. SnyderImke de Pater  J.R. ForsterPatrick Palmer  Y.-J. KuanWendy R. Williams  Chi C. CheungBridget R. Smith 《Icarus》2002,157(1):193-204

We compare images of Comet Hale-Bopp (1995 O1) in HCN and CN taken near perihelion (April 1, 1997) to determine the origin of CN in comets. We imaged the J=1→0 transition of HCN at λ=3 mm with the BIMA Array. Data from two weeks around perihelion were summed within four phase bins based on the rotational period of the comet. This increases both the signal-to-noise ratio and the u-v coverage while decreasing the smearing of the spatial features. The similarly phased narrowband CN images were taken at Lowell Observatory within the same range of dates as the HCN images. We find that there is a better correlation between HCN and CN than between HCN and the optically dominant dust. If the CN in jets does have a dust source it would have to have a very low albedo and/or small particle size. The production rates are consistent with HCN being a primary parent of CN, although there are discrepancies between the HCN destruction scalelength and the CN production scalelength which we discuss.  相似文献