Solute distribution in porous rhyolite as evaluated by sequential centrifugation     

Tadashi Yokoyama  Satoru NakashimaTakashi Murakami  Lionel MercuryYusuke Kirino 《Applied Geochemistry》2011,26(8):1524-1534

Pore water in a porous rhyolite, having a porosity of 27% and pore radii ranging from >25 μm to 0.008 μm, was centrifugally extracted stepwise with increasing centrifugal speed to examine the potential variations of the compositions of pore water and their relationships to reaction and transport occurring in the rock. The rock was soaked for from 1 h to 7 days in an aqueous solution prior to centrifugation. To evaluate the effect of adsorption under minimum effect of dissolution, Li⁺ and Br⁻ were added to the solution as tracer ions. As centrifugal speed increased, water was extracted in order of large to small pores and the thickness of residual water film became thinner. The concentrations of ions dissolving from the rock (Na⁺, K⁺, Ca²⁺, etc.) after 7 days of immersion were relatively constant in pores of 1-10 μm radii and exponentially increased by 3-100 fold with decreasing pore radius to 0.1 μm. These ions are dissolved from the rock and transported toward the exterior of the rock by diffusion. The calculation using a reactive-transport equation showed that the observed concentration changes reflect the change in solute distribution profile with pore size. The concentration of Si after 7 days of immersion was approximately constant or slightly decreased with increasing centrifugal speed, which appears to be controlled by the solubility. The concentration of Li⁺ decreased with increasing centrifugal speed after 1 h of immersion but the trend changed after 7 days of reaction. Initial behavior of Li⁺ is explained by adsorption on pore walls, and the change of trend is explained by desorption of that previously adsorbed, slight amounts of dissolution, and inflow from the outside of the rock. The change in concentration of Br⁻ with increasing centrifugal speed was small, probably because Br⁻ was not adsorbed on the surfaces. The sequential centrifugation thus provides information on the solute distribution associated with reaction and transport occurring in rock pores.  相似文献   

Lower Palaeozoic unconformities in an intracratonic platform setting: glacial erosion versus tectonics in the eastern Murzuq Basin (southern Libya)     

Jean-François Ghienne  Julien Moreau  Lionel Degermann  Jean-Loup Rubino 《International Journal of Earth Sciences》2013,102(2):455-482

The stratigraphic record of the eastern Murzuq Basin has been importantly influenced by deformation resulting in angular and/or deeply erosional unconformities, though the overall context is intracratonic. Major transgressive events and the Ordovician glaciation are nevertheless documented, allowing the delineation of tectonic-, eustasy- or climate-driven unconformities. Lower Palaeozoic key events and related unconformities that characterize the North Gondwana platform have therefore a signature in the eastern Murzuq Basin. The basement/cover unconformity, also known as the infra-Tassilian surface, truncates all the deformed and metamorphosed Lower Cambrian and older rocks. Above is a ?Middle Cambrian to Lower Ordovician megasequence (Murizidié and Hasawnah Fms.), which is in turn truncated by an intra-Ordovician, angular unconformity. This megasequence is unconformably overlain by a Middle Ordovician (Hawaz Fm.) to Silurian (Tanzzuft and Akakus Fms) megasequence, which includes the Upper Ordovician glaciogenic unit (Mamuniyat Fm.), bounded at the base by a polygenic glacial erosion surface showing corrugated glacial lineations, tillites, and glaciotectonic structures. The Middle Ordovician to Silurian megasequence is finally truncated by a base-Devonian, angular unconformity overlain by fluvial sandstones. Regarding the possibility that those fluvial deposits may be as younger as Late Devonian in the eastern Murzuq Basin based on palaeoflora, the so-called Caledonian unconformity might be here a much younger (mid-Eifelian?) surface, and the occurrence of the Lower Devonian “Tadrart Fm.” is questioned. The Upper Ordovician glacial erosion surface, which is sometimes referred to as the Taconic unconformity, usually truncates Middle Ordovician strata in the Murzuq Basin but reaches significantly deeper stratigraphic levels in places that have been previously involved in the intra-Ordovician deformation event. In the Murizidié (southeastern Murzuq Basin), the infra-Tassilian surface, the intra-Ordovician unconformity, and the Upper Ordovician glacial erosion surface amalgamate together. Here, an estimate of the glacial erosion depth cannot be derived from the stratigraphic hiatus beneath the glacial incision, the main part of which relate to the intra-Ordovician tectonic event. The Upper Ordovician climate-related glacial erosion surface is not a valid unconformity for a sequence hierarchy framework of the Lower Palaeozoic, although it presents most of the physical attributes of tectonic-driven unconformities.  相似文献   

Comment on “Parent body depth‐pressure‐temperature relationships and the style of the ureilite anatexis” by P. H. Warren (MAPS 47:209–227)     

Cyrena Anne Goodrich  Lionel Wilson  James A. Van Orman  Patrick Michel 《Meteoritics & planetary science》2013,48(6):1096-1106

Ureilites are carbon‐rich ultramafic (olivine + dominantly low‐Ca pyroxene) achondrites with poorly understood petrogenesis. One major problem concerns the origin of extensive variation in FeO content (olivine core Fo values ranging from approximately 75 to 95) among the individual ureilites. The two main competing hypotheses to explain this variation are: (1) equilibrium smelting, in which ureilite Fo values were established by pressure‐dependent (depth‐linked) carbon redox reactions on the ureilite parent body during partial melting; or (2) nebular inheritance, in which the variation in FeO contents was derived from ureilite precursors and was preserved during partial melting. The paper “Parent body depth‐pressure‐temperature relationships and the style of the ureilite anatexis” by Warren (2012) discusses a series of topics related to ureilite petrogenesis. In each case, an argument is presented within the context of smelting versus nonsmelting models. Collectively, these arguments create the impression that there are many valid arguments against smelting. The purpose of this comment is to point out flaws in some of these arguments, and/or to show that the issues they address are independent of smelting versus nonsmelting models. Both equilibrium smelting and nebular inheritance (simple anatexis) models face challenges in explaining all the properties of ureilites, but both remain viable.  相似文献   

EnVision: taking the pulse of our twin planet     

Richard C. Ghail  Colin Wilson  Marina Galand  David Hall  Chris Cochrane  Philippa Mason  Joern Helbert  Franck MontMessin  Sanjay Limaye  Manish Patel  Neil Bowles  Daphne Stam  Jan-Erik Wahlund  Fabio Rocca  David Waltham  Tamsin A. Mather  Juliet Biggs  Matthew Genge  Philippe Paillou  Karl Mitchell  Lionel Wilson  Upendra N. Singh 《Experimental Astronomy》2012,33(2-3):337-363

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The effect of submerged plateaux on Pleistocene gyral circulation and sea-surface temperatures in the Southwest Pacific     

Bruce W. Hayward  George H. Scott  Martin P. Crundwell  James P. Kennett  Lionel Carter  Helen L. Neil  Ashwaq T. Sabaa  Kate Wilson  J. Stuart Rodger  Grace Schaefer  Hugh R. Grenfell  Qianyu Li 《Global and Planetary Change》2008,63(4):309-316

Uniquely in the Southern Hemisphere the New Zealand micro-continent spans the interface between a subtropical gyre and the Subantarctic Circumpolar Current. Its 20° latitudinal extent includes a complex of submerged plateaux, ridges, saddles and basins which, in the present interglacial, are partial barriers to circulation and steer the Subtropical (STF) and Subantarctic (SAF) fronts. This configuration offers a singular opportunity to assess the influence of bottom topography on oceanic circulation through Pleistocene glacial – interglacial (G/I) cycles, its effect on the location and strength of the fronts, and its ability to generate significant differences in mixed layer thermal history over short distances.For this study we use new planktic foraminiferal based sea-surface temperature (SST) estimates spanning the past 1 million years from a latitudinal transect of four deep ocean drilling sites. We conclude that: 1. the effect of the New Zealand landmass was to deflect the water masses south around the bathymetric impediments; 2. the effect of a shallow submerged ridge on the down-current side (Chatham Rise), was to dynamically trap the STF along its crest, in stark contrast to the usual glacial–interglacial (G–I) meridional migration that occurs in the open ocean; 3. the effect of more deeply submerged, downstream plateaux (Campbell, Bounty) was to dynamically trap the SAF along its steep southeastern margin; 4. the effects of saddles across the submarine plateaux was to facilitate the development of jets of subtropical and subantarctic surface water through the fronts, forming localized downstream gyres or eddies during different phases in the G–I climate cycles; 5. the deep Pukaki Saddle across the Campbell-Bounty Plateaux guided a branch of the SAF to flow northwards during each glacial, to form a strong gyre of circumpolar surface water in the Bounty Trough, especially during the mid-Pleistocene Climate Transition (MIS 22-16) when exceptionally high SST gradients existed across the STF; 6. the shallower Mernoo Saddle, at the western end of the Chatham Rise, provided a conduit for subtropical water to jet southwards across the STF in the warmest interglacial peaks (MIS 11, 5.5) and for subantarctic water to flow northwards during glacials; 7. although subtropical or subantarctic drivers can prevail at a particular phase of a G–I cycles, it appears that the Antarctic Circumpolar Current is the main influence on the regional hydrography.Thus complex submarine topography can affect distinct differences in the climate records over short distances with implications for using such records in interpreting global or regional trends. Conversely, the local topography can amplify the paleoclimate record in different ways in different places, thus enhancing its value for the study of more minor paleoceanographic influences that elsewhere are more difficult to detect. Such sites include DSDP 594, which like some other Southern Ocean sites, has the typical late Pleistocene asymmetrical saw-tooth G–I climate pattern transformed to a gap-tooth pattern of quasi-symmetrical interglacial spikes that interrupt extended periods of minimum glacial temperatures.  相似文献   

Resource partitioning among cladocerans in a littoral macrophyte zone: implications for the transfer of essential compounds     

Hélène Masclaux  Gilles Bourdier  Pascal Riera  Martin J. Kainz  Lionel Jouve  Emilie Duffaud  Alexandre Bec 《Aquatic Sciences - Research Across Boundaries》2014,76(1):73-81

The maintenance of species diversity in a given environment is strongly linked to resource partitioning. Littoral macrophyte zones are heterogeneous environments with high microcrustacean diversity, where zooplankton have dietary access to seston as well as organisms growing on macrophytic surfaces (epiphyton). We conducted a field study in a macrophyte-rich backwater of the river Allier to examine how seston and epiphyton were used as potential food sources by four dominant cladoceran species. Fatty acids were analyzed in these two food sources to assess how their differential uptake affects the trophic trajectory of essential compounds from these resources to cladocerans. Our results showed resource partitioning among the four cladocerans studied; while Eurycercus fed mostly on epiphyton, Daphnia mostly consumed phytoplankton, and Ceriodaphnia and Simocephalus were able to forage on sestonic and epiphytic resources. Based on their polyunsaturated fatty acid (PUFA) content, it was evident that epiphyton was of higher food quality than seston in this macrophyte-rich backwater system. Variability of PUFA compositions of seston and epiphyton, and diversity of foraging strategies of cladoceran species, which represent the major link between microorganisms and consumers at higher trophic levels, affect dietary energy pathways and point to a variable PUFA transfer efficiency in backwater food webs.  相似文献   

Influence of a Two-scale Surface Roughness on a Neutral Turbulent Boundary Layer     

Pietro Salizzoni  Lionel Soulhac  Patrick Mejean  Richard J. Perkins 《Boundary-Layer Meteorology》2008,127(1):97-110

Flow in the urban boundary layer is strongly influenced by the surface roughness, which is composed principally of isolated buildings or groups of buildings. Previous research has shown that the flow regime depends on the characteristic height of these obstacles (H), and the spacing between them (W). In reality, the urban boundary layer contains roughness elements with a wide range of length scales; in many practical situations these can be classified into large-scale roughness—buildings, or groups of buildings—and small-scale roughness, such as street furniture and elements on the façades and roofs. It is important to understand how the small-scale roughness might modify mass and momentum transfer in the urban boundary layer, but relatively little information is available concerning the potential interaction between large- and small-scale roughness elements in the different flow regimes. This problem has been studied using wind-tunnel experiments, by measuring vertical velocity profiles over a two-dimensional obstacle array, adding small-scale roughness elements to the top of larger parallel square bars. The experiments were performed for different cavity aspect ratios: the results show that the small-scale roughness increases the turbulence intensities and the momentum transfer when the large-scale obstacles are closely packed (H/W > 1) but it has very little effect for more widely-spaced obstacles (H/W < 1).  相似文献   

Flow in a Street Canyon for any External Wind Direction     

Lionel Soulhac  Richard J. Perkins  Pietro Salizzoni 《Boundary-Layer Meteorology》2008,126(3):365-388

An analytical model has been developed for the flow along a street canyon (of height H and width W), generated by an external wind blowing at any angle relative to the axis of the street. Initially, we consider the special case of a wind blowing parallel to the street. The interior of the street is decomposed into three regions, and the flow within each region is assumed to depend only on the external wind and the distance to the closest solid boundary. This decomposition leads to two different flow regimes: one for narrow streets (H/W > 1/2) and one for wide streets (H/W < 1/2). The theoretical model agrees well with results obtained from numerical simulations using a Reynolds-Averaged Navier–Stokes model. We then generalize the model to the case of arbitrary wind direction. Numerical solutions show that the streamlines of the mean flow in the street have a spiral form, and for most angles of incidence, the mass flux along the street scales on the component of the external wind resolved parallel to the street. We use this result to generalize the model derived for wind blowing parallel to the street, and the results from this model agree well with the numerical simulations. The model that has been developed can be evaluated rapidly using only very modest computing power, so it is suitable for use as an operational tool.  相似文献   

Late Cretaceous (Cenomanian-Turonian) ammonites from southern Morocco and south western Algeria     

Christian Meister  André Piuz  Lionel Cavin  Larbi Boudad  Flavio Bacchia  El M. Ettachfini  M. Benyoucef 《Arabian Journal of Geosciences》2017,10(1):1

On the basis of nine lithostratigraphical profiles, 23 cephalopods taxa (nautilus and ammonites) are described from the Preafrican Trough and the Kem Kem region. Among them, a new species is proposed: Spathites (Jeanrogericeras) asflaensis nov. sp. This fauna is placed in its biostratigraphical framework and correlated with the standard zonation of the late Cenomanian–early Turonian. Moreover, stratigraphic correlations are proposed for the whole Maghreb from the Tarfaya Basin in the west to central Tunisia in the east. Selected taxa reveal the paleogeographical context of the western Tethys; a complex distribution of emerged areas and epicontinental seas impacted by an important marine trangression that constantly modified the costaline.  相似文献   

Thermodynamic properties of solutions in metastable systems under negative or positive pressures   总被引：1，自引：0，他引：1  

Lionel Mercury  Mohamed Azaroual  Yves Tardy 《Geochimica et cosmochimica acta》2003,67(10):1769-1785

Metastable systems are created when the interface between the atmosphere (in which P_atm = 1 bar) and water forms a spherical meniscus either concave toward the air (water filling capillaries, wherein P_water < P_atm) or convex toward the air (fog water droplet, wherein P_water > P_atm). Soil water, undergoing negative pressure (“capillary potential”) remains bound to the solid matrix (instead of flowing downward) by the capillary meniscus, concave toward the undersaturated dry atmosphere. The positive counterpart of tensile water in soils is the pressurized water contained in fine droplets suspended in oversaturated humid air, as in clouds. All these systems are anisobaric domains the phases of which have different pressures. Geochemical consequences of such characteristics are assessed here by calculating the consequences of the positive or negative water potential on the equilibrium constants of reactions taking place in stretched or pressurized aqueous solutions. Thermodynamic properties of aqueous species are obtained by using the TH model, used explicitly for positive pressures but extrapolated to negative ones for soil solutions. It appears that soil water dissolves gases, offering an alternative explanation of the observed enrichment of atmospheric noble gases in groundwater and of carbonic gas in the unsaturated zone below the root zone. Water droplets obviously show the opposite behavior, that is, a decreasing dissolutive capability with decreasing droplet size (water pressure increases), inducing some climatic consequences. An application of this approach to the solid-solution equilibria is performed by comparing experimental solubility of amorphous silica in unsaturated media on the one hand, to theoretical calculations taking account of the negative water pressure on the other hand. This comparison outlines the potential complexity of anisobaric situations in nature and the necessity to develop a suitable approach for solid pressure.  相似文献