Chemical aspects of iron oxide coagulation in water: Laboratory studies and implications for natural systems     

Liyuan Liang  James J. Morgan 《Aquatic Sciences - Research Across Boundaries》1990,52(1):32-55

Initial coagulation rates of colloidal hematite (-Fe₂O₃) particles (diameter less than 0.1 µm) were measured experimentally in well-defined laboratory systems at constant temperature. The relative stability ratio,W, was obtained at various ionic strengths in NaCl medium and at pH values in the range from 3 to 12. ExperimentalW values ranged from 1 to 10⁴ in various systems. The results delineate the roles ofspecific andgeneralized coagulation mechanisms for iron oxides. Among the specifically-interacting species (G _ads ⁰ >G _coul ⁰ ) studied were phosphate, monomeric organic acids of various structures, and polymeric organic acids. The critical coagulation-restabilization concentrations of specifically-interacting anions (from 10^–7 to 10^–4 molar) can be compared with the general effects of non-specific electrolyte coagulants (10^–3 to 10^–1 molar). The laboratory results are interpreted with the help of a Surface Complex Formation/Diffuse Layer Model (SCF/DLM) which describes variations of interfacial charge and potential resulting from variations of coagulating species in solution. Comparison of these laboratory experiments with observations on iron behavior in estuarine and lake waters aids in understanding iron removal mechanisms and coagulation time scales in natural systems.  相似文献   

An experimental study of anorthosite dissolution in lunar picritic magmas: Implications for crustal assimilation processes     

Zachary Morgan  Yan Liang  Paul Hess 《Geochimica et cosmochimica acta》2006,70(13):3477-3491

Experiments characterizing the kinetics of anorthosite dissolution in lunar picritic magmas (very low-Ti, low-Ti, and high-Ti picritic glasses) were conducted at 0.6 GPa and 1250-1400 °C using the dissolution couple method. Reaction between the anorthosite and lunar picritic magmas at 1250-1300 °C produced a spinel + melt layer. Reaction between the anorthosite and an olivine-saturated low-Ti magma at 1250-1300 °C produced a crystal-free region between the spinel + melt layer and the olivine-saturated magma. The anorthosite dissolution experiments conducted at 1400 °C simply dissolved anorthosite and did not result in a crystal-bearing region. The rate of anorthosite dissolution strongly depends on temperature and composition of the reacting melt. Concentration profiles that develop during anorthosite dissolution are nonlinear and extend from the picritic glass compositions to anorthite. These profiles feature a large and continuous variation in melt density and viscosity from the anorthosite-melt interface to the initial picritic magmas. In both the low-Ti and high-Ti magmas the diffusive fluxes of TiO₂, Al₂O₃, and SiO₂ are strongly coupled to the concentration gradients of CaO and FeO. Anorthosite dissolution may play an important role in producing the chemical variability of the lunar picritic magmas, the origin of spinel in the lunar basalts and picritic glasses, and the petrogenesis of the high-Al basalts.  相似文献   

下庄铀矿田337矿床成矿流体稀土元素示踪     

张国玉  王正其  梁良 《华东地质学院学报》2006,29(1):27-31

337铀矿床位于下庄矿田东缘,区内发育近EW向、NNE向构造裂隙群及NW向辉绿岩和正长岩脉体,发育以碱性为主的多种围岩蚀变。区内矿床主要赋矿围岩的稀土元素特征属壳源型。矿石内金属矿物以沥青铀矿为主,矿石的LREE/HREE比值为3.25,Sm/Nd比值平均为0.307,Ce/Yb比值为7.127,这些数据都显示出成矿流体具有较深来源。矿石较围岩亏损稀土元素尤其是轻稀土元素,稀土元素分布模式平缓,与幔源辉绿岩特别是与正长岩的稀土元素分布模式相近,负铕异常比围岩更为强烈,反映成矿流体的来源具有幔源性。结合区域地质特征,可以认为337矿床成矿流体来源具有幔源性质。  相似文献   

Zircon LA-ICP-MS U-Pb age, Ce^4＋/Ce^3＋ ratios and the geochemical features of the Machangqing complex associated with copper deposit     

梁华英  喻亨祥  莫测辉  张玉泉  谢应雯 《中国地球化学学报》2006,25(3):223-229

1IntroductionQuite a number of porphyry copper deposits havebeen found in the Cenozoic alkali-intrusions along theJinshajiang-Ailaoshan-Red River fault zone,whichconstitute the Cenozoic ore belt in China.The Cenozo-ic alkali-intrusive rocks are similar in…  相似文献   

鄱阳盆地构造—沉积特征及其演化史   总被引：3，自引：3，他引：3       下载免费PDF全文

梁兴  叶舟  吴根耀  郑华平  徐克定  张廷山  刘家铎 《地质科学》2006,41(3):404

 鄱阳盆地是发育在江南—九岭和怀玉—官帽基底拆离造山带上的白垩-古近纪张扭性断陷盆地,明显受近南北走向的赣江走滑断裂系和前白垩系逆冲断裂系晚期反转的双重因素控制,呈“两坳夹一隆”的区域构造格局。受赣江、进贤—石门街走滑断裂夹持的南昌凹陷,呈近南北向凹凸相间展布格局。进贤—石门街走滑断裂以东地区,“南断北超”型断陷自南而北由北东走向渐转为北北东向展布,其源于晚印支-燕山期北东向逆冲断裂在晚期的反转作用,西缘和北部受赣江断裂系东枝走滑断裂影响明显而发生转向。鄱阳盆地经历了早白垩世晚期(冷水坞组沉积期)拉分盆地、晚白垩世早-中期(周家店组—南雄组沉积早期)走滑张扭断(坳)陷盆地、晚白垩世晚期(南雄组沉积中-晚期)走滑伸展盆地和古近纪坳陷盆地等演化阶段,东南部断陷区(江埠—二甲村凹陷)由于喜马拉雅期的隆升剥蚀而只残存周家店组早期坳陷和周家店组中期—南雄组中期断陷两个发育阶段的沉积。  相似文献   

用BP神经网络预测土抗剪强度指标c、ψ   总被引：1，自引：0，他引：1  

张高峰  梁宾桥  谌会芹 《岩土工程技术》2006,20(1)

提出了应用BP神经网络来预测土抗剪强度指标c、ψ.结合工程实例,详细介绍了该方法的建模过程,结果表明预测结果和实测结果很接近,神经网络在土性参数方面应用前景很广阔.  相似文献   

电子地图中多尺度地图数据显示的研究   总被引：10，自引：2，他引：10  

吕华新  李霖  翟亮 《测绘信息与工程》2005,30(6):22-24

将计算机三维模型简化中的LOD思想引入到电子地图的组织和显示中,提出了同一比例尺数字地图不同详细程度的分层显示方法和不同比例尺数字地图嵌套显示方法,实现了电子地图的多级缩放。  相似文献   

非等截面桩超声波成孔质量检测     

韩亮 《物探与化探》2005,29(2):185-188

分析了非等截面超声波成孔质量检测的几个主要影响因素,给出了相应得改进措施。用工程实例说明超声波反射技术是一种保证非等截面桩成孔质量和成桩质量必不可少的检测方法。  相似文献   

激光剥蚀等离子体质谱分析中激光剥蚀参数对信号响应的影响   总被引：5，自引：1，他引：5  

徐鸿志靳兰兰  李爱荣帅琴 胡圣虹 《岩矿测试》2005,24(3):171-175

探讨了激光剥蚀等离子体质谱固体微区分析中激光剥蚀参数对元素分析信号灵敏度及稳定性的影响。这些参数包括激光功率、脉冲频率、剥蚀孔经、散焦距离、剥蚀方式等。讨论了优化的激光剥蚀等离子体质谱信号采集及数据处理方式。在全质量范围内选用具有代表性的元素作为研究对象,建立了激光剥蚀的一般性特征规律和266nm紫外激光系统的最佳操作条件。在选定的激光剥蚀参数下,大多数被测元素的检出限为22.8~457ng/g,能够满足固体微区分析的要求。  相似文献   

拉萨北部林周盆地林子宗火山岩层序新议   总被引：21，自引：4，他引：21  

董国臣  莫宣学  赵志丹  王亮  周肃 《地质通报》2005,24(6):549-557

林子宗火山岩是西藏冈底斯地区典型的新生代火山岩，可分为3个组：典中组、年波组和帕那组，主要由玄武安山岩、安山岩、英安岩、粗安岩、钾玄岩、流纹岩和相应的火山碎屑岩夹灰岩、河湖相沉积岩组成。经过林周盆地火山地质填图，发现林子宗火山岩层序较原定层序复杂得多，其中在典中组原定的安山质一英安质火山岩的底部新发现了一套流纹质火山岩，顶部发现河湖相沉积；年波组在原定上部安山质火山岩中新厘定出钾玄质火山岩，在顶部发现了红色泥岩；帕那组的底部还发现了球粒流纹岩和枕状流纹质熔结凝灰岩。据此重新论述了西藏林周盆地林子宗火山岩的地层层序及区域变化特征，进一步划分出8个段，属3个火山喷发旋回的产物。林子宗火山岩的形成时代，典中组为61．45～64．43Ma，年波组54．07Ma，帕那组43．93～48．72Ma。  相似文献