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11.
This paper provides an overview of regional geochemical mapping using stream sediments from central and south-western Nigeria. A total of 1569 stream sediment samples were collected and 54 major and trace elements determined by ICP-MS and Au, Pd and Pt by fire assay. Multivariate statistical techniques (e.g., correlation analysis and principal factor analysis) were used to explore the data, following appropriate data transformation, to understand the data structure, investigate underlying processes controlling spatial geochemical variability and identify element associations. Major geochemical variations are controlled by source geology and provenance, as well as chemical weathering and winnowing processes, more subtle variations are a result of land use and contamination from anthropogenic activity.  相似文献   
12.
The hygroscopic growth of individual aerosol particles has been measured with a Tandem Differential Mobility Analyser. The hygroscopic growth spectra were analysed in terms of diameter change with increasing RH from 20% to 85%. The measurements were carried out during the GCE cloud experiment at Kleiner Feldberg, Taunus, Germany in October and November 1990.Two groups of particles with different hygroscopic growth were observed. The less-hygroscopic group had average growth factors of 1.11, 1.04 and 1.02 for particle diameters of 50, 150 and 300 nm, respectively. The more-hygroscopic group had average growth factors of 1.34, 1.34, and 1.37 for the same particle diameters. The average fraction of less-hygroscopic particles was about 50%. Estimates of the soluble fractions of the particles belonging to the two groups are reported.Hygroscopic growth spectra for total aerosol, interstitial aerosol and cloud drop residuals were measured. A comparison of these hygroscopic growths of individual aerosol particles provides clear evidence for the importance of hygroscopic growth in nucleation scavenging. The measured scavenged fraction of particles as a function of diameter can be explained by the hygroscopic growth spectra.  相似文献   
13.
The paper involves detailed geochemical and mineralogical analysis of lacustrine sediments from a 95 cm core profile collected in the closed lake basin of the Laguna de Gallocanta, central Iberian Chain. The environmental and depositional changes are confirmed by: (1) variations in concentrations of SiO2, CaO and P2O5, (2) Fe2O3:MnO-ratios, (3) (CaO,MgO):SiO2-ratio, (4) statistical relationship of silica and phosphate content to metallic oxide content, (5) the Mg:Ca-ratio of protodolomites in relation to the position of the diffraction angle of dolomite's major diffraction peak (dol100, and (6) changes in mineralogical composition.Three sedimentary units were identifyed and characterized by their mineralogical and geochemical composition. The deposition of the underlying strata (section 1) occurred under sub-arid conditions. The environment changed to sub-humid conditions during deposition of the sediments in section 2 (post Middle Ages). Increasing aridity influenced the accumulation of the upper sediments (section 3).It is also proven that mineralogical analyses of lacustrine sediments allows mostly conclusions on the limnic environments during deposition. In contrast to this, geochemical features of lacustrine sediments indicate weathering and soil forming processes during deposition and the overall geomorphological system.  相似文献   
14.
DNA adducts in cod embryos and larvae were analysed by 32P-postlabeling to test the hypothesis that anthropogenic substances, which could form reactive intermediates, are involved in the reproductive failure of cod (Gadus morhua) from the Baltic Sea. A comparison with cod from the Barents Sea was performed. The mean value of DNA adducts in cod embryos/larvae from the Baltic Sea was 2.3 nmol of adducts/mol nucleotides, compared to 0.12 nmol of adducts/mol nucleotides in the embryos/larvae from the Barents Sea.  相似文献   
15.
A battery of biochemical biomarkers and the SigmaPCB concentration in adult female perch (Perca fluviatilis) verified an aquatic pollution gradient with the city of Stockholm (Sweden) as a point source of anthropogenic substances. The investigation included both an upstream gradient, 46 km westwards through Lake M?laren, and a downstream gradient, 84 km eastwards through the Stockholm archipelago. Besides the main gradient from Stockholm, there were strong indications of pollution coming from the Baltic Sea. The results indicated a severe pollution situation in central Stockholm, with poor health status of the perch, characterised by increased specific EROD activity in the liver, increased liver EROD somatic index, decreased AChE activity in the muscle, increased amount of DNA adducts in the liver, and a high concentration of biliary 1-pyrenol. In addition, laboratory exposure to common EROD inducers elicited an abnormal response, suggestive of chronic intoxication.  相似文献   
16.
Catchment storage capacity is an important factor in the determination of catchment sensitivity to climate variability. Quantification of catchment sensitivity is in turn important in the regional assessment of the effects of possible climate change. In the present paper, an empirical regional model is proposed that quantifies catchment sensitivity as the ratio of present maximum reservoir storage to catchment storage capacity. Catchment storage capacity is defined theoretically using readily available catchment variables. Present maximum reservoir storage in a catchment, as determined from recession analysis, is expressed as a fraction of catchment storage capacity; the fraction defines catchment sensitivity and depends on storage capacity and annual net precipitation. Average annual conditions for present maximum reservoir storage and average annual net precipitation are used to test the developed model. Although the study used data from only 15 catchments in the Upper Loire region in France, the model proved statistically valid. Storage capacity calculated with the model compares favourably with the baseflow index and a storage index defined in previous research. Values of storage capacity are probable with respect to reported water resources in the area. With the model catchment sensitivity can easily be assessed. Flood or drought prone catchments can be identified as well as a catchment's sensitivity to a catchment-type transition (baseflow versus direct flow dominated catchments). © 1998 John Wiley & Sons, Ltd.  相似文献   
17.
A high-resolution videomagnetograph that records the images of opposite circular polarization simultaneously has been constructed for the Swedish vacuum solar telescope at La Palma. Magnetograms are obtained by off-line integration of bursts consisting of typically 50 frames of 20 ms exposures, with bad frames rejected, and the frame-to-frame image motion of the remaining frames compensated for by cross-correlation techniques. The short exposures combined with frame selection and elimination of image motion optimizes the resolution and thereby also the S/N, allowing good magnetograms to be obtained with an effective exposure time of less than 1 s at an image scale of 0.1 pixel–1. The advantages and limitations of the system are discussed and compared with other techniques of making filter magnetograms are discussed.  相似文献   
18.
The study illustrates the critical role of accurate geological structural mapping to delineate crystalline aquifer zones more prone to high health risk due to elevated dissolved As in drinking wells.The analysis revisits the results from more than 1200 groundwater samples collected over ten years from domestic wells across the Tampere region(Finland).It is demonstrated that the highest dissolved As concentrations in the region(up to 2230 μg/L)are exclusively found near major faults and deformation zones(FDZs)detected via geophysical and geological surveys,and that a clear correlation exists between dissolved concentrations and the distance from the FDZs(r).Almost all values exceeding the drinking water limit(10 μg/L)occur at r8 km,while concentrations above 100 μg/L occur at r4 km.Solidphase As concentrations in bedrock show less dependency on FDZ than aqueous concentrations.This behavior is explained considering different mechanisms,which include enhanced sulfide oxidation and fracture connectivity,promoting preferential transport of dissolved As to FDZs and mixing of waters from different redox zones,mobilizing preferentially As(Ⅲ)or As(V).Fe hydro-oxides may also precipitate/dissolve preferentially because of FDZs,while residence time may influence the contact time between water and As-bearing minerals.It is concluded that the accurate mapping of FDZs,and in general of structural geology,provides an important preliminary information to identify where localized,sitespecific characterization of hydrogeology and geochemistry is more urgent to reduce As-related health risk from groundwater intake.  相似文献   
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